CN106346922B - A kind of automobile stretch-proof sizing level land blanket - Google Patents

A kind of automobile stretch-proof sizing level land blanket Download PDF

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Publication number
CN106346922B
CN106346922B CN201610663594.3A CN201610663594A CN106346922B CN 106346922 B CN106346922 B CN 106346922B CN 201610663594 A CN201610663594 A CN 201610663594A CN 106346922 B CN106346922 B CN 106346922B
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machine
product
sizing
parts
pet
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CN106346922A (en
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曹纯才
王江龙
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KUNSHAN TONGCHANG AUTOMOTIVE NEW MATERIALS Co Ltd
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KUNSHAN TONGCHANG AUTOMOTIVE NEW MATERIALS Co Ltd
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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
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    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
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    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/38Layered products comprising a layer of synthetic resin comprising epoxy resins
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    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60NSEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
    • B60N3/00Arrangements or adaptations of other passenger fittings, not otherwise provided for
    • B60N3/04Arrangements or adaptations of other passenger fittings, not otherwise provided for of floor mats or carpets
    • B60N3/048Arrangements or adaptations of other passenger fittings, not otherwise provided for of floor mats or carpets characterised by their structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558Impact strength, toughness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
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    • B32B2307/744Non-slip, anti-slip
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/08Cars
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

A kind of manufacturing method of automobile stretch-proof sizing level land blanket provided by the invention, includes the following steps:The manufacture of the PET carpet surface bed of materials;Sizing is cooled down, cut-parts processing after the completion of sizing;The manufacture of expansion buffer layer;The fitting of expansion buffer layer, compression molding;The manufacture of skid resistant course;Skid resistant course fitting sizing;Epoxy resin it is compound;The manufacture of antistatic layer;Antistatic layer it is compound;Polytetrafluoroethylene (PTFE) it is compound.The manufacturing method of the automobile stretch-proof sizing level land blanket, production cost is relatively low, and product hardness can be adjusted as required, and technological process is simple, convenient for being widely applied, carries out industrialized production.

Description

A kind of automobile stretch-proof sizing level land blanket
Technical field
The present invention relates to a kind of manufacturing methods of carpet, and in particular to a kind of manufacturer of automobile stretch-proof sizing carpet Method.
Background technology
Carpet is with the natural fibers such as cotton, fiber crops, hair, silk, grass or chemical synthetic fiber class raw material, manually or mechanic Skill is knitted, synthetic tuft or the ground laying being formed by weaving.It is beautiful with the traditional technique of long history in world wide One of art category.Be covered in the ground of house, hotel, gymnasium, show room, vehicle, ship, aircraft etc., be reduced noise, every Heat and decorative effect.There are many carpet sorting technique, have manual knotted carpet, hand woven plain weave carpet, hand by manufacturing process point Work tufted carpet, manual felt carpet, machine-made carpet;There are carpet, a heatable brick bed blanket, wall tapestry, prayer rug etc. by purposes point;There is wool by raw material point Carpet, silk rug, jute rug, chemical fibre carpet etc..
With the rapid development of economy, people's living standards continue to improve, automobile industry development is rapid, and people are to automobile Requirement be not only automobile quality in itself, function and appearance grace, the requirement to the upholstery of automobile is also increasingly It is high.
Existing automobile level land blanket generally answers the glue sizing of 50g in carpet back, reduces its extensibility, and re-glue technique Complexity is difficult to control product hardness, and temperature is high, and product hardness is too big, and temperature is low, and glue is not dried completely, influences product quality. In addition glue is volatile, and smell is big, does not meet environmental requirement.
And the present invention mixes low melting point polyester fiber with conventional polyester fiber, and carpet surface is manufactured by needling process Material is heated by baking oven, melts low melting point polyester fiber inside fabric, with conventional polyester fibres bond after cooling, is formed Tablet makes it have the carpet product of certain degree of hardness and extensibility, this is simple for process, easy to control, environmental protection.
Invention content
Above-mentioned to solve the problems, such as, the purpose of the present invention is to provide a kind of systems of automobile stretch-proof sizing level land blanket Method is made, the method production cost is relatively low, and product hardness can be adjusted as required, and technological process is simple, be pushed away convenient for large area Extensively, industrialized production is carried out.
