CN106336827A - Super glue with fast solidification - Google Patents
Super glue with fast solidification Download PDFInfo
- Publication number
- CN106336827A CN106336827A CN201610744733.5A CN201610744733A CN106336827A CN 106336827 A CN106336827 A CN 106336827A CN 201610744733 A CN201610744733 A CN 201610744733A CN 106336827 A CN106336827 A CN 106336827A
- Authority
- CN
- China
- Prior art keywords
- parts
- seccotine
- acid
- ethyl
- ethyoxyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a super glue with fast solidification, which is prepared from, by weight, 18-32 parts of myristic acid ethyl ester, 26-45 parts of (s)-2-cthyoxyl-3-(4-hydroxyphenyl) ethyl propionate, 25-43 parts of 2-(4-methoxy phenoxy) propionic acid, 45-60 parts of N-3-(2-oxocycloalkyl) propionyl-2-thioxo-thiazolidine-4-carboxylic ethyl ester, 20-35 parts of O-ethoxy-dithioformic acid, and 5-15 parts of catalysts. The super glue with fast solidification has good shock resistance and medium resistance and can be used under 80 DEG C.
Description
Technical field
The present invention relates to seccotine field, more particularly to a kind of seccotine of quick solidifying.
Background technology
The concept of adhesive: adhesive is that one kind leans on interface interaction (chemical force or physical force) firm for various solid materials
The material bonding together, be bonding agent or adhesive, referred to as " glue " again.
The application of adhesive widely, be related to building, packaging, space flight, aviation, electronics, automobile, plant equipment,
The every field of the national economy such as health care, light textile.
However, the current strength adhesive curing using is not fast, the pliable and tough difference of glued membrane, poor impact resistance, not media-resistant, Zhi Neng
Use under room temperature.
Content of the invention
The invention mainly solves the technical problem of providing a kind of seccotine of quick solidifying, quick solidifying, resistance to impact are good, resistance to
Medium, can be used below at 80 DEG C.
For solving above-mentioned technical problem, one aspect of the present invention is: a kind of seccotine of quick solidifying is provided,
This seccotine is made up of following components: ethyl myristate, (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4-
Methoxyphenoxy) propanoic acid, n-3-(2- oxocycloalkyl base) propionyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, o- ethyl xanthan
Acid and catalyst, the weight content of its each component is: 18 ~ 32 parts of ethyl myristate, (s) -2- ethyoxyl -3- (4- hydroxy benzeness
Base) 26 ~ 45 parts of ethyl propionate, 2-(4- methoxyphenoxy) 25 ~ 43 parts of propanoic acid, n-3-(2- oxocycloalkyl base) propionyl -2- sulfur
For 45 ~ 60 parts of tetrahydro-thiazoles-4-carboxylic acid's ethyl ester, 20 ~ 35 parts of o- ethoxy-dithioformic acid and 5 ~ 15 parts of catalyst.
In a preferred embodiment of the present invention, described catalyst is tisiw12o40/tio2.
In a preferred embodiment of the present invention, described (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate
Weight content is 28 ~ 40 parts.
In a preferred embodiment of the present invention, described 2-(4- methoxyphenoxy) propanoic acid weight content be 27 ~
38 parts.
The invention has the beneficial effects as follows: quick solidifying of the present invention, resistance to impact are good, media-resistant, can be used below at 80 DEG C.
Specific embodiment
The enforcement it is clear that described will be clearly and completely described to the technical scheme in the embodiment of the present invention below
Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of not making creative work, broadly falls into the model of present invention protection
Enclose.
Embodiment 1
A kind of seccotine of quick solidifying, this seccotine is made up of following components: ethyl myristate, (s) -2- ethyoxyl -3- (4-
Hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid, n-3-(2- oxocycloalkyl base) propionyl -2- thio tetrahydrochysene thiophene
Azoles -4- carboxylic acid, ethyl ester, o- ethoxy-dithioformic acid and tisiw12o40/tio2Catalyst, the weight content of its each component is: Semen Myristicae
18 parts of acetoacetic ester, 28 parts of (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid 27
Part, n-3-(2- oxocycloalkyl base) 45 parts of propionyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, 20 parts of o- ethoxy-dithioformic acid and
tisiw12o40/tio25 parts of catalyst.
Embodiment 2
A kind of seccotine of quick solidifying, this seccotine is made up of following components: ethyl myristate, (s) -2- ethyoxyl -3- (4-
Hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid, n-3-(2- oxocycloalkyl base) propionyl -2- thio tetrahydrochysene thiophene
Azoles -4- carboxylic acid, ethyl ester, o- ethoxy-dithioformic acid and tisiw12o40/tio2Catalyst, the weight content of its each component is: Semen Myristicae
32 parts of acetoacetic ester, 40 parts of (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid 38
Part, n-3-(2- oxocycloalkyl base) 60 parts of propionyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, 35 parts of o- ethoxy-dithioformic acid and
tisiw12o40/tio215 parts of catalyst.
