CN106336925A - Preparation method of fuel additive - Google Patents
Preparation method of fuel additive Download PDFInfo
- Publication number
- CN106336925A CN106336925A CN201610876105.2A CN201610876105A CN106336925A CN 106336925 A CN106336925 A CN 106336925A CN 201610876105 A CN201610876105 A CN 201610876105A CN 106336925 A CN106336925 A CN 106336925A
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- CN
- China
- Prior art keywords
- parts
- mixed
- added
- standby
- polyisobutylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000002816 fuel additive Substances 0.000 title abstract 6
- 238000003756 stirring Methods 0.000 claims abstract description 40
- 239000003921 oil Substances 0.000 claims abstract description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 24
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 238000001914 filtration Methods 0.000 claims abstract description 17
- 239000000706 filtrate Substances 0.000 claims abstract description 16
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011812 mixed powder Substances 0.000 claims abstract description 14
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000010355 oscillation Effects 0.000 claims abstract description 8
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 8
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 8
- 229910001923 silver oxide Inorganic materials 0.000 claims abstract description 6
- 239000003747 fuel oil additive Substances 0.000 claims description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- QUTGXAIWZAMYEM-UHFFFAOYSA-N 2-cyclopentyloxyethanamine Chemical compound NCCOC1CCCC1 QUTGXAIWZAMYEM-UHFFFAOYSA-N 0.000 claims description 14
- 241001523405 Limax Species 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 8
- 208000035126 Facies Diseases 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 238000013517 stratification Methods 0.000 claims description 7
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims description 6
- 244000060011 Cocos nucifera Species 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 6
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical class CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- OFUAIAKLWWIPTC-UHFFFAOYSA-L magnesium;naphthalene-2-carboxylate Chemical class [Mg+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 OFUAIAKLWWIPTC-UHFFFAOYSA-L 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 6
- -1 acyl diethanolamine Chemical compound 0.000 claims description 5
- 150000005218 dimethyl ethers Chemical class 0.000 claims description 5
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 210000000582 semen Anatomy 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 abstract description 7
- 239000011593 sulfur Substances 0.000 abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 5
- 239000011574 phosphorus Substances 0.000 abstract description 5
- 238000003860 storage Methods 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 238000004945 emulsification Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 abstract 4
- 229960002317 succinimide Drugs 0.000 abstract 2
- 241000237858 Gastropoda Species 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 9
- 239000000446 fuel Substances 0.000 description 8
- 239000003502 gasoline Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 6
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000001804 emulsifying effect Effects 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2381—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds polyamides; polyamide-esters; polyurethane, polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a preparation method of a fuel additive and belongs to the technical field of fuel additives. The preparation method comprises the steps that firstly, snail shells are taken and smashed for ultrasonic oscillation, filtrate and filtration residues are respectively collected after filtration, then polyisobutylene, maleic anhydride and the like are subjected to stirring reaction, pH is regulated, standing is performed for layering, an organic phase is collected to obtain polyisobutylene succinimide, then silver oxide, aluminum oxide and the like are mixed with the filtration residues, the mixture is ball-milled into powder, the mixed powder is mixed with methyl alcohol to obtain mixed liquid, the mixed liquid is mixed with the filtrate, the polyisobutylene succinimide and the like to obtain a base material, and finally the base material, castor oil, potassium nitrate and the like are stirred and discharged to obtain the fuel additive. The prepared fuel additive is suitable for long-term storage and transportation, an oil layer emulsification phenomenon does not occur, engine running is not affected, the fuel additive does not contain sulfur, phosphorus and other substances, is green, environmentally friendly, does not destroy the environment or harm human and has a broad application prospect.
Description
Technical field
The invention discloses a kind of preparation method of fuel oil additive, belong to fuel oil additive preparing technical field.
Background technology
Carbon on engine can involuntary slowly deposit in engine interior, when people ignore the presence of carbon distribution, its meeting
Slowly swallow engine power, reduce fuel economy, deteriorate discharge, and lead to a series of engine failure.Additionally, vapour
The tail gas of car discharge, except combustion product carbon dioxide, vapor are that in addition to harmless components, remaining is harmful components.