In order to achieve the above objectives, the technical solution adopted by the present invention is:
A kind of automobile stretch-proof sizing level land blanket, including the PET carpet surface bed of materials, the PET carpet surfaces bed of material includes weight Than the common PET fiber and 10% low-melting point PET fiber for 90%, low melting point polyester fiber is combined with conventional polyester fiber, Low-melting fiber plays adhesive effect, and conventional polyester fiber is material of main part, and low-melting fiber is after high temperature melt and common fine Tie up bonding, carpet material of the formation with certain degree of hardness and extensibility;The thickness of the PET carpet surfaces bed of material is 0.5~0.8 mm;The front of the PET carpet surfaces bed of material is equipped with erosion resistant coating, and the thickness of the erosion resistant coating is 0.1~0.2 mm, the erosion resistant coating For epoxy resin layer;The back side of the PET carpet surfaces bed of material is equipped with expansion buffer layer, and the thickness of the expansion buffer layer is 0.2 ~0.3 mm, the expansion buffer layer include following weight proportion raw material:
Polyurethane:40~50 parts, PET:20~30 parts, carbon nano-fiber:2~4 parts, bentonite:1~2 part, white oil:1~ 2 parts, citric acid:0.5~1 part, vinyltrimethoxysilane:0.4~0.8 part, sebacic acid dioctyl ester:2~3 parts, shock resistance Modifying agent:1~2 part.
Further, the anti-impact modifier is styrol copolymer.
Further, the back side of the expansion buffer layer is equipped with skid resistant course, and the thickness of the skid resistant course is 0.2~0.4 mm; The skid resistant course is equipped with anti-skid chequer;The skid resistant course includes following weight proportion raw material:
Epoxy resin:40~50 parts, polyurethane:50~60 parts, white oil:1~2 part, citric acid:0.1~1 part, coupling agent: 0.5~1 part;Fire retardant:0.1~1 part;Antiseptic:1~2 part;Plasticizer:1~2 part;Stabilizer:0.5~0.8 part;Xiang Rong Agent:1~2 part;Curing agent:0.1~1 part.
Further, the front of the erosion resistant coating be equipped with antistatic layer, the antistatic layer be PP film layers, the antistatic layer Including following weight proportion raw material:
PP:80~100 parts;Antistatic agent:5~10 parts;Vinyltrimethoxysilane:0.5~1 part;White oil:2~3 Part;Citric acid:0.1~1 part;Calcium carbonate:0.8~1.5 part.
Further, the coupling agent is gamma-aminopropyl-triethoxy-silane;The fire retardant is DMMP and pentaerythrite Mixture;The antiseptic is tea tree ethereal oil;The plasticizer is diethylene glycol dibenzoate;The stabilizer is Ca Zn composite Stabilizer and pentaerythrite composition by weight ratio are 1:2 mixture;The phase flux is maleic anhydride inoculated polypropylene PP-g- MAH;The curing agent is trimethylhexamethylenediamine.
Coupling agent of the present invention is a kind of organo silane coupling agent, can reduce the viscosity of molten synthetic resin, and improvement is filled out The dispersion degree of agent is filled to improve processing performance, and then product is made to obtain good surface quality and machinery, heat and electrical property etc., and And for the coupling agent is compared to some metal coupling agents, itself is more environmentally-friendly;The antiseptic has good antibacterial property, can To prevent the growth of bacterium, extend the service life of carpet;And by the way that diethylene glycol dibenzoate is added to waterproof and oilproof Enhance its plasticizing effect in layer, also enhance its flexibility, be more prone to process;
The present invention, which adds in the stabilizer, can so that bonding skid resistant course property more stablizes, and prevents it from decomposing, aging, together When calcium-zinc composite stabilizing agent compared to stabilizers such as some other metallic lead classes for, not only stablizing effect is good, at the same it is also nontoxic, After environmental protection and pentaerythrite mixing, stablizing effect can be further enhanced;The phase flux can greatly improve composite wood The compatibility of material and the dispersibility of filler, so as to improve composite material machinery intensity, and substance itself is nontoxic;By adding Curing reaction speed can be promoted by stating curing agent, reduce the reaction time, while trimethylhexamethylenediamine can also rise in itself To the effect for the wearability and mechanical strength for improving product, and its is cheap, nontoxic.
Separately.The antistatic agent is ethoxylated alkyl acid amide class non-ionic antistatic agent.
Separately have, the front of the antistatic layer is equipped with waterproof ventilative layer, and the waterproof ventilative layer is polytetrafluoroethylene ethylene layer, institute The thickness for stating waterproof ventilative layer is 0.1~0.2 mm.
