CN106350943A - Modified impact-resistant composite weftless cloth and manufacturing method thereof - Google Patents

Modified impact-resistant composite weftless cloth and manufacturing method thereof Download PDF

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Publication number
CN106350943A
CN106350943A CN201610777226.1A CN201610777226A CN106350943A CN 106350943 A CN106350943 A CN 106350943A CN 201610777226 A CN201610777226 A CN 201610777226A CN 106350943 A CN106350943 A CN 106350943A
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China
Prior art keywords
parts
fiber
composite fibre
adhesive
laminated cloth
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CN201610777226.1A
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Chinese (zh)
Inventor
陈鹏
郭振勤
丁旭
任良元
陶锴
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JIANGSU LINRY NEW MSTAR TECHNOLOGY Ltd
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JIANGSU LINRY NEW MSTAR TECHNOLOGY Ltd
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Priority to CN201610777226.1A priority Critical patent/CN106350943A/en
Publication of CN106350943A publication Critical patent/CN106350943A/en
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/4291Olefin series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/593Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)

Abstract

The invention discloses modified impact-resistant composite weftless cloth which is composed of PE fiber, PBO fiber, a high-density polyethylene thin film and an adhesive. A weight ratio of the PBO fiber to the PE fiber is 1:9-3:7, and the adhesive is composed of, by weight, 70-80 parts of waterborne polyurethane, 15-25 parts of polyethylene glycol, 2-6 parts of rosin, 2-5 parts of plasticizer, 3-7 parts of diisooctyl phthalate, 2-3 parts of curing agent, 10-15 parts of defoamer, 5-8 parts of solvent oil, 5 parts of nano silica and 5 parts of nano silicon carbide. The PBO fiber is added into the PE fiber for composition, so that strength of the weftless cloth is improved, and tenacity and impact resistance of the weftless cloth are improved; nano silica and nano silicon carbide are added into the adhesive for modifying, so that average indentation degree of the weftless cloth is lowered greatly, and secondary injury to human body is reduced. The manufacturing method is simple in step and time saving, and the modified impact-resistant composite weftless cloth manufactured by the method is excellent in performance.

