CN106319929A - Preparation method of aging resistant silk fibers - Google Patents
Preparation method of aging resistant silk fibers Download PDFInfo
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- CN106319929A CN106319929A CN201610686157.3A CN201610686157A CN106319929A CN 106319929 A CN106319929 A CN 106319929A CN 201610686157 A CN201610686157 A CN 201610686157A CN 106319929 A CN106319929 A CN 106319929A
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- Prior art keywords
- silk fiber
- gamma
- cellulose
- fibroin
- silk
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- 239000000835 fiber Substances 0.000 title claims abstract description 100
- 230000032683 aging Effects 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 57
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 claims abstract description 55
- 229940080345 gamma-cyclodextrin Drugs 0.000 claims abstract description 55
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 45
- 239000002245 particle Substances 0.000 claims abstract description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004332 silver Substances 0.000 claims abstract description 13
- 229910052709 silver Inorganic materials 0.000 claims abstract description 13
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims description 53
- 239000000243 solution Substances 0.000 claims description 46
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- 239000003921 oil Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 108010022355 Fibroins Proteins 0.000 claims description 17
- 239000011259 mixed solution Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- 239000001913 cellulose Substances 0.000 claims description 12
- 229920002678 cellulose Polymers 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000000017 hydrogel Substances 0.000 claims description 10
- 238000005470 impregnation Methods 0.000 claims description 10
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 10
- -1 after stirring Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 241000218646 Cedrus deodara Species 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 6
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 5
- JBJAAHCMRSHTAO-UHFFFAOYSA-N [K].I(=O)(=O)C1=C(C(=O)O)C=CC=C1 Chemical compound [K].I(=O)(=O)C1=C(C(=O)O)C=CC=C1 JBJAAHCMRSHTAO-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 230000008961 swelling Effects 0.000 claims description 5
- 238000002604 ultrasonography Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 4
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 229920013822 aminosilicone Polymers 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- 238000006073 displacement reaction Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 241001479543 Mentha x piperita Species 0.000 claims 1
- 239000000499 gel Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 230000001580 bacterial effect Effects 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 2
- 241000255789 Bombyx mori Species 0.000 description 14
- 239000004744 fabric Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005286 illumination Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 244000246386 Mentha pulegium Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- 241001312402 Helvella corium Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000294611 Punica granatum Species 0.000 description 1
- 235000014360 Punica granatum Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XGKPLOKHSA-N [2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XGKPLOKHSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 239000007766 cera flava Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
- C08B37/0012—Cyclodextrin [CD], e.g. cycle with 6 units (alpha), with 7 units (beta) and with 8 units (gamma), large-ring cyclodextrin or cycloamylose with 9 units or more; Derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/006—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with wool-protecting agents; with anti-moth agents
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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Abstract
The invention relates to field of textile materials, and discloses a preparation method of aging resistant silk fibers. The preparation method comprises the following steps: 1, preparing gamma-cyclodextrin monoaldehyde; 2, preparing silver-loaded gamma-cyclodextrin monoaldehyde; 3, preparing cellulose-fibroin-titanium dioxide xerogel particles; 4, grafting the silk fibers; 5, carrying out impregnated finishing on the silk fibers. The silk fibers prepared by the invention can effectively delay the aging of the silk fibers and avoid borer plaque and bacterial plaque, and further has long aging. In addition, the preparation method of the aging resistant silk fibers can keep the original flexibility of silk and enhance the tensile strength of the silk, and is environment-friendly and harmless, and further does not affect human bodies.
Description
Technical field
The present invention relates to textile material field, particularly relate to silk fiber field.
Background technology
Silkworm silk is the matured silkworm secreted concretionary continuous fiber of silk liquid, also referred to as natural silk when cocooing, and is a kind of natural
Fiber, is one of human use's animal fiber the earliest.Silkworm silk light weight and elongated, fabric sheen is good, comfortable and easy to wear, and feel is smooth
Plentiful, poor heat conductivity, moisture absorption is breathed freely, and is widely used in and knits the various silks and satins of system and knitwear.But owing to silkworm silk main component is by moving
Thing albumen, quality is the most fragile, easily turns to be yellow, hardens after long-time illumination；On the other hand, silk fiber is vulnerable to micro-life
Thing.The erosion of insects, not only affects attractive in appearance and feel, but also can make silk fiber accelerated ageing, and intensity declines, and easily breaks
Damage.
