CN106338882A - Extreme ultraviolet multilayer film and production method thereof - Google Patents

Extreme ultraviolet multilayer film and production method thereof Download PDF

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Publication number
CN106338882A
CN106338882A CN201510962257.XA CN201510962257A CN106338882A CN 106338882 A CN106338882 A CN 106338882A CN 201510962257 A CN201510962257 A CN 201510962257A CN 106338882 A CN106338882 A CN 106338882A
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layer
array structure
zigzag
euv
multiplayer films
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CN106338882B (en
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姚舜
喻波
金春水
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Changguang Jizhi Optical Technology Co.,Ltd.
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Changchun Institute of Optics Fine Mechanics and Physics of CAS
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
    • G03F1/22Masks or mask blanks for imaging by radiation of 100nm or shorter wavelength, e.g. X-ray masks, extreme ultraviolet [EUV] masks; Preparation thereof
    • G03F1/24Reflection masks; Preparation thereof

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  • General Physics & Mathematics (AREA)
  • Optical Filters (AREA)

Abstract

The invention relates to the field of extreme ultraviolet multilayer films, and concretely discloses an extreme ultraviolet multilayer film and a production method thereof. The extreme ultraviolet multilayer film sequentially comprises a substrate, a plurality of periodic Si/Mo layers, a zigzag array structure layer and an infrared reflecting layer. The extreme ultraviolet multilayer film can effectively realize light split of infrared lights and extreme ultraviolet lights in order to realize spectroscopic purification of an extreme ultraviolet light source.

Description

A kind of multiplayer films in EUV and preparation method thereof
Technical field
The present invention relates to multiplayer films in EUV field, more particularly, to there is the extreme ultraviolet of infrared spectroscopy function The design of multilayer film and preparation.
Background technology
In recent years, extreme ultraviolet photolithographic (euv lithograph, euvl) technology is widely developed. Euvl is used 13.5nm wavelength light source as service band, is capable of more than ten nanometers, or even several receives The lithographic line width of rice, and then the great integrated level increasing integrated circuit, to the miniaturization of electronic equipment, Low-power consumption development is extremely important.
Extreme ultraviolet photolithographic equipment is typically made up of EUV light source, illuminator and projection objective.Wherein, EUV light source provides the extreme ultraviolet radiation needed for photolithographic exposure.There is high-power and high-purity spectrum EUV light source be the precondition realizing extreme ultraviolet photolithographic volume production, be also current extreme ultraviolet photolithographic skill One of difficult point of art.
At present, extreme ultraviolet radiation can be produced by synchrotron radiation and high-temperature high-density plasma radiation. In Practical Project, more had practical value based on the EUV light source of high-temperature high-density plasma radiation. According to the different excitation principles of plasma, EUV light source can be divided into discharge plasma again (discharge produced plasma, dpp) light source and laser plasma (laser produced Plasma, lpp) light source two types.The former excites plasma using interelectrode electrion, But because plasma distance electrode is nearer, inevitably hot injury is produced to electrode and fragment hits Hit, limit the application of dpp light source.The latter excites plasma using driving laser bombardment target, It is capable of high-power, stable extreme ultraviolet output, in recent years by extensive research and application. The lpp light source being applied to extreme ultraviolet lithography is typically by driving light source, target system and collection system Constitute.Wherein, drive light source general from the gas laser being capable of high-power output, such as co2 Laser instrument etc.;Target system is made up of target and target transmission mechanism, and common target has sn droplet target, Xe gas target etc.;Collection system is to collect the extreme ultraviolet light beam that plasma resonance goes out, and is converged To the device of intermediate focus (intermediate focus, if), generally use and be coated with extreme ultraviolet reflection The ellipsoid of film is collected mirror to realize this function.Meanwhile, in order to reduce fragment, extreme ultraviolet photolithographic is set The damage of standby middle illuminator, improves the spectral purity penetrating light, also can arrange in lpp light source and remove Fragment system and spectrum purification system etc..In lpp light source, collect, through ellipsoid, the light bag that mirror is collected Include extreme ultraviolet, DUV (deep ultraviolet, duv) and carry out the infrared of self-driven light source Light (infrared, ir).Wherein, the heat effect that infrared light produces can cause reflecting mirror in optical system Face deformation, strong influence image quality, meanwhile, the hot injury that infrared light causes also can significantly contract The service life of short system.In this regard, research worker proposes multiple solutions.
