CN106366741B - A kind of film anti-static liquid and its antistatic film preparation method - Google Patents

A kind of film anti-static liquid and its antistatic film preparation method Download PDF

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CN106366741B
CN106366741B CN201610743829.XA CN201610743829A CN106366741B CN 106366741 B CN106366741 B CN 106366741B CN 201610743829 A CN201610743829 A CN 201610743829A CN 106366741 B CN106366741 B CN 106366741B
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film
static liquid
liquid
static
antistatic
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CN106366741A (en
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杨怡君
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18Homopolymers or copolymers of tetrafluoroethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof

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  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses a kind of film anti-static liquid, the film anti-static liquid is grouped as by the group of following weight percent: ethyl alcohol 60~80%, conduction liquid 1.6~10%, white spirit 2.8~14%, essence 0.1~0.2%, water 7~30%;The invention also discloses a kind of antistatic film preparation methods, comprising steps of ethyl alcohol, conduction liquid, white spirit, essence, water are uniformly mixed by a. by ratio;B., anti-static liquid is coated uniformly on to the surface of eptfe membrane;C. anti-static liquid is equably absorbed by eptfe membrane;D. absorbing has the polytetrafluoroethylene film of anti-static liquid to pass through drying and processing;E. dried polytetrafluoroethylene film is wrapped.The electrostatic quantity that drag chain generates at work can be effectively reduced for wrapping up drag chain in the antistatic film made using the above-mentioned formula and production method, while also effectively achieving dust-proof effect.