Authorization Notice No. is that the patent of invention of CN103741458A discloses a kind of antibacterial moth proofing agent of silk fabric, it
Be made up of the component of following parts by weight: Fructus Caryophylli powder 7-15 part, Punica granatum L. corium farinosum 7-14 part, silicone oil 5-9 part, Cera Flava 2-7 part,
Alkylolamides 3-9 part, polyvinylpyrrolidone 2-6 part, xylene monosulfonic acid potassium 4-7 part, lactose 2-7 part, starch 3-7 part, wine
Essence 20-24 part, phenyl salicylate 5-9 part, Span60 5-9 part.The silk fabric of this invention is antibacterial mothproof whole
Reason agent has antibacterial mothproof effect, excellent effect.(2) finish fabric has good washability and soft feel；(3) work is prepared
Skill is simple, harmless to human non-toxic, will not destroy the silkworm silk in silk fabric.
But the antibacterial moth proofing agent of above-mentioned silk fabric is ageing poor, it is impossible to keep effect for a long time, and to silkworm silk
After fibre finish, the compliance of silkworm silk can be affected.Further, the antibacterial moth proofing agent of this silk fabric does not possess anti-aging function.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides the preparation method of a kind of ageing-resistant silk fiber.The present invention
The silk fiber prepared can effectively delay silk fiber aging and it can be avoided that eat into speckle and the generation of bacterial plaque, and timeliness is long, this
Outward, additionally it is possible to keep the original compliance of silkworm silk and promote the tensile strength of silkworm silk, and environmentally friendly, human body will not be made
Become impact.
The concrete technical scheme of the present invention is: the preparation method of a kind of ageing-resistant silk fiber, sequentially includes the following steps:
Step 1: by gamma-cyclodextrin, o-iodoxy benzoic acid potassium, dimethyl sulfoxide 5-10:3-5:100 in mass ratio mixing,
After being completely dissolved, solution is reacted in the ultrasound bath of 40-50 DEG C 8-16h；Filter after reaction, take filtrate, will filter with acetone
Liquid agitation and dilution 40-50 times, filters again, takes solid, and is dissolved with the water of solid masses 30-35 times, then carries out
Filter, take filtrate for three times, the dried gamma-cyclodextrin list aldehyde for preparing, standby.
Step 2: above-mentioned prepared part gamma-cyclodextrin list aldehyde is formulated as the gamma-cyclodextrin list that mass concentration is 4-6%
Aldehyde solution, adds the silver nitrate that quality is 0.3-0.5 times of gamma-cyclodextrin list aldehyde in gamma-cyclodextrin list aldehyde solution, stirs
After, solution ph is controlled at 4-6, under the conditions of lucifuge, be heated to 50-60 DEG C and be incubated 2-3h, being then centrifuged for isolated
Solid, solid is clean, dried, it is dissolved in sodium hydroxide solution, adding quality in sodium hydroxide solution is solid 0.5-
The sodium borohydride of 1.5%, regulates pH to 7-8, is then stirred, and recentrifuge separates and prepares after drying load silver γ-ring and sticks with paste
The single aldehyde of essence.
Step 3: cellulose, fibroin albumen are formulated as cellulose mass concentration be 2-4%, fibroin albumen quality concentration be
The mixed solution of 1-3%, successively adds the load silver gamma-cyclodextrin list aldehyde of mixed solution quality 0.5-1.5% in mixed solution
With the Ethylene glycol diglycidyl ether of mixed solution quality 0.1-0.3%, prepare mixed sols after being uniformly dispersed, by mixed sols
Mix with titania hydrosol 4-6:1 in mass ratio, be transferred to after stirring in the environment of-10 DEG C to-6 DEG C freeze 2-3
My god, thaw after frost, prepare cellulose-fibroin-titanium dioxide hydrogel；With ethanol to cellulose-fibroin-titanium dioxide
After hydrogel carries out solvent displacement for several times, prepare cellulose-fibroin-titanium dioxide alcogel；To cellulose-fibroin-titanium dioxide
Titanium alcogel carries out supercritical fluid drying, eventually passes through grinding and prepares cellulose-fibroin-titanium dioxide xerogel particles.
