CN106348359B - A kind of decolorizing printing and dyeing waste water agent and preparation method thereof - Google Patents
A kind of decolorizing printing and dyeing waste water agent and preparation method thereof Download PDFInfo
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- CN106348359B CN106348359B CN201610904387.2A CN201610904387A CN106348359B CN 106348359 B CN106348359 B CN 106348359B CN 201610904387 A CN201610904387 A CN 201610904387A CN 106348359 B CN106348359 B CN 106348359B
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- sludge
- ink jet
- waste water
- jet printing
- printing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Water Treatment By Sorption (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of decolorizing printing and dyeing waste water agent and preparation method thereof, the decolorising agent is mainly made of black water ink jet printing pulp thickening object, 5-10 parts of sepiolite and 5-10 parts of calcium miberal powder that mass fraction is 80-90, preparation method are as follows: black water ink jet printing pulp thickening object is modulated into the pulpous state of certain solid content, and appropriate alkaline matter is added and is neutralized to neutrality；A certain amount of sepiolite is added into sludge and calcium miberal powder stirs evenly；Sludge is heated to 50-90 DEG C of dehydration while stirring, sludge is made to form bulk, takes off Chinese effluent；Blocky sludge hot is squeezed dry after being lower than 50% to moisture content；Sludge isolation air is heated to 350-700 DEG C of heat preservation 1-5h；Sludge is broken into graininess after being down to certain temperature, is prepared into decolorizing printing and dyeing waste water agent.The present invention realizes the extraction of high concentration black water ink jet printing waste liquor contamination object and resource utilization, and decolorization rate of wastewater can reach 95% or more, and can be recycled.
Description
Technical field
The invention belongs to environmental engineering technical field, in particular to a kind of decolorizing printing and dyeing waste water agent and its preparation side
Method.
Background technique
Dyeing waste water water quality is complicated, organic contamination weight, and containing a large amount of non-fixing dyes in waste water, coloration is high, color-variable
Change, waste water is difficult to decolorization, and actual production mostly uses chemical coagulation, absorption or ion-exchange to be handled.
Water-based ink is widely used because of its health, environmental protection, safe characteristic in every field.Currently, a large amount of modeling
Material packaging material uses water-based ink in stamp, printing more and more, produces in application process a certain amount of highly concentrated
Spend water-based ink stamp waste liquid.Contain the pollutants such as pigment, water soluble acrylic resin, alcohol, amine (ammonia) in this kind of stamp waste liquid,
Its content of organics is more, and coloration is high, pollution it is extremely serious (coloration: 30,000 times or more, CODCr: 100,000-50 ten thousand mg/L), it is difficult to locate
Reason.It generallys use the physico-chemical process such as Coagulation Method to be pre-processed, i.e., the dosing coagulant into waste liquid, pollutant is made to agglomerate shape
It at sludge, is separated by solid-liquid separation using the mechanical dehydrations method such as filters pressing, centrifugal dehydration, water outlet is carried out again at other chemistry or biology
It manages to qualified discharge.Since pollutant concentration is high in waste liquid, the sludge solid content of formation is up to 5-10%, and mud cake is aqueous after dehydration
Rate is still up to 80% or more.Landfill disposal is carried out usually as solid waste by the mud cake formed after mechanism filter-pressing or centrifugal dehydration,
It is easy to cause secondary pollution.
Summary of the invention
It is useless using a kind of preparation printing and dyeing of black water ink jet printing pulp thickening object that the purpose of the present invention is to provide a kind of
The method of water decolorant.
A kind of decolorizing printing and dyeing waste water agent, mainly by mass fraction be 80-90 black water ink jet printing pulp thickening object,
The calcium miberal powder composition of 5-10 parts of sepiolite and 5-10 part, preparation method are as follows: by black water ink jet printing pulp thickening object
It is modulated into the pulpous state sludge of certain solid content, and appropriate alkaline matter is added and is neutralized to neutrality；Quality percentage is added into sludge
Calcium miberal powder (in terms of over dry mud dry weight) than sepiolite and 5%-15% for 5%-15% stirs evenly；Sludge is added while stirring
Heat makes sludge form bulk, takes off Chinese effluent to 50-90 DEG C of dehydration；Blocky sludge hot is squeezed and is done after being lower than 50% to moisture content
It is dry；Sludge isolation air is heated to 350-700 DEG C of heat preservation 1-5h；Sludge is broken into graininess after being down to certain temperature, preparation
At decolorizing printing and dyeing waste water agent.