A kind of manufacturing method of automobile stretch-proof sizing level land blanket, includes the following steps:
A:The manufacture of the PET carpet surface bed of materials:By the common PET fiber and 10% low-melting point PET fiber that weight ratio is 90% It puts into and shredding is carried out in opener;Then by shredding, treated that PET fiber is put into blending box mixes;It then will be mixed It closes uniform PET fiber and is put into carding machine that carry out comb flat;PET fiber is sent in lapping machine after comb is flat and is spread Net, and it is paved into multi-layered web;PET fiber is sent in needing machine into the hand-manipulating of needle after lapping and pierces working process;Needle is pierced After product handled in rolls by lapper;By treated in rolls, product is sent into fluffing machine progress raising processing; Finally by raising, treated that product is crimped again by lapper can be prepared by the PET carpet surface bed of materials;
B:Product obtained in step A is sent into baking oven sizing, is cooled down after the completion of sizing, cut-parts processing;
C:The manufacture of expansion buffer layer:Dispensing is carried out by the formula, the material prepared is mixed evenly, Ran Houzai It is merged to obtain expansion buffer layer blend by colloidal sol machine;
D:The blend of the expansion buffer layer of molten condition is injected into the storage glue groove of gluing machine, it then will be in step B The back of obtained product is passed through above gluing machine storage glue groove, successively carries out gluing, scraper plate, traction, slice by gluing machine, most Fitting sizing is integrally formed afterwards, is then heated by forming machine, compression molding, wherein 200~220 DEG C of temperature, pressurize 90~100 seconds time;
E:The manufacture of skid resistant course:By it is described formula carry out dispensing, the material prepared is mixed evenly, then using Colloidal sol machine is merged to obtain skid resistant course blend;
F:The blend of the skid resistant course of molten condition is injected into the storage glue groove of gluing machine, then will be obtained in step D Product back pass through gluing machine storage glue groove above, successively by gluing machine carry out gluing, scraper plate, traction, slice, finally will Fitting sizing is integrally formed, and is then heated by forming machine, compression molding, wherein 200~220 DEG C of temperature, the dwell time 90~100 seconds, the skid resistant course surface embossed of product is handled finally by embossing machine;
G:Epoxy resin is effectively combined with each other with the product front obtained in step F by blanching compounding machine, wherein Combined temp is 150~160 DEG C;
H:The manufacture of antistatic layer:Dispensing is carried out by formula, the material prepared is added in mixing machine and is mixed evenly, and is mixed It is 100~110 DEG C to close temperature, and incorporation time is 10~15 minutes, after mixing, is transferred in cooling and stirring machine 30~40 Stirring at low speed 5~10 minutes at DEG C, finally enter extruder be plasticized at 170~180 DEG C, pelletizing, finally be die cut, wind be It can;
I:Antistatic layer and the front for obtaining product in step G are effectively combined with each other by blanching compounding machine, Middle combined temp is 150~160 DEG C;
J:Polytetrafluoroethylene (PTFE) is effectively combined with each other with the product front obtained in step I by blanching compounding machine, Middle combined temp is 150~160 DEG C.
Further more, the temperature that colloidal sol machine is merged in the step C is 210~220 DEG C, the time of fusion is 10~15 min;The temperature that colloidal sol machine is merged in the step E is 190~200 DEG C, and the time of fusion is 12~18 min.
The beneficial effects of the present invention are:
(1)Manufacturing method of the present invention, the machine used all are all purpose instruments, and production cost is relatively low, and product is hard Degree can be adjusted as required, and technological process is simple, and therefore, the difficulty of production is relatively low, convenient for being widely applied, carry out industrial metaplasia Production.
(2)Automobile stretch-proof that the method for the present invention is prepared sizing level land blanket, by by low melting point polyester fiber with it is general Logical polyester fiber is combined together, and wherein low-melting fiber plays adhesive effect, and conventional polyester fiber is material of main part, and low melting point is fine Dimension is bonding with general fibre after high temperature melt, forms the carpet material with certain degree of hardness and extensibility.
(3)The automobile stretch-proof sizing level land blanket that the method for the present invention is prepared, the skid resistant course not only has good Antiskid effect, while by setting anti-skid chequer in anti-skidding layer surface, further increase the antiskid effect of the carpet;In addition, The problem of bacterium is easily grown in view of automotive interior inhibits the taste of carpet bacterium by adding antiseptic in skid resistant course It is raw.
(4)Automobile stretch-proof that the method for the present invention is prepared sizing level land blanket, by add erosion resistant coating, antistatic layer, The multifunction that expanding layer and waterproof ventilative layer etc. further realize carpet is buffered, meets consumer demand.
(5)The automobile stretch-proof sizing level land blanket that the method for the present invention is prepared, adhesion technique belong to mechanical heat bonding, into Unharmful substance volatilizees during type, and product itself is not in harmful substance, and VOC numerical value contents are relatively low, meet environmental requirement, The safe and healthy of rider is not influenced.
Description of the drawings
Fig. 1 is a kind of structure diagram of automobile stretch-proof sizing level land blanket in the embodiment of the present invention;
Wherein, 1 is skid resistant course, and 2 be buffering expanding layer, and 3 be the PET carpet surface bed of materials, and 4 be erosion resistant coating, and 5 be antistatic layer, 6 For waterproof ventilative layer.
Specific embodiment
Clear, complete description will be carried out to the technical solution in the embodiment of the present invention below, it is clear that described implementation Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiments obtained under the premise of creative work is not made belong to what the present invention protected Range.