Step 4: successively add silk fiber, gamma-cyclodextrin list aldehyde and fiber in the aqueous hydrochloric acid solution that pH value is 5-6
Element-fibroin-titanium dioxide xerogel particles, the post-heating that stirs is to 38-42 DEG C of reaction 2-3h, wherein silk fiber, γ-ring
The mass ratio of dextrin list aldehyde, cellulose-fibroin-titanium dioxide xerogel particles and aqueous hydrochloric acid solution is 2-3:3-5:1-3:100；
Then to adding enough sodium cyanoborohydrides, react 3-5 days, finally reactant liquor is adjusted to neutrality, silk fiber is taken out also
Clean.
Step 5: the impregnation process in dressing liquid of the silk fiber after step 4 being processed, takes out after dipping and is dried,
Prepare ageing-resistant silk fiber；Described dressing liquid include the mothproof quintessence oil of 5-15wt%, the hydrophilic amino silicone oil of 1-3wt%,
The ethanol of 10-30wt% and the water of surplus.
Step 1 of the present invention first prepares gamma-cyclodextrin list aldehyde with gamma-cyclodextrin, and gamma-cyclodextrin list aldehyde can be grafted to silkworm silk
On fiber.In step 2, take a part of gamma-cyclodextrin list aldehyde, utilize the adsorption of gamma-cyclodextrin list aldehyde to carry out carrying silver, it is possible to
Silk fiber is made to have antibacterial effect.Step 3 cellulose, fibroin albumen, load silver gamma-cyclodextrin list aldehyde are prepared cellulose-
Fibroin-titanium dioxide xerogel particles, has extra specific surface area and outstanding adsorption, and selects cellulose, fibroin albumen
As main material, it is possible to promoting the tensile strength of silk fiber, fibroin albumen is as the homology material of silk fiber, affinity
More preferably, titanium dioxide has outstanding anti-light aging, it is possible to delay silk fiber by illumination yellow, aging；Ethylene glycol bisthioglycolate contracts
Water glycerin ether can improve the degree of cross linking in hydrogel forming process, and stability is more preferable.Step 4 is by gamma-cyclodextrin list aldehyde, fiber
Element-fibroin-titanium dioxide xerogel particles is grafted on silk fiber.Silk fiber after grafting be impregnated in arrangement by step 5
In liquid, gamma-cyclodextrin list aldehyde molecule has micro-cavities, and cellulose-fibroin-titanium dioxide xerogel particles has the three of complexity
Tieing up pore passage structure, both cooperate and can fully adsorb composition mothproof in dressing liquid, and absorption fastness is good, and has slow
Release effect, so that silk fiber is mothproof ageing good.
Further, the particle diameter of described cellulose-fibroin-titanium dioxide xerogel particles is less than or equal to 1 micron.
Further, described silk fiber before step 4 through pretreatment: silk fiber is 35-45 DEG C in temperature
Water in swelling 1-3h, by silk fiber and to impregnated in mass concentration be 0.2-0.4%'s to then take out 1:60-80 in mass ratio
In solution of potassium carbonate, boil 0.5-1h；Finally silk fiber taking-up is dried standby.
Pretreated silk fiber can preferably be grafted with gamma-cyclodextrin list aldehyde.
Further, in step 5, the impregnation technology of silk fiber is: silk fiber is 1:100-with the mass ratio of dressing liquid
200；Dressing liquid temperature is 45-55 DEG C；Dip time is 8-10h.
Further, mothproof quintessence oil described in step 5 is Deodar Cedar (Himalayan Cedar) quintessence oil, Herba Lysimachiae foenum-graeci quintessence oil, Peppermint essential oil, Radix Cinnamomi porrecti quintessence oil
In one or more mixture.
It is compared with the prior art, the invention has the beneficial effects as follows: the silk fiber that the present invention prepares can effectively delay silkworm
Silk fiber is aging and it can be avoided that moth speckle and the generation of bacterial plaque, and timeliness is long, additionally it is possible to keep the original compliance of silkworm silk
With promote the tensile strength of silkworm silk, and environmentally friendly, human body is not resulted in impact.When the mothproof effect of silk fiber becomes
During difference, can again be impregnated in dressing liquid.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
The preparation method of a kind of ageing-resistant silk fiber, sequentially includes the following steps:
Step 1: by gamma-cyclodextrin, o-iodoxy benzoic acid potassium, dimethyl sulfoxide 7.5:4:100 in mass ratio mixing, complete
After CL, solution is reacted in the ultrasound bath of 45 DEG C 12h；Filter after reaction, take filtrate, with acetone, filtrate is stirred
Dilute 45 times, again filter, take solid, and dissolved with the water of solid masses 32 times, then carry out third time and filter, take filter
Liquid, the dried gamma-cyclodextrin list aldehyde for preparing, standby.