The invention has the following advantages that
A. the decolorising agent of high concentration black water ink jet printing pulp thickening object preparation is used for decolorizing printing and dyeing waste water, decoloration
Rate nearly 100%, and decolorization rate is fast；
B. decolorizing printing and dyeing waste water agent is prepared with high concentration black water ink jet printing pulp thickening object, realizes the money of solid waste
Sourceization utilizes, and has prevented sludge secondary pollution problem；
C. decolorising agent uses rear 450-750 DEG C of hot recycling, can be recycled, and effect is constant.
Specific embodiment
The present invention is further illustrated below by specific embodiment.
Embodiment 1
A kind of decolorizing printing and dyeing waste water agent, mainly by mass fraction be 85 black water ink jet printing pulp thickening sludge,
10 parts of sepiolites and 5 parts of calcium miberal powder compositions.Preparation method are as follows: be modulated into black water ink jet printing waste liquid acid out sludge solid
The pulpous state of content 10%, and alkaline matter is added and is neutralized to neutrality；The sepiolite that mass percent is 11.8% is added into sludge
And 5.9% calcium miberal powder (in terms of over dry mud dry weight) stirs evenly, conditioning of mud specific gravity；Sludge is heated to 75 while stirring
DEG C dehydration, so that sludge is formed bulk, take off Chinese effluent；Blocky sludge hot is squeezed dry after being lower than 50% to moisture content；By sludge
Isolation air is heated to 500 DEG C of heat preservation 2h；It is broken into graininess after sludge cooling, is prepared into decolorizing printing and dyeing waste water agent.
The decolorising agent of preparation is added in cotton dyeing waste water by 8g/L waste water dosage, stirs 60min, precipitating goes to decontaminate
Mud particle, decolorization rate of wastewater 95.8%；After mud granule recycles 600 DEG C of hot recyclings, it can be recycled.
The decolorising agent of preparation is added in mao dyeing waste water by 10g/L waste water dosage, stirs 60min, precipitating removal
Mud granule, decolorization rate of wastewater 95.6%；After mud granule recycles 600 DEG C of hot recyclings, it can be recycled.
Using the method for the present invention, the high efficiency extraction and money of pollutant in high concentration black water ink jet printing waste liquid are realized
Sourceization utilizes, and has prevented secondary pollution, and decolorizing printing and dyeing waste water rate is made to reach 95% or more, and decolorization rate is fast, and particle is easily heavy
It forms sediment, opens the new way that solid wastes recycling utilizes.
Embodiment 2
A kind of decolorizing printing and dyeing waste water agent, mainly by mass fraction be 90 black water ink jet printing pulp thickening sludge, 8
Part sepiolite and 2 parts of calcium miberal powders compositions.Preparation method are as follows: black water ink jet printing waste liquid acid out sludge is modulated into and is contained admittedly
The pulpous state of amount 10%, and alkaline matter is added and is neutralized to neutrality；Added into sludge mass percent be 8.9% sepiolite and
2.3% calcium miberal powder (in terms of over dry mud dry weight) stirs evenly, conditioning of mud specific gravity；Sludge is heated to 70 DEG C while stirring
Dehydration, makes sludge form bulk, takes off Chinese effluent；Blocky sludge hot is squeezed dry after being lower than 50% to moisture content；By sludge every
Exhausted air is heated to 550 DEG C of heat preservation 2h；It is broken into graininess after sludge cooling, is prepared into decolorizing printing and dyeing waste water agent.
The decolorising agent of preparation is added in acrylic fibers dyeing waste water by 6g/L waste water dosage, stirs 60min, precipitating removal
Mud granule, decolorization rate of wastewater 99.8%；After mud granule recycles 600 DEG C of hot recyclings, it can be recycled.
