CN1063193C - Transparent core-shell particle toughened polystyrene material - Google Patents
Transparent core-shell particle toughened polystyrene material Download PDFInfo
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- CN1063193C CN1063193C CN97106352A CN97106352A CN1063193C CN 1063193 C CN1063193 C CN 1063193C CN 97106352 A CN97106352 A CN 97106352A CN 97106352 A CN97106352 A CN 97106352A CN 1063193 C CN1063193 C CN 1063193C
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Abstract
The present invention relates to toughened polystyrene material of transparent core-shell particles, which comprises 1 to 20 weight parts of core-shell particles and 80 to 99 weight parts of polystyrene. Each core-shell particle comprises a core and a shell, wherein the core contains an alkenyl arene chain segment, a propenoate chain segment and a crosslinking agent; the shell contains an alkenyl arene chain segment; one end of the chain segment of the shell is connected with the core by the crosslinking agent; the particle diameter of each core-shell particulate is from 60 to 150 nanometers. The material has the transparence of pure polystyrene and has shock strength which is about two times larger than that of the pure polystyrene at the same time; the material can be used in plastic industry.
Description
The present invention relates to core-shell particle toughened polystyrene material, particularly transparent core-shell particle toughened polystyrene material.
Polystyrene is the most facile kind in the transparent plastics, but owing to himself fragility shortcoming, is very limited in the application, only is used for low grade products at present.So far, people have done a large amount of work and have been used for the toughness reinforcing of p-poly-phenyl ethene, as: the terpolymer (ABS resin) of the graft copolymerization of vinylbenzene and polyhutadiene (high-impact polystyrene), vinylbenzene and vinyl cyanide, divinyl and the blend of polystyrene and other polymkeric substance etc.But the general transparency of the material of these method gained is relatively poor.Because the composite emulsion polymerization technology can design the macromolecule emulsion microballoon from microcosmic, regulate copolymer component, the refractive index of nucleocapsid and base material is complementary, change the composite emulsion polymerization condition simultaneously and make the core-shell particle size be lower than 0.1 μ m, can not influenced the transparent polystyrene of the transparency through physical mixed.Along with going deep into that particulate blending toughening, enhancing are studied, people have been used for multiple core-shell particle the blending and modifying of plastics.Document Polym.Mater.Sci.Eng.1993,70, the A.Maazouz of France among the 13-14, what usefulness U.S. Rohm andHaas companies such as H.Sautereau provided is glue nuclear with butyl polyacrylate or polyhutadiene, is that the core-shell particle (median size 300nm) of shell has been made the research report to TOUGHENING MODIFICATION OF EPOXY RESINS with the crosslinked polymethylmethacrylaparticles.Can improve the toughness of Resins, epoxy greatly and don't reduce its thermal characteristics with this core-shell particle, toughness reinforcing degree can be regulated by the core-shell particle structure.But the particulate mean sizes is the transparency that 300nm obviously can influence base material, the transparent problem of not mentioned material still in this report.
For overcoming the shortcoming that exists in the above-mentioned document, the purpose of this invention is to provide a kind of core-shell particle toughened polystyrene material, this material not only has the transparency of pure polystyrene, and has than the better shock strength of pure polystyrene.
The objective of the invention is to realize: a kind of core-shell particle toughened polystyrene material by following technical scheme, comprise core-shell particle and polystyrene, in parts by weight, core-shell particle content is 1～20 part, polystyrene content is 80～99 parts, the core-shell particle particle diameter is 60～150 nanometers, core-shell particle comprises nuclear, shell, nuclear contains alkenyl arene segment, acrylate segment and linking agent, shell is the segment that contains alkenyl arene, the segment of shell links by an end and the nuclear phase of linking agent, and nuclear is 1: 1.279～1.830 with the weight ratio of shell.
