CN106336665A - Antibacterial material - Google Patents

Antibacterial material Download PDF

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Publication number
CN106336665A
CN106336665A CN201610702140.2A CN201610702140A CN106336665A CN 106336665 A CN106336665 A CN 106336665A CN 201610702140 A CN201610702140 A CN 201610702140A CN 106336665 A CN106336665 A CN 106336665A
Authority
CN
China
Prior art keywords
parts
nano
chlorhexidine
phenylenediamine
diphenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610702140.2A
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Chinese (zh)
Inventor
李春清
韦树宝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUILIN FUGANG NEW MATERIAL Co Ltd
Original Assignee
GUILIN FUGANG NEW MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUILIN FUGANG NEW MATERIAL Co Ltd filed Critical GUILIN FUGANG NEW MATERIAL Co Ltd
Priority to CN201610702140.2A priority Critical patent/CN106336665A/en
Publication of CN106336665A publication Critical patent/CN106336665A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2286Oxides; Hydroxides of metals of silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

The invention relates to an antibacterial material comprising the following raw materials by weight: 10-100 parts of organic silicon resin, 10-50 parts of nano silver oxide, 10-60 parts of p-amino benzoate, 5-30 parts of cedarwood oil, 2-10 parts of benzyl benzoate, 1-5 parts of N,N'-diphenyl-p-phenylenediamine, 1-10 parts of white carbon black, 1-5 parts of chitosan, 1-4 parts of nano-zinc oxide, 1-6 parts of zinc diethyldithiocarbamate, 1-7 parts of 2-Mercaptoimidazoline, 1-10 parts of dioctyl phthalate and 4-12 parts of chlorhexidine. The antibacterial material is wear-resisting and durable, thermal conductivity is 0.8 W/(m. K) at the temperature of above 20 and below 1500 DEG C, and the compression strength is more than 6MPa.

Description

A kind of anti-biotic material
Technical field
The present invention relates to a kind of anti-biotic material, belong to chemical material field.
Background technology
Existing knitted underwear clothes, great majority are to be made up although comfortable and easy to wear of woven, but warmth retention property is poor, And occur compared with bad smell after wearing time length.With growth in the living standard, people increasingly pay attention to live quality it is desirable to Can obtain has the clothing of comfort, and the living environment of hygiene and health.More and more higher is required for various textiles, Particularly safely, feel at ease, comfortable, the healthy, formation of health, cleaning etc. " green " idea, make the antibacterial of textile, mould proof, anti- Smelly Final finishing processing is more exposed to the attention of people.
Content of the invention
The technical problem to be solved is to provide a kind of anti-biotic material, and anti-biotic material of the present invention is wear-resisting, prolonged resistance to With, more than 20 DEG C and less than 1500 DEG C pyroconductivity be 0.45w/ (m k) below, compressive strength be more than 2mpa.
The technical scheme is that a kind of anti-biotic material, by the raw material of following weight portion Composition:
Organic siliconresin 10-100 part, nano phase ag_2 o 10-50 part, para amidocyanogen benzoic Acid ester 10-60 part, cedar wood oil 5-30 Part, benzoic ether 2-10 part, n-n '-diphenyl-p-phenylenediamine's 1-5 part, white carbon 1-10 part, shitosan 1-5 part, nano oxygen Change zinc 1-4 part, zinc diethyl dithiocarbamate 1-6 part, 2- mercapto imidazoline 1-7 part, dioctyl phthalate 1- 10 parts, Chlorhexidine 4-12 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described anti-biotic material, is made up of the raw material of following weight portion:
20 parts of organic siliconresin, 11 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic acid 4 parts of ester, 4 parts of n-n '-diphenyl-p-phenylenediamine, 7 parts of white carbon, 5 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio 5 parts of carbaminate, 5 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
Further, described anti-biotic material, is made up of the raw material of following weight portion:
100 parts of organic siliconresin, 50 parts of nano phase ag_2 o, 60 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic acid 2 parts of ester, 5 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 3 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio 4 parts of carbaminate, 5 parts of 2- mercapto imidazoline, 6 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
Further, described anti-biotic material, is made up of the raw material of following weight portion:
50 parts of organic siliconresin, 30 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 30 parts of cedar wood oil, benzoic acid 6 parts of ester, 4 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 4 parts of shitosan, 3 parts of nano zine oxide, diethyl-dithio 4 parts of carbaminate, 3 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 6 parts of Chlorhexidine.
The invention has the beneficial effects as follows:
Anti-biotic material of the present invention is wear-resisting, durable in use, more than 20 DEG C and less than 1500 DEG C pyroconductivity be 0.8w/ (m k) below, compressive strength is more than 6mpa.
Specific embodiment
Hereinafter the principle and feature of the present invention is described, example is served only for explaining the present invention, is not intended to limit Determine the scope of the present invention.
Embodiment 1
Described anti-biotic material, is made up of the raw material of following weight portion:
20 parts of organic siliconresin, 11 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic acid 4 parts of ester, 4 parts of n-n '-diphenyl-p-phenylenediamine, 7 parts of white carbon, 5 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio 5 parts of carbaminate, 5 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
Embodiment 2
Described anti-biotic material, is made up of the raw material of following weight portion:
100 parts of organic siliconresin, 50 parts of nano phase ag_2 o, 60 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic acid 2 parts of ester, 5 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 3 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio 4 parts of carbaminate, 5 parts of 2- mercapto imidazoline, 6 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
Embodiment 3
Described anti-biotic material, is made up of the raw material of following weight portion:
50 parts of organic siliconresin, 30 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 30 parts of cedar wood oil, benzoic acid 6 parts of ester, 4 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 4 parts of shitosan, 3 parts of nano zine oxide, diethyl-dithio 4 parts of carbaminate, 3 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 6 parts of Chlorhexidine.
This anti-biotic material adopts this area routine techniques means preparation, is recorded by experiment, the antibacterial of embodiment 1-3 preparation Material more than 20 DEG C and less than 1500 DEG C pyroconductivity be 0.8w/ (m k) below, compressive strength be more than 6mpa.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.

