CN106351065A - Preparation method of antibacterial waterproof packaging paper - Google Patents

Preparation method of antibacterial waterproof packaging paper Download PDF

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Publication number
CN106351065A
CN106351065A CN201610743214.7A CN201610743214A CN106351065A CN 106351065 A CN106351065 A CN 106351065A CN 201610743214 A CN201610743214 A CN 201610743214A CN 106351065 A CN106351065 A CN 106351065A
Authority
CN
China
Prior art keywords
wpp
preparation
waterproof paper
paper packing
antibacterial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610743214.7A
Other languages
Chinese (zh)
Inventor
周恒永
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LONG LI DE PACKAGING AND PRINTING Co Ltd
Original Assignee
LONG LI DE PACKAGING AND PRINTING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LONG LI DE PACKAGING AND PRINTING Co Ltd filed Critical LONG LI DE PACKAGING AND PRINTING Co Ltd
Priority to CN201610743214.7A priority Critical patent/CN106351065A/en
Publication of CN106351065A publication Critical patent/CN106351065A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J101/00—Adhesives based on cellulose, modified cellulose, or cellulose derivatives
    • C09J101/02—Cellulose; Modified cellulose
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Packages (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a preparation method of antibacterial waterproof packaging paper. The preparation method comprises the following steps: preparation of waterproof packaging paper at first: adding a water repellent agent in a making process of conventional papermaking; successively adhering the prepared waterproof packaging paper through a thermoplastic adhesive; and dipping the adhered waterproof packaging paper in a tin nitride solution with certain concentration, washing and drying, dipping in a silver nitrate solution with certain concentration, and washing and drying to obtain the antibacterial waterproof paper. The antibacterial waterproof paper is high in waterproofness and antibacterial property, meanwhile is formed by compounding a plurality of layers of packaging paper, and therefore is high in strength, good in toughness, impact-resistant and high in stability.

