CN106366441A - Anti-aging outdoor fan surface material and preparation method thereof - Google Patents

Anti-aging outdoor fan surface material and preparation method thereof Download PDF

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Publication number
CN106366441A
CN106366441A CN201610777382.8A CN201610777382A CN106366441A CN 106366441 A CN106366441 A CN 106366441A CN 201610777382 A CN201610777382 A CN 201610777382A CN 106366441 A CN106366441 A CN 106366441A
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CN
China
Prior art keywords
parts
aging
coupling agent
zeolite powder
polypropylene
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Pending
Application number
CN201610777382.8A
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Chinese (zh)
Inventor
盛春
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Suzhou Lingyun Craft Fan Factory
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Suzhou Lingyun Craft Fan Factory
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Priority to CN201610777382.8A priority Critical patent/CN106366441A/en
Publication of CN106366441A publication Critical patent/CN106366441A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

The invention discloses an anti-aging outdoor fan surface material and a preparation method thereof. The anti-aging outdoor fan surface material is prepared by the following raw materials in parts by weight: 40-50 parts of polypropylene, 4-8 parts of polyvinyl chloride, 3-6 parts of chopped glass fiber, 10-15 parts of zeolite powder, 0.3-1 part of an ultraviolet light absorber, 1-3 parts of nano titania, 2-4 parts of methyl methacrylate-butadiene-styrene, 1-2 parts of a coupling agent, 0.5-1 part of polyoxyethylene castor oil and 0.3-1 part of an antioxidant. The fan surface material prepared by the invention is good forming effect and smooth in surface, has good ageing resistance, can effectively delay the aging of plastics, has a certain toughness and is suitable for outdoor use.