The decolorising agent of preparation is added in cotton dyeing waste water by 10g/L waste water dosage, stirs 60min, precipitating removal
Mud granule, decolorization rate of wastewater 96.1%；After mud granule recycles 600 DEG C of hot recyclings, it can be recycled.
Using the method for the present invention, the high efficiency extraction and money of pollutant in high concentration black water ink jet printing waste liquid are realized
Sourceization utilizes, and has prevented secondary pollution, and cationic dyeing decolorization rate of wastewater is made to reach nearly 100%, reactive dyeing
96% or more decolorization rate of wastewater, decolorization rate is fast, and particle easily precipitates, and opens the new way that solid wastes recycling utilizes.
Embodiment 3
By 600 DEG C of hot recyclings of decolorising agent of recycling, it is useless that different fabrics printing and dyeings are added to by 10g/L waste water dosage respectively
In water, 60min is stirred, precipitating removal mud granule, up to 96.8%, hair decolorizing printing and dyeing waste water rate reaches cotton dyeing decolorization rate of wastewater
96.5%, acrylic fibers decolorizing printing and dyeing waste water rate is up to 99.9%, and decolorizing effect is without significant change.
Using the method for the present invention, both realized in high concentration black water ink jet printing waste liquid the high efficiency extraction of pollutant and
Resource utilization has prevented secondary pollution, opens the new way that solid wastes recycling utilizes, and can recycle.
Claims (1)
1. a kind of decolorizing printing and dyeing waste water agent, which is characterized in that mainly given up by the black water ink jet printing that mass fraction is 80-90
Liquid extract, 5-10 parts of sepiolite and 5-10 parts of calcium miberal powder composition, preparation method are as follows:
Black water ink jet printing pulp thickening object is modulated into the pulpous state sludge of certain solid content, and appropriate alkaline matter is added
It is neutralized to neutrality；
The calcium miberal powder that sepiolite and 5%-15% that mass percent is 5%-15% are added into sludge stirs evenly, the quality hundred
Divide ratio in terms of over dry mud dry weight；Sludge is heated to 70-90 DEG C of dehydration while stirring, sludge is made to form bulk, abjection water row
It puts；
Blocky sludge hot is squeezed dry after being lower than 50% to moisture content；
Sludge isolation air is heated to 350-700 DEG C of heat preservation 1-5h；
Sludge is broken into graininess after being down to certain temperature, is prepared into decolorizing printing and dyeing waste water agent；
Wherein, the black water ink jet printing pulp thickening object is acid out object；The calcium miberal powder is calcium carbonate, calcium oxide
Or mixtures thereof；The sepiolite specific gravity is greater than 1.2g/m3, particle is 200-500 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610904387.2A CN106348359B (en) | 2016-10-18 | 2016-10-18 | A kind of decolorizing printing and dyeing waste water agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610904387.2A CN106348359B (en) | 2016-10-18 | 2016-10-18 | A kind of decolorizing printing and dyeing waste water agent and preparation method thereof |
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| CN106348359A CN106348359A (en) | 2017-01-25 |
| CN106348359B true CN106348359B (en) | 2019-11-19 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101362073A (en) * | 2008-09-27 | 2009-02-11 | 山东大学 | Preparation method of acidification sludge bentonite granules |
| CN102205964A (en) * | 2011-04-25 | 2011-10-05 | 山东大学 | Granular activated carbon filler for paper mill sludge and preparation method thereof |
| CN103752274A (en) * | 2013-12-12 | 2014-04-30 | 西北农林科技大学 | Amphiprotic-Gemini type cationic composite adsorbent, and preparation method thereof |
-
2016
- 2016-10-18 CN CN201610904387.2A patent/CN106348359B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101362073A (en) * | 2008-09-27 | 2009-02-11 | 山东大学 | Preparation method of acidification sludge bentonite granules |
| CN102205964A (en) * | 2011-04-25 | 2011-10-05 | 山东大学 | Granular activated carbon filler for paper mill sludge and preparation method thereof |
| CN103752274A (en) * | 2013-12-12 | 2014-04-30 | 西北农林科技大学 | Amphiprotic-Gemini type cationic composite adsorbent, and preparation method thereof |
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| CN106348359A (en) | 2017-01-25 |
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