CN106365539A - Silt compounded curing agent - Google Patents

Silt compounded curing agent Download PDF

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Publication number
CN106365539A
CN106365539A CN201610761959.6A CN201610761959A CN106365539A CN 106365539 A CN106365539 A CN 106365539A CN 201610761959 A CN201610761959 A CN 201610761959A CN 106365539 A CN106365539 A CN 106365539A
Authority
CN
China
Prior art keywords
curing agent
mass parts
composite curing
sludge composite
agent according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610761959.6A
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Chinese (zh)
Inventor
刘晓军
李佑广
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Heng Ji Sheng Technology Co Ltd
Original Assignee
Tianjin Heng Ji Sheng Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Heng Ji Sheng Technology Co Ltd filed Critical Tianjin Heng Ji Sheng Technology Co Ltd
Priority to CN201610761959.6A priority Critical patent/CN106365539A/en
Publication of CN106365539A publication Critical patent/CN106365539A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/021Ash cements, e.g. fly ash cements ; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration ; Kiln dust cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D3/00Improving or preserving soil or rock, e.g. preserving permafrost soil
    • E02D3/12Consolidating by placing solidifying or pore-filling substances in the soil

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Soil Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention relates to a curing agent, in particular to a silt compounded curing agent which is prepared from the following components in parts by mass: 20-50 parts of an inorganic material adhesive, 2-5 parts of an activator and 2-10 parts of an organic matter surfactant. The silt compounded curing agent is mainly acted on silt, can replace the traditional construction process of vacuum preloading, rockery skin changing and filling and dynamic compaction and can be used for foundation treatment of expressways, municipal roads, storage yards and various building places.