Step 2: above-mentioned prepared part gamma-cyclodextrin list aldehyde is formulated as the gamma-cyclodextrin list aldehyde that mass concentration is 5%
Solution, adds the silver nitrate that quality is 0.4 times of gamma-cyclodextrin list aldehyde in gamma-cyclodextrin list aldehyde solution, after stirring, and will
Solution ph controls 5, under the conditions of lucifuge, is heated to 55 DEG C and is incubated 2.5h, being then centrifuged for isolated solid, by solid
Clean, dried, it is dissolved in sodium hydroxide solution, in sodium hydroxide solution, adds the sodium borohydride that quality is solid 1%, adjust
Joint pH to 7.5, is then stirred, and recentrifuge separates and prepares after drying and carries silver gamma-cyclodextrin list aldehyde.
Step 3: cellulose, fibroin albumen are formulated as cellulose mass concentration be 3%, fibroin albumen quality concentration be
The mixed solution of 2%, load silver gamma-cyclodextrin list aldehyde and the mixing of successively adding mixed solution quality 1% in mixed solution are molten
The Ethylene glycol diglycidyl ether of liquid quality 0.2%, prepares mixed sols after being uniformly dispersed, by mixed sols and titanium dioxide water
Colloidal sol 56:1 in mass ratio mixes, and is transferred in the environment of-8 DEG C frost 2.5 days, thaws after frost after stirring, system
Obtain cellulose-fibroin-titanium dioxide hydrogel；With ethanol, cellulose-fibroin-titanium dioxide hydrogel is carried out solvent for several times to put
After changing, prepare cellulose-fibroin-titanium dioxide alcogel；Cellulose-fibroin-titanium dioxide alcogel is carried out shooting flow
Soma is dry, eventually passes through and grinds the cellulose-fibroin-titanium dioxide xerogel particles preparing particle diameter less than 1 micron.
Step 4: by silk fiber swelling 2h in the water that temperature is 40 DEG C, then take out 1:70 in mass ratio by silk fibroin
Tie up and impregnated in the solution of potassium carbonate that mass concentration is 0.3%, boil 45min；Finally silk fiber taking-up is dried standby.
Successively pretreated silk fiber, gamma-cyclodextrin list aldehyde and fibre is added in the aqueous hydrochloric acid solution that pH value is 5.5
Dimension element-fibroin-titanium dioxide xerogel particles, the post-heating that stirs is to 40 DEG C of reactions 2.5h, wherein silk fiber, γ-rings
The mass ratio of dextrin list aldehyde, cellulose-fibroin-titanium dioxide xerogel particles and aqueous hydrochloric acid solution is 2.5:4:2:100；Then
To adding enough sodium cyanoborohydrides, react 4 days, finally reactant liquor is adjusted to neutrality, silk fiber is taken out and cleans.
Step 5: the impregnation process in dressing liquid of the silk fiber after step 4 being processed, takes out after dipping and is dried,
Prepare ageing-resistant silk fiber；Described dressing liquid includes the Deodar Cedar (Himalayan Cedar) quintessence oil of 5wt%, the Radix Cinnamomi porrecti quintessence oil of 5wt%, the parent of 2wt%
Aqueous amido silicon oil, the ethanol of 20wt% and the water of surplus.Impregnation technology is: silk fiber is 1 with the mass ratio of dressing liquid:
150；Dressing liquid temperature is 50 DEG C；Dip time is 9h.