Description

A kind of modification shock resistance is combined laminated cloth and preparation method thereof
Technical field
The present invention relates to special fibre textile technology field, more particularly, to a kind of modification shock resistance is combined laminated cloth and its system Preparation Method.
Background technology
Pe fiber is the abbreviation of superhigh molecular weight polyethylene fibers, is that specific strength and specific modulus highest are fine in the world at present Dimension, its molecular weight 1,000,000~5,000,000 the spun fiber of polyethylene institute, because the impact resistance of this fiber is good, specific energy Absorb big, militarily can make protection dress material, the helmet, bullet resistant material, the such as armor facing of helicopter, tank and naval vessel Plate, the guard shield cover of radar, guided missile cover, flak jackets, Anti-assassinate clothes, shield etc., wherein induce one to note with the application of flak jackets the most Mesh.It has the advantages that soft, bulletproof effect be better than aramid fiber, become the majority fibers capturing U.S.'s bullet-proof vest market. In addition the ratio attack load value u/p of superhigh molecular weight polyethylene fibers composite is 10 times of steel, is glass fibre and aramid fiber More than 2 times.External shellproof, the anti-riot helmet made with this fibre-reinforced resin composite materials has become steel helmet and aramid fiber strengthens Composite helmet and making process thereof succedaneum.
Laminated cloth be using pe fiber be base material, through the uniform piddler of advanced high technology equipment, with high-strength elastic body resin Dipping gluing and thin film bonding, then form bullet resistant material through 0 °/90 ° biorthogonals are laminated, the shock resistance of laminated cloth with The proportioning of the preparation of pe fiber and adhesive has very big association.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of modification shock resistance and is combined laminated cloth and its system Preparation Method.
A kind of modification shock resistance proposed by the present invention is combined laminated cloth, thin by pe fiber, pbo fiber, high density polyethylene (HDPE) Film and adhesive composition.
Preferably, the weight of described pbo fiber and pe fiber is than between 1:9 to 3:7.
Preferably, described adhesive is made up of following weight portion: aqueous polyurethane 70-80 part, Polyethylene Glycol 15-25 part, Colophonium 2-6 part, plasticizer 2-5 part, diisooctyl phthalate 3-7 part, firming agent 2-3 part, defoamer 10-15 part, solvent Oily 5-8 part, 5 parts of nano silicon oxide, 5 parts of nanometer silicon carbide.
A kind of modification shock resistance is combined the preparation method of laminated cloth, and this preparation method comprises the following steps:
S1, by aqueous polyurethane, Polyethylene Glycol, Colophonium, plasticizer, diisooctyl phthalate, defoamer, solvent Oil, nano silicon oxide are received, stirring 15min is subsequently adding firming agent and is again stirring for 2min and obtains adhesive after the mixing of rice carborundum;
S2, obtains composite fibre after pe fiber is uniformly mixed in the same direction with pbo fiber, by composite fibre around being located at cylinder On, and cylinder is put into yarn unwinding rack enter to exercise composite fibre and tile on density polyethylene film with high, and after tiling terminates Brushing adhesive on polyethylene film, obtains polyethylene composite fibre film;
S3, by polyethylene composite fibre film after 35-60 DEG C of air-dried 15-20min, polyethylene composite fibre film is cut to The square polyethylene composite fibre film of 1mx1m, obtains unidirectional no latitude piece;
S4, unidirectional for 4-6 block no latitude piece is stacked, and so that the composite fibre on adjacent two layers no latitude piece is mutually perpendicular to, and Brushing adhesive between adjacent two layers no latitude piece;
S5, the no latitude piece after stacking puts into press at 120-130 DEG C, and under the conditions of pressure 2-3mpa, molding 15-25min obtains It is combined laminated cloth to modified shock resistance.