Description

A kind of film anti-static liquid and its antistatic film preparation method
[technical field]
The present invention relates to a kind of film anti-static liquids, in particular to film anti-static liquid and its antistatic film system Preparation Method.
[background technique]
Automatic assembly line production process can usually use manipulator, and plurality of positions, which has, in manipulator uses drag chain knot In ceaselessly operation, the drag chain of manipulator is connected for structure, drag chain, manipulator in structural establishment and the drag chain connecting with manipulator Wire and cable also follow drag chain ceaselessly move back and forth, wire and cable prolonged operation movement will lead to wire and cable Rubber ruptures it could even be possible to making its fracture.Since drag chain, manipulator and the drag chain connecting with manipulator are being made for a long time Also a large amount of dust, electrostatic can be generated in industry, and for precise electronic, dust and electrostatic are the jinxs of electronic product, for that can keep away Exempt from a large amount of dusts and electrostatic that drag chain, manipulator and the wire and cable being connect on drag chain with manipulator are generated in operation process. Would generally use at present film by drag chain, manipulator and connect with manipulator drag chain wire and cable wrap up it is quiet to reduce Electricity and dust, in order to protect the wire and cable on drag chain, traditional way is to wrap up a protective layer in the external of wire and cable, Use plastic film usually to encase the wire and cable on drag chain to be protected.However plastic film is usually PU material system Make, the generation of electrostatic cannot be prevented well, the wire and cable on drag chain is wrapped up by plastic film and is still also had largely Electrostatic generates.If the surface electrostatic of film is very big in use using without the film Jing Guo antistatic process, The big film surface of static content will assemble very more dusts, electrostatic and dust for requiring the product of production environment harshness will Directly affect the quality of product or there are product quality hidden danger, in addition, electrostatic be also for the damage of electronic product greatly it is especially big, Directly electronic component can be burnt or be punctured.Film without antistatic process is not to be able to satisfy production environment harshness The production requirement of automatic assembly line.
For presently, there are the technical issues of, be badly in need of developing the protective film of the high wire and cable of a antistatic performance To substitute conventional films.
[summary of the invention]
The technical problem to be solved by the present invention is to provide a kind of film anti-static liquid, which can effectively be dropped on film The electrostatic quantity that drag chain in low mechanical equipment is generated in operation process, thus effectively improve mechanical equipment service life and Produce the yield of product.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is that: a kind of film anti-static liquid, feature exist In the film anti-static liquid is grouped as by the group of following weight percent:
Ethyl alcohol 60~80%,
Conduction liquid 1.6~10%,
White spirit 2.8~14%,
Essence 0.1~0.2%,
Water 7~30%.
Preferably, the weight percentage of the film anti-static liquid are as follows:
Ethyl alcohol 65~75%,
Conduction liquid 2.5~7%,
White spirit 5.8~8.3%,
Essence 0.15~0.2%,
Water 12~25%.
Compared with the prior art, the invention has the advantages that: it is obtained by experimental test for several times, ethyl alcohol poly- to varicosity four Fluoride film has infiltration function, and not will cause damage to eptfe membrane, and it is poly- that ethanol molecule can penetrate into varicosity In the molecular structure of tetrafluoroethylene, using this characteristic, conduction liquid molecule is brought into the molecular structure of film, film is made Achieve the effect that conduction, and conduction liquid molecule can be promoted interior in conduction for a long time in the molecular structure of film, electrostatic will not The surface of film is rested on, meanwhile, white spirit, which is added, in conduction liquid has cleaning function, it can be with the dirty of cleaning film surface Dirt, the film made using the electrostatic liquid, the drag chain which can be effectively reduced in mechanical equipment are produced in operation process Raw electrostatic quantity, to effectively improve the service life of mechanical equipment and produce the yield of product.
Another technical problem that the present invention solves is to provide a kind of antistatic film preparation method, is produced using this method The antistatic film come is used to wrap up the drag chain of mechanical equipment, and the drag chain which can be effectively reduced in mechanical equipment exists The electrostatic quantity that operation process generates, while also having the function of dust-proof.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is that:
A kind of antistatic film preparation method, which comprises the steps of:
A. ethyl alcohol, conduction liquid, white spirit, essence, water percentage composition ratio by weight are placed in container, in room temperature It is uniformly mixed under state, then uniformly mixed anti-static liquid is stood into a period of time;
B. the step a anti-static liquid mixed is poured into coating machine, starts coating machine, anti-static liquid is coated uniformly on swollen The surface of body polytetrafluoroethylene film;
C. the coated eptfe membrane of step b is stood at normal temperature, makes anti-static liquid equably by varicosity Polytetrafluoroethylene film absorbs;
D. the polytetrafluoroethylene film of anti-static liquid handles through room temperature drying or heating, drying step c absorption;
E. the dried polytetrafluoroethylene film of step d is wrapped with coiler, plastic cement core is packed into coiler, will be coated There is the polytetrafluoroethylene film finished product of anti-static liquid to be involved on plastic cement core, it is smooth to spool.