A part of toxicant in the tail gas of Engine Exhaust Emission, is due to non-complete combustion of fuel or fuel gas temperature
Relatively low and lead to, such as carbon monoxide, Hydrocarbon and oxynitride.Another part noxious substance, is due to combustor
Interior high temperature, environment under high pressure and the oxynitride that produces；In addition with fuel and dioxy produced by additive burning itself
Change the material such as sulfur and lead compound.In these materials, carbon monoxide is combined with the haemachrome in blood of human body, hinders blood absorption
Oxygen is poisoned to death with conveying oxygen, is referred to as vehicle exhaust first exhaust public hazards.
Fuel oil additive is by organic nano molecule and peace and quiet activation factor, antioxygen, anti-corrosion, breakdown of emulsion etc. 10 multiple material group
Become.It is directed to the oxious component development such as sulfur in oil product, colloid and carbon on engine, and octane improvement and Cetane number,
Have lifting power, promote that work by combustion, antioxygen be wear-resistant, cleaning, dispersion, breakdown of emulsion, anti-corrosion, the effects such as lubricate.Divide by nanometer
Sub- material, the long-chain carbon key in direct aggression oil molecule, produce " microexplosion " in fuel oil room, make fuel oil secondary-atomizing, cause completely
Burning, lifts engine power, improves the thermal efficiency, reduces oil consumption, reduces discharge.
Existing fuel oil additive is easily met water during transport, storage, use and is caused oil reservoir emulsifying, in profit circle
And form emulsifying breast slag, lead to drainage screen to block, and oil reservoir emulsifying is easily brought moisture in gas handling system and combustor into and caused
Corrosion and the normal operation of impact electromotor, and existing fuel oil additive has pollution containing sulfur, phosphorus etc. to environment mostly
Material, can cause secondary pollution, endanger human health.
Content of the invention
Present invention mainly solves technical problem: normal for the easy Emulsification Effect electromotor of existing fuel oil additive at present
Operate and contain the material such as sulfur, phosphorus, the problem polluting the environment and human body being damaged, a kind of system of fuel oil additive is provided
Preparation Method, the method takes Limax shell first and pulverizes and carry out sonic oscillation, filters and collects filtrate and filtering residue respectively, subsequently will gather
The stirring reactions such as isobutene., maleic anhydride, adjust ph stratification, collect organic faciess and obtain polyisobutylene imidodicarbonic diamide, then will
Silver oxide, aluminium oxide etc. become powder with above-mentioned filtering residue mixing and ball milling, and mixed-powder and absolute methanol are stirred to obtain mixed liquor, subsequently will
Mixed liquor and above-mentioned filtrate and polyisobutylene imidodicarbonic diamide etc. stir to obtain base material, finally stir base material, Oleum Ricini, potassium nitrate etc.
Discharging, you can obtain fuel oil additive, the easy long term storage of the fuel oil additive that the present invention is obtained, transport, and be not in oil reservoir
Emulsion, will not impact to electromotor operating, and the not material such as sulfur-bearing, phosphorus in fuel oil additive, and environmental protection will not
Environment and human body are caused damage, has broad application prospects.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) choosing 5～7 weight is 30～40g Limax, and deionized water is cleaned 3～5 times, after cleaning breaks Crusta Limax into pieces, stripping
Decapsidate, shell is carried out pulverizing 10～20min with pulverizer, collects ground product, and is added in beaker, adds in beaker
100～200ml dehydrated alcohol, is placed in supersonic oscillations instrument, ultrasonic 30～40min under 220～240w, subsequently filters,
Collect filtrate and filtering residue respectively, standby；
(2) weigh 5～8g polyisobutylene to be added in the there-necked flask with thermometer and reflux, flask is placed in oil bath
In pot, it is warming up to 80～90 DEG C, adds 1～3g maleic anhydride, stirring reaction 30～40min, then raise temperature to 160～170
DEG C, add 2～4ml1- amino-8-naphthol -3,6- disulfonic acid, stirring reaction 2～3h, reaction terminates, and adds divinyl many
Ethamine, adjusting ph is 7.0, adds 100～200ml deionized water, stirs 10～20min, stratification, collects organic faciess,
I.e. polyisobutylene imidodicarbonic diamide, standby；
(3) weigh 6～8g silver oxide, 3～5g aluminium oxide, 3～5 parts of silicon oxides and the standby filtering residue of step (1) and be added to ball milling
In machine, ball milling 1～2h, cross 100～200 mesh sieves, obtain mixed-powder, mixed-powder is added in beaker, add 300～
400ml absolute methanol, stirs 20～30min, obtains mixed liquor；
(4) count by weight, weigh the standby filtrate of 60～70 portions of above-mentioned mixed liquors, 30～40 parts of steps (1), 6～12 parts
The standby polyisobutylene imidodicarbonic diamide of cocos nucifera oil acyl diethanolamine, 10～20 parts of steps (2), 20～30 portions of diisopropyl ethers and 1～3 part
2-Butoxyethyl acetate, is added in beaker, after stirring, obtains base material；
(5) count by weight, weigh 40～50 parts of above-mentioned base materials, 3～5 portions of single hard fatty acids glyceride, 8～12 portions of Semen Ricinis
Oil, 5～10 parts of magnesium naphthenates, 6～8 parts of polymethoxy dimethyl ethers and 1～3 part of potassium nitrate, are added in blender, stir
Afterwards, discharging, obtains fuel oil additive.