Embodiment one
A kind of automobile stretch-proof sizing level land blanket, including the PET carpet surface bed of materials(3), the PET carpet surfaces bed of material(3)Packet Include the common PET fiber and 10% low-melting point PET fiber that weight ratio is 90%, the PET carpet surfaces bed of material(3)Thickness be 0.65 mm;The PET carpet surfaces bed of material(3)Front be equipped with erosion resistant coating(4), the erosion resistant coating(4)Thickness for 0.16 mm, The erosion resistant coating(4)For epoxy resin layer;The PET carpet surfaces bed of material(3)The back side be equipped with expansion buffer layer(2), it is described swollen Swollen buffer layer(2)Thickness for 0.25 mm, the expansion buffer layer(2)Including following weight proportion raw material:
Polyurethane:45 parts, PET:26 parts, carbon nano-fiber:3 parts, bentonite:1.6 parts, white oil:1.5 parts, citric acid: 0.8 part, vinyltrimethoxysilane:0.6 part, sebacic acid dioctyl ester:2.5 parts, anti-impact modifier:1.54 part.
Further, the anti-impact modifier is styrol copolymer.
Further, the expansion buffer layer(2)The back side be equipped with skid resistant course(1), the skid resistant course(1)Thickness be 0.3 mm;The skid resistant course(1)It is equipped with anti-skid chequer;The skid resistant course(1)Including following weight proportion raw material:
Epoxy resin:45 parts, polyurethane:54 parts, white oil:1.48 parts, citric acid:0.58 part, coupling agent:0.75 part;Resistance Fire agent:0.6 part;Antiseptic:1.56 part;Plasticizer:1.52 part;Stabilizer:0.64 part;Phase flux:1.57 part;Curing agent:0.5 Part.
Further, the erosion resistant coating(4)Front be equipped with antistatic layer(5), the antistatic layer(5)For PP film layers, institute State antistatic layer(5)Including following weight proportion raw material:
PP:90 parts;Antistatic agent:7 parts;Vinyltrimethoxysilane:0.76 part;White oil:2.52 part;Citric acid: 0.54 part;Calcium carbonate:1.1 part.
Further, the coupling agent is gamma-aminopropyl-triethoxy-silane;The fire retardant is DMMP and pentaerythrite Mixture;The antiseptic is tea tree ethereal oil;The plasticizer is diethylene glycol dibenzoate;The stabilizer is Ca Zn composite Stabilizer and pentaerythrite composition by weight ratio are 1:2 mixture;The phase flux is maleic anhydride inoculated polypropylene PP-g- MAH;The curing agent is trimethylhexamethylenediamine.
Separately.The antistatic agent is ethoxylated alkyl acid amide class non-ionic antistatic agent.
Separately have, the antistatic layer(5)Front be equipped with waterproof ventilative layer(6), the waterproof ventilative layer(6)For polytetrafluoro Pvdf layer, the waterproof ventilative layer(6)Thickness be 0.15 mm.
Again, the manufacturing method of a kind of automobile stretch-proof sizing level land blanket, includes the following steps:
A:The PET carpet surface bed of materials(3)Manufacture:By the common PET fiber and 10% low-melting point PET fibre that weight ratio is 90% Dimension, which is put into, carries out shredding in opener;Then by shredding, treated that PET fiber is put into blending box mixes;Then will Uniformly mixed PET fiber is put into carding machine comb and be put down;PET fiber is sent in lapping machine after comb is flat and is carried out Lapping, and it is paved into multi-layered web;PET fiber is sent in needing machine into the hand-manipulating of needle after lapping and pierces working process;By needle Product after thorn is handled in rolls by lapper;By treated in rolls, product is sent at fluffing machine progress raising Reason;Finally by raising, treated that product is crimped again by lapper can be prepared by the PET carpet surface bed of materials(3);
B:Product obtained in step A is sent into baking oven sizing, is cooled down after the completion of sizing, cut-parts processing;
C:Expansion buffer layer(2)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, so It is merged to obtain expansion buffer layer using colloidal sol machine afterwards(2)Blend;
D:By the expansion buffer layer of molten condition(2)Blend be injected into the storage glue groove of gluing machine, then by step B In the obtained back of product pass through above gluing machine storage glue groove, successively carry out gluing, scraper plate, traction, slice by gluing machine, Finally fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 210 DEG C of temperature, the dwell time 95 seconds;
E:Skid resistant course(1)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, Ran Houzai It is merged to obtain skid resistant course by colloidal sol machine(1)Blend;
F:By the skid resistant course of molten condition(1)Blend be injected into the storage glue groove of gluing machine, then will be in step D The back of the product arrived is passed through above gluing machine storage glue groove, successively carries out gluing, scraper plate, traction, slice by gluing machine, finally Fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 210 DEG C of temperature, the dwell time 95 Second, finally by embossing machine to the skid resistant course of product(1)Surface embossed processing;
G:Epoxy resin is effectively combined with each other with the product front obtained in step F by blanching compounding machine, wherein Combined temp is 155 DEG C;
H:Antistatic layer(5)Manufacture:Dispensing is carried out by formula, the material prepared is added in mixing machine and is mixed Even, mixing temperature is 105 DEG C, and incorporation time is 12 minutes, after mixing, is transferred in cooling and stirring machine the low speed at 35 DEG C Stirring 8 minutes, finally enter extruder be plasticized at 175 DEG C, pelletizing, finally cross cutting, winding;
I:By antistatic layer(5)It is effectively combined with each other by blanching compounding machine with the front for obtaining product in step G, Wherein combined temp is 155 DEG C;
J:Polytetrafluoroethylene (PTFE) is effectively combined with each other with the product front obtained in step I by blanching compounding machine, Middle combined temp is 155 DEG C.