Embodiment 3
A kind of seccotine of quick solidifying, this seccotine is made up of following components: ethyl myristate, (s) -2- ethyoxyl -3- (4-
Hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid, n-3-(2- oxocycloalkyl base) propionyl -2- thio tetrahydrochysene thiophene
Azoles -4- carboxylic acid, ethyl ester, o- ethoxy-dithioformic acid and tisiw12o40/tio2Catalyst, the weight content of its each component is: Semen Myristicae
25 parts of acetoacetic ester, 34 parts of (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid 33
Part, n-3-(2- oxocycloalkyl base) 53 parts of propionyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, 27 parts of o- ethoxy-dithioformic acid and
tisiw12o40/tio210 parts of catalyst.
The beneficial effect of the seccotine of quick solidifying of the present invention is: quick solidifying of the present invention, resistance to impact are good, media-resistant, can be
80 DEG C used below.
The foregoing is only embodiments of the invention, not thereby limit the present invention the scope of the claims, every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in the technology neck of other correlations
Domain, is included within the scope of the present invention.
Claims (4)
1. a kind of seccotine of quick solidifying is it is characterised in that this seccotine is made up of following components: ethyl myristate, (s)-
2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) propanoic acid, n-3-(2- oxocycloalkyl base) third
Acyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, o- ethoxy-dithioformic acid and catalyst, the weight content of its each component is: Semen Myristicae
18 ~ 32 parts of acetoacetic ester, 26 ~ 45 parts of (s) -2- ethyoxyl -3- (4- hydroxy phenyl) ethyl propionate, 2-(4- methoxyphenoxy) third
Sour 25 ~ 43 parts, n-3-(2- oxocycloalkyl base) 45 ~ 60 parts of propionyl -2- thio tetrahydro-thiazoles-4-carboxylic acid ethyl ester, o- ethyl xanthan
20 ~ 35 parts of acid and 5 ~ 15 parts of catalyst.
2. the seccotine of quick solidifying according to claim 1 is it is characterised in that described catalyst is tisiw12o40/
tio2.
3. the seccotine of quick solidifying according to claim 1 is it is characterised in that described (s) -2- ethyoxyl -3- (4- hydroxyl
Base phenyl) ethyl propionate weight content be 28 ~ 40 parts.
4. the seccotine of quick solidifying according to claim 1 is it is characterised in that described 2-(4- methoxyphenoxy) third
The weight content of acid is 27 ~ 38 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610744733.5A CN106336827A (en) | 2016-08-29 | 2016-08-29 | Super glue with fast solidification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610744733.5A CN106336827A (en) | 2016-08-29 | 2016-08-29 | Super glue with fast solidification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106336827A true CN106336827A (en) | 2017-01-18 |
Family
ID=57822651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610744733.5A Pending CN106336827A (en) | 2016-08-29 | 2016-08-29 | Super glue with fast solidification |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106336827A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925076A (en) * | 2012-11-27 | 2013-02-13 | 李晓宇 | Super glue for gluing shoes |
| CN103146312A (en) * | 2011-12-07 | 2013-06-12 | 王连义 | Super glue |
| CN103497715A (en) * | 2013-08-28 | 2014-01-08 | 南京和木新材料科技发展有限公司 | Strong glue |
| CN104371594A (en) * | 2014-10-17 | 2015-02-25 | 周嘉颖 | High-power adhesive for bonding floor and heating elements |
-
2016
- 2016-08-29 CN CN201610744733.5A patent/CN106336827A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146312A (en) * | 2011-12-07 | 2013-06-12 | 王连义 | Super glue |
| CN102925076A (en) * | 2012-11-27 | 2013-02-13 | 李晓宇 | Super glue for gluing shoes |
| CN103497715A (en) * | 2013-08-28 | 2014-01-08 | 南京和木新材料科技发展有限公司 | Strong glue |
| CN104371594A (en) * | 2014-10-17 | 2015-02-25 | 周嘉颖 | High-power adhesive for bonding floor and heating elements |
Non-Patent Citations (5)
| Title |
|---|
| 刘树文: "《合成香料技术手册》", 31 January 2009, 中国轻工业出版社 * |
| 李叶芝等: "3-(2-氧代环烷基)丙酸与(R)-2-硫代四氢噻唑-4-羧酸乙酯的反应", 《高等学校化学学报》 * |
| 蔡小华等: "(S)-2-乙氧基-3-(4-羟基苯基)丙酸乙酯的合成", 《应用化学》 * |
| 解庆范等: "TiSiW12O40/TiO2的制备及光催化性能的研究", 《泉州师范学院学报（自然科学）》 * |
| 郑建仙: "《功能性食品甜味剂》", 30 November 1997, 中国轻工业出版社 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170118 |