Description

A kind of preparation method of antibacterial waterproof paper packing (WPP)
Technical field
The present invention relates to a kind of preparation method of antibacterial waterproof paper packing (WPP).
Background technology
In food packaging applications, we are most commonly that the plastic sheath bag paper made by polyethylene, and it makes the former of employing Material is plastics, has certain toxicity, in our daily uses, particularly some white collars working clan, and it is fixed to miss potter Take out, and take out retailer to scheme conveniently, cover a plastic bag in plastics or paper bowl, then food is placed on plastics In bag, general food its just processed also there is certain temperature, when these plastic bags meet high temperature, it will discharge Some noxious substances murder by poisoning consumer slowly.Meanwhile, some food, in order to be able to extend the shelf life, can increase packaging in outer layer Paper, its wrapping paper all has the effect of certain antibacterial, but effect is mostly undesirable, and its technics comparing of most of wrapping paper is multiple Miscellaneous, relative cost of manufacture also can increase.
Content of the invention
The purpose of the present invention is that provides a kind of waterproof, antibacterial characteristics strong, by multilamellar bag to solve the above problems Dress paper is composited the preparation method of antibacterial waterproof paper packing (WPP).
To achieve these goals, the present invention is achieved by the following technical solutions: a kind of antibacterial waterproof paper packing (WPP) Preparation method, comprises the following steps:
1) first prepare waterproof paper packing (WPP): add water repellent agent in the making of conventional papermaking；
2) waterproof paper packing (WPP) preparing is passed sequentially through Thermoplastic adhesive bonding；
3) again the waterproof paper packing (WPP) after bonding is immersed in certain density nitridation solution of tin, scrubbed, drying, then is immersed in In certain density silver nitrate solution more scrubbed, drying just obtains antibacterial waterproof paper.
Further, described water repellent agent by quality parts ratio be 50 parts of phenolic resin, 30 parts of alkyl ketene dimers and 20 parts of sulfite pulp compositions.
Further, described water repellent agent addition and paper slurry amount are 3-5:100 in mass ratio.
Especially, described antibacterial waterproof paper packing (WPP) is to be bonded by 1-5 layer waterproof paper packing (WPP).
Particularly, described Thermoplastic adhesive is made up of polyvinyl alcohol, cellulose, starch and multiple auxiliary agent, described Multigroup auxiliary agent is made up of the mixing of one or more of firming agent, coupling agent, toughener, viscosifier, filler, stabilizer.
Further, described antibacterial waterproof paper packing (WPP) be quality be 1000-1500g/, thickness be 2-5mm.
In sum the method have the advantages that the antibacterial waterproof paper packing (WPP) waterproof of the present invention, antibacterial characteristics are strong, It is composited through multi-layer packaging paper, intensity is high, good toughness, impact resistance, and stability is strong simultaneously.
Specific embodiment
Specific embodiment 1: a kind of preparation method of antibacterial waterproof paper packing (WPP), comprise the following steps: 1) first prepare waterproof bag Dress paper: add 3% water repellent agent in the making of conventional papermaking, water repellent agent is 50 parts of phenolic resin, 30 parts of alkyl by quality parts ratio Ketene dimer and 20 parts of sulfite pulp compositions；
2) prepare 3 waterproof paper packing (WPP)s are passed sequentially through Thermoplastic adhesive bonding, Thermoplastic adhesive is by polyethylene Alcohol, cellulose, starch and firming agent, coupling agent, toughener, viscosifier, filler mixing composition；
3) again the waterproof paper packing (WPP) after bonding is immersed in certain density nitridation solution of tin, scrubbed, drying, then is immersed in In certain density silver nitrate solution more scrubbed, drying just obtains antibacterial waterproof paper, and the antibacterial waterproof paper packing (WPP) of preparation is matter Measure as 1000g/, thickness is 2mm.
Specific embodiment 2: a kind of preparation method of antibacterial waterproof paper packing (WPP), comprise the following steps: 1) first prepare waterproof bag Dress paper: add 4% water repellent agent in the making of conventional papermaking, water repellent agent is 50 parts of phenolic resin, 30 parts of alkyl by quality parts ratio Ketene dimer and 20 parts of sulfite pulp compositions；
2) prepare 4 waterproof paper packing (WPP)s are passed sequentially through Thermoplastic adhesive bonding, Thermoplastic adhesive is by polyethylene Alcohol, cellulose, starch and firming agent, coupling agent, toughener, viscosifier, filler, stabilizer mixing composition；
3) again the waterproof paper packing (WPP) after bonding is immersed in certain density nitridation solution of tin, scrubbed, drying, then is immersed in In certain density silver nitrate solution more scrubbed, drying just obtains antibacterial waterproof paper, and the antibacterial waterproof paper packing (WPP) of preparation is matter Measure as 1200g/, thickness is 4mm.
Specific embodiment 3: a kind of preparation method of antibacterial waterproof paper packing (WPP), comprise the following steps: 1) first prepare waterproof bag Dress paper: add 5% water repellent agent in the making of conventional papermaking, water repellent agent is 50 parts of phenolic resin, 30 parts of alkyl by quality parts ratio Ketene dimer and 20 parts of sulfite pulp compositions；
2) prepare 5 waterproof paper packing (WPP)s are passed sequentially through Thermoplastic adhesive bonding, Thermoplastic adhesive is by polyethylene Alcohol, cellulose, starch and coupling agent, toughener, viscosifier mixing composition；
3) again the waterproof paper packing (WPP) after bonding is immersed in certain density nitridation solution of tin, scrubbed, drying, then is immersed in In certain density silver nitrate solution more scrubbed, drying just obtains antibacterial waterproof paper, and the antibacterial waterproof paper packing (WPP) of preparation is matter Measure as 1500g/, thickness is 5mm.
Embodiment provided above is the better embodiment of the present invention, is only used for the convenient explanation present invention, not to this Bright make any pro forma restriction, any those of ordinary skill in the art, if without departing from the carried skill of the present invention In the range of art feature, using the Equivalent embodiments locally changing done by disclosed technology contents or modify, and Without departing from the technical characteristic content of the present invention, all still fall within the range of the technology of the present invention feature.

Claims (7)