Further more, the temperature that colloidal sol machine is merged in the step C is 215 DEG C, the time of fusion is 12 min;The step The temperature that colloidal sol machine is merged in rapid E is 195 DEG C, and the time of fusion is 15 min.
Embodiment two
A kind of automobile stretch-proof sizing level land blanket, including the PET carpet surface bed of materials(3), the PET carpet surfaces bed of material(3)Packet Include the common PET fiber and 10% low-melting point PET fiber that weight ratio is 90%, the PET carpet surfaces bed of material(3)Thickness be 0.5mm;The PET carpet surfaces bed of material(3)Front be equipped with erosion resistant coating(4), the erosion resistant coating(4)Thickness for 0.1 mm, institute State erosion resistant coating(4)For epoxy resin layer;The PET carpet surfaces bed of material(3)The back side be equipped with expansion buffer layer(2), the expansion Buffer layer(2)Thickness for 0.3 mm, the expansion buffer layer(2)Including following weight proportion raw material:
Polyurethane:42 parts, PET:28 parts, carbon nano-fiber:2 parts, bentonite:1 part, white oil:2 parts, citric acid:0.5 part, Vinyltrimethoxysilane:0.8 part, sebacic acid dioctyl ester:3 parts, anti-impact modifier:2 parts.
Further, the anti-impact modifier is styrol copolymer.
Further, the expansion buffer layer(2)The back side be equipped with skid resistant course(1), the skid resistant course(1)Thickness be 0.2 mm;The skid resistant course(1)It is equipped with anti-skid chequer;The skid resistant course(1)Including following weight proportion raw material:
Epoxy resin:40 parts, polyurethane:50 parts, white oil:1 part, citric acid:1 part, coupling agent:0.5 part;Fire retardant:0.2 Part;Antiseptic:1.2 part;Plasticizer:1.8 part;Stabilizer:0.5 part;Phase flux:1 part;Curing agent:1 part.
Further, the erosion resistant coating(4)Front be equipped with antistatic layer(5), the antistatic layer(5)For PP film layers, institute State antistatic layer(5)Including following weight proportion raw material:
PP:80 parts;Antistatic agent:5 parts;Vinyltrimethoxysilane:1 part;White oil:3 parts;Citric acid:0.2 part;Carbon Sour calcium:1.5 part.
Further, the coupling agent is gamma-aminopropyl-triethoxy-silane;The fire retardant is DMMP and pentaerythrite Mixture;The antiseptic is tea tree ethereal oil;The plasticizer is diethylene glycol dibenzoate;The stabilizer is Ca Zn composite Stabilizer and pentaerythrite composition by weight ratio are 1:2 mixture;The phase flux is maleic anhydride inoculated polypropylene PP-g- MAH;The curing agent is trimethylhexamethylenediamine.
Separately.The antistatic agent is ethoxylated alkyl acid amide class non-ionic antistatic agent.
Separately have, the antistatic layer(5)Front be equipped with waterproof ventilative layer(6), the waterproof ventilative layer is polytetrafluoroethyl-ne Alkene layer, the waterproof ventilative layer(6)Thickness be 0.1 mm.