Embodiment 2
The preparation method of a kind of ageing-resistant silk fiber, sequentially includes the following steps:
Step 1: by gamma-cyclodextrin, o-iodoxy benzoic acid potassium, dimethyl sulfoxide 5:3:100 in mass ratio mixing, completely
After dissolving, solution is reacted in the ultrasound bath of 40 DEG C 16h；Filter after reaction, take filtrate, filtrate is stirred dilute with acetone
Release 40 times, again filter, take solid, and dissolved with the water of solid masses 30 times, then carry out third time and filter, take filter
Liquid, the dried gamma-cyclodextrin list aldehyde for preparing, standby.
Step 2: above-mentioned prepared part gamma-cyclodextrin list aldehyde is formulated as the gamma-cyclodextrin list aldehyde that mass concentration is 4%
Solution, adds the silver nitrate that quality is 0.3 times of gamma-cyclodextrin list aldehyde in gamma-cyclodextrin list aldehyde solution, after stirring, and will
Solution ph controls 4, under the conditions of lucifuge, is heated to 50 DEG C and is incubated 3h, being then centrifuged for isolated solid, washed by solid
Only, after drying, it is dissolved in sodium hydroxide solution, in sodium hydroxide solution, adds the sodium borohydride that quality is solid 0.5%, adjust
Joint pH to 7, is then stirred, and recentrifuge separates and prepares after drying and carries silver gamma-cyclodextrin list aldehyde.
Step 3: cellulose, fibroin albumen are formulated as cellulose mass concentration be 2%, fibroin albumen quality concentration be
The mixed solution of 1%, successively adds load silver gamma-cyclodextrin list aldehyde and the mixing of mixed solution quality 0.5% in mixed solution
The Ethylene glycol diglycidyl ether of solution quality 0.1%, prepares mixed sols, by mixed sols and titanium dioxide after being uniformly dispersed
Hydrosol 4:1 in mass ratio mixes, and is transferred in the environment of-10 frost 2 days, thaws after frost after stirring, and prepares
Cellulose-fibroin-titanium dioxide hydrogel；With ethanol, cellulose-fibroin-titanium dioxide hydrogel is carried out solvent for several times to replace
After, prepare cellulose-fibroin-titanium dioxide alcogel；Cellulose-fibroin-titanium dioxide alcogel is carried out supercritical fluid
It is dried, eventually passes through and grind the cellulose-fibroin-titanium dioxide xerogel particles preparing particle diameter less than 1 micron.
Step 4: by silk fiber swelling 3h in the water that temperature is 35 DEG C, then take out 1:60 in mass ratio by silk fibroin
Tie up and impregnated in the solution of potassium carbonate that mass concentration is 0.2%, boil 1h；Finally silk fiber taking-up is dried standby.
Successively pretreated silk fiber, gamma-cyclodextrin list aldehyde and fiber is added in the aqueous hydrochloric acid solution that pH value is 5
Element-fibroin-titanium dioxide xerogel particles, the post-heating that stirs is to 38 DEG C of reactions 3h, wherein silk fiber, gamma-cyclodextrins
The mass ratio of single aldehyde, cellulose-fibroin-titanium dioxide xerogel particles and aqueous hydrochloric acid solution is 2:3:1:100；Then to interpolation
Enough sodium cyanoborohydrides, react 3 days, finally reactant liquor are adjusted to neutrality, are taken out by silk fiber and clean.
Step 5: the impregnation process in dressing liquid of the silk fiber after step 4 being processed, takes out after dipping and is dried,
Prepare ageing-resistant silk fiber；Described dressing liquid include the Herba Lysimachiae foenum-graeci quintessence oil of 5wt%, the hydrophilic amino silicone oil of 1wt%,
The ethanol of 10wt% and the water of surplus.Impregnation technology is: silk fiber is 1:100 with the mass ratio of dressing liquid；Dressing liquid temperature
It it is 45 DEG C；Dip time is 10h.
Embodiment 3
The preparation method of a kind of ageing-resistant silk fiber, sequentially includes the following steps:
Step 1: by gamma-cyclodextrin, o-iodoxy benzoic acid potassium, dimethyl sulfoxide 10:5:100 in mass ratio mixing, completely
After dissolving, solution is reacted in the ultrasound bath of 50 DEG C 8h；Filter after reaction, take filtrate, with acetone by filtrate agitation and dilution
50 times, again filter, take solid, and dissolved with the water of solid masses 35 times, then carry out third time and filter, take filtrate,
The dried gamma-cyclodextrin list aldehyde for preparing, standby.