Description

A kind of sludge composite curing agent
Technical field
The present invention relates to a kind of firming agent, particularly to a kind of sludge composite curing agent.
Background technology
Traditionally draining concretion method, broken is mainly had using the method for processing foundation of the blowing-filling sludge processing and auger ground Stone (sand) stake displacement method, Deep Mixing Method etc..Rubble (sand) stake displacement method and Deep Mixing Method construction costs all compare high Expensive, be not suitable for large area and adopt.The processing method traditionally widely applied is draining concretion method: according to different loading draining shapes Formula, it is low-yield that discharging consolidation mainly has preloading, vacuum method, vacuum well-point dewatering method, vacuum electroosmosis precipitation to combine Heavy-tamping method and low position vacuum preloading method.
Now conventional to two kinds traditional reclaimed ground treatment technology is briefly outlined below:
1st, vacuum method
Vacuum method is on setting sand bedding course and vertical drainage channel base, closing membrane is closed be reinforced soft The weak soil body, and it is evacuated formation vacuum so that producing negative pressure in this sand bedding course and drainage channel.Consolidation is produced under this suction function Pressure, makes soil body pore water continually discharge to complete the foundation reinforcement method of soil solidifying.Vacuum method design refers to Mark requires: the vacuum under vacuum preloading film is not less than 80kpa.Vacuum preloading applies in general to Muddy Bottoms soft clay foundation.Very The general water discharge time of empty preconsolidation measure is longer (90 180 days about), disposes groundwork bearing capacity typically 60 80kpa.Technique of soft soil foundation treatment requires blowing-filling sludge surface through long period dry in the sun (6 December), and personnel and board-plugging device can be allowed to exist Operation can go into operation thereon, and need to buy thick technique sand bedding course more than 1 meter.Time length, low bearing capacity are its greatest problem, vacuum Precompressed is finished groundwork bearing capacity and is not reached technical requirements, constructing roadbed also needs to fill out 1 meter of thick mountain skin stone.
2nd, change and fill out displacement method
Cushion is to dig out Udoll part, change fill out the low compressibilities such as the larger sand of intensity, crushed-gravel (mountain skin stone) dissipate Body material, to improve foundation bearing capacity, to reduce settlement of foundation.The method is to dispose the relatively effective ways of shallow layer soft soil foundation. Change the foundation bearing capacity after filling out typically in 120 200kpa.Change and fill out crowded silt and about need 23 meters of thick mountain skin rock layers, substantial amounts of mountain skin Stone outward transport not only increased transport pressure, and the stone acquisition mountain skin stone that cuts into a mountain brokenly causes to environment greatly to destroy.Change to fill out and squeeze silt The maximum problem of method is that freight volume is big and serious to environmental protection destruction.
In recent years, the Soft Soil being formed with substantial amounts of Marine shoal and dredging and reclamation urgently develops, and passes The treatment of foundation with soft soil method of system, cycle long cost is high, and foundation bearing capacity is low, needs strange land roping lot of materials to enter line replacement, both broke It is broken ecological environment, and poor durability, the contradiction between economic development and environment protection.
Stablizing silt soil using sludge curing agent is the hot technology in silt soil Treatment process then, this mud penus In special soil, there is higher moisture content and organic matter.The sludge treatment solidification of China is still in the starting stage.
Content of the invention
In order to solve problem of the prior art, the invention provides a kind of sludge composite curing agent, it mainly acts on silt Mud, can substitute vacuum preloading+change the traditional construction technique filling out mountain stone skin+strong rammer, can be used for highway, town road, port Mouth stockyard and the basement process of various building yard.
The technical solution adopted in the present invention is as follows:
A kind of sludge composite curing agent, including the component of following mass parts: the inorganic material cement of 20-50 mass parts, The Organic substance surfactant of the exciting agent of 2-5 mass parts and 2-10 mass parts.
Inorganic material cement is the mixture of one or more of cement, clinker, slag or flyash.
Exciting agent is the mixture of one or more of sulfide, alkali or inorganic salts.
Organic substance surfactant is dehydration flocculant, anion surfactant, nonionic surfactant or slow setting The mixture of one or more of agent.
Dehydration flocculant is polyacrylamide.
Anion surfactant is soap, sodium alkyl sulfonate, sodium alklyarylsulfonate, alkyl sodium sulfate, secondary alkyl sulfide The mixture of one or more of sour sodium.
Nonionic surfactant is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy, fat Fat amine polyoxyethylene ether, alkylolamideses polyoxyethylene ether, one or more of Block polyoxyethylene-polyethenoxy ether mixed Compound.
The sludge composite curing agent of the present invention, its Organic substance surfactant plays surface-active action and deferred action, Make inorganic material cement be more easy to enter inside soil particle, so that ion-exchange reactionss is carried out rapidly, thoroughly, adjust simultaneously The time delay of firming agent.
The sludge composite curing agent of the present invention can carry out the sludge solidification of road foundation, and its cost of building the road not only can drop Low 20%-50%, and the combination property (durability and stability) of roadbed is also significantly better than conventional sandstone roadbed, especially plate body Property good, intensity is high.
The mud of dredging desilting can also be converted into earth working material by sludge composite curing agent, can according to moisture content not With, this firming agent and mud are stirred and spreads out and puts on compacting, make induration short-term consolidation and sclerosis, both can build park, and make island, and Can build the road sill, completely can be from sea water, the immersion of fresh water, and its later strength can more and more higher.
The technical scheme that the present invention provides has the benefit that
1st, improve comprcssive strength, the unconfined compressive strength ratio of the silt consolidation body that sludge composite curing agent obtains is individually general The unconfined compressive strength of the induration of logical portland cement improves nearly 300%, and the prolongation with curing time, its consolidation The unconfined compressive strength of body is still stepping up.
2nd, improve water stability, due to its distinctive mechanism of action, the solidification to mud is permanent, city is tested Test specimen and the same conditional maintenance test specimen carry out immersion observation, no dissipate solution phenomenon, and intensity free of losses.
Specific embodiment
For making the object, technical solutions and advantages of the present invention clearer, embodiment of the present invention will be made into one below Step ground describes in detail.
Embodiment one
A kind of sludge composite curing agent, including the component of following mass parts: the cement of 20 mass parts, the sulfuration of 2 mass parts Thing and the dehydration flocculant of 2 mass parts, wherein dehydration flocculant uses polyacrylamide.
Embodiment two
A kind of sludge composite curing agent, including the component of following mass parts: the cement of 50 mass parts, the sulfuration of 5 mass parts Thing and the dehydration flocculant of 10 mass parts, wherein dehydration flocculant uses polyacrylamide.
Embodiment three
A kind of sludge composite curing agent, including the component of following mass parts: the clinker of 20 mass parts, 2 mass parts Sulfide and the dehydration flocculant of 2 mass parts, wherein dehydration flocculant uses polyacrylamide.
Example IV
A kind of sludge composite curing agent, including the component of following mass parts: the slag of 20 mass parts, the sulfuration of 2 mass parts Thing and the dehydration flocculant of 2 mass parts, wherein dehydration flocculant uses polyacrylamide.
Embodiment five
A kind of sludge composite curing agent, including the component of following mass parts: the flyash of 50 mass parts, the sulfur of 5 mass parts Compound and the dehydration flocculant of 10 mass parts, wherein dehydration flocculant uses polyacrylamide.
Embodiment six
A kind of sludge composite curing agent, including the component of following mass parts: the flyash of 50 mass parts, the alkali of 5 mass parts With the dehydration flocculant of 10 mass parts, wherein dehydration flocculant uses polyacrylamide.
Embodiment seven
A kind of sludge composite curing agent, including the component of following mass parts: the flyash of 20 mass parts, the alkali of 2 mass parts With the anion surfactant of 2 mass parts, wherein anion surfactant is using soap, sodium alkyl sulfonate, alkylaryl The mixture of one or more of sodium sulfonate, alkyl sodium sulfate, Teepol.
Embodiment eight
A kind of sludge composite curing agent, including the component of following mass parts: the flyash of 50 mass parts, the alkali of 5 mass parts With the nonionic surfactant of 10 mass parts, wherein nonionic surfactant uses fatty alcohol-polyoxyethylene ether, alkyl phenol Polyoxyethylene ether, aliphatic acid polyethenoxy, aliphatic amine polyoxyethylene ether, alkylolamideses polyoxyethylene ether, Block polyoxyethylene- The mixture of one or more of polyethenoxy ether.
Embodiment nine
A kind of sludge composite curing agent, including the component of following mass parts: the flyash of 30 mass parts, the alkali of 5 mass parts Retarder with 5 mass parts.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.