In the present invention, adding pbo fiber to be combined in pe fiber, thus increasing the intensity of laminated cloth, improve The toughness of laminated cloth and impact resistance, add nano silicon oxide and nanometer silicon carbide to be modified in adhesive, make laminated cloth Average depression degree substantially reduce, decrease the secondary injury to human body, with Colophonium, adhesive be modified using plasticizer, Substantially increase the viscosity of adhesive, maintain the elasticity of laminated cloth, facilitate the dispersion of impulsive force, improve the anti-of laminated cloth Impact, the addition of defoamer reduces the surface tension of adhesive, makes the surface of laminated cloth tend to smooth, improves laminated cloth Performance, the preparation method step of the present invention is simple, saves the time, the compound laminated cloth performance of the modified shock resistance preparing is excellent Good.
Specific embodiment
With reference to specific embodiment, the present invention is explained further.
Embodiment one
A kind of modification shock resistance is combined laminated cloth, by pe fiber, pbo fiber, density polyethylene film with high and adhesive group Become, for 1:9, adhesive is made up of the wherein weight of pbo fiber and pe fiber ratio following weight portion: 70 parts of aqueous polyurethane, gathers 15 parts of ethylene glycol, 2 parts of Colophonium, 2 parts of plasticizer, 3 parts of diisooctyl phthalate, 2 parts of firming agent, self-emulsifying type modified silicon oil 10 parts of defoamer, 5 parts of No. 120 solvent naphthas, 5 parts of nano silicon oxide, 5 parts of nanometer silicon carbide.
Its preparation method comprises the following steps:
S1, by 70 parts of aqueous polyurethane, 15 parts of Polyethylene Glycol, 2 parts of Colophonium, 2 parts of plasticizer, diisooctyl phthalate 3 parts, 5 parts of 10 parts, No. 120 solvent naphthas of self-emulsifying type modified silicon oil defoamer, nano silicon oxide receive 5 parts of 5 part, meter carborundum, mix After conjunction, stirring 15min is subsequently adding firming agent and is again stirring for 2min and obtains adhesive;
S2, obtains composite fibre after pe fiber is uniformly mixed in the same direction with pbo fiber, by composite fibre around being located at cylinder On, and cylinder is put into yarn unwinding rack enter to exercise composite fibre and tile on density polyethylene film with high, and after tiling terminates Brushing adhesive on polyethylene film, obtains polyethylene composite fibre film;
S3, by polyethylene composite fibre film after 35 DEG C of air-dried 15min, polyethylene composite fibre film is cut to 1mx1m Square polyethylene composite fibre film, obtain unidirectional no latitude piece;
S4,4 pieces of unidirectional no latitude pieces are stacked, and so that the composite fibre on adjacent two layers no latitude piece is mutually perpendicular to, and Brushing adhesive between adjacent two layers no latitude piece;
S5, the no latitude piece after stacking puts into press at 120 DEG C, and under the conditions of pressure 2mpa, molding 15min obtains modified resisting The compound laminated cloth of impact.
Embodiment two
A kind of modification shock resistance is combined laminated cloth, by pe fiber, pbo fiber, density polyethylene film with high and adhesive group Become, for 2:9, adhesive is made up of the wherein weight of pbo fiber and pe fiber ratio following weight portion: 75 parts of aqueous polyurethane, gathers 20 parts of ethylene glycol, 4 parts of Colophonium, 3 parts of plasticizer, 5 parts of diisooctyl phthalate, 2 parts of firming agent, self-emulsifying type modified silicon oil 13 parts of defoamer, 6 parts of No. 120 solvent naphthas, 5 parts of nano silicon oxide, 5 parts of nanometer silicon carbide.
Its preparation method comprises the following steps:
S1, by 75 parts of aqueous polyurethane, 20 parts of Polyethylene Glycol, 4 parts of Colophonium, 3 parts of plasticizer, diisooctyl phthalate 5 parts, 2 parts of firming agent, 6 parts of 13 parts, No. 120 solvent naphthas of self-emulsifying type modified silicon oil defoamer, 5 parts of nano silicon oxide, nano-sized carbon 5 parts of SiClx, after mixing, stirring 15min is subsequently adding firming agent and is again stirring for 2min and obtains adhesive;