Step 2: above-mentioned prepared part gamma-cyclodextrin list aldehyde is formulated as the gamma-cyclodextrin list aldehyde that mass concentration is 6%
Solution, adds the silver nitrate that quality is 0.5 times of gamma-cyclodextrin list aldehyde in gamma-cyclodextrin list aldehyde solution, after stirring, and will
Solution ph controls 6, under the conditions of lucifuge, is heated to 60 DEG C and is incubated 2h, being then centrifuged for isolated solid, washed by solid
Only, after drying, it is dissolved in sodium hydroxide solution, in sodium hydroxide solution, adds the sodium borohydride that quality is solid 1.5%, adjust
Joint pH to 8, is then stirred, and recentrifuge separates and prepares after drying and carries silver gamma-cyclodextrin list aldehyde.
Step 3: cellulose, fibroin albumen are formulated as cellulose mass concentration be 4%, fibroin albumen quality concentration be
The mixed solution of 3%, successively adds load silver gamma-cyclodextrin list aldehyde and the mixing of mixed solution quality 1.5% in mixed solution
The Ethylene glycol diglycidyl ether of solution quality 0.3%, prepares mixed sols, by mixed sols and titanium dioxide after being uniformly dispersed
Hydrosol 6:1 in mass ratio mixes, and is transferred in the environment of-6 DEG C frost 3 days, thaws after frost after stirring, and prepares
Cellulose-fibroin-titanium dioxide hydrogel；With ethanol, cellulose-fibroin-titanium dioxide hydrogel is carried out solvent for several times to replace
After, prepare cellulose-fibroin-titanium dioxide alcogel；Cellulose-fibroin-titanium dioxide alcogel is carried out supercritical fluid
It is dried, eventually passes through and grind the cellulose-fibroin-titanium dioxide xerogel particles preparing particle diameter less than 1 micron.
Step 4: by silk fiber swelling 1h in the water that temperature is 45 DEG C, then take out 1:80 in mass ratio by silk fibroin
Tie up and impregnated in the solution of potassium carbonate that mass concentration is 0.4%, boil 0.5h；Finally silk fiber taking-up is dried standby.
Successively pretreated silk fiber, gamma-cyclodextrin list aldehyde and fiber is added in the aqueous hydrochloric acid solution that pH value is 6
Element-fibroin-titanium dioxide xerogel particles, the post-heating that stirs is to 42 DEG C of reactions 2h, wherein silk fiber, gamma-cyclodextrins
The mass ratio of single aldehyde, cellulose-fibroin-titanium dioxide xerogel particles and aqueous hydrochloric acid solution is 3:5:3:100；Then to interpolation
Enough sodium cyanoborohydrides, react 5 days, finally reactant liquor are adjusted to neutrality, are taken out by silk fiber and clean.
Step 5: the impregnation process in dressing liquid of the silk fiber after step 4 being processed, takes out after dipping and is dried,
Prepare ageing-resistant silk fiber；Described dressing liquid includes the Herba Lysimachiae foenum-graeci quintessence oil of 10wt%, the Peppermint essential oil of 5wt%, the parent of 3wt%
Aqueous amido silicon oil, the ethanol of 30wt% and the water of surplus.Impregnation technology is: silk fiber is 1 with the mass ratio of dressing liquid:
200；Dressing liquid temperature is 55 DEG C；Dip time is 8h.
To the prepared ageing-resistant silk fiber of the embodiment of the present invention 1 and carry out ageing-resistant test with kind silk fiber, survey
Strip part is: by ageing-resistant silk fiber and place 200h under the Halogen light that illumination is l250lx with kind silk fiber, away from
From for 30cm, temperature controls at 30 DEG C.Carrying out fracture strength and elongation at break is tested, ageing-resistant silk fiber is compared
With kind silk fiber, fracture strength height 30-40%, elongation at break height 20-30%.
Carrying out mothproof effect through the prepared ageing-resistant silk fiber of the embodiment of the present invention 1 to test, mothproof effect can
Up to 1-2, and after repeatedly washing, still can keep better effects.Additionally to ageing-resistant silk fiber fabric and same kind
Silk fiber fabric carries out stiffness test, and ageing-resistant silk fiber boardness is to declining about 3-5%, therefore to silkworm silk
The pliability impact of fiber is little.