The application process of the present invention is: takes the fuel oil additive that the 1kg present invention is obtained to add to the gasoline of 1000kg mixed
Close, the fuel combination obtaining is added automotive oil tank.After testing, the fuel oil additive that the present invention is obtained can effectively reduce vapour
Tail gas discharges, and pollutant discharge amount slip reaches 65～85%, and the average rate of economizing gasoline under different vehicle conditions reaches 18～22%, and this
The fuel oil additive that invention is obtained can effectively improve automobile power 25～35%, eliminates carbon distribution more than 98%.
The invention has the beneficial effects as follows:
(1) the easy long term storage of fuel oil additive that the present invention is obtained, during transport, use, oil reservoir is less prone to oil reservoir emulsifying
Phenomenon, will not have undesirable effect to the normal operation of electromotor after use；
(2) fuel oil additive that the present invention is obtained can make that the burning of fuel is more abundant, and exhaust emissions reduces further, and carbon distribution is more
Few, additionally, the present invention is without materials such as sulfur, phosphorus, environment and human body will not be worked the mischief.
Specific embodiment
Choosing 5～7 weight first is 30～40g Limax, and deionized water is cleaned 3～5 times, after cleaning strikes Crusta Limax
Broken, peel off shell, shell is carried out pulverizing 10～20min with pulverizer, collect ground product, and be added in beaker, to beaker
Middle addition 100～200ml dehydrated alcohol, is placed in supersonic oscillations instrument, ultrasonic 30～40min under 220～240w, subsequently
Filter, collect filtrate and filtering residue respectively, standby；Subsequently weigh 5～8g polyisobutylene to be added to thermometer and reflux
There-necked flask in, flask is placed in oil bath pan, is warming up to 80～90 DEG C, add 1～3g maleic anhydride, stirring reaction 30
～40min, then raises temperature to 160～170 DEG C, adds 2～4ml1- amino-8-naphthol -3,6- disulfonic acid, and stirring reaction 2～
3h, reaction terminates, and adds the many ethamine of divinyl, and adjusting ph is 7.0, adds 100～200ml deionized water, stirring 10～
20min, stratification, collection organic faciess, i.e. polyisobutylene imidodicarbonic diamide, standby；Weigh 6～8g silver oxide, 3～5g oxidation again
Aluminum, 3～5 parts of silicon oxides and the standby filtering residue of above-mentioned steps are added in ball mill, and ball milling 1～2h crosses 100～200 mesh sieves, obtains
To mixed-powder, mixed-powder is added in beaker, adds 300～400ml absolute methanol, stir 20～30min, obtain
Mixed liquor；Subsequently count by weight, weigh the standby filtrate of 60～70 portions of above-mentioned mixed liquors, 30～40 parts of above-mentioned steps, 6～
The standby polyisobutylene imidodicarbonic diamide of 12 parts of cocos nucifera oil acyl diethanolamine, 10～20 parts of above-mentioned steps, 20～30 portions of diisopropyl ethers and 1
～3 parts of 2-Butoxyethyl acetates, are added in beaker, after stirring, obtain base material；Finally count by weight, weigh
40～50 parts of above-mentioned base materials, 3～5 parts of single hard fatty acids glyceride, 8～12 parts of Oleum Ricini, 5～10 parts of magnesium naphthenates, 6～8 parts
Polymethoxy dimethyl ether and 1～3 part of potassium nitrate, are added in blender, after stirring, discharging, and obtain fuel oil additive.