Again, the manufacturing method of a kind of automobile stretch-proof sizing level land blanket, includes the following steps:
A:The PET carpet surface bed of materials(3)Manufacture:By the common PET fiber and 10% low-melting point PET fibre that weight ratio is 90% Dimension, which is put into, carries out shredding in opener;Then by shredding, treated that PET fiber is put into blending box mixes;Then will Uniformly mixed PET fiber is put into carding machine comb and be put down;PET fiber is sent in lapping machine after comb is flat and is carried out Lapping, and it is paved into multi-layered web;PET fiber is sent in needing machine into the hand-manipulating of needle after lapping and pierces working process;By needle Product after thorn is handled in rolls by lapper;By treated in rolls, product is sent at fluffing machine progress raising Reason;Finally by raising, treated that product is crimped again by lapper can be prepared by the PET carpet surface bed of materials(3);
B:Product obtained in step A is sent into baking oven sizing, is cooled down after the completion of sizing, cut-parts processing;
C:Expansion buffer layer(2)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, so It is merged to obtain expansion buffer layer using colloidal sol machine afterwards(2)Blend;
D:By the expansion buffer layer of molten condition(2)Blend be injected into the storage glue groove of gluing machine, then by step B In the obtained back of product pass through above gluing machine storage glue groove, successively carry out gluing, scraper plate, traction, slice by gluing machine, Finally fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 200 DEG C of temperature, the dwell time 100 seconds;
E:Skid resistant course(1)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, Ran Houzai It is merged to obtain skid resistant course by colloidal sol machine(1)Blend;
F:By the skid resistant course of molten condition(1)Blend be injected into the storage glue groove of gluing machine, then will be in step D The back of the product arrived is passed through above gluing machine storage glue groove, successively carries out gluing, scraper plate, traction, slice by gluing machine, finally Fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 220 DEG C of temperature, the dwell time 100 Second, finally by embossing machine to the skid resistant course of product(1)Surface embossed processing;
G:Epoxy resin is effectively combined with each other with the product front obtained in step F by blanching compounding machine, wherein Combined temp is 150 DEG C;
H:Antistatic layer(5)Manufacture:Dispensing is carried out by formula, the material prepared is added in mixing machine and is mixed Even, mixing temperature is 100 DEG C, and incorporation time is 10 minutes, after mixing, is transferred in cooling and stirring machine the low speed at 40 DEG C Stirring 10 minutes, finally enter extruder be plasticized at 180 DEG C, pelletizing, finally cross cutting, winding;
I:By antistatic layer(5)It is effectively combined with each other by blanching compounding machine with the front for obtaining product in step G, Wherein combined temp is 150 DEG C;
J:Polytetrafluoroethylene (PTFE) is effectively combined with each other with the product front obtained in step I by blanching compounding machine, Middle combined temp is 150 DEG C.
Further more, the temperature that colloidal sol machine is merged in the step C is 210 DEG C, the time of fusion is 15 min;The step The temperature that colloidal sol machine is merged in rapid E is 190 DEG C, and the time of fusion is 18 min.
Embodiment three
A kind of automobile stretch-proof sizing level land blanket, including the PET carpet surface bed of materials(3), the PET carpet surfaces bed of material(3)Packet Include the common PET fiber and 10% low-melting point PET fiber that weight ratio is 90%, the PET carpet surfaces bed of material(3)Thickness be 0.8 mm;The PET carpet surfaces bed of material(3)Front be equipped with erosion resistant coating(4), the erosion resistant coating(4)Thickness for 0.2 mm, institute State erosion resistant coating(4)For epoxy resin layer;The PET carpet surfaces bed of material(3)The back side be equipped with expansion buffer layer(2), the expansion Buffer layer(2)Thickness for 0.2 mm, the expansion buffer layer(2)Including following weight proportion raw material:
Polyurethane:50 parts, PET:20 parts, carbon nano-fiber:4 parts, bentonite:2 parts, white oil:1 part, citric acid:1 part, second Alkenyl trimethoxy silane:0.4 part, sebacic acid dioctyl ester:2 parts, anti-impact modifier:1 part.
Further, the anti-impact modifier is styrol copolymer.
Further, the expansion buffer layer(2)The back side be equipped with skid resistant course(1), the skid resistant course(1)Thickness be 0.4 mm;The skid resistant course(1)It is equipped with anti-skid chequer;The skid resistant course(1)Including following weight proportion raw material:
Epoxy resin:50 parts, polyurethane:60 parts, white oil:2 parts, citric acid:0.2 part, coupling agent:1 part;Fire retardant:0.8 Part;Antiseptic:2 parts;Plasticizer:1 part;Stabilizer:0.8 part;Phase flux:1.8 part;Curing agent:0.2 part.
Further, the erosion resistant coating(4)Front be equipped with antistatic layer(5), the antistatic layer(5)For PP film layers, institute State antistatic layer(5)Including following weight proportion raw material:
PP:100 parts;Antistatic agent:10 parts;Vinyltrimethoxysilane:0.5 part;White oil:2 parts;Citric acid:0.9 Part;Calcium carbonate:0.8 part.
Further, the coupling agent is gamma-aminopropyl-triethoxy-silane;The fire retardant is DMMP and pentaerythrite Mixture;The antiseptic is tea tree ethereal oil;The plasticizer is diethylene glycol dibenzoate;The stabilizer is Ca Zn composite Stabilizer and pentaerythrite composition by weight ratio are 1:2 mixture;The phase flux is maleic anhydride inoculated polypropylene PP-g- MAH;The curing agent is trimethylhexamethylenediamine.