Raw materials used, equipment in the present invention, unless otherwise noted, is the conventional raw material of this area, equipment；In the present invention
Method therefor, unless otherwise noted, is the conventional method of this area.
The above, be only presently preferred embodiments of the present invention, not impose any restrictions the present invention, every according to the present invention
Any simple modification, change and the equivalent transformation that above example is made by technical spirit, all still falls within the technology of the present invention side
The protection domain of case.
Claims (5)
1. the preparation method of an ageing-resistant silk fiber, it is characterised in that sequentially include the following steps:
Step 1: by gamma-cyclodextrin, o-iodoxy benzoic acid potassium, dimethyl sulfoxide 5-10:3-5:100 in mass ratio mixing, completely
After dissolving, solution is reacted in the ultrasound bath of 40-50 DEG C 8-16h；Filter after reaction, take filtrate, with acetone, filtrate is stirred
Mix dilution 40-50 times, again filter, take solid, and dissolved with the water of solid masses 30-35 times, then carry out third time
Filter, take filtrate, the dried gamma-cyclodextrin list aldehyde for preparing, standby；
Step 2: above-mentioned prepared part gamma-cyclodextrin list aldehyde is formulated as the gamma-cyclodextrin list aldehyde that mass concentration is 4-6% molten
Liquid, adds the silver nitrate that quality is 0.3-0.5 times of gamma-cyclodextrin list aldehyde in gamma-cyclodextrin list aldehyde solution, after stirring,
Solution ph is controlled at 4-6, under the conditions of lucifuge, be heated to 50-60 DEG C and be incubated 2-3h, be then centrifuged for isolated solid
Body, solid is clean, dried, it is dissolved in sodium hydroxide solution, adding quality in sodium hydroxide solution is solid 0.5-
The sodium borohydride of 1.5%, regulates pH to 7-8, is then stirred, and recentrifuge separates and prepares after drying load silver γ-ring and sticks with paste
The single aldehyde of essence；
Step 3: cellulose, fibroin albumen are formulated as cellulose mass concentration be 2-4%, fibroin albumen quality concentration be 1-
The mixed solution of 3%, successively add in mixed solution mixed solution quality 0.5-1.5% load silver gamma-cyclodextrin list aldehyde and
The Ethylene glycol diglycidyl ether of mixed solution quality 0.1-0.3%, after being uniformly dispersed prepare mixed sols, by mixed sols with
Titania hydrosol 4-6:1 in mass ratio mixes, and is transferred in the environment of-10 DEG C to-6 DEG C frost 2-3 days after stirring,
Thaw after frost, prepare cellulose-fibroin-titanium dioxide hydrogel；With ethanol to cellulose-fibroin-titanium dioxide water
After gel carries out solvent displacement for several times, prepare cellulose-fibroin-titanium dioxide alcogel；To cellulose-fibroin-titanium dioxide
Alcogel carries out supercritical fluid drying, eventually passes through grinding and prepares cellulose-fibroin-titanium dioxide xerogel particles；
Step 4: successively add silk fiber, gamma-cyclodextrin list aldehyde and cellulose-silk in the aqueous hydrochloric acid solution that pH value is 5-6
Element-titanium dioxide xerogel particles, the post-heating that stirs is to 38-42 DEG C of reaction 2-3h, wherein silk fiber, gamma-cyclodextrin
The mass ratio of single aldehyde, cellulose-fibroin-titanium dioxide xerogel particles and aqueous hydrochloric acid solution is 2-3:3-5:1-3:100；Then
To adding enough sodium cyanoborohydrides, react 3-5 days, finally reactant liquor is adjusted to neutrality, silk fiber is taken out and cleans；
Step 5: the impregnation process in dressing liquid of the silk fiber after step 4 being processed, takes out after dipping and is dried, and prepares
Ageing-resistant silk fiber；Described dressing liquid includes the mothproof quintessence oil of 5-15wt%, the hydrophilic amino silicone oil of 1-3wt%, 10-
The ethanol of 30wt% and the water of surplus.
The preparation method of a kind of ageing-resistant silk fiber the most as claimed in claim 1, it is characterised in that described cellulose-silk
The particle diameter of element-titanium dioxide xerogel particles is less than or equal to 1 micron.