Example 1
Choosing 5 weight first is 30g Limax, and deionized water is cleaned 3 times, breaks Crusta Limax into pieces, peel off shell after cleaning, will
Shell pulverizer carries out pulverizing 10min, collects ground product, and is added in beaker, adds the anhydrous second of 100ml in beaker
Alcohol, is placed in supersonic oscillations instrument, ultrasonic 30min under 220w, subsequently filters, and collects filtrate and filtering residue respectively, standby；With
Weigh 5g polyisobutylene afterwards to be added in the there-necked flask with thermometer and reflux, flask is placed in oil bath pan, rise
Temperature, to 80 DEG C, adds 1g maleic anhydride, stirring reaction 30min, then raises temperature to 160 DEG C, add 2ml1- amino -8- naphthalene
Phenol -3,6- disulfonic acid, stirring reaction 2h, reaction terminates, and adds the many ethamine of divinyl, and adjusting ph is 7.0, adds 100ml
Deionized water, stirring 10min, stratification, collection organic faciess, i.e. polyisobutylene imidodicarbonic diamide, standby；Weigh 6g oxidation again
Silver, 3g aluminium oxide, 3 parts of silicon oxides and the standby filtering residue of above-mentioned steps are added in ball mill, and ball milling 1h crosses 100 mesh sieves, obtains
Mixed-powder, mixed-powder is added in beaker, adds 300ml absolute methanol, stirs 20min, obtains mixed liquor；Subsequently
Count by weight, weigh the standby filtrate of 60 portions of above-mentioned mixed liquors, 30 parts of above-mentioned steps, 6 parts of cocos nucifera oil acyl diethanolamine, 10 parts
The standby polyisobutylene imidodicarbonic diamide of above-mentioned steps, 20 portions of diisopropyl ethers and 1 part of 2-Butoxyethyl acetate, are added to beaker
In, after stirring, obtain base material；Finally count by weight, weigh 40 parts of above-mentioned base materials, 3 parts of single hard fatty acids glyceride,
8 parts of Oleum Ricini, 5 parts of magnesium naphthenates, 6 parts of polymethoxy dimethyl ethers and 1 part of potassium nitrate, are added in blender, after stirring,
Discharging, obtains fuel oil additive.
This example operation is easy, during use, takes the fuel oil additive that the 1kg present invention is obtained to add to the gasoline of 1000kg
Mixing, the fuel combination obtaining is added automotive oil tank.After testing, the fuel oil additive that the present invention is obtained can effectively reduce
Motor vehicle exhaust emission, pollutant discharge amount slip reaches 65%, and the average rate of economizing gasoline under different vehicle conditions reaches 18%, and system of the present invention
The fuel oil additive obtaining can effectively improve automobile power 25%, eliminates carbon distribution 98.5%.
Example 2
Choosing 6 weight first is 35g Limax, and deionized water is cleaned 4 times, breaks Crusta Limax into pieces, peel off shell after cleaning, will
Shell pulverizer carries out pulverizing 15min, collects ground product, and is added in beaker, adds the anhydrous second of 150ml in beaker
Alcohol, is placed in supersonic oscillations instrument, ultrasonic 35min under 230w, subsequently filters, and collects filtrate and filtering residue respectively, standby；With
Weigh 7g polyisobutylene afterwards to be added in the there-necked flask with thermometer and reflux, flask is placed in oil bath pan, rise
Temperature, to 85 DEG C, adds 2g maleic anhydride, stirring reaction 35min, then raises temperature to 165 DEG C, add 3ml1- amino -8- naphthalene
Phenol -3,6- disulfonic acid, stirring reaction 2.5h, reaction terminates, and adds the many ethamine of divinyl, and adjusting ph is 7.0, adds
150ml deionized water, stirring 15min, stratification, collection organic faciess, i.e. polyisobutylene imidodicarbonic diamide, standby；Weigh 7g again
Silver oxide, 4g aluminium oxide, 4 parts of silicon oxides and the standby filtering residue of above-mentioned steps are added in ball mill, and ball milling 1.5h crosses 150 mesh
Sieve, obtains mixed-powder, mixed-powder is added in beaker, adds 350ml absolute methanol, stirs 25min, is mixed
Liquid；Subsequently count by weight, weigh the standby filtrate of 65 portions of above-mentioned mixed liquors, 35 parts of above-mentioned steps, 9 parts of cocos nucifera oil acyl diethanol
The standby polyisobutylene imidodicarbonic diamide of amine, 15 parts of above-mentioned steps, 25 portions of diisopropyl ethers and 2 parts of 2-Butoxyethyl acetates, add
To in beaker, after stirring, obtain base material；Finally count by weight, weigh 45 parts of above-mentioned base materials, 4 parts of single hard fatty acids
Glyceride, 10 parts of Oleum Ricini, 8 parts of magnesium naphthenates, 7 parts of polymethoxy dimethyl ethers and 2 parts of potassium nitrate, are added in blender, stir
After mixing uniformly, discharging, obtain fuel oil additive.