Description

A kind of anti-aging outdoor covering of the fan material and preparation method thereof
Technical field
The present invention relates to covering of the fan field of material technology is and in particular to a kind of anti-aging outdoor covering of the fan material and its preparation side Method.
Background technology
Fan is air inducing articles for use, the thing of summertime indispensability.China Han fan culture has deep cultural deposits, is han nationality One integration section of culture, has had the history of thousand.The material of fan has a lot, and plastic fan is so that it is frivolous, cost is low Advantage and be widely used, plastic fan includes covering of the fan and fan handle, and plastics covering of the fan is of long duration or easily sends out under the conditions of Exposure to Sunlight out of doors Life is aging, and jaundice becomes fragile, thus affecting its service life.
Content of the invention
For the deficiencies in the prior art, the invention provides a kind of anti-aging outdoor covering of the fan material and preparation method thereof.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: polypropylene 40-50 part, polychlorostyrene second Alkene 4-8 part, glass chopped strands 3-6 part, zeolite powder 10-15 part, UV absorbers 0.3-1 part, nano titanium oxide 1-3 Part, MBS 2-4 part, coupling agent 1-2 part, polyoxyethylene caster seed oil 0.5-1 part, antioxygen Agent 0.3-1 part.
Preferably, be made up of the raw material of following weight portion: 45 parts of polypropylene, 6 parts of polrvinyl chloride, 4 parts of glass chopped strands, 13 parts of zeolite powder, 0.6 part of UV absorbers, 2 parts of nano titanium oxide, 3 parts of MBS, 1.5 parts of coupling agent, 0.6 part of polyoxyethylene caster seed oil, 0.5 part of antioxidant.
Preferably, described coupling agent is aminopropyl triethoxysilane.
Preferably, the mesh number of described zeolite powder is 400-600 mesh.
The preparation method of anti-aging outdoor covering of the fan material, step is as follows:
1) by polypropylene, polrvinyl chloride, zeolite powder, nano titanium oxide, MBS, Coupling agent, polyoxyethylene caster seed oil are proportionally added in high mixer, and mix homogeneously adds glass chopped strands, antioxygen Agent, UV absorbers, mix homogeneously, obtain compound;
2) add mixture in extruder, be squeezed into the melt of molten condition in the presence of screw rod, shifted To in mould, cure under pressure, cooling and shaping, obtain final product.
The invention has the advantages that: MBS can improve the soft of plastic in the present invention Toughness, the addition of glass chopped strands, titanium dioxide and other auxiliary agent, can be good at absorbing ultraviolet, reduce light, heat etc. because The impact to macromolecular material physical property for the element, slows down rate of ageing, the covering of the fan material good forming effect of present invention preparation, surface light Clean, there is good ageing resistance, can effectively delay plastic ageing, and possess certain pliability, being suitable for open air makes With.
Specific embodiment
Purpose, technical scheme and advantage for making the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described it is clear that described embodiment is the present invention one Divide embodiment, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making The every other embodiment being obtained under the premise of creative work, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: 45 parts of polypropylene, polrvinyl chloride 6 Part, 4 parts of glass chopped strands, 13 parts of 500 mesh zeolite powder, 0.6 part of UV absorbers, 2 parts of nano titanium oxide, metering system 3 parts of sour methyl ester-butadiene-styrene, 1.5 parts of aminopropyl triethoxysilane coupling agent, 0.6 part of polyoxyethylene caster seed oil, 0.5 part of antioxidant.
The preparation method of anti-aging outdoor covering of the fan material, step is as follows:
1) by polypropylene, polrvinyl chloride, zeolite powder, nano titanium oxide, MBS, Coupling agent, polyoxyethylene caster seed oil are proportionally added in high mixer, and mix homogeneously adds glass chopped strands, antioxygen Agent, UV absorbers, mix homogeneously, obtain compound;
2) add mixture in extruder, be squeezed into the melt of molten condition in the presence of screw rod, shifted To in mould, cure under pressure, cooling and shaping, obtain final product.
Embodiment 2:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: 42 parts of polypropylene, polrvinyl chloride 5 Part, 4 parts of glass chopped strands, 12 parts of 500 mesh zeolite powder, 0.5 part of UV absorbers, 1.5 parts of nano titanium oxide, methyl-prop 3 parts of e pioic acid methyl ester-butadiene-styrene, 1.5 parts of aminopropyl triethoxysilane coupling agent, polyoxyethylene caster seed oil 0.6 Part, 0.5 part of antioxidant.
The preparation method of anti-aging outdoor covering of the fan material, with embodiment 1.
Embodiment 3:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: 48 parts of polypropylene, polrvinyl chloride 4 Part, 6 parts of glass chopped strands, 15 parts of 400 mesh zeolite powder, 0.6 part of UV absorbers, 2 parts of nano titanium oxide, metering system 3.5 parts of sour methyl ester-butadiene-styrene, 1.8 parts of aminopropyl triethoxysilane coupling agent, polyoxyethylene caster seed oil 0.7 Part, 0.7 part of antioxidant.
The preparation method of anti-aging outdoor covering of the fan material, with embodiment 1.
Embodiment 4:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: 40 parts of polypropylene, polrvinyl chloride 8 Part, 3 parts of glass chopped strands, 15 parts of 600 mesh zeolite powder, 0.3 part of UV absorbers, 3 parts of nano titanium oxide, metering system 2 parts of sour methyl ester-butadiene-styrene, 2 parts of aminopropyl triethoxysilane coupling agent, 0.5 part of polyoxyethylene caster seed oil, anti- 1 part of oxygen agent.
The preparation method of anti-aging outdoor covering of the fan material, with embodiment 1.
Embodiment 5:
A kind of anti-aging outdoor covering of the fan material, is made up of the raw material of following weight portion: 50 parts of polypropylene, polrvinyl chloride 4 Part, 6 parts of glass chopped strands, 10 parts of 500 mesh zeolite powder, 1 part of UV absorbers, 1 part of nano titanium oxide, methacrylic acid 4 parts of methyl ester-butadiene-styrene, 1 part of aminopropyl triethoxysilane coupling agent, 1 part of polyoxyethylene caster seed oil, antioxidant 0.3 part.
The preparation method of anti-aging outdoor covering of the fan material, with embodiment 1.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation are made a distinction with another entity or operation, and not necessarily require or imply these entities or deposit between operating In any this actual relation or order.And, term " inclusion ", "comprising" or its any other variant are intended to Comprising of nonexcludability, wants so that including a series of process of key elements, method, article or equipment and not only including those Element, but also include other key elements being not expressly set out, or also include for this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element that limited by sentence "including a ..." it is not excluded that Also there is other identical element including in the process of described key element, method, article or equipment.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to the foregoing embodiments The present invention has been described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or carries out equivalent to wherein some technical characteristics;And these modification or Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (5)