2009, a kind of multiplayer films in EUV covering balzed grating, of Dutch fom laboratory design Structure, is capable of the light splitting of infrared light and extreme ultraviolet, and then realizes the purification of light source light spectrum.
Content of the invention
It is contemplated that overcoming the defect of existing technology, in order to not affect mosi multilayer film to service band (13.5nm) reduce the reflectance of infrared band while reflectance, the invention provides a kind of tool There is the multiplayer films in EUV of infrared spectroscopy function.
For achieving the above object, the present invention employs the following technical solutions:
On the one hand, the invention provides a kind of multiplayer films in EUV, wherein, described multilayer film wraps successively Include: substrate, the si/mo layer in multiple cycle, zigzag array structure layer and infrared reflecting layer.This Bright proposing introduces zigzag array structure layer in mosi multilayer film upper surface, can be effectively realized red Outer light and the light splitting of extreme ultraviolet, and then realize the spectrum purification of EUV light source.Euv and ir is many Reflectance mechanism on tunic is different, and euv reflection is the superposition effect based on the reflection of periodic multilayer membrane interface Really, ir reflection is the high reflectance to ir wave band based on metal (as mo).When multi-layer film surface is deposited In one layer and the uneven infrared reflecting layer of multilamellar membrane interface, euv will reflect according to multilamellar membrane interface, Ir will reflect according to infrared reflecting layer.For example, when infrared reflecting layer and multilamellar membrane interface have a degree During angle (0 < a < 90), for equidirectional incident euv and ir, its reflected light will separate 2a degree. In addition, constituting structure sheaf using si material, the absorption to euv for the surface structure can also be reduced.Thus, The present invention proposes and introduces zigzag array structure layer in mosi multilayer film upper surface, realizes extreme ultraviolet The spectrum purification in source.
Yet another aspect, present invention also offers a kind of preparation method of multiplayer films in EUV, including step Rapid: s1, preparation substrate;S2, prepare the si/mo layer in multiple cycles on the substrate;S3, Zigzag array structure layer is prepared on described si/mo layer;S4, on described zigzag array structure layer Deposition infrared reflecting layer.
The beneficial effects of the present invention is: multiplayer films in EUV provided by the present invention can be effectively real Existing infrared light and the light splitting of extreme ultraviolet, and then realize the spectrum purification of EUV light source.And, this The impact inventing the reflectance to operation wavelength for the provided multiplayer films in EUV structure is less.
Brief description
Fig. 1 is the structural representation of the multiplayer films in EUV according to one embodiment of the invention.
Fig. 2 is the structure of the class triangular array of the multiplayer films in EUV according to one embodiment of the invention Schematic diagram.
Fig. 3 is multiplayer films in EUV according to embodiments of the invention 1-7 and comparative example 1 in extreme ultraviolet ripple The schematic diagram of the reflectance of section.
Fig. 4 is multiplayer films in EUV according to embodiments of the invention 1-7 and comparative example 1 to 10.6 μm The schematic diagram of the reflectance of infrared light.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with accompanying drawing And specific embodiment, the present invention will be described in further detail.It should be appreciated that it is described herein Specific embodiment is only in order to explain the present invention, and is not construed as limiting the invention.