Separately.The antistatic agent is ethoxylated alkyl acid amide class non-ionic antistatic agent.
Separately have, the antistatic layer(5)Front be equipped with waterproof ventilative layer(6), the waterproof ventilative layer(6)For polytetrafluoro Pvdf layer, the waterproof ventilative layer(6)Thickness be 0.2 mm.
Again, the manufacturing method of a kind of automobile stretch-proof sizing level land blanket, includes the following steps:
A:The PET carpet surface bed of materials(3)Manufacture:By the common PET fiber and 10% low-melting point PET fibre that weight ratio is 90% Dimension, which is put into, carries out shredding in opener;Then by shredding, treated that PET fiber is put into blending box mixes;Then will Uniformly mixed PET fiber is put into carding machine comb and be put down;PET fiber is sent in lapping machine after comb is flat and is carried out Lapping, and it is paved into multi-layered web;PET fiber is sent in needing machine into the hand-manipulating of needle after lapping and pierces working process;By needle Product after thorn is handled in rolls by lapper;By treated in rolls, product is sent at fluffing machine progress raising Reason;Finally by raising, treated that product is crimped again by lapper can be prepared by the PET carpet surface bed of materials(3);
B:Product obtained in step A is sent into baking oven sizing, is cooled down after the completion of sizing, cut-parts processing;
C:Expansion buffer layer(2)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, so It is merged to obtain expansion buffer layer using colloidal sol machine afterwards(2)Blend;
D:By the expansion buffer layer of molten condition(2)Blend be injected into the storage glue groove of gluing machine, then by step B In the obtained back of product pass through above gluing machine storage glue groove, successively carry out gluing, scraper plate, traction, slice by gluing machine, Finally fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 220 DEG C of temperature, the dwell time 90 seconds;
E:Skid resistant course(1)Manufacture:Dispensing is carried out by the formula, the material prepared is mixed evenly, Ran Houzai It is merged to obtain skid resistant course by colloidal sol machine(1)Blend;
F:By the skid resistant course of molten condition(1)Blend be injected into the storage glue groove of gluing machine, then will be in step D The back of the product arrived is passed through above gluing machine storage glue groove, successively carries out gluing, scraper plate, traction, slice by gluing machine, finally Fitting sizing is integrally formed, is then heated by forming machine, compression molding, wherein 200 DEG C of temperature, the dwell time 90 Second, finally by embossing machine to the skid resistant course of product(1)Surface embossed processing;
G:Epoxy resin is effectively combined with each other with the product front obtained in step F by blanching compounding machine, wherein Combined temp is 160 DEG C;
H:Antistatic layer(5)Manufacture:Dispensing is carried out by formula, the material prepared is added in mixing machine and is mixed Even, mixing temperature is 110 DEG C, and incorporation time is 15 minutes, after mixing, is transferred in cooling and stirring machine the low speed at 30 DEG C Stirring 5 minutes, finally enter extruder be plasticized at 170 DEG C, pelletizing, finally cross cutting, winding;
I:By antistatic layer(5)It is effectively combined with each other by blanching compounding machine with the front for obtaining product in step G, Wherein combined temp is 160 DEG C;
J:Polytetrafluoroethylene (PTFE) is effectively combined with each other with the product front obtained in step I by blanching compounding machine, Middle combined temp is 160 DEG C.
Further more, the temperature that colloidal sol machine is merged in the step C is 220 DEG C, the time of fusion is 10 min;The step The temperature that colloidal sol machine is merged in rapid E is 200 DEG C, and the time of fusion is 12 min.
A kind of automobile stretch-proof sizing level land blanket provided by the invention, by by low melting point polyester fiber and conventional polyester Fiber is combined together, and wherein low-melting fiber plays adhesive effect, and conventional polyester fiber is material of main part, and low-melting fiber passes through It is bonding with general fibre after high temperature melt, form the carpet material with certain degree of hardness and extensibility.Secondly, described one kind Automobile stretch-proof sizing level land blanket, the skid resistant course not only have good antiskid effect, while by being set in anti-skidding layer surface Anti-skid chequer is put, further increases the antiskid effect of the carpet;In addition, it is contemplated that automotive interior easily grows asking for bacterium Topic inhibits the growth of carpet bacterium by adding antiseptic in skid resistant course.Meanwhile a kind of automobile tension of the present invention Sizing level land blanket is stretched, by adding erosion resistant coating, antistatic layer, buffering expanding layer and waterproof ventilative layer etc. further realization carpet Multifunction, meet consumer demand.Furthermore a kind of automobile stretch-proof sizing level land blanket of the present invention, adhesion technique Belong to mechanical heat bonding, unharmful substance volatilizees in forming process, and product itself is not in harmful substance, VOC numerical value contents It is relatively low, meet environmental requirement, do not influence the safe and healthy of rider.In addition, manufacturing method of the present invention, the machine used All it is all purpose instrument, production cost is relatively low, and product hardness can be adjusted as required, and technological process is simple, therefore, the difficulty of production Spend it is relatively low, convenient for being widely applied, carry out industrialized production.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention In sharp claimed range.