1. a kind of preparation method of antibacterial waterproof paper packing (WPP) it is characterised in that: comprise the following steps:
First prepare waterproof paper packing (WPP): add water repellent agent in the making of conventional papermaking；
The waterproof paper packing (WPP) preparing is passed sequentially through Thermoplastic adhesive bonding；
Again the waterproof paper packing (WPP) after bonding is immersed in certain density nitridation solution of tin, scrubbed, drying, then is immersed in one Determine in the silver nitrate solution of concentration, more scrubbed, dry just obtain antibacterial waterproof paper.
2. a kind of antibacterial waterproof paper packing (WPP) according to claim 1 preparation method it is characterised in that: described water repellent agent by Quality parts ratio is 50 parts of phenolic resin, 30 parts of alkyl ketene dimers and 20 parts of sulfite pulps form.
3. a kind of antibacterial waterproof paper packing (WPP) according to claim 1 preparation method it is characterised in that: described water repellent agent adds Entering amount with paper slurry amount is 3-5:100 in mass ratio.
4. a kind of antibacterial waterproof paper packing (WPP) according to claim 1 preparation method it is characterised in that: described antibacterial waterproof Wrapping paper is to be bonded by 1-5 layer waterproof paper packing (WPP).
5. a kind of antibacterial waterproof paper packing (WPP) according to claim 1 preparation method it is characterised in that: described thermoplastic cement Glutinous agent is made up of polyvinyl alcohol, cellulose, starch and multiple auxiliary agent.
6. a kind of antibacterial waterproof paper packing (WPP) according to claim 5 preparation method it is characterised in that: described multigroup auxiliary agent It is made up of the mixing of one or more of firming agent, coupling agent, toughener, viscosifier, filler, stabilizer.
7. a kind of antibacterial waterproof paper packing (WPP) according to claim 1 preparation method it is characterised in that: described antibacterial waterproof Wrapping paper is quality is 1000-1500g/, and thickness is 2-5mm.
CN201610743214.7A 2016-08-29 2016-08-29 Preparation method of antibacterial waterproof packaging paper Pending CN106351065A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610743214.7A CN106351065A (en) 2016-08-29 2016-08-29 Preparation method of antibacterial waterproof packaging paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610743214.7A CN106351065A (en) 2016-08-29 2016-08-29 Preparation method of antibacterial waterproof packaging paper

Publications (1)

Publication Number Publication Date
CN106351065A true CN106351065A (en) 2017-01-25

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107083723A (en) * 2017-06-29 2017-08-22 苏州安特实业有限公司 A kind of water repellent wrapping paper based on nanometer string and preparation method thereof
CN110143011A (en) * 2019-05-20 2019-08-20 刘佳秀 A kind of preparation method of antibacterial waterproof carton
CN110438843A (en) * 2019-07-11 2019-11-12 陕西科技大学 The antibacterial varnished wall paper and preparation method of reuse paper diaper leftover pieces fiber preparation
CN113661291A (en) * 2019-04-08 2021-11-16 花王株式会社 Antibacterial paper and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101037854A (en) * 2007-03-08 2007-09-19 武汉市江夏区江南实业有限公司 Waterproof packing cardboard and producing method thereof
KR101098771B1 (en) * 2010-08-10 2011-12-26 김해곤 Interior materials using silver grass and manufacturing method thereof
CN103255679A (en) * 2013-05-06 2013-08-21 金红叶纸业集团有限公司 Antibacterial mixed liquor, antibacterial paper and production process thereof
WO2015107089A1 (en) * 2014-01-14 2015-07-23 Instituto Tecnológico Del Embalaje, Transporte Y Logística (Itene) Antimicrobial compositions for food packaging consisting of salicylaldehyde and carvacrol, thymol or their mixture
CN105780590A (en) * 2016-03-07 2016-07-20 上海渊泉集币收藏品有限公司 Silver-loaded antibacterial paper and preparing method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101037854A (en) * 2007-03-08 2007-09-19 武汉市江夏区江南实业有限公司 Waterproof packing cardboard and producing method thereof
KR101098771B1 (en) * 2010-08-10 2011-12-26 김해곤 Interior materials using silver grass and manufacturing method thereof
CN103255679A (en) * 2013-05-06 2013-08-21 金红叶纸业集团有限公司 Antibacterial mixed liquor, antibacterial paper and production process thereof
WO2015107089A1 (en) * 2014-01-14 2015-07-23 Instituto Tecnológico Del Embalaje, Transporte Y Logística (Itene) Antimicrobial compositions for food packaging consisting of salicylaldehyde and carvacrol, thymol or their mixture
CN105780590A (en) * 2016-03-07 2016-07-20 上海渊泉集币收藏品有限公司 Silver-loaded antibacterial paper and preparing method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107083723A (en) * 2017-06-29 2017-08-22 苏州安特实业有限公司 A kind of water repellent wrapping paper based on nanometer string and preparation method thereof
CN113661291A (en) * 2019-04-08 2021-11-16 花王株式会社 Antibacterial paper and manufacturing method thereof
CN113661291B (en) * 2019-04-08 2023-08-22 花王株式会社 Antibacterial paper and manufacturing method thereof
CN110143011A (en) * 2019-05-20 2019-08-20 刘佳秀 A kind of preparation method of antibacterial waterproof carton
CN110438843A (en) * 2019-07-11 2019-11-12 陕西科技大学 The antibacterial varnished wall paper and preparation method of reuse paper diaper leftover pieces fiber preparation

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Application publication date: 20170125

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