On the one hand, as shown in accompanying drawing 1 of the present invention, multiplayer films in EUV provided by the present invention wraps successively Include substrate 1, the si/mo layer 2 in multiple cycles, zigzag array structure layer 3 and infrared reflecting layer 4. Si/mo layer 2 interface based on multiple cycles for the reflection of extreme ultraviolet, and the reflection of infrared light is based on red The ultimate principle of outer reflective layer 4.When the si/mo layer 2 of infrared reflecting layer 4 and multiple cycles has folder The light splitting of infrared light and extreme ultraviolet during angle, can be realized.So, the present invention proposed in multiple weeks The si/mo layer upper surface of phase introduces zigzag array structure layer, can be effectively realized infrared light and pole The light splitting of ultraviolet light, and then realize the spectrum purification of EUV light source;And, provided by the present invention The impact of the reflectance to operation wavelength for the multiplayer films in EUV structure is less.Si/mo of the present invention Dividing of si and mo out-of-order in layer, can be si/mo layer or mo/si layer, bi-material replaces heap Folded.Preferably, the surface of si/mo layer multi-layer film of the present invention is mo, prepares thereon afterwards Zigzag array structure layer.
In some embodiments, described substrate is silicon chip, fused quartz, devitrified glass, super-low expansion quartz One or more of glass.Wherein, super-low expansion quartz glass, ule (ultra-low expansion), I.e. ultra-low thermal expansion glass.
In some embodiments, described multilayer film has the si/mo layer in 40-50 cycle.Above-mentioned technology In scheme, described periodic multilayer film is the periodic multilayer film having mo and si bi-material to constitute. Specifically, the thickness of each cycle si/mo layer can be determined by operation wavelength and operating angle, preferably 6.5nm-7.3nm, more preferably 7nm.Described si/mo layer can be by magnetron sputtering or ion beamlet The film plating process such as sputtering are realized.
In some embodiments, the thickness of the si/mo layer in each cycle is 6.5nm-7.3nm, and described every The thickness of mo material described in the si/mo layer in individual cycle accounts for the 35%-45% of described si/mo thickness degree, Further, the thickness of described mo material accounts for the 40% about of si/mo layer periodic thickness, i.e. γ-value For 0.4 about.
In some embodiments, described zigzag array structure layer can for class triangular array structure and/or Undulating array structure.Multiplayer films in EUV in one embodiment is shown according to Fig. 1 of the present invention The structure of class triangular array.
In some embodiments, described zigzag array structure layer is zigzag oldered array structure or sawtooth Shape disordered array structure.
In some embodiments, described zigzag oldered array structure by photoetching, glancing angle deposition technology, Nano impression or diamond cutting cutting method are realized.Wherein, described oldered array structure also can pass through graze Angle deposition technique is realized, but need to assist other technologies, such as pre- glove etc..
In some embodiments, described zigzag disordered array structure pass through photoetching, glancing angle deposition technology, Nano impression or diamond cutting cutting method are realized.
In some embodiments, described zigzag array structure layer is made up of si material, described zigzag battle array Array structure layer is 10 ° -80 ° with the angle at the inclination angle of described si/mo layer, and described zigzag array The height of structure sheaf is 45nm-55nm.Further, the thickness of described zigzag array structure layer Thickness is 50nm.Described zigzag array structure layer is formed on the surface of si/mo layer has homogeneous inclination The inclined-plane array of angle, so that the multiplayer films in EUV of the present invention is capable of infrared light and extremely purple The light splitting of outer light, and then realize the spectrum purification of EUV light source, and multiplayer films in EUV structure pair The impact of the reflectance of operation wavelength is less.Zigzag array structure layer described above and described si/mo The angular range at the inclination angle of layer can not only meet and can divide open infrared light with euv in certain distance, And it is easy to operate.If the thickness thickness of zigzag array structure layer described above is more than 55nm, Euv absorption loss water can be led to excessive;If being less than 45nm, microstructure unit density is big, and light splitting is imitated Really relatively weak.Under thickness certain condition, inclination angle is larger, then zigzag cellular construction is too small, point Cloth density is big, processes relative difficulty, and the reflectance of euv is affected big;Inclination angle is excessive, incident Light is almost glancing incidence, or even negative incidence degree, infrared reflectance reduction.
In some embodiments, described infrared reflecting layer is by one or more of mo, ru, ti or zr Composition, and the thickness of described outer red reflex layer is 4.5nm-5.5nm.Preferably, described infrared reflecting layer It is made up of mo.Periodic multilayer film is the basis realizing euv reflection, but infrared light is had simultaneously Stronger reflection, by the zigzag array structure layer micro structure on surface be capable of euv with infrared Reflection direction is different.If being used ru as infrared reflecting layer, the multiplayer films in EUV that the present invention provides is also There is certain oxidation resistance.