S2, obtains composite fibre after pe fiber is uniformly mixed in the same direction with pbo fiber, by composite fibre around being located at cylinder On, and cylinder is put into yarn unwinding rack enter to exercise composite fibre and tile on density polyethylene film with high, and after tiling terminates Brushing adhesive on polyethylene film, obtains polyethylene composite fibre film;
S3, by polyethylene composite fibre film after 45 DEG C of air-dried 17min, polyethylene composite fibre film is cut to 1mx1m Square polyethylene composite fibre film, obtain unidirectional no latitude piece;
S4,5 pieces of unidirectional no latitude pieces are stacked, and so that the composite fibre on adjacent two layers no latitude piece is mutually perpendicular to, and Brushing adhesive between adjacent two layers no latitude piece;
S5, the no latitude piece after stacking puts into press at 125 DEG C, and under the conditions of pressure 3mpa, molding 20min obtains modified resisting The compound laminated cloth of impact.
Embodiment three
A kind of modification shock resistance is combined laminated cloth, by pe fiber, pbo fiber, density polyethylene film with high and adhesive group Become, for 3:7, adhesive is made up of the wherein weight of pbo fiber and pe fiber ratio following weight portion: 80 parts of aqueous polyurethane, gathers 25 parts of ethylene glycol, 6 parts of Colophonium, 5 parts of plasticizer, 7 parts of diisooctyl phthalate, 3 parts of firming agent, self-emulsifying type modified silicon oil 15 parts of defoamer, 8 parts of No. 120 solvent naphthas, 5 parts of nano silicon oxide, 5 parts of nanometer silicon carbide.
Its preparation method comprises the following steps:
S1, by 80 parts of aqueous polyurethane, 25 parts of Polyethylene Glycol, 6 parts of Colophonium, 5 parts of plasticizer, diisooctyl phthalate 7 parts, 3 parts of firming agent, 8 parts of 15 parts, No. 120 solvent naphthas of self-emulsifying type modified silicon oil defoamer, 5 parts of nano silicon oxide, nano-sized carbon 5 parts of SiClx, after mixing, stirring 15min is subsequently adding firming agent and is again stirring for 2min and obtains adhesive;
S2, obtains composite fibre after pe fiber is uniformly mixed in the same direction with pbo fiber, by composite fibre around being located at cylinder On, and cylinder is put into yarn unwinding rack enter to exercise composite fibre and tile on density polyethylene film with high, and after tiling terminates Brushing adhesive on polyethylene film, obtains polyethylene composite fibre film;
S3, by polyethylene composite fibre film after 60 DEG C of air-dried 20min, polyethylene composite fibre film is cut to 1mx1m Square polyethylene composite fibre film, obtain unidirectional no latitude piece;
S4,6 pieces of unidirectional no latitude pieces are stacked, and so that the composite fibre on adjacent two layers no latitude piece is mutually perpendicular to, and Brushing adhesive between adjacent two layers no latitude piece;
S5, the no latitude piece after stacking puts into press at 130 DEG C, and under the conditions of pressure 3mpa, molding 25min obtains modified resisting The compound laminated cloth of impact.
In the present invention, adding pbo fiber to be combined in pe fiber, thus increasing the intensity of laminated cloth, improve The toughness of laminated cloth and impact resistance, add nano silicon oxide and nanometer silicon carbide to be modified in adhesive, make laminated cloth Average depression degree substantially reduce, decrease the secondary injury to human body, with Colophonium, adhesive be modified using plasticizer, Substantially increase the viscosity of adhesive, maintain the elasticity of laminated cloth, facilitate the dispersion of impulsive force, improve the anti-of laminated cloth Impact, the addition of defoamer reduces the surface tension of adhesive, makes the surface of laminated cloth tend to smooth, improves laminated cloth Performance, the preparation method step of the present invention is simple, saves the time, the compound laminated cloth performance of the modified shock resistance preparing is excellent Good.
More than, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, and any Those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its invention Design in addition equivalent or change, all should be included within the scope of the present invention.