1. a kind of anti-aging outdoor covering of the fan material is it is characterised in that be made up of the raw material of following weight portion: polypropylene 40-50 Part, polrvinyl chloride 4-8 part, glass chopped strands 3-6 part, zeolite powder 10-15 part, UV absorbers 0.3-1 part, nano-silica Change titanium 1-3 part, MBS 2-4 part, coupling agent 1-2 part, polyoxyethylene caster seed oil 0.5-1 Part, antioxidant 0.3-1 part.
2. anti-aging outdoor covering of the fan material as claimed in claim 1 is it is characterised in that raw material system by following weight portion Become: 45 parts of polypropylene, 6 parts of polrvinyl chloride, 4 parts of glass chopped strands, 13 parts of zeolite powder, UV absorbers 0.6 part, nanometer two 2 parts of titanium oxide, 3 parts of MBS, 1.5 parts of coupling agent, 0.6 part of polyoxyethylene caster seed oil, 0.5 part of antioxidant.
3. anti-aging outdoor covering of the fan material as claimed in claim 2 is it is characterised in that described coupling agent is aminopropyl three second TMOS.
4. anti-aging outdoor covering of the fan material as claimed in claim 2 is it is characterised in that the mesh number of described zeolite powder is 400- 600 mesh.
5. described anti-aging outdoor covering of the fan material as arbitrary in claim 1-4 preparation method it is characterised in that step such as Under:
1) by polypropylene, polrvinyl chloride, zeolite powder, nano titanium oxide, MBS, coupling Agent, polyoxyethylene caster seed oil are proportionally added in high mixer, and mix homogeneously adds glass chopped strands, antioxidant, purple Outer light absorber, mix homogeneously, obtain compound;
2) add mixture in extruder, be squeezed into the melt of molten condition in the presence of screw rod, be transferred into mould In tool, cure under pressure, cooling and shaping, obtain final product.
CN201610777382.8A 2016-08-31 2016-08-31 Anti-aging outdoor fan surface material and preparation method thereof Pending CN106366441A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610777382.8A CN106366441A (en) 2016-08-31 2016-08-31 Anti-aging outdoor fan surface material and preparation method thereof

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CN106366441A true CN106366441A (en) 2017-02-01

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652498A (en) * 2017-08-31 2018-02-02 苏州盛风文化创意发展有限公司 A kind of Multifunction fan plane materiel material and preparation method thereof
CN107828071A (en) * 2017-11-03 2018-03-23 苏州梅香雅筑工艺品有限公司 A kind of plastics covering of the fan with flame retardant coating
CN110294898A (en) * 2019-07-26 2019-10-01 株洲飞鹿高新材料技术股份有限公司 A kind of glass fiber reinforced polypropylene composite material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942147A (en) * 2010-03-31 2011-01-12 深圳市科聚新材料有限公司 Hardened transparent polypropylene material for fan blades and preparation method thereof
CN102212230A (en) * 2011-04-22 2011-10-12 临海市四通制管有限公司 Cooling fan blade of diesel engine and manufacture method thereof
CN102653615A (en) * 2012-05-23 2012-09-05 临海市四通制管有限公司 Method for preparing blade of cooling fan of automobile engine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101942147A (en) * 2010-03-31 2011-01-12 深圳市科聚新材料有限公司 Hardened transparent polypropylene material for fan blades and preparation method thereof
CN102212230A (en) * 2011-04-22 2011-10-12 临海市四通制管有限公司 Cooling fan blade of diesel engine and manufacture method thereof
CN102653615A (en) * 2012-05-23 2012-09-05 临海市四通制管有限公司 Method for preparing blade of cooling fan of automobile engine

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652498A (en) * 2017-08-31 2018-02-02 苏州盛风文化创意发展有限公司 A kind of Multifunction fan plane materiel material and preparation method thereof
CN107828071A (en) * 2017-11-03 2018-03-23 苏州梅香雅筑工艺品有限公司 A kind of plastics covering of the fan with flame retardant coating
CN110294898A (en) * 2019-07-26 2019-10-01 株洲飞鹿高新材料技术股份有限公司 A kind of glass fiber reinforced polypropylene composite material and preparation method thereof

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Application publication date: 20170201

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