On the other hand, present invention also offers a kind of preparation method of multiplayer films in EUV, including step: S1, preparation substrate;S2, prepare the si/mo in multiple cycles on the substrate using magnetron sputtering method Layer;S3, on described si/mo layer prepare zigzag array structure layer;S4, utilize magnetron sputtering method Infrared reflecting layer is deposited on described zigzag array structure layer.
Specifically, in an embodiment, the preparation method of multiplayer films in EUV of the present invention can be wrapped Include step, step 1, preparation fused quartz substrate 1, roughness 0.2nm;Step 2, splashed using magnetic control Penetrate preparation 40 period m o/si layers 2, cycle 7nm, γ-value 0.4;Step 3, utilize glancing angle deposition Technology, the si nano wire having 30 ° of inclinations angle in multi-layer film surface deposition forms class triangular array knot Structure 3, as shown in Figure 2;Step 4, deposited in class triangular array structure 3 using magnetron sputtering Mo metal level, thickness 5nm.
In some embodiments, described step s3 includes deposition on described si/mo layer and has inclination angle Silicon nanowires forms zigzag array structure layer.The concrete scope at above-mentioned inclination angle and concrete deposition operation Relevant, for example, select glancing angle deposition method when being deposited, this inclination angle then with glancing angle deposition When the glancing angle that uses relevant, further specifically, described step s3 may include in described si/mo On layer, graze deposition has the silicon nanowires formation zigzag array structure layer at 30 ° of inclinations angle.
In some embodiments, described zigzag array structure layer can for class triangular array structure and/or The angle at the inclination angle of undulating array structure, described zigzag array structure layer and described si/mo layer For 10 ° -80 °, and the thickness thickness of described zigzag array structure layer is 45nm-55nm.
In some embodiments, described zigzag array structure layer is zigzag oldered array structure or sawtooth Shape disordered array structure, described zigzag oldered array structure is by photoetching, nano impression or diamond cutting Cutting method is realized, and described zigzag disordered array structure passes through photoetching, glancing angle deposition technology, nanometer Impressing or diamond cutting cutting method are realized.
In some embodiments, described substrate is silicon chip, fused quartz, devitrified glass, super-low expansion quartz One of glass, the thickness of described substrate is 100mm-300mm, and described step s1 also includes The surface of described substrate is processed through design.Face shape for ensureing reflecting mirror does not change, The thickness of described substrate is preferably 100mm-300mm;Or described substrate can be designed as plane mirror, , in 10mm, the concrete thickness of substrate selects can in conjunction with actual application environment for substrate thickness.According to , it is preferable that described substrate surface high frequency roughness is less than 0.2nm, it can for some embodiments of the present invention Realized by methods such as mechanical polishing, ion beam polishing or magnetic fluid polishings.
Embodiment 1-7
There is the multiplayer films in EUV of infrared spectroscopy function, include substrate 1, Duo Gezhou from bottom to up successively The si/mo layer 2 of phase, zigzag array structure layer 3 and infrared reflecting layer 4.Embodiment 1-7 adopts Material and thickness are as shown in table 1.
Comparative example 1
A kind of comprise substrate, the multilayer film of multicycle simo layer, described substrate selects fused quartz, coarse Spend for 0.2nm;The si/mo layer in the plurality of cycle was 50 cycles, and periodic thickness is 7nm, γ-value For 0.4, the top layer of the si/mo layer in the plurality of cycle is si.
Table 1 is material and thickness in the multiplayer films in EUV of embodiment 1-7.
Table 1
Table 2 is the result of calculation of embodiment 1-7 and comparative example 1.
Table 2
Above with respect to the convention in the basis test of extreme ultraviolet reflectance, using 6 ° of angle of incidence, I.e. incident illumination and multilayer film interface normal angular separation are 6 °.Described in table 2, spectrophotometric result refers to infrared light The angle separated with extreme ultraviolet.Result of calculation such as table 2, Fig. 3-4 to embodiment 1-7 and comparative example 1 Shown.