Claims (6)

1. a kind of modification shock resistance be combined laminated cloth it is characterised in that by pe fiber, pbo fiber, density polyethylene film with high and Adhesive forms.
2. a kind of modification shock resistance according to claim 1 is combined laminated cloth it is characterised in that described pbo fiber and pe The weight of fiber is than between 1:9 to 3:7.
3. according to claim 1 a kind of modification shock resistance be combined laminated cloth material it is characterised in that described adhesive by with Lower weight portion composition: aqueous polyurethane 70-80 part, Polyethylene Glycol 15-25 part, Colophonium 2-6 part, plasticizer 2-5 part, O-phthalic Sour di-isooctyl 3-7 part, firming agent 2-3 part, defoamer 10-15 part, solvent naphtha 5-8 part, 5 parts of nano silicon oxide, nano silicon carbide 5 parts of silicon.
4. a kind of modification shock resistance according to claim 3 is combined laminated cloth it is characterised in that described defoamer is from breast Change type modified silicon oil defoamer.
5. a kind of modification shock resistance according to claim 3 is combined laminated cloth it is characterised in that described solvent naphtha is boiling range 80~120 DEG C of No. 120 solvent naphthas.
6. a kind of modification shock resistance is combined the preparation method of laminated cloth it is characterised in that this preparation method comprises the following steps:
S1, by aqueous polyurethane, Polyethylene Glycol, Colophonium, plasticizer, diisooctyl phthalate, defoamer, solvent naphtha, receives Rice silicon oxide is received, stirring 15min is subsequently adding firming agent and is again stirring for 2min and obtains adhesive after the mixing of rice carborundum;
S2, obtains composite fibre after pe fiber is uniformly mixed in the same direction with pbo fiber, by composite fibre around being located on cylinder, and Cylinder is put into yarn unwinding rack enter to exercise composite fibre and tile on density polyethylene film with high, and the polyethylene after tiling terminates Brushing adhesive on thin film, obtains polyethylene composite fibre film;
S3, by polyethylene composite fibre film after 35-60 DEG C of air-dried 15-20min, polyethylene composite fibre film is cut to The square polyethylene composite fibre film of 1mx1m, obtains unidirectional no latitude piece;
S4, unidirectional for 4-6 block no latitude piece is stacked, and so that the composite fibre on adjacent two layers no latitude piece is mutually perpendicular to, and in phase Brushing adhesive between adjacent two-layer no latitude piece;
S5, the no latitude piece after stacking puts into press at 120-130 DEG C, and under the conditions of pressure 2-3mpa, molding 15-25min is changed Property shock resistance be combined laminated cloth.
CN201610777226.1A 2016-08-30 2016-08-30 Modified impact-resistant composite weftless cloth and manufacturing method thereof Pending CN106350943A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876797A (en) * 2021-01-18 2021-06-01 上海仪耐新材料科技有限公司 Bulletproof radome and manufacturing method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1278566A (en) * 2000-07-13 2001-01-03 陈成泗 Making process, production equipment and application of high-performance composite no-weft PE fiber cloth
CN101016442A (en) * 2006-02-08 2007-08-15 宁波大学 Macromolecule adhesive for preparing high-strength polythene weftless fabric and preparing method thereof
US20100015406A1 (en) * 2005-05-16 2010-01-21 Ashok Bhatnagar Laminated felt articles
CN102535021A (en) * 2010-12-13 2012-07-04 宋锋 Process for manufacturing continuous non-woven cloth and cross cloth with more than two layers
CN102529242A (en) * 2011-12-16 2012-07-04 宁波荣溢化纤科技有限公司 Preparation method of ultra-high molecular weight polyethylene unidirectional (UD) fabric
CN105088536A (en) * 2015-07-06 2015-11-25 北京航天雷特机电工程有限公司 Preparation method of anti-sinking material in body armor
CN106281086A (en) * 2016-08-19 2017-01-04 济宁迅大管道防腐材料有限公司 A kind of refractory polyethylene anticorrosion adhesive tape and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1278566A (en) * 2000-07-13 2001-01-03 陈成泗 Making process, production equipment and application of high-performance composite no-weft PE fiber cloth
US20100015406A1 (en) * 2005-05-16 2010-01-21 Ashok Bhatnagar Laminated felt articles
CN101016442A (en) * 2006-02-08 2007-08-15 宁波大学 Macromolecule adhesive for preparing high-strength polythene weftless fabric and preparing method thereof
CN102535021A (en) * 2010-12-13 2012-07-04 宋锋 Process for manufacturing continuous non-woven cloth and cross cloth with more than two layers
CN102529242A (en) * 2011-12-16 2012-07-04 宁波荣溢化纤科技有限公司 Preparation method of ultra-high molecular weight polyethylene unidirectional (UD) fabric
CN105088536A (en) * 2015-07-06 2015-11-25 北京航天雷特机电工程有限公司 Preparation method of anti-sinking material in body armor
CN106281086A (en) * 2016-08-19 2017-01-04 济宁迅大管道防腐材料有限公司 A kind of refractory polyethylene anticorrosion adhesive tape and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876797A (en) * 2021-01-18 2021-06-01 上海仪耐新材料科技有限公司 Bulletproof radome and manufacturing method thereof

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Application publication date: 20170125