Preferentially, the temperature of the step a normal temperature state is 18~25 DEG C, and mixing time is 5~15 minutes, the standing Time is 15~35 minutes.
Preferentially, the temperature of the step c normal temperature state is 18~25 DEG C, the e-PTFE second after absorbing anti-static liquid The sheet resistance value of alkene film is 104~108Ohm.
Preferentially, the heating temperature of the step d is 45~80 DEG C, and the heating, drying time is 5~10 minutes.
Compared with the prior art, the invention has the advantages that: the antistatic film made using this method is for wrapping The drag chain of mechanical equipment is wrapped up in, which can be effectively reduced the electrostatic number that the drag chain in mechanical equipment is generated in operation process Amount, while also having the function of dust-proof.
[Detailed description of the invention]
Detailed description of the invention is to be used to provide further understanding of the present invention herein, is to constitute part of this application, but simultaneously It does not constitute an undue limitation on the present invention, in the accompanying drawings:
Fig. 1 is the process flow chart of present invention production antistatic film.
Description of symbols: 1- mixed processes;2- coats process;3- absorbs process;4- baking process;Process is wrapped in 5-.
[specific embodiment]
Come that the present invention will be described in detail below in conjunction with attached drawing and specific embodiment, illustrative examples of the invention with And explanation is used to explain the present invention, but not as a limitation of the invention.
Embodiment 1: the film anti-static liquid of 100ml is made, comprising: ethyl alcohol 60ml, conduction liquid 1.6ml, white spirit 8.3ml, essence 0.1ml, water 30ml.Antistatic film is prepared by following steps: mixed processes 1, by ethyl alcohol, conduction Liquid, white spirit, essence, water percentage composition ratio by weight are placed in container, are uniformly mixed in the state of room temperature, Described in essence can first use lemon extract, then anti-static liquid that will be uniformly mixed stands a period of time;Process 2 is coated, The anti-static liquid that mixed processes 1 mix pours into coating machine, starts coating machine, anti-static liquid is coated uniformly on e-PTFE The surface of vinyl film;Process 3 is absorbed, the coating coated eptfe membrane of process 2 is stood at normal temperature, makes to prevent quiet It is electro-hydraulic equably to be absorbed by eptfe membrane;Baking process 4 absorbs absorption process 3 polytetrafluoro for having anti-static liquid Vinyl film is dried through room temperature or heating, drying is handled;Process 5 is wrapped, the dried polytetrafluoroethylene film of baking process 4 is used and is beaten Plastic cement core is packed into coiler by the package of volume machine, and the polytetrafluoroethylene film finished product for being coated with anti-static liquid is involved in plastic cement core On, it is smooth to spool.The temperature of 1 normal temperature state of mixed processes is 18 DEG C, and mixing time is 5 minutes, when the standing Between be 15 minutes.The temperature for absorbing 3 normal temperature state of process is 18 DEG C, the eptfe membrane after absorbing anti-static liquid Sheet resistance value be 108Ohm.The heating temperature of the baking process 4 is 45 DEG C, and the heating, drying time is 10 minutes.Using The antistatic film that the present embodiment formula and its preparation process make is used to wrap up the drag chain of mechanical equipment, and the antistatic is thin The electrostatic quantity that the drag chain in mechanical equipment is generated in operation process can be effectively reduced in film, test by experiment, which prevents quiet Electrical property is able to satisfy the production requirement of high-precision electronic component, can greatly improve the yield of product in process of production.
Embodiment 2: the film anti-static liquid of 100ml is made, comprising: ethyl alcohol 65ml, conduction liquid 2.5ml, white spirit 14ml, Essence 0.15ml, water 18.35ml.Wherein the essence can first use lemon extract.The antistatic film of the present embodiment uses The method of above-described embodiment 1 is prepared, wherein the temperature of 1 normal temperature state of the mixed processes is 25 DEG C, mixing time 10 Minute, the time of repose is 30 minutes.The temperature for absorbing 3 normal temperature state of process is 25 DEG C, after absorbing anti-static liquid The sheet resistance value of eptfe membrane is 107Ohm.The heating temperature of the baking process 4 is 80 DEG C, heating, drying Time is 5 minutes.The antistatic film made using the present embodiment formula and its preparation process is for wrapping up mechanical equipment Drag chain, which can be effectively reduced the electrostatic quantity that the drag chain in mechanical equipment is generated in operation process, by reality Test examination, the film antistatic performance are able to satisfy the production requirement of high-precision electronic component, in process of production can be significantly Improve the yield of product.
Embodiment 3: the film anti-static liquid of 100ml is made, comprising: ethyl alcohol 70ml, conduction liquid 5ml, white spirit 7.8ml, Essence 0.2ml, water 17ml.Wherein the essence can first use lemon extract.The antistatic film of the present embodiment is using implementation The method of example 1 is prepared, wherein the temperature of 1 normal temperature state of the mixed processes is 20 DEG C, mixing time is 8 minutes, described Time of repose is 27 minutes.The temperature for absorbing 3 normal temperature state of process is 20 DEG C, the e-PTFE after absorbing anti-static liquid The sheet resistance value of vinyl film is 106Ohm.The heating temperature of the baking process 4 is 70 DEG C, and the heating, drying time is 6 points Clock.The antistatic film made using the present embodiment formula and its preparation process is used to wrap up the drag chain of mechanical equipment, should The electrostatic quantity that the drag chain in mechanical equipment is generated in operation process can be effectively reduced in antistatic film, test by experiment, should Film antistatic performance is able to satisfy the production requirement of high-precision electronic component, can greatly improve product in process of production Yield.