By extremely purple designed by embodiment 1-3 visible laciniation layer height present invention in 50nm Outer multilayer film has higher reflectance.Increase with laciniation layer height, multilayer film is to extreme ultraviolet Reflectance be in oscillatory type decay, when laciniation layer height be 50nm when, of the present invention many Tunic is of a relatively high to the reflectance of extreme ultraviolet.For thinner laciniation layer, multilayer film is to pole The reflectance of ultraviolet can increased, but the requirement due to inclination angle, laciniation layer distribution density Increase, the difficulty brought to processing also can increase.
By the inclination angle of embodiment 1,4 visible laciniation layers, spectrophotometric result is had a significant effect, Inclination angle is too small, and spectrophotometric result is relatively weak;Inclination angle is excessive, and reflecting effect is relatively weak, but all Achievable infrared spectroscopy effect.
Embodiment 1,6,7 is visible, the functional impact on multilayer film of infrared reflecting layer thickness, excessively thin Infrared reflecting layer relatively low to infrared reflectance, blocked up infrared reflecting layer is to the reflectance of ultraviolet relatively Low.
Periodicity mosi multilayer film introduces spectral absorption layer (or spectral absorption Rotating fields), can Reduce the reflection to DUV for the multilayer film, improve the photoresist exposure problems being caused by DUV. The present invention is to introduce the function that structure sheaf achieves infrared spectroscopy on periodicity mosi multilayer film.According to Embodiment result is learnt, triangular array structure has clear and definite direction to the reflection of infrared light, permissible The light splitting ability of structure is described by the spacing of infrared light at fixed range and extreme ultraviolet.The present invention The multiplayer films in EUV being provided can be effectively realized the light splitting of infrared light and extreme ultraviolet, Jin Ershi The spectrum purification of existing EUV light source.And, multiplayer films in EUV structure provided by the present invention is to work The impact making the reflectance of wavelength is less.And the multiplayer films in EUV that comparative example 1 is provided do not possess red Outer light splitting effect.
The specific embodiment of present invention described above, does not constitute limiting the scope of the present invention. The done various other corresponding change of any technology according to the present invention design and deformation, all should wrap Containing within the scope of the invention as claimed.
In the description of this specification, reference term " embodiment ", " some embodiments ", " example ", The description of " specific example " or " some examples " etc. means the concrete spy with reference to this embodiment or example description Levy, structure, material or feature are contained at least one embodiment or the example of the present invention.At this In description, identical embodiment or example are not necessarily referring to the schematic representation of above-mentioned term. And, the specific features of description, structure, material or feature can be in any one or more realities Apply in example or example and combine in an appropriate manner.
Although embodiments of the invention have been shown and described above it is to be understood that above-mentioned reality Applying example is exemplary it is impossible to be interpreted as limitation of the present invention, and those of ordinary skill in the art exists Within the scope of the invention can be to above-described embodiment in the case of principle without departing from the present invention and objective It is changed, changes, replacing and modification.

Claims (14)

1. a kind of multiplayer films in EUV is it is characterised in that described multilayer film includes successively: substrate, many The si/mo layer in individual cycle, zigzag array structure layer and infrared reflecting layer.
2. multiplayer films in EUV according to claim 1 is it is characterised in that described substrate is silicon One of piece, fused quartz, devitrified glass, super-low expansion quartz glass.
3. multiplayer films in EUV according to claim 1 is it is characterised in that described multilayer film has There is the si/mo layer in 40-50 cycle.
4. multiplayer films in EUV according to claim 1 is it is characterised in that the si in each cycle The thickness of/mo layer is 6.5nm-7.3nm, and mo material described in the si/mo layer in each cycle described Thickness account for the 35%-45% of described si/mo thickness degree.
5. multiplayer films in EUV according to claim 1 is it is characterised in that described zigzag battle array Array structure layer can be class triangular array structure and/or undulating array structure.
6. the multiplayer films in EUV according to any one of claim 1-5 it is characterised in that Described zigzag array structure layer is zigzag oldered array structure or zigzag disordered array structure.
7. multiplayer films in EUV according to claim 6 is it is characterised in that described zigzag has Sequence array structure can be realized by one or more of photoetching, nano impression or diamond cutting cutting method.
8. multiplayer films in EUV according to claim 6 it is characterised in that described zigzag no Sequence array structure passes through in photoetching, Glancing angledeposition, nano impression or diamond cutting cutting method Plant or multiple realization.
9. multiplayer films in EUV according to claim 1 is it is characterised in that described zigzag battle array Array structure layer is made up of si material, the inclination angle of described zigzag array structure layer and described si/mo layer Angle be 10 ° -80 °, and the thickness thickness of described zigzag array structure layer be 45nm-55nm.
10. multiplayer films in EUV according to claim 1 is it is characterised in that described infrared anti- Penetrate layer to be made up of one or more of mo, ru, ti or zr, and the thickness of described outer red reflex layer For 4.5nm-5.5nm.
A kind of 11. preparation methoies of multiplayer films in EUV are it is characterised in that include step:
S1 prepares substrate;
S2 prepares the si/mo layer in multiple cycles on the substrate;
S3 prepares zigzag array structure layer on described si/mo layer;
S4 deposits infrared reflecting layer on described zigzag array structure layer.
12. preparation methoies according to claim 11 it is characterised in that described step s2 and Step s4 is all realized by magnetron sputtering method, and described step s3 includes preparation on described si/mo layer The silicon nanowires with inclination angle forms zigzag array structure layer.
13. preparation methoies according to claim 10 are it is characterised in that described zigzag array Structure sheaf can be class triangular array structure and/or undulating array structure, described zigzag array junctions Structure layer is 10 ° -80 ° with the angle at the inclination angle of described si/mo layer, and described zigzag array structure The height of layer is 45nm-55nm.
14. preparation methoies according to claim 11 are it is characterised in that described zigzag array Structure sheaf is zigzag oldered array structure or zigzag disordered array structure, the orderly battle array of described zigzag Array structure is realized by photoetching, nano impression or diamond cutting cutting method, described zigzag disordered array knot Structure passes through photoetching, glancing angle deposition technology, nano impression or diamond cutting cutting method and realizes.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108165926A (en) * 2017-12-18 2018-06-15 苏州宏策光电科技有限公司 The method of the Mo/Si multilayer films of direct magnetic control technology manufacturing cycle thickness transverse direction two-dimensional gradient distribution
CN110632687A (en) * 2018-06-22 2019-12-31 中国科学院上海微系统与信息技术研究所 Metamaterial crystal structure capable of regulating and controlling electromagnetic wave absorption and preparation method thereof
CN113219794A (en) * 2021-05-14 2021-08-06 中国科学院长春光学精密机械与物理研究所 Extreme ultraviolet collecting mirror with energy recovery function and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105068166A (en) * 2014-05-27 2015-11-18 中国科学院上海微系统与信息技术研究所 Manufacturing method for high linear density EUV multilayer blazed grating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105068166A (en) * 2014-05-27 2015-11-18 中国科学院上海微系统与信息技术研究所 Manufacturing method for high linear density EUV multilayer blazed grating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108165926A (en) * 2017-12-18 2018-06-15 苏州宏策光电科技有限公司 The method of the Mo/Si multilayer films of direct magnetic control technology manufacturing cycle thickness transverse direction two-dimensional gradient distribution
CN110632687A (en) * 2018-06-22 2019-12-31 中国科学院上海微系统与信息技术研究所 Metamaterial crystal structure capable of regulating and controlling electromagnetic wave absorption and preparation method thereof
CN110632687B (en) * 2018-06-22 2021-07-27 中国科学院上海微系统与信息技术研究所 Metamaterial crystal structure capable of regulating and controlling electromagnetic wave absorption and preparation method thereof
CN113219794A (en) * 2021-05-14 2021-08-06 中国科学院长春光学精密机械与物理研究所 Extreme ultraviolet collecting mirror with energy recovery function and preparation method thereof

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