The preparation method of a kind of ageing-resistant silk fiber the most as claimed in claim 1, it is characterised in that described silk fiber exists
Through pretreatment before step 4: by silk fiber swelling 1-3h in the water that temperature is 35-45 DEG C, then take out in mass ratio
1:60-80 is by silk fiber and impregnated in the solution of potassium carbonate that mass concentration is 0.2-0.4%, boils 0.5-1h；Finally will
Silk fiber taking-up is dried standby.
The preparation method of a kind of ageing-resistant silk fiber the most as claimed in claim 1, it is characterised in that silk fibroin in step 5
The impregnation technology of dimension is: silk fiber is 1:100-200 with the mass ratio of dressing liquid；Dressing liquid temperature is 45-55 DEG C；During dipping
Between be 8-10h.
5. the preparation method of a kind of ageing-resistant silk fiber as described in claim 1 or 4, it is characterised in that described in step 5
Mothproof quintessence oil is one or more mixture in Deodar Cedar (Himalayan Cedar) quintessence oil, Herba Lysimachiae foenum-graeci quintessence oil, Peppermint essential oil, Radix Cinnamomi porrecti quintessence oil.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142717A (en) * | 2017-06-28 | 2017-09-08 | 南通大学 | A kind of production method of the anti-aging geotextiles of the hydrosol |
| CN108309168A (en) * | 2017-12-31 | 2018-07-24 | 广州海鑫无纺布实业有限公司 | A kind of preparation method of high-durability frosted cleaning cloth |
| CN114904388A (en) * | 2022-04-18 | 2022-08-16 | 广西科技大学 | Ag @ essential oil @ cyclodextrin/bamboo charcoal @ TiO 2 Nano material and application thereof |
| CN115748255A (en) * | 2022-11-28 | 2023-03-07 | 浙江理工大学 | High-conductivity scrub-resistant intelligent sensing silk fiber and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102373618A (en) * | 2011-11-18 | 2012-03-14 | 张家港耐尔纳米科技有限公司 | Silver-carried alginic acid fiber and preparation method thereof |
| CN104530437A (en) * | 2014-12-02 | 2015-04-22 | 天津工业大学 | Preparation method of cyclodextrin grafted chitosan polymer with water pollutant separating property |
| CN105220479A (en) * | 2015-09-21 | 2016-01-06 | 中国丝绸博物馆 | A kind of preparation method being applicable to the silk fiber of textiles historical relic's protection |
| CN105837861A (en) * | 2016-04-03 | 2016-08-10 | 苏鑫 | Composite natural polymer gel material |
-
2016
- 2016-08-17 CN CN201610686157.3A patent/CN106319929B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102373618A (en) * | 2011-11-18 | 2012-03-14 | 张家港耐尔纳米科技有限公司 | Silver-carried alginic acid fiber and preparation method thereof |
| CN104530437A (en) * | 2014-12-02 | 2015-04-22 | 天津工业大学 | Preparation method of cyclodextrin grafted chitosan polymer with water pollutant separating property |
| CN105220479A (en) * | 2015-09-21 | 2016-01-06 | 中国丝绸博物馆 | A kind of preparation method being applicable to the silk fiber of textiles historical relic's protection |
| CN105837861A (en) * | 2016-04-03 | 2016-08-10 | 苏鑫 | Composite natural polymer gel material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142717A (en) * | 2017-06-28 | 2017-09-08 | 南通大学 | A kind of production method of the anti-aging geotextiles of the hydrosol |
| CN108309168A (en) * | 2017-12-31 | 2018-07-24 | 广州海鑫无纺布实业有限公司 | A kind of preparation method of high-durability frosted cleaning cloth |
| CN114904388A (en) * | 2022-04-18 | 2022-08-16 | 广西科技大学 | Ag @ essential oil @ cyclodextrin/bamboo charcoal @ TiO 2 Nano material and application thereof |
| CN114904388B (en) * | 2022-04-18 | 2023-08-22 | 广西科技大学 | Ag@ essential oil @ cyclodextrin/bamboo charcoal @ TiO 2 Nanomaterial and application thereof |
| CN115748255A (en) * | 2022-11-28 | 2023-03-07 | 浙江理工大学 | High-conductivity scrub-resistant intelligent sensing silk fiber and preparation method and application thereof |
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