Embodiment 4: the film anti-static liquid of 100ml is made, comprising: ethyl alcohol 75ml, conduction liquid 7ml, white spirit 5.8ml, Essence 0.2ml, water 12ml.Wherein the essence can first use lemon extract.The antistatic film of the present embodiment is using implementation The method of example 1 is prepared, wherein the temperature of 1 normal temperature state of the mixed processes is 21 DEG C, mixing time is 12 minutes, described Time of repose is 20 minutes.The temperature for absorbing 3 normal temperature state of process is 22 DEG C, the e-PTFE after absorbing anti-static liquid The sheet resistance value of vinyl film is 104Ohm.The heating temperature of the baking process 4 is 64 DEG C, and the heating, drying time is 7 points Clock.The antistatic film made using the present embodiment formula and its preparation process is used to wrap up the drag chain of mechanical equipment, should The electrostatic quantity that the drag chain in mechanical equipment is generated in operation process can be effectively reduced in antistatic film, test by experiment, should Film antistatic performance is able to satisfy the production requirement of high-precision electronic component, can greatly improve product in process of production Yield.
Embodiment 5: the film anti-static liquid of 100ml is made, comprising: ethyl alcohol 80ml, conduction liquid 10ml, white spirit 2.8ml, Essence 0.2ml, water 7ml.Wherein the essence can first use lemon extract.The antistatic film of the present embodiment uses embodiment 1 method is prepared, wherein the temperature of 1 normal temperature state of the mixed processes is 24 DEG C, mixing time is 14 minutes, described quiet Setting the time is 35 minutes.The temperature for absorbing 3 normal temperature state of process is 23 DEG C, the e-PTFE second after absorbing anti-static liquid The sheet resistance value of alkene film is 104Ohm.The heating temperature of the baking process 4 is 55 DEG C, and the heating, drying time is 8 minutes. The antistatic film made using the present embodiment formula and its preparation process is used to wrap up the drag chain of mechanical equipment, this prevents quiet The electrostatic quantity that the drag chain in mechanical equipment is generated in operation process can be effectively reduced in conductive film, test by experiment, the film Antistatic performance is able to satisfy the production requirement of high-precision electronic component, can greatly improve the good of product in process of production Rate.
The thin selection eptfe membrane of film that the above embodiment of the present invention uses, the eptfe membrane Be grouped as by the group of following weight percent: wherein polytetrafluorethylepowder powder is 65~75%, and petroleum ether is 8~16%, coal Oil is 12~25%.Wherein, eptfe membrane is prepared by following techniques, mixed processes: first by above-mentioned polytetrafluoro The ratio of ethylene powder, petroleum ether and kerosene percentage composition by weight is poured into container and is uniformly mixed;Extrusion forming: plunger is used Formula extruder, the purpose of extrusion forming are to remove the air admixed after auxiliary agent between resin particle, make to be tightly combined between resin particle, Increase the cohesive force between resin particle, and obtain the green body more slightly smaller than extrusion die material chamber, the compacting of preform in two steps, the One step first under low pressure, is pressed into pasty material " blank ", and second step is that " blank " is put into pushing machine, further pushes away It is pressed into " pre-molding product ";Calendering procedure: calendering be by squeeze out rodlike profile be made it is membranaceous, convenient for its postorder stretch, sheet Made-up belt is rolled by front and back roller uniform velocity, and the ratio between calendering front and back film transverse area claims calendering multiple, increases calendering multiple, has Conducive to crystallinity is improved, porosity is reduced, mechanical property and electrical property especially dieletric strength are significantly improved.Calender line It is middle using hot wind drying to film heating, at a temperature of 160~200 DEG C, the height of temperature is generally different with the thickness of film, one Under fixed pressure, above-mentioned polytetrafluoroethylene (PTFE) is also known as PTFE, arranges PTFE molecule regularly along the direction of calendering, And increase the cross-linking of PTFE macromolecular, while the basic solvent naphtha removed in mixture, basis is rolled into through calender Membrane stage;Stretching process: in a heated condition, 170 DEG C or so, film is drawn along one or both of plane coordinates direction It stretches, is arranged so that macromolecular chain is stretched along draw direction, so as to improve certain performances of film;Solidify sintering process: after stretching Sample be heated to 327 DEG C of fusing point or more under certain heating rate, speed is 9 ms/min, and keeps the temperature one under certain stress Section time, polymer molecule are amorphous state by crystalline transformation, and the single resin particle of dispersion is glutinous by phase counterdiffusion melting It is continuous whole to form one, then through cooling, polymer molecule is gradually converted into crystal habit by amorphous, is shape after making to stretch At the technical process that is fixed up of reticular structure.Cooling process: cooling purpose be prevent from accelerating at a higher temperature it is compacted Become and influence film performance, cooling environment is the temperature range of 20~70 DEG C/h.
The above only illustrates the present invention to facilitate, and is not departing from the scope that the present invention creates, is being familiar with this technology Those skilled in the art done various simply in a disguised form still fall within protection scope of the present invention with modification.