Claims (7)

1. a kind of sludge composite curing agent is it is characterised in that include the component of following mass parts: the inorganic material of 20-50 mass parts Material cement, the Organic substance surfactant of the exciting agent of 2-5 mass parts and 2-10 mass parts.
2. a kind of sludge composite curing agent according to claim 1 is it is characterised in that described inorganic material cement is The mixture of one or more of cement, clinker, slag or flyash.
3. a kind of sludge composite curing agent according to claim 1 it is characterised in that described exciting agent be sulfide, The mixture of one or more of alkali or inorganic salts.
4. a kind of sludge composite curing agent according to claim 1 is it is characterised in that described Organic substance surfactant It is the mixture of one or more of dehydration flocculant, anion surfactant, nonionic surfactant or retarder.
5. a kind of sludge composite curing agent according to claim 4 is it is characterised in that described dehydration flocculant is poly- third Acrylamide.
6. a kind of sludge composite curing agent according to claim 4 is it is characterised in that described anion surfactant Mixing for one or more of soap, sodium alkyl sulfonate, sodium alklyarylsulfonate, alkyl sodium sulfate, Teepol Thing.
7. a kind of sludge composite curing agent according to claim 4 is it is characterised in that described nonionic surfactant It is fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy, aliphatic amine polyoxyethylene ether, alkylol acyl Amine polyoxyethylene ether, the mixture of one or more of Block polyoxyethylene-polyethenoxy ether.
CN201610761959.6A 2016-08-29 2016-08-29 Silt compounded curing agent Pending CN106365539A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610761959.6A CN106365539A (en) 2016-08-29 2016-08-29 Silt compounded curing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610761959.6A CN106365539A (en) 2016-08-29 2016-08-29 Silt compounded curing agent

Publications (1)

Publication Number Publication Date
CN106365539A true CN106365539A (en) 2017-02-01

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108218321A (en) * 2018-02-01 2018-06-29 温州市东海建筑安装工程有限公司 Civil material curing agent and preparation method
CN108726927A (en) * 2017-04-20 2018-11-02 连云港港口工程设计研究院有限公司 A kind of port construction material reclamation composition using mud
CN114315063A (en) * 2022-01-05 2022-04-12 三峡大学 Sludge curing device and sludge curing method
CN115010425A (en) * 2022-05-17 2022-09-06 中国地质大学(武汉) Sludge curing agent for industrial slag combined with waste polystyrene foam particles

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108726927A (en) * 2017-04-20 2018-11-02 连云港港口工程设计研究院有限公司 A kind of port construction material reclamation composition using mud
CN108218321A (en) * 2018-02-01 2018-06-29 温州市东海建筑安装工程有限公司 Civil material curing agent and preparation method
CN114315063A (en) * 2022-01-05 2022-04-12 三峡大学 Sludge curing device and sludge curing method
CN115010425A (en) * 2022-05-17 2022-09-06 中国地质大学(武汉) Sludge curing agent for industrial slag combined with waste polystyrene foam particles

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Application publication date: 20170201

RJ01 Rejection of invention patent application after publication