In the technique scheme, in parts by weight, core-shell particle content is 3～10 parts, and core-shell particle particle diameter preferable range is 80～120 nanometers, and alkenyl arene is vinylbenzene, alpha-methyl styrene, p-methylstyrene, and preferred version is a vinylbenzene.Used linking agent is two methacryloxypropyl phenyl-propanes, polyethersulfone diene macromonomer or its mixture.Acrylate is methyl acrylate, ethyl propenoate, propyl acrylate, butyl acrylate, and preferred version is a butyl acrylate.
The preparation method of above-mentioned cross-linked core-shell copolymerized particle adopts the multi-step emulsion polymerization method, when the fs forms nuclear, add acrylate and alkenyl arene, with two methacryloxypropyl phenyl-propanes (BVA) or polyethersulfone diene macromonomer (BVPES) with it copolymerzation with cross-linking be nuclear, subordinate phase adds vinylbenzene again and forms shell, has molecular chain to be associated between nuclear and the shell.The gained emulsion through breakdown of emulsion, methyl alcohol wash, drying etc. promptly gets hard core-shell particulate powder.
In the above-mentioned core-shell particle with crosslinked nuclear, double methyl methacrylate class linking agent can be two methacryloxypropyl phenyl-propanes (BVA) or polyethersulfone diene macromonomer (BVPES) consumption account for nuclear partial monosomy gross weight 0.1～20%, preferable range 1～5%.Content of butyl acrylate is 5～50% of nuclear partial monosomy weight in nuclear, preferable range 10～30%.Used initiator can be Potassium Persulphate (K
2S
2O
8), ammonium persulphate [(NH
4)
2S
2O
8] and the redox system of above-mentioned two kinds of initiators and ferrous sulfate, consumption is 0.1～1% of a monomer total amount, preferable range is 0.2～0.5%.The emulsifying agent sodium oleate divides two portions to add in the polyreaction of core-shell particle, when a part is nucleation, for 0.5～10% of monomer weight in the nuclear, decides on want size, and is generally more suitable about 1～2%; Adding sodium oleate during the polymerization of second section shell is about 1% of shell monomers total amount, splashes into simultaneously with initiator.The total amount of water is 1.5～3 times of monomer total amount in the prescription that feeds intake.
The preparation method of core-shell particle toughened polystyrene material comprises following four kinds: (1) solution blending, (2) mechanical blending, the mass polymerization on the throne of (3) core-shell particle, the suspension polymerization on the throne of (4) core-shell particle.
Solution blending technology is with the mixed solvent of toluene and chloroform (toluene: chloroform=1～1.7) dissolving transparent polystyrene pellet and core-shell particle mixture, solid content 10～40%, preferable range 15～25%.Promptly get the blending toughening material except that after desolvating.Get solution and handle mensuration light transmission, impact-resistance in mercury upper berth film drying.
Mechanical blending process carries out on mixing roll, get a certain amount of transparent polystyrene pellet and core-shell copolymerized particle and put into the mixing roll blend, 195～220 ℃ of melting temperatures, 200～210 ℃ of preferable range: mixing time can take out in 7～20 minutes, preferable range 8～15 minutes; Screw speed is 550～700rpm.This intermingling material is made the impact batten through injection (210～220 ℃ of injection temperatures) or compressing tablet (200～205 ℃ of compressing tablet temperature), is used for performance test.
Bulk technique on the throne is: at the new core-shell copolymerized particle that adds predetermined amount in the vinylbenzene that steams, add initiator dibenzoyl peroxide (BPO) or Diisopropyl azodicarboxylate (AIBN), its amount is 0.1～1% of monomer weight, preferable range 0.2～0.5%,, pour in the mould and promptly get core-shell particle blending and modifying transparent polystyrene material to certain viscosity in 70～90 ℃ of pre-polymerizations in 45～95 ℃ of temperature programmings.Through machining is test bars, records light transmission and shock strength.