Claims (6)

1. a kind of film anti-static liquid, which is characterized in that the film anti-static liquid is grouped by the group of following weight percent At:
Ethyl alcohol 60~80%,
Conduction liquid 1.6~10%,
White spirit 2.8~14%,
Essence 0.1~0.2%,
Water 7~30%.
2. film anti-static liquid according to claim 1, which is characterized in that the weight percent of the film anti-static liquid contains Amount are as follows:
Ethyl alcohol 65~75%,
Conduction liquid 2.5~7%,
White spirit 5.8~8.3%,
Essence 0.15~0.2%,
Water 12~25%.
3. a kind of antistatic film preparation method, which comprises the steps of:
A. ethyl alcohol of any of claims 1 or 2, conduction liquid, white spirit, essence, water percentage composition ratio by weight are placed on It in container, is uniformly mixed in the state of room temperature, then uniformly mixed anti-static liquid is stood into a period of time;
B. the step a anti-static liquid mixed is poured into coating machine, starts coating machine, anti-static liquid is coated uniformly on varicosity and is gathered The surface of tetrafluoroethylene;
C. the coated eptfe membrane of step b is stood at normal temperature, makes anti-static liquid equably by varicosity poly- four Fluoride film absorbs;
D. step c is absorbed has the polytetrafluoroethylene film of anti-static liquid to handle by room temperature drying and processing or heating, drying;
E. the dried polytetrafluoroethylene film of step d is wrapped with coiler, plastic cement core is packed into coiler, is coated with preventing The polytetrafluoroethylene film finished product of electrostatic liquid is involved on plastic cement core, smooth to spool.
4. antistatic film preparation method according to claim 3, it is characterised in that: the temperature of the step a normal temperature state Degree is 18~25 DEG C, and mixing time is 5~15 minutes, and the time of repose is 15~35 minutes.
5. antistatic film preparation method according to claim 3, it is characterised in that: the temperature of the step c normal temperature state Degree is 18~25 DEG C, and the sheet resistance value of the eptfe membrane after absorbing anti-static liquid is 104~108Ohm.
6. antistatic film preparation method according to claim 3, it is characterised in that: the heating temperature of the step d is 45~80 DEG C, the heating, drying time is 5~10 minutes.
CN201610743829.XA 2016-08-17 2016-08-17 A kind of film anti-static liquid and its antistatic film preparation method Active CN106366741B (en)

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CN107446156A (en) * 2017-08-22 2017-12-08 江苏泛亚微透科技股份有限公司 Composite, its preparation method and its preparation facilities of graphite ene coatings are coated with eptfe membrane face
CN107864543A (en) * 2017-11-06 2018-03-30 张永宏 The preparation method of Electrostatic Absorption film
CN108864464A (en) * 2018-05-30 2018-11-23 温州市佳联塑胶有限公司 A kind of preparation method of PVC film anti-static liquid and anti-static PVC film
CN109016579B (en) * 2018-07-26 2021-05-18 昱天(上海)新材料有限公司 Preparation method of three-layer structure durable and non-hydrolytic type static elimination microporous film

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DE3717668A1 (en) * 1987-05-26 1988-12-15 Hoechst Ag ELECTRICALLY CONDUCTIVE COATING MEASUREMENT, METHOD FOR THEIR PRODUCTION AND THEIR USE
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CN1836628A (en) * 2005-03-24 2006-09-27 李培芳 Disposable damping electric conductor
CN202440459U (en) * 2012-01-19 2012-09-19 中山市万丰胶粘电子有限公司 Anti-static protection film
CN205097635U (en) * 2015-07-23 2016-03-23 杨怡君 Thin film
CN105504612A (en) * 2016-02-01 2016-04-20 天津市天塑科技集团有限公司 Preparation method of anti-static polytetrafluoroethylene thin film

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