CN106364202A - Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth - Google Patents
Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth Download PDFInfo
- Publication number
- CN106364202A CN106364202A CN201610749024.6A CN201610749024A CN106364202A CN 106364202 A CN106364202 A CN 106364202A CN 201610749024 A CN201610749024 A CN 201610749024A CN 106364202 A CN106364202 A CN 106364202A
- Authority
- CN
- China
- Prior art keywords
- cloth
- mass percent
- resin
- layer
- transfer printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38207—Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
- B41M5/38214—Structural details, e.g. multilayer systems
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Coloring (AREA)
- Decoration By Transfer Pictures (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to the technical field of thermal sublimation transfer printing, and discloses a temperature-sensitive viscous dry thermal sublimation transfer printing digital cloth which sequentially comprises a base material cloth, a water-absorbing and permeable layer, a porous layer, a channel layer and a surface bonding layer from bottom to top. The surface bonding layer is a compound of any two or more of polyvinyl alcohol-vinyl acetate copolymer, ethylene-vinyl acetate-vinyl alcohol copolymer, sodium carboxymethyl cellulose and polyvinyl alcohol and polyhydric alcohol. The porous layer is interpenetrating network resin, which can expand to hold dye and absorb ink quickly, and water molecules can enter the water-absorbing and water-permeable layer quickly by adjusting resin composition and controlling network density. The surface bonding layer has no viscosity at normal temperature, so that the surface bonding layer can be conveniently wound, when the surface bonding layer is heated to a specific temperature, the surface bonding layer has good viscosity, an elastic printing stock is bonded, and the details of a transfer image are clear; after the transfer printing is finished and the temperature is reduced, the cloth substrate automatically breaks away from the printing stock, and has the characteristics of temperature sensitivity and cyclic coating of the cloth substrate.
Description
Technical field
The present invention relates to thermal dye sublimation transfer printing technical field, a kind of more particularly, to temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number
Plaiting.
Background technology
Thermal-printing Technology refers to for the contents such as word, figure to use hot print ink printed in common paper or high accuracy
On printing paper, then it is heated to 180～230 DEG C within a few minutes through corresponding thermal transfer equipment, the image color on paper is forced
Very it is transferred to a kind of special process on unlike material.Mode of printing is divided into transfer film print and transfer processing two large divisions, turns
Die printing adopts net-point printing, and pattern is pre-printed film surface, and the pattern level of printing enriches, bright in luster, thousand changes
Wan Hua, aberration is little, and repeatability is good, and is suitable for producing in enormous quantities；By heat transfer machine time processing, (heating adds for transfer processing
Pressure) exquisite pattern on transfer film is transferred in product surface, after molding, layer of ink is molten with product surface is integrated, true to nature beautiful,
Greatly improve the class of product.
Number of patent application is 201420299814.5 quick-dry type thermal dye sublimation transfer printing number cloth, and this digital cloth includes digital cloth
Layer, except water layer, ink-absorbed coated layer and antiseized sealing coat, after ink-absorbed coated layer absorbs ink, except the space hole in water layer absorbs ink
Moisture in water, accelerates the speed that the quick-dry type thermal dye sublimation transfer printing number cloth after absorbing ink is dried；Remove a part simultaneously
Moisture, disperse dyes molecules sublimated be transferred on leaflet after can also rapid draing, there is certain progress.
Elastic fabric is an important class textile material, can be expanded growth by during thermal transfer, and thermal dye sublimation transfer printing number
Plaiting is more stable, because both expanded by heating degree are different, thus easily cause the pattern being transferred on stock occur ghost image,
Dim pattern is unclear, and yield rate is not high.In order to solve this problem, researcher have developed viscosity thermal sublimation digit cloth in recent years, but
Generally rate of drying is slow, is suitable for single spraying head, the requirement of 15～30 ms/h of double nozzle printing machine manufacturing speed.But with
Digital printing making to quickly grow, printer speed has been promoted to 100～2000 ms/h, and the making of pattern is also got over
Come more complicated, the rate of drying of the digital transfer paper that current technology produces can not meet the demand of printing speed.Thus it is anxious
It is dry type thermal sublimation digit cloth that a kind of viscosity with Thermo-sensitive need to be developed, it is possible to achieve good transferring effect, rate of drying are fast, one-tenth
Product rate is high, cloth base material coating capable of circulation.
Content of the invention
The present invention be directed to prior art in elastic fabric transfer dim pattern unclear, yield rate is not high, rate of drying not
The shortcoming that print speed demand can be met, there is provided a kind of rate of drying is fast, transfer clear patterns, high yield rate, cloth base material can
The temperature sensitive viscosity of cycling coating is dry type thermal dye sublimation transfer printing number cloth.
In order to solve above-mentioned technical problem, the present invention is addressed by following technical proposals:
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, includes base material cloth, water suction pervious bed, porous from the bottom to top successively
Layer, channel layer, surface binder layer；The digital cloth of the present invention has scalable intensity, during thermal dye sublimation transfer printing, uses base material cloth
The temperature sensitive viscosity made is that dry type thermal dye sublimation transfer printing number cloth can be reused, and has not only saved production cost, and has saved
Change the time of transfer printing digital paper, improve production efficiency.Surface binder layer is calculated by mass percentage, and component and content are divided
Not as follows:
Tackifying resin compositionss 58～78%；
Polyhydric alcohol 22～42%；
Wherein, tackifying resin compositionss are polyvinyl alcohol-vinyl acetate co-polymer, ethylene-vinylacetate-vinyl alcohol
Two or more combination any in copolymer, sodium carboxymethyl cellulose, polyvinyl alcohol.
During room temperature, surface viscosity layer does not have viscosity, and when being heated to 190～230 DEG C, surface viscosity layer produces viscosity, glues
Live stock transfer, until being all transferred to pattern on stock, after cooling to less than 100 DEG C, the viscosity of sticky table surface layer disappears
Lose, automatically disengage stock, make transferring effect intact, picture is clear, and yield rate greatly improves, thus has Thermo-sensitive.