Claims (4)

1. a kind of anti-biotic material is it is characterised in that be made up of the raw material of following weight portion:
Organic siliconresin 10-100 part, nano phase ag_2 o 10-50 part, para amidocyanogen benzoic Acid ester 10-60 part, cedar wood oil 5-30 part, Benzoic ether 2-10 part, n-n '-diphenyl-p-phenylenediamine's 1-5 part, white carbon 1-10 part, shitosan 1-5 part is nano oxidized Zinc 1-4 part, zinc diethyl dithiocarbamate 1-6 part, 2- mercapto imidazoline 1-7 part, dioctyl phthalate 1-10 Part, Chlorhexidine 4-12 part.
2. anti-biotic material according to claim 1 is it is characterised in that be made up of the raw material of following weight portion:
20 parts of organic siliconresin, 11 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic ether 4 Part, 4 parts of n-n '-diphenyl-p-phenylenediamine, 7 parts of white carbon, 5 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio amino 5 parts of zinc formate, 5 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
3. anti-biotic material according to claim 1 is it is characterised in that be made up of the raw material of following weight portion:
100 parts of organic siliconresin, 50 parts of nano phase ag_2 o, 60 parts of para amidocyanogen benzoic Acid ester, 20 parts of cedar wood oil, benzoic ether 2 Part, 5 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 3 parts of shitosan, 4 parts of nano zine oxide, diethyl-dithio amino 4 parts of zinc formate, 5 parts of 2- mercapto imidazoline, 6 parts of dioctyl phthalate, 11 parts of Chlorhexidine.
4. anti-biotic material according to claim 1 is it is characterised in that be made up of the raw material of following weight portion:
50 parts of organic siliconresin, 30 parts of nano phase ag_2 o, 40 parts of para amidocyanogen benzoic Acid ester, 30 parts of cedar wood oil, benzoic ether 6 Part, 4 parts of n-n '-diphenyl-p-phenylenediamine, 8 parts of white carbon, 4 parts of shitosan, 3 parts of nano zine oxide, diethyl-dithio amino 4 parts of zinc formate, 3 parts of 2- mercapto imidazoline, 8 parts of dioctyl phthalate, 6 parts of Chlorhexidine.
CN201610702140.2A 2016-08-22 2016-08-22 Antibacterial material Pending CN106336665A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610702140.2A CN106336665A (en) 2016-08-22 2016-08-22 Antibacterial material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610702140.2A CN106336665A (en) 2016-08-22 2016-08-22 Antibacterial material

Publications (1)

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CN106336665A true CN106336665A (en) 2017-01-18

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760035A (en) * 2017-11-24 2018-03-06 马鞍山松鹤信息科技有限公司 A kind of medical antibacterial high polymer material and preparation method thereof
CN108623956A (en) * 2018-06-20 2018-10-09 苏州新益特塑胶科技有限公司 A kind of use for electronic products antibiotic plastic
CN108752706A (en) * 2018-06-20 2018-11-06 佛山市禅城区钜艺塑料厂 A kind of nano composite antibacterial master batch
CN109043681A (en) * 2018-06-27 2018-12-21 浙江梵丝璐服饰有限公司 A kind of Graphene antibiosis fiber body shaping underwear

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927491A (en) * 2015-07-02 2015-09-23 龚灿锋 Antibacterial flame retardant coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927491A (en) * 2015-07-02 2015-09-23 龚灿锋 Antibacterial flame retardant coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760035A (en) * 2017-11-24 2018-03-06 马鞍山松鹤信息科技有限公司 A kind of medical antibacterial high polymer material and preparation method thereof
CN108623956A (en) * 2018-06-20 2018-10-09 苏州新益特塑胶科技有限公司 A kind of use for electronic products antibiotic plastic
CN108752706A (en) * 2018-06-20 2018-11-06 佛山市禅城区钜艺塑料厂 A kind of nano composite antibacterial master batch
CN109043681A (en) * 2018-06-27 2018-12-21 浙江梵丝璐服饰有限公司 A kind of Graphene antibiosis fiber body shaping underwear

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