Claims (2)

1. a kind of manufacturing method of automobile stretch-proof sizing level land blanket, which is characterized in that include the following steps;
A:The manufacture of the PET carpet surface bed of materials:By the common PET fiber and 10% low-melting point PET fiber input that weight ratio is 90% Shredding is carried out into opener;Then by shredding, treated that PET fiber is put into blending box mixes;Then it will mix equal Even PET fiber is put into carding machine comb and be put down;PET fiber is sent in lapping machine after comb is flat and carries out lapping, And it is paved into multi-layered web;PET fiber is sent in needing machine into the hand-manipulating of needle after lapping and pierces working process;Needle thorn is terminated Product afterwards is handled in rolls by lapper;By treated in rolls, product is sent into fluffing machine progress raising processing;Finally By raising, treated that product is crimped again by lapper can be prepared by the PET carpet surface bed of materials;
B:Product obtained in step A is sent into baking oven sizing, is cooled down after the completion of sizing, cut-parts processing;
C:The manufacture of expansion buffer layer:Dispensing is carried out by following weight proportion raw material:Polyurethane:40~50 parts, PET:20~30 Part, carbon nano-fiber:2~4 parts, bentonite:1~2 part, white oil:1~2 part, citric acid:0.5~1 part, vinyl trimethoxy Silane:0.4~0.8 part, sebacic acid dioctyl ester:2~3 parts, anti-impact modifier:1~2 part, the material prepared is mixed Uniformly, it is then merged to obtain expansion buffer layer blend using colloidal sol machine;
D:The blend of the expansion buffer layer of molten condition is injected into the storage glue groove of gluing machine, then will be obtained in step B Product back pass through gluing machine storage glue groove above, successively by gluing machine carry out gluing, scraper plate, traction, slice, finally paste It closes sizing to be integrally formed, then be heated by forming machine, compression molding, wherein 200~220 DEG C of temperature, the dwell time 90 ~100 seconds;
E:The manufacture of skid resistant course:Dispensing is carried out by following weight proportion raw material:Epoxy resin:40~50 parts, polyurethane:50~60 Part, white oil:1~2 part, citric acid:0.1~1 part, coupling agent:0.5~1 part;Fire retardant:0.1~1 part;Antiseptic:1~2 part; Plasticizer:1~2 part;Stabilizer:0.5~0.8 part;Phase flux:1~2 part;Curing agent:0.1~1 part, the material prepared is mixed Conjunction stirs evenly, and is then merged to obtain skid resistant course blend using colloidal sol machine;
F:The blend of the skid resistant course of molten condition is injected into the storage glue groove of gluing machine, the production that then will be obtained in step D The back of product is passed through above gluing machine storage glue groove, successively carries out gluing, scraper plate, traction, slice by gluing machine, finally will fitting Sizing is integrally formed, and is then heated by forming machine, compression molding, wherein 200~220 DEG C of temperature, and the dwell time 90~ 100 seconds, the skid resistant course surface embossed of product is handled finally by embossing machine;
G:Epoxy resin is effectively combined with each other with the product front obtained in step F by blanching compounding machine, wherein compound Temperature is 150~160 DEG C;
H:The manufacture of antistatic layer:Dispensing is carried out by following weight proportion raw material:PP:80~100 parts;Antistatic agent:5~10 Part;Vinyltrimethoxysilane:0.5~1 part;White oil:2~3 parts;Citric acid:0.1~1 part;Calcium carbonate:0.8~1.5 part, The material prepared is added in mixing machine and is mixed evenly, and mixing temperature is 100~110 DEG C, and incorporation time is 10~15 minutes, After mixing, stirring at low speed 5~10 minutes at 30~40 DEG C are transferred in cooling and stirring machine, extruder is finally entered and exists Plasticizing, pelletizing at 170~180 DEG C are finally die cut, wind;
I:Antistatic layer and the front for obtaining product in step G are effectively combined with each other by blanching compounding machine, wherein multiple It is 150~160 DEG C to close temperature;
J:Polytetrafluoroethylene (PTFE) is effectively combined with each other with the product front obtained in step I by blanching compounding machine, wherein multiple It is 150~160 DEG C to close temperature.
A kind of 2. manufacturing method of automobile stretch-proof sizing level land blanket according to claim 1, which is characterized in that the step The temperature that colloidal sol machine is merged in rapid C is 210~220 DEG C, and the time of fusion is 10~15 min;Colloidal sol in the step E The temperature that machine is merged is 190~200 DEG C, and the time of fusion is 12~18 min.
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