Suspension polymerization process on the throne is: add deionized water and the new monomer styrene that steams in there-necked flask; monomer is 1: 1～1: 3.5 with the ratio of deionized water; preferable range 1: 1.5～1: 2.5; add quantitative core-shell copolymerized particle and polyethylene of dispersing agent alcohol, carboxymethyl cellulose again, magnesiumcarbonate, lime carbonate etc. and initiator dibenzoyl peroxide or Diisopropyl azodicarboxylate.Dispersant dosage is 0.5～3% of a monomer weight, preferable range 1～2%: initiator amount is 0.2～2% of a monomer weight, preferable range 0.3～1%.Open to stir and to make it to be uniformly dispersed in 85～90 ℃ of polymerizations 4 hours through separating, wash, be drying to obtain pearl modification transparent polystyrene.This material in 215 ℃ of injection moldings or in 200 ℃ hot-forming be test bars, measure light transmission and shock strength.
Above-mentioned core-shell copolymerized particle accounts for transparent polystyrene or the styrene monomer part by weight is 1～20%, preferable range 3～10%.
The present invention is owing to adopt the particle toughened transparent polystyrene of cross-linked core-shell of 60～150 nanometers, and rationally controlled the add-on of core-shell particle and selected suitable core-shell particle, thereby make the toughening material that obtains both keep the transparency of pure polystyrene, make the shock strength of polystyrene material increase nearly 1 times simultaneously, obtained effect preferably.
[embodiment 1]
Sodium oleate 1 gram is put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (vinylbenzene 45 grams, butyl acrylate 5 grams, two methacryloxypropyl phenyl-propane 0.82 gram), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
8(with 20 ml deionized water dissolving, 0.16 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (65 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.2 gram), H
2The mixture of O (25 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 60 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 2]
Sodium oleate 1 gram is put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (vinylbenzene 30 grams, butyl acrylate 20 grams, two methacryloxypropyl phenyl-propane 0.82 gram), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator (NH
4)
2S
2O
8(with 20 ml deionized water dissolving, 0.16 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (65 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), (NH
4)
2S
2O
8(0.2 gram), H
2The mixture of O (25 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion to solid content about 5%, with 5% salt naphtenic acid, adds about 580 milliliters through alcohol dilution altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 60 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 3]
Sodium oleate 1.5 grams are put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (vinylbenzene 40 grams, methyl acrylate 5 grams, two methacryloxypropyl phenyl-propane 1.0 grams), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
8(with 20 ml deionized water dissolving, 0.16 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (70 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.4 gram), H
2The mixture of O (20 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 70 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 4]
Sodium oleate 1.5 grams are put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (alpha-methyl styrene 40 grams, methyl acrylate 5 grams, two methacryloxypropyl phenyl-propane 0.8 gram), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
8(with 20 ml deionized water dissolving, 0.16 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (70 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.4 gram), H
2The mixture of O (20 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 70 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 5]
Sodium oleate 1.5 grams are put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (p-methylstyrene-45 gram, butyl acrylate 7 grams, two methacryloxypropyl phenyl-propane 1.0 grams), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
5(with 20 ml deionized water dissolving, 0.20 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (70 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.4 gram), H
2The mixture of O (20 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 70 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 6]
Sodium oleate 1.5 grams are put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (alpha-methyl styrene 37 grams, butyl acrylate 3 grams, two methacryloxypropyl phenyl-propane 1.0 grams), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
8(with 20 ml deionized water dissolving, 0.18 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (75 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.4 gram), H
2The mixture of O (20 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 70 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 7]
Sodium oleate 1.5 grams are put into there-necked flask, add 1 gram sodium bicarbonate and letting nitrogen in and deoxidizing.Add 140 gram deionized water dissolving and turn on agitator, treat that emulsifying agent sodium oleate and sodium bicarbonate dissolve the back (about 20 minutes) that is uniformly dispersed, add first monomer mixture (vinylbenzene 36 grams, butyl acrylate 4 grams, two methacryloxypropyl phenyl-propane 1.5 grams), after continuing to stir 20 minutes abundant dispersions, move in 95 ℃ of water-baths, add initiator K
2S
2O
8(with 20 ml deionized water dissolving, 0.2 gram) reaction 1 hour, this moment, system was blue look, was cooled to 80 ℃.Suction filtration is removed condensation product, adds 0.1 gram sodium oleate again, simultaneously drip styrene (70 