This example operation is easy, during use, takes the fuel oil additive that the 1kg present invention is obtained to add to the gasoline of 1000kg
Mixing, the fuel combination obtaining is added automotive oil tank.After testing, the fuel oil additive that the present invention is obtained can effectively reduce
Motor vehicle exhaust emission, pollutant discharge amount slip reaches 75%, and the average rate of economizing gasoline under different vehicle conditions reaches 20%, and system of the present invention
The fuel oil additive obtaining can effectively improve automobile power 30%, eliminates carbon distribution 99%.
Example 3
Choosing 7 weight first is 40g Limax, and deionized water is cleaned 5 times, breaks Crusta Limax into pieces, peel off shell after cleaning, will
Shell pulverizer carries out pulverizing 20min, collects ground product, and is added in beaker, adds the anhydrous second of 200ml in beaker
Alcohol, is placed in supersonic oscillations instrument, ultrasonic 40min under 240w, subsequently filters, and collects filtrate and filtering residue respectively, standby；With
Weigh 8g polyisobutylene afterwards to be added in the there-necked flask with thermometer and reflux, flask is placed in oil bath pan, rise
Temperature, to 90 DEG C, adds 3g maleic anhydride, stirring reaction 40min, then raises temperature to 170 DEG C, add 4ml1- amino -8- naphthalene
Phenol -3,6- disulfonic acid, stirring reaction 3h, reaction terminates, and adds the many ethamine of divinyl, and adjusting ph is 7.0, adds 200ml
Deionized water, stirring 20min, stratification, collection organic faciess, i.e. polyisobutylene imidodicarbonic diamide, standby；Weigh 8g oxidation again
Silver, 5g aluminium oxide, 5 parts of silicon oxides and the standby filtering residue of above-mentioned steps are added in ball mill, and ball milling 2h crosses 200 mesh sieves, obtains
Mixed-powder, mixed-powder is added in beaker, adds 400ml absolute methanol, stirs 30min, obtains mixed liquor；Subsequently
Count by weight, weigh the standby filtrate of 70 portions of above-mentioned mixed liquors, 40 parts of above-mentioned steps, 12 parts of cocos nucifera oil acyl diethanolamine, 20
The standby polyisobutylene imidodicarbonic diamide of part above-mentioned steps, 30 portions of diisopropyl ethers and 3 parts of 2-Butoxyethyl acetates, are added to beaker
In, after stirring, obtain base material；Finally count by weight, weigh 50 parts of above-mentioned base materials, 5 parts of single hard fatty acids glyceride,
12 parts of Oleum Ricini, 10 parts of magnesium naphthenates, 8 parts of polymethoxy dimethyl ethers and 3 parts of potassium nitrate, are added in blender, stir
Afterwards, discharging, obtains fuel oil additive.
This example operation is easy, during use, takes the fuel oil additive that the 1kg present invention is obtained to add to the gasoline of 1000kg
Mixing, the fuel combination obtaining is added automotive oil tank.After testing, the fuel oil additive that the present invention is obtained can effectively reduce
Motor vehicle exhaust emission, pollutant discharge amount slip reaches 85%, and the average rate of economizing gasoline under different vehicle conditions reaches 22%, and system of the present invention
The fuel oil additive obtaining can effectively improve automobile power 35%, eliminates carbon distribution more than 99.5%.
Claims (1)
1. a kind of preparation method of fuel oil additive is it is characterised in that concrete preparation process is:
(1) choosing 5～7 weight is 30～40g Limax, and deionized water is cleaned 3～5 times, after cleaning breaks Crusta Limax into pieces, stripping
Decapsidate, shell is carried out pulverizing 10～20min with pulverizer, collects ground product, and is added in beaker, adds in beaker
100～200ml dehydrated alcohol, is placed in supersonic oscillations instrument, ultrasonic 30～40min under 220～240w, subsequently filters,
Collect filtrate and filtering residue respectively, standby；
(2) weigh 5～8g polyisobutylene to be added in the there-necked flask with thermometer and reflux, flask is placed in oil bath
In pot, it is warming up to 80～90 DEG C, adds 1～3g maleic anhydride, stirring reaction 30～40min, then raise temperature to 160～170
DEG C, add 2～4ml1- amino-8-naphthol -3,6- disulfonic acid, stirring reaction 2～3h, reaction terminates, and adds divinyl many
Ethamine, adjusting ph is 7.0, adds 100～200ml deionized water, stirs 10～20min, stratification, collects organic faciess,
I.e. polyisobutylene imidodicarbonic diamide, standby；
(3) weigh 6～8g silver oxide, 3～5g aluminium oxide, 3～5 parts of silicon oxides and the standby filtering residue of step (1) and be added to ball milling
In machine, ball milling 1～2h, cross 100～200 mesh sieves, obtain mixed-powder, mixed-powder is added in beaker, add 300～
400ml absolute methanol, stirs 20～30min, obtains mixed liquor；
(4) count by weight, weigh the standby filtrate of 60～70 portions of above-mentioned mixed liquors, 30～40 parts of steps (1), 6～12 parts
The standby polyisobutylene imidodicarbonic diamide of cocos nucifera oil acyl diethanolamine, 10～20 parts of steps (2), 20～30 portions of diisopropyl ethers and 1～3 part
2-Butoxyethyl acetate, is added in beaker, after stirring, obtains base material；
(5) count by weight, weigh 40～50 parts of above-mentioned base materials, 3～5 portions of single hard fatty acids glyceride, 8～12 portions of Semen Ricinis
Oil, 5～10 parts of magnesium naphthenates, 6～8 parts of polymethoxy dimethyl ethers and 1～3 part of potassium nitrate, are added in blender, stir
Afterwards, discharging, obtains fuel oil additive.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097118A (en) * | 2017-06-20 | 2018-12-28 | 益科路博（天津）生物科技有限公司 | A kind of environmental protection fuel oil additive and preparation method thereof |
| CN112852508A (en) * | 2020-12-29 | 2021-05-28 | 东方傲立石化有限公司 | Oil quality improver and preparation method thereof |
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| CN101328427A (en) * | 2007-06-22 | 2008-12-24 | 陈金义 | Formula of emulsified mixing oil |
| US8778034B2 (en) * | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
| CN104357111A (en) * | 2014-10-19 | 2015-02-18 | 青岛拓联信息技术有限公司 | Methanol gasoline additive with stable performance |
| US9447351B2 (en) * | 2008-07-11 | 2016-09-20 | Basf Se | Composition and method to improve the fuel economy of hydrocarbon fueled internal combustion engines |
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2016
- 2016-10-08 CN CN201610876105.2A patent/CN106336925B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8778034B2 (en) * | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
| CN101328427A (en) * | 2007-06-22 | 2008-12-24 | 陈金义 | Formula of emulsified mixing oil |
| US9447351B2 (en) * | 2008-07-11 | 2016-09-20 | Basf Se | Composition and method to improve the fuel economy of hydrocarbon fueled internal combustion engines |
| CN104357111A (en) * | 2014-10-19 | 2015-02-18 | 青岛拓联信息技术有限公司 | Methanol gasoline additive with stable performance |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097118A (en) * | 2017-06-20 | 2018-12-28 | 益科路博（天津）生物科技有限公司 | A kind of environmental protection fuel oil additive and preparation method thereof |
| CN109097118B (en) * | 2017-06-20 | 2021-06-25 | 益科路博（天津）生物科技有限公司 | Environment-friendly fuel additive and preparation method thereof |
| CN112852508A (en) * | 2020-12-29 | 2021-05-28 | 东方傲立石化有限公司 | Oil quality improver and preparation method thereof |
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| CN106336925B (en) | 2017-12-22 |
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