Preferably, the number of hydroxyl is 3～9 in polyhydric alcohol.
Preferably, the quality of every square metre of base material cloth upper surface tack coat is 3.0～5.0g.Surface binder layer is net
Shape structure, it is possible to increase the uniformity that digital cloth is bondd with stock, general tack coat ink transmitance is low, leads to print and does
Dry speed is slow, and the surface mesh structure of the present invention and four-layer structure can make ink fast strikethrough, significantly improve rate of drying,
This external enwergy maximizes adhesive effect with stock, improves the uniformity with elastic fabric bonding, can avoid appearance during transfer
, so that stock pattern in detail is clearly demarcated, color saturation is bright-coloured for pattern ghost image.
Preferably, channel layer is calculated by mass percentage, component and content are as follows respectively:
Resin combination 40～72%；
Porous silica 28～60%；
Wherein, resin combination be vinyl alcohol-vinyl acetate copolymer, ethylene-vinyl alcohol-acetate ethylene copolymer,
Two or more combination any in polyvinyl acetate, sodium carboxymethyl cellulose, cellulose.
The present invention adopts the porous silica can be with the porosity of effective control channel layer, and silicon dioxide and resin group
Compound can effective regulation channel layer space, thus improve the absorption transmission speed to ink for the channel layer.
In type channel layer under room temperature, porous silica silicon compound has very strong water permeable ability and passes to porous layer；?
Intermolecular hydrogen bonding in high temperature transfer condition undersurface layer reduces, using the teaching of the invention it is possible to provide bigger space, dye molecule is from transfer printing digital
Quickly fully distil in cloth coating material, transferring effect is preferable.This gap structure of channel layer makes ink permeate rapidly, and
Ensure that dye molecule and water are efficiently transported to porous layer.
Preferably, porous layer is cellulose or sodium carboxymethyl cellulose or starch is led to cation-modified polyacrylamide
Cross the interpenetrating network resin of isocyanate-crosslinked formation, or polyacrylamide or cellulose or sodium carboxymethyl cellulose and sun from
Sub- modified starch is by the interpenetrating network resin of isocyanate-crosslinked formation.Wherein, according to mass percent calculate, cellulose or
Sodium carboxymethyl cellulose or starch are 62%～79%, and cation-modified polyacrylamide is 18%～30%, and isocyanates are
3%～8%；Or polyacrylamide or cellulose or sodium carboxymethyl cellulose are 62%～79%, cationic modified starch is
18%～30%, isocyanates are 3%～8%.Isocyanates are the group of aliphatic diisocyanate and PPDI
Close.Cellulose is hydroxyethyl cellulose, hydroxypropyl cellulose, any two kinds of combinations in carboxymethyl cellulose；Cation-modified
Polyacrylamide is the polyacrylamide homo polymer of cationization and combining of polyacrylamide-hydroxyethylacrylate copolymer；Sun
Cation reagent used by ionizing includes quaternary ammonium salt and tertiary amine salt, and quaternary ammonium salt is n, n, n- trimethyl -2- (2- first
Base -1- oxo -2- acrylic epoxide) ethyl ammonium chloride-acrylamide copolymer, tertiary amine salt is dimethylamino-propyl acryloyl
Amine hydrochlorate-acrylamide copolymer；Aliphatic diisocyanate is hexamethylene diisocyanate (hdi) or isophorone two
Isocyanates (ipdi) or hydrogenation methylenebis phenyl isocyanate (h12mdi).There is space, gap structure can increase between cellulose
Big blotting amount, shortens transfer time, improve production efficiency.
In prior art, after the ink absorbing layer in transfer printing digital cloth absorbs dyestuff, interpenetrating network resin can rapid expanding " pocket
Live " dyestuff, thus reaching the effect increasing blotting amount, but the hydrone in ink and dye molecule all catch, due to speed is dried
Degree is related to interpenetrating network resin expansion, and the transmitance of wherein hydrone is very low, and therefore quick-dry type thermal dye sublimation transfer printing is digital
Cloth can only meet 15～50 ms/h of printer operating speed be dried require it is impossible to meet existing printer operating speed 100～
2000 ms/h of demand, the present invention passes through to adjust resin composition and the controlling network density permeable property of raising, is increasing blotting
Realize hydrone while amount and rapidly enter water suction pervious bed.
Preferably, the quality of every square metre of base material cloth upper channel layer is 1.0～3.0g.On every square metre of base material cloth
When the quality of channel layer is 1.0～3.0g, it is printed with very strong water permeable ability under room temperature and passes to porous layer；In high temperature transfer bar
Part lower channel layer intermolecular hydrogen bonding reduces, using the teaching of the invention it is possible to provide bigger space, and dye molecule is fast from transfer printing digital cloth coating material
Speed fully distils, and transferring effect is preferable.When the quality of every square metre of base material cloth upper channel layer is less than 1.0g, dark images print
Arise that situation do not done by ink, wrapup procedure easily dim pattern, directly affects transferring effect and produce substandard products problem.Often
Square metre base material cloth upper channel layer quality be more than 3.0g when, surface layer is too thick, can affect the distillation of dye molecule, also can lead
Transferring effect is caused to be deteriorated, channel layer is too thick directly to increase production cost.
On every square metre of base material cloth, the quality of porous layer is 3.5～5.0g.Porous layer on every square metre of base material cloth
When quality is 3.5～5.0g, the blotting time is short, it is rapid to be dried；On every square metre of base material cloth, the quality of porous layer is less than 3.5g
When, blotting time lengthening, rate of drying is slack-off；When on every square metre of base material cloth, the quality of porous layer is more than 5.0 grams, during blotting
Between, rate of drying all show excellent, but material cost increase.
Preferably, water suction pervious bed is the complex of resin combination and porous mineral.Water suction pervious bed is by water
Molecule quickly passes to base material cloth.Water suction pervious bed is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 40～65%；
Porous mineral 35～60%；
Wherein, resin combination is 45～70% by mass percent organosilicon modified crylic acid resin and quality hundred
Divide than the water-absorbing resin composition for 30～55%.
Preferably, organosilicon modified crylic acid resin is the modified acrylic resin of dimethicone, Methylethyl silicon
In the modified acrylic resin of the modified acrylic resin of the modified acrylic resin of oil, vinyl silicone oil, methyl phenyl silicone oil
Any one or two kinds combination.Hydrophilic one end is arranged in the side towards porous layer for the permeable water accepting layer, and hydrophobic side is arranged in
So that water molecule energy fast strikethrough base material cloth, rate of drying can significantly improve for base material cloth side.
Preferably, water-absorbing resin is Acrylic Acid-sodium Acrylate Copolymers, acrylamide-sodium acrylate copolymer, carboxylic first
Two or more combination any in base cellulose-acrylate copolymer, water-absorbing resin has water-wet side and hydrophobic side,
Water-wet side forms hole, and by the water adsorption in ink in hole, hydrophobic end molecule promotes hydrone to pass to base material cloth, and base material
Cloth and drying system directly contact are it is ensured that hydrone rapid draing, beneficial to the drying printing to ink after on dielectric material, real
Show printing and do effect, thus meeting 100～2000 ms/h of printing and making demand.Porous mineral is titanium dioxide
Silicon or Calcium Carbonate or aluminium oxide or kieselguhr, the loose structure of solid can rapidly, sufficiently absorb the hydrone in ink, carries
The high rate of drying of transfer paper.
Preferably, the quality of the pervious bed that absorbs water on every square metre of base material cloth is 2.0～3.0g.
The present invention, due to employing above technical scheme, has significant technique effect: the invention provides one kind is temperature sensitive
Viscosity is dry type thermal dye sublimation transfer printing number cloth, includes base material cloth, water suction pervious bed, porous layer, channel layer, table from the bottom to top successively
Face tack coat.Surface binder layer is network structure, makes ink fast strikethrough, and this external enwergy maximizes adhesive effect with stock, carries
The high uniformity with elastic fabric bonding, can avoid pattern ghost image during transfer so that stock pattern in detail is clearly demarcated,
Color saturation is bright-coloured；Very strong water permeable ability is had to pass to porous layer under channel layer room temperature；Channel layer includes gap structure, improves
The infiltration rate of ink is transmitted with quick, so that dielectric material has, perfect color true to nature, color saturation be bright-coloured, image is thin
Section is clearly demarcated and has saved ink；After porous layer absorbs dyestuff, interpenetrating network resin one side can expand " catching " dyestuff, from
And reach the useful achievement increasing blotting amount, on the other hand carried with network density by controlling the resin composition of interpenetrating network resin
High water-permeability matter, realizes hydrone and rapidly enters water suction pervious bed, reaches the useful achievement dramatically increasing transfer cloth rate of drying；
The water-wet side of water suction pervious bed forms hole, and by the water adsorption in ink in hole, hydrophobic end molecule promotes hydrone to pass to
Base material cloth, and base material cloth and exsiccator directly contact are it is ensured that hydrone rapid draing, black after on dielectric material beneficial to printing to
The drying of water, shortens the drying time of dielectric material it is achieved that printing and does effect.The same terms (temperature, humidity, pattern
Deng) under, quick-dry type thermal dye sublimation transfer printing number cloth drying time be 2～5 minutes, can meet print speed be 15～50 meters/little
When demand；And the drying time of the present invention is 0～60 second, the need of 100～2000 ms/h of printer operating speed can be met
Ask, thus realizing printing the effect done.The present invention has that drying time is short, blotting amount big, good transferring effect, cloth base material can follow
The feature of ring coating.
Brief description
Fig. 1 is the structural representation of the present invention；
Fig. 2 is the plane graph of surface binder layer.
Specific embodiment
Example below is that the present invention is described in further detail, but is not to limit the scope of the present invention.
Reference examples 1
Autohension quick-drying thermal dye sublimation transfer printing number paper, includes substrate paper, hydrophobic layer, water accepting layer, blotting from down to up successively
Layer and meshy surface layer.
Hydrophobic layer is that waterborne organic silicon is acrylic resin modified.Waterborne organic silicon acrylic resin modified for dimethicone
Modified acrylic resin or the silicon oil modified acrylic resin of Methylethyl or the modified acrylic resin of vinyl silicone oil or
The modified acrylic resin of methyl phenyl silicone oil.On every square metre of substrate paper, the quality of hydrophobic layer is 1.5g.
Water accepting layer includes space hole.Water accepting layer is acrylic acid -2- acrylamide -2- Sodium methacrylate. copolymer.Often put down
On the substrate paper of square rice, the quality of water accepting layer is 2g.
Ink absorbing layer is cation-modified polyacrylamide fibers element interpenetrating network resin.Blotting on every square metre of substrate paper
The quality of layer is 6.5g.
By weight percentage, the polyvinyl alcohol-vinyl acetate co-polymer being 35% and weight percent contain meshy surface layer
Measure the sodium carboxymethyl cellulose composition for 65%, meshy surface layer includes through hole.Netted surface layer on every square metre of substrate paper
Quality be 3g.
Embodiment 1
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 70%；
Tetramethylolmethane 30%；
Wherein, tackifying resin compositionss are 58% by mass percent polyvinyl alcohol and the carboxylic that mass percent is 42%
Sodium carboxymethylcellulose pyce forms.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 3.0g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 72%；
Porous silica 28%；
Wherein, the polyvinyl acetate that resin combination is 30% by mass percent and mass percent are 70%
Vinyl alcohol-vinyl acetate copolymer forms.The quality of every square metre of base material cloth 1 upper channel layer 4 is 2.0g.
Cellulose that porous layer 3 is 62% by mass percent, mass percent are 30% cation-modified polypropylene
The isocyanates reaction that amide is 8% by mass percent is obtained, and the ethoxy that cellulose is 20% by mass percent is fine
Dimension element and the hydroxypropyl cellulose composition that mass percent is 80%, cation-modified polyacrylamide by mass percent is
The polyacrylamide homo polymer of 40% cationization and polyacrylamide -2-(Acryloyloxy)ethanol copolymerization that mass percent is 60%
Thing forms, and the hdi that isocyanates are 80% by mass percent and the PPDI that mass percent is 20% form,
Cation reagent used by cationization is n, n, n- trimethyl -2- (2- methyl isophthalic acid-oxo -2- acrylic epoxide) ethylmercury chloride
Ammonium-acrylamide copolymer.On every square metre of base material cloth 1, the quality of porous layer 3 is 4.2g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 40%；
Aluminium oxide 60%；
Wherein, resin combination is 45% by mass percent the acrylic resin of dimethicone modification and quality
Percentage ratio is 55% water-absorbing resin composition；The Acrylic Acid-sodium Acrylate Copolymers that water-absorbing resin is 60% by mass percent
The acrylamide-sodium acrylate copolymer being 40% with mass percent forms.Absorb water on every square metre of base material cloth 1 pervious bed
2 quality is 2.4g.
Embodiment 2
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 60%；
Glycerol 40%；
Wherein, tackifying resin compositionss are 35% by mass percent polyvinyl alcohol and mass percent be 65% poly-
Vinyl alcohol-vinyl acetate copolymer.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 4.0g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 58%；
Porous silica 42%；
Wherein, resin combination is 37% by mass percent ethylene-vinyl alcohol-acetate ethylene copolymer and quality
Percentage ratio is 63% sodium carboxymethyl cellulose composition.The quality of every square metre of base material cloth 1 upper channel layer 4 is 3.0g.
Cellulose that porous layer 3 is 75% by mass percent, mass percent are that 20% cationic modified starch leads to
Cross the reaction of isocyanates that mass percent is 5% to be obtained, the carboxymethyl cellulose that cellulose is 30% by mass percent and
Mass percent is 70% hydroxyethyl cellulose composition, ipdi and percent mass that isocyanates are 68% by mass percent
Than the PPDI composition for 32%.On every square metre of base material cloth 1, the quality of porous layer 3 is 3.5g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 65%；
Calcium Carbonate 35%；
Wherein, the silicon oil modified acrylic resin of resin combination is 70% by mass percent Methylethyl and matter
Amount percentage ratio is 30% water-absorbing resin composition；The Acrylic acid-sodium acrylate copolymerization that water-absorbing resin is 50% by mass percent
Thing and carboxymethyl cellulose-acrylate copolymer composition that mass percent is 50%.Absorb water on every square metre of base material cloth 1
The quality of pervious bed 2 is 3.0g.
Embodiment 3
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 78%；
Tetramethylolmethane 22%；
Wherein, tackifying resin compositionss are 40% by mass percent polyvinyl alcohol-vinyl acetate co-polymer and matter
Amount percentage ratio is 60% ethylene-vinylacetate-vinyl alcohol copolymer.Every square metre of base material cloth 1 upper surface tack coat 5
Quality is 3.4g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 60%；
Porous silica 40%；
Wherein, resin combination is 45% by mass percent vinyl alcohol-vinyl acetate copolymer and percent mass
Than the sodium carboxymethyl cellulose composition for 55%.The quality of every square metre of base material cloth 1 upper channel layer 4 is 2.4g.
Sodium carboxymethyl cellulose that porous layer 3 is 79% by mass percent, mass percent are that 18% cation changes
Property starch by mass percent be 3% isocyanates reaction be obtained, the h that isocyanates are 72% by mass percent12mdi
The PPDI being 28% with mass percent forms.On every square metre of base material cloth 1, the quality of porous layer 3 is
4.8g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 53%；
Silicon dioxide 47%；
Wherein, resin combination is 60% by mass percent the acrylic resin of vinyl silicone oil modification and quality
Percentage ratio is 40% water-absorbing resin composition；Acrylic Acid-sodium Acrylate Copolymers that water-absorbing resin is 25% by mass percent,
Mass percent is 45% acrylamide-sodium acrylate copolymer and carboxymethyl cellulose-the third that mass percent is 30%
Olefin(e) acid ester copolymer forms.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.2g.
Embodiment 4
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 75%；
Penta tetrol 25%；
Wherein, tackifying resin compositionss are 37% by mass percent polyvinyl alcohol-vinyl acetate co-polymer and matter
Amount percentage ratio is 63% sodium carboxymethyl cellulose composition.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is
3.8g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 40%；
Porous silica 60%；
Wherein, resin combination is 66% by mass percent vinyl alcohol-vinyl acetate copolymer and percent mass
Than the cellulose composition for 34%.The quality of every square metre of base material cloth 1 upper channel layer 4 is 1.5g.
Polyacrylamide that porous layer 3 is 70% by mass percent, mass percent are 25% cation-modified shallow lake
The isocyanates reaction that powder is 5% by mass percent is obtained, ipdi and matter that isocyanates are 40% by mass percent
Amount percentage ratio is 60% PPDI composition.On every square metre of base material cloth 1, the quality of porous layer 3 is 5.0g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 45%；
Kieselguhr 55%；
Wherein, resin combination is 48% by mass percent the acrylic resin of methyl phenyl silicone oil modification and matter
Amount percentage ratio is 52% water-absorbing resin composition；The acrylic amide-acrylic sodium that water-absorbing resin is 40% by mass percent is altogether
Polymers and carboxymethyl cellulose-acrylate copolymer composition that mass percent is 60%.Inhale on every square metre of base material cloth 1
The quality of water pervious bed 2 is 2.0g.
Embodiment 5
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 65%；
Bios Ⅰ 35%；
Wherein, the polyethylene of the polyvinyl alcohol by mass percent 70% for the tackifying resin compositionss and mass percent 30%
Alcohol-vinyl acetate co-polymer composition.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 4.6g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 55%；
Porous silica 45%；
Wherein, resin combination is by the ethylene-vinyl alcohol-acetate ethylene copolymer of mass percent 83% and quality hundred
Divide the polyvinyl acetate composition than 17%.The quality of every square metre of base material cloth 1 upper channel layer 4 is 1.0g.
Cellulose that porous layer 3 is 68% by mass percent, mass percent be 24% cationic modified starch altogether
The isocyanates reaction that polymers is 8% by mass percent is obtained, and the carboxymethyl that cellulose is 60% by mass percent is fine
Dimension element and the hydroxypropyl cellulose composition that mass percent is 40%, the h that isocyanates are 38% by mass percent12Mdi and
Mass percent is 62% PPDI composition.On every square metre of base material cloth 1, the quality of porous layer 3 is 3.8g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 52%；
Aluminium oxide 48%；
Wherein, resin combination is 66% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 34%, the dimethicone modification that organosilicon modified crylic acid resin is 50% by mass percent
Acrylic resin and the silicon oil modified acrylic resin of the Methylethyl that mass percent is 50%；Water-absorbing resin is by percent mass
The acrylamide-sodium acrylate copolymer group being 30% than the Acrylic Acid-sodium Acrylate Copolymers for 70% and mass percent
Become.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.8g.
Embodiment 6
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 68%；
Mannitol 32%；
Wherein, tackifying resin compositionss are by the polyvinyl alcohol-vinyl acetate co-polymer of mass percent 60% and quality
The composition of percentage ratio 40% ethylene-vinylacetate-vinyl alcohol copolymer.Every square metre of base material cloth 1 upper surface tack coat 5
Quality is 3.5g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 72%；
Porous silica 28%；
Wherein, the polyvinyl acetate that resin combination is 40% by mass percent and mass percent are 60%
Sodium carboxymethyl cellulose forms.The quality of every square metre of base material cloth 1 upper channel layer 4 is 1.5g.
Cellulose that porous layer 3 is 73% by mass percent, mass percent are that 20% cationic modified starch leads to
Cross the reaction of isocyanates that mass percent is 7% to be obtained, the carboxymethyl cellulose that cellulose is 80% by mass percent and
Mass percent is 20% hydroxyethyl cellulose composition, hdi and percent mass that isocyanates are 20% by mass percent
Than the PPDI composition for 80%.On every square metre of base material cloth 1, the quality of porous layer 3 is 4.6g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 65%；
Calcium Carbonate 35%；
Wherein, resin combination is 55% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 45%, the dimethicone modification that organosilicon modified crylic acid resin is 30% by mass percent
Acrylic resin and the modified acrylic resin of vinyl silicone oil that mass percent is 70%；Water-absorbing resin is by mass percent
Carboxymethyl cellulose-acrylate copolymer for 68% and the acrylic amide-acrylic sodium copolymerization that mass percent is 32%
Thing forms.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.5g.
Embodiment 7
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 58%；
Sucrose 42%；
Wherein, tackifying resin compositionss are by the polyvinyl alcohol-vinyl acetate co-polymer of mass percent 24% and quality
The composition of percentage ratio 76% sodium carboxymethyl cellulose.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 4.2g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 63%；
Porous silica 37%；
Wherein, resin combination is 50% by mass percent ethylene-vinyl alcohol-acetate ethylene copolymer and quality
Percentage ratio is 50% cellulose composition.The quality of every square metre of base material cloth 1 upper channel layer 4 is 1.8g.
Starch that porous layer 3 is 64% by mass percent, mass percent are 30% cation-modified polyacrylamide
The isocyanates reaction that amine is 6% by mass percent is obtained, and cation-modified polyacrylamide by mass percent is
The polyacrylamide homo polymer of 80% cationization and polyacrylamide -2-(Acryloyloxy)ethanol copolymerization that mass percent is 20%
Thing composition, the ipdi that isocyanates are 10% by mass percent and the PPDI group that mass percent is 90%
Become, the cation reagent used by cationization is dimethylamino propyl acrylamide hydrochlorate-acrylamide copolymer.Every square
On the base material cloth 1 of rice, the quality of porous layer 3 is 4.7g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 57%；
Silicon dioxide 43%；
Wherein, resin combination is 62% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 38%, the dimethicone modification that organosilicon modified crylic acid resin is 60% by mass percent
Acrylic resin and the modified acrylic resin of methyl phenyl silicone oil that mass percent is 40%；Water-absorbing resin is by percent mass
Than the carboxymethyl cellulose-acrylate copolymer for 84% and acrylic amide-acrylic sodium that mass percent is 16% more altogether
Polymers forms.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.6g.
Embodiment 8
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 67%；
Pentite 33%；
Wherein, tackifying resin compositionss are by the ethylene-vinylacetate-vinyl alcohol copolymer of mass percent 19% and matter
The composition of amount percentage ratio 81% sodium carboxymethyl cellulose.The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 4.7g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 64%；
Porous silica 36%；
Wherein, resin combination is 12% by mass percent vinyl alcohol-vinyl acetate copolymer and percent mass
Than the sodium carboxymethyl cellulose composition for 88%.The quality of every square metre of base material cloth 1 upper channel layer 4 is 2.8g.
Sodium carboxymethyl cellulose that porous layer 3 is 68% by mass percent, mass percent are that 25% cation changes
Property polyacrylamide by mass percent be 7% isocyanates reaction be obtained, cation-modified polyacrylamide is by quality
Percentage ratio is the polyacrylamide homo polymer of 30% cationization and polyacrylamide-acrylic acid hydroxyl that mass percent is 70%
Methacrylate copolymers form, and the hdi that isocyanates are 50% by mass percent and mass percent are 50% to benzene two isocyanide
Acid esters forms, and the cation reagent used by cationization is n, n, n- trimethyl -2- (2- methyl isophthalic acid-oxo -2- acrylic oxygen
Base) ethyl ammonium chloride-acrylamide copolymer.On every square metre of base material cloth 1, the quality of porous layer 3 is 4.0g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 44%；
Kieselguhr 56%；
Wherein, resin combination is 65% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 35%, the vinyl silicone oil modification that organosilicon modified crylic acid resin is 48% by mass percent
Acrylic resin and the modified acrylic resin of methyl phenyl silicone oil that mass percent is 52%；Water-absorbing resin is by percent mass
Carboxymethyl cellulose-the acrylic ester copolymer being 24% than the Acrylic Acid-sodium Acrylate Copolymers for 76% and mass percent
Thing forms.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.7g.
Embodiment 9
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 62%；
Glucose 38%；
Wherein, the poly- second that tackifying resin compositionss are 62% by the polyvinyl alcohol of mass percent 23%, mass percent
The ethylene-vinylacetate-vinyl alcohol copolymer composition of enol-vinyl acetate co-polymer and mass percent 15%.Often put down
The quality of the base material cloth 1 upper surface tack coat 5 of square rice is 3.3g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 58%；
Porous silica 42%；
Wherein, the polyvinyl acetate that resin combination is 20% by mass percent and mass percent are 80%
Cellulose forms.The quality of every square metre of base material cloth 1 upper channel layer 4 is 2.3g.
Cellulose that porous layer 3 is 72% by mass percent, mass percent are 20% cation-modified polypropylene
The isocyanates reaction that amide is 8% by mass percent is obtained, and the carboxymethyl that cellulose is 50% by mass percent is fine
Dimension element and the hydroxypropyl cellulose composition that mass percent is 50%, cation-modified polyacrylamide by mass percent is
The polyacrylamide homo polymer of 50% cationization and polyacrylamide -2-(Acryloyloxy)ethanol copolymerization that mass percent is 50%
Thing composition, the ipdi that isocyanates are 90% by mass percent and the PPDI group that mass percent is 10%
Become.Cation reagent used by cationization is dimethylamino propyl acrylamide hydrochlorate-acrylamide copolymer.Every square
On the base material cloth 1 of rice, the quality of porous layer 3 is 4.4g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 58%；
Aluminium oxide 42%；
Wherein, resin combination is 59% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 41%, the Methylethyl that organosilicon modified crylic acid resin is 20% by mass percent is silicon oil modified
Acrylic resin and the modified acrylic resin of methyl phenyl silicone oil that mass percent is 80%；Water-absorbing resin is by quality hundred
Divide the Acrylic Acid-sodium Acrylate Copolymers for 83% for the ratio and cellulose-sodium acrylate copolymer group that mass percent is 17%
Become.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.7g.
Embodiment 10
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 70%；
Fructose 30%；
Wherein, the poly- second that tackifying resin compositionss are 50% by the polyvinyl alcohol of mass percent 30%, mass percent
The sodium carboxymethyl cellulose composition of enol-vinyl acetate co-polymer and mass percent 20%.On every square metre of base material cloth 1
The quality of surface binder layer 5 is 4.1g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 66%；
Porous silica 34%；
Wherein, resin combination is 30% by mass percent vinyl alcohol-vinyl acetate copolymer, percent mass
The polyvinyl acetate composition being 8% than the sodium carboxymethyl cellulose for 62% and mass percent.Every square metre of base material cloth 1
The quality of upper channel layer 4 is 1.7g.
Starch that porous layer 3 is 70% by mass percent, mass percent are 24% cation-modified polyacrylamide
The isocyanates reaction that amine is 6% by mass percent is obtained；Cation-modified polyacrylamide by mass percent is
The polyacrylamide homo polymer of 70% cationization and polyacrylamide -2-(Acryloyloxy)ethanol copolymerization that mass percent is 30%
Thing forms, the h that isocyanates are 65% by mass percent12Mdi and the PPDI group that mass percent is 35%
Become.Cation reagent used by cationization is dimethylamino propyl acrylamide hydrochlorate-acrylamide copolymer.Every square
On the base material cloth 1 of rice, the quality of porous layer 3 is 3.8g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 62%；
Calcium Carbonate 38%；
Wherein, resin combination is 56% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 44%, the Methylethyl that organosilicon modified crylic acid resin is 27% by mass percent is silicon oil modified
Acrylic resin and the modified acrylic resin of vinyl silicone oil that mass percent is 73%；Water-absorbing resin is by percent mass
Acrylamide-sodium acrylate copolymer and the matter being 25% than the Acrylic Acid-sodium Acrylate Copolymers for 50%, mass percent
Amount percentage ratio is 25% carboxymethyl cellulose-acrylate copolymer composition.Absorb water on every square metre of base material cloth 1 pervious bed
2 quality is 2.4g.
Embodiment 11
Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth, as shown in figure 1, including base material cloth 1, water suction from the bottom to top successively
Pervious bed 2, porous layer 3, channel layer 4, surface binder layer 5, surface binder layer 5 is meshy surface tack coat.
Surface binder layer 5 is calculated by mass percentage, and component and content are as follows respectively:
Tackifying resin compositionss 75%；
Volemitol 25%；
Wherein, tackifying resin compositionss are by the polyvinyl alcohol-vinyl acetate co-polymer of mass percent 22%, quality hundred
Divide the sodium carboxymethyl cellulose composition than the ethylene-vinylacetate-vinyl alcohol copolymer for 10% and mass percent 68%.
The quality of every square metre of base material cloth 1 upper surface tack coat 5 is 5.0g.
Channel layer 4 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 48%；
Porous silica 52%；
Wherein, resin combination is 40% by mass percent ethylene-vinyl alcohol-acetate ethylene copolymer, quality hundred
Point than the vinyl alcohol-vinyl acetate copolymer for 20% and cellulose that mass percent is 40% composition.Every square metre
The quality of base material cloth 1 upper channel layer 4 is 3.0g.
Cellulose that porous layer 3 is 64% by mass percent, mass percent are 28% cation-modified polypropylene
The isocyanates reaction that amide is 8% by mass percent is obtained；The ethoxy that cellulose is 60% by mass percent is fine
Dimension element and the hydroxypropyl cellulose composition that mass percent is 40%, cation-modified polyacrylamide by mass percent is
The polyacrylamide homo polymer of 58% cationization and polyacrylamide -2-(Acryloyloxy)ethanol copolymerization that mass percent is 42%
Thing forms, and the ipdi that isocyanates are 55% by mass percent and mass percent form for 45% PPDI.
Cation reagent used by cationization is n, n, n- trimethyl -2- (2- methyl isophthalic acid-oxo -2- acrylic epoxide) ethylmercury chloride
Ammonium-acrylamide copolymer.On every square metre of base material cloth 1, the quality of porous layer 3 is 4.3g.
Water suction pervious bed 2 is calculated by mass percentage, and component and content are as follows respectively:
Resin combination 56%；
Silicon dioxide 44%；
Wherein, resin combination is 67% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 33%, the Methylethyl that organosilicon modified crylic acid resin is 60% by mass percent is silicon oil modified
Acrylic resin and the modified acrylic resin of vinyl silicone oil that mass percent is 40%；Water-absorbing resin is by percent mass
The acrylamide-sodium acrylate copolymer group being 48% than the Acrylic Acid-sodium Acrylate Copolymers for 52% and mass percent
Become.On every square metre of base material cloth 1, the quality of water suction pervious bed 2 is 2.0g.
It is 24 DEG C～26 DEG C in temperature, under the conditions of relative humidity is 53%～57%, effect such as table 1 institute of each embodiment
Show:
| Embodiment | Drying time (second) | Print speed (m/h) |
| Reference examples 1 | 321 | 40～50 |
| Embodiment 1 | 30 | 500～1000 |
| Embodiment 2 | 12 | 600～1100 |
| Embodiment 3 | 40 | 700～1200 |
| Embodiment 4 | 35 | 800～1300 |
| Embodiment 5 | 51 | 900～1400 |
| Embodiment 6 | 45 | 900～1500 |
| Embodiment 7 | 8 | 1000～1600 |
| Embodiment 8 | 35 | 1000～1700 |
| Embodiment 9 | 17 | 1300～1800 |
| Embodiment 10 | 24 | 1400～1900 |
| Embodiment 11 | 12 | 1500～2000 |
In a word, the foregoing is only presently preferred embodiments of the present invention, all equalizations made according to scope of the present invention patent
Change and modification, all should belong to the covering scope of patent of the present invention.
Claims (10)
1. temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number cloth it is characterised in that including base material cloth (1) from the bottom to top successively, inhaling
Water pervious bed (2), porous layer (3), channel layer (4), surface binder layer (5), surface binder layer (5) is calculated by mass percentage,
Component and content are as follows respectively:
Tackifying resin compositionss 58～78%；
Polyhydric alcohol 22～42%；
Wherein, tackifying resin compositionss are polyvinyl alcohol-vinyl acetate co-polymer, ethylene-vinylacetate-vinyl alcohol copolymerization
Two or more combination any in thing, sodium carboxymethyl cellulose, polyvinyl alcohol.
2. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: hydroxyl in polyhydric alcohol
The number of base is 3～9.
3. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: every square metre
The quality of base material cloth (1) upper surface tack coat (5) is 3.0～5.0g.
4. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: channel layer (4)
Calculate by mass percentage, component and content are as follows respectively:
Resin combination 40～72%；
Porous silica 28～60%；
Wherein, resin combination is vinyl alcohol-vinyl acetate copolymer, ethylene-vinyl alcohol-acetate ethylene copolymer, poly-vinegar
Two or more combination any in vinyl acetate, sodium carboxymethyl cellulose, cellulose.
5. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: porous layer (3)
It is cellulose or sodium carboxymethyl cellulose or starch is mutual by isocyanate-crosslinked formation with cation-modified polyacrylamide
Wear network resin, or polyacrylamide or cellulose or sodium carboxymethyl cellulose pass through isocyanates with cationic modified starch
The interpenetrating network resin being cross-linked to form.
6. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: every square metre
The quality of base material cloth (1) upper channel layer (4) is 1.0～3.0g, and the quality of every square metre of the upper porous layer (3) of base material cloth (1) is
3.5～5.0g.
7. temperature sensitive viscosity according to claim 1 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: water suction pervious bed
(2) calculate by mass percentage, component and content are as follows respectively:
Resin combination 40～65%；
Porous mineral 35～60%；
Wherein, resin combination is 45～70% by mass percent organosilicon modified crylic acid resin and mass percent
Water-absorbing resin composition for 30～55%.
8. temperature sensitive viscosity according to claim 7 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: organic-silicon-modified
Acrylic resin is the silicon oil modified acrylic resin of the modified acrylic resin of dimethicone, Methylethyl, vinyl silicon
Any one in the modified acrylic resin of the modified acrylic resin of oil, methyl phenyl silicone oil or two kinds of combinations.
9. temperature sensitive viscosity according to claim 7 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: water-absorbing resin is
In Acrylic Acid-sodium Acrylate Copolymers, acrylamide-sodium acrylate copolymer, carboxymethyl cellulose-acrylate copolymer
Arbitrarily two or more combination, porous mineral is silicon dioxide or Calcium Carbonate or aluminium oxide or kieselguhr.
10. temperature sensitive viscosity according to claim 7 be dry type thermal dye sublimation transfer printing number cloth it is characterised in that: every square metre
The quality of the upper pervious bed (2) that absorbs water of base material cloth (1) be 2.0～3.0g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749024.6A CN106364202B (en) | 2016-08-28 | 2016-08-28 | Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610749024.6A CN106364202B (en) | 2016-08-28 | 2016-08-28 | Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106364202A true CN106364202A (en) | 2017-02-01 |
| CN106364202B CN106364202B (en) | 2019-02-05 |
Family
ID=57903636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610749024.6A Active CN106364202B (en) | 2016-08-28 | 2016-08-28 | Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106364202B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108360293A (en) * | 2017-12-28 | 2018-08-03 | 杭州润意科技有限公司 | Cylindrical composite film thermal sublimation transfer printing digital paper |
| CN111094492A (en) * | 2017-08-23 | 2020-05-01 | 可隆工业株式会社 | Adhesive composition, adhesive comprising the same, and preparation method thereof |
| CN118370462A (en) * | 2024-04-13 | 2024-07-23 | 九江正圣科技发展有限公司 | Preparation method of heat transfer printing pyrograph explosion-proof tempered glass photo frame and heat transfer printing pyrograph explosion-proof tempered glass photo frame |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102909982A (en) * | 2012-09-12 | 2013-02-06 | 浙江欧丽数码喷绘材料有限公司 | Waterproof PP(propene polymer) synthesized paper for ink-jet printing and preparation method thereof |
| JP2015016603A (en) * | 2013-07-10 | 2015-01-29 | 凸版印刷株式会社 | Thermal transfer sheet |
| CN204095228U (en) * | 2014-06-06 | 2015-01-14 | 杭州华大海天科技有限公司 | The digital cloth of high blotting calorimetric sublimation transfer |
| CN204451575U (en) * | 2014-12-30 | 2015-07-08 | 杭州华大海天科技有限公司 | The digital paper of a kind of tack quick-drying thermal dye sublimation transfer printing |
| CN104553431B (en) * | 2014-12-30 | 2019-03-12 | 杭州华大海天科技有限公司 | Self-adhesive quick-drying thermal sublimation transfer printing digital cloth |
-
2016
- 2016-08-28 CN CN201610749024.6A patent/CN106364202B/en active Active
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111094492A (en) * | 2017-08-23 | 2020-05-01 | 可隆工业株式会社 | Adhesive composition, adhesive comprising the same, and preparation method thereof |
| US11613679B2 (en) | 2017-08-23 | 2023-03-28 | Kolon Industries, Inc. | Adhesive composition, adhesive comprising same, and manufacturing method therefor |
| CN108360293A (en) * | 2017-12-28 | 2018-08-03 | 杭州润意科技有限公司 | Cylindrical composite film thermal sublimation transfer printing digital paper |
| CN108360293B (en) * | 2017-12-28 | 2021-04-02 | 杭州润意科技有限公司 | Cylindrical composite film thermal sublimation transfer printing digital paper |
| CN118370462A (en) * | 2024-04-13 | 2024-07-23 | 九江正圣科技发展有限公司 | Preparation method of heat transfer printing pyrograph explosion-proof tempered glass photo frame and heat transfer printing pyrograph explosion-proof tempered glass photo frame |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106364202B (en) | 2019-02-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106364202B (en) | Temperature-sensitive viscous instant-drying type thermal sublimation transfer printing digital cloth | |
| CN103397576B (en) | High ink absorption thermal sublimation transfer digital paper | |
| KR102218627B1 (en) | In-line digital printing system for textile materials | |
| CN104553431B (en) | Self-adhesive quick-drying thermal sublimation transfer printing digital cloth | |
| US9499000B2 (en) | Sublimation transfer paper for inkjet printing | |
| CN109367313A (en) | A kind of ultra-thin thermal dye sublimation transfer printing paper | |
| CN103381721B (en) | The digital paper of composite membrane quick-dry type thermal dye sublimation transfer printing | |
| CN106337321B (en) | Temperature sensitive viscosity is dry type thermal dye sublimation transfer printing number paper | |
| CN106379068B (en) | Instant-drying type thermal sublimation transfer printing digital PP paper | |
| CN106364205B (en) | That is dry type thermal dye sublimation transfer printing number paper | |
| CN109267363A (en) | Leather like coating glue surface oil-based ink digital printing process | |
| CN104928976A (en) | Preparation method of coating solution of printing paper, manufacturing process of printing paper and printing paper | |
| CN104553432B (en) | Self-adhesive quick-drying thermal sublimation transfer printing digital paper | |
| CN102616048A (en) | Digital dyeing and printing paper for silk and wool fabric, and preparation method thereof | |
| CN106245461B (en) | That is the high blotting calorimetric sublimation transfer number paper of dry type | |
| CN204451575U (en) | The digital paper of a kind of tack quick-drying thermal dye sublimation transfer printing | |
| CN201505610U (en) | Coating machine | |
| CN112227112A (en) | Processing method of thermal sublimation transfer paper with high absorption performance | |
| CN106394050B (en) | Instant-drying type thermal sublimation transfer printing digital PET film | |
| CN208558689U (en) | Environment-friendly type, which is pasted, shifts straight calico paper | |
| CN205997528U (en) | I.e. dry type thermal dye sublimation transfer printing number paper | |
| CN108867164A (en) | A kind of improvement macromolecule coating fluid and the preparation method and application thereof | |
| CN113263850B (en) | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof | |
| CN108360298A (en) | Spherical composite film heat sublimation transfer number paper | |
| KR101663078B1 (en) | Adhesion material with resisting dye migration and method for manufacturing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 311501 No. 599, Baiyun East Road, Tonglu Economic Development Zone, Hangzhou, Zhejiang Patentee after: Hangzhou Huada Haitian Technology Co.,Ltd. Address before: 311501 No. 599, Baiyun East Road, Tonglu Economic Development Zone, Hangzhou, Zhejiang Patentee before: HANGZHOU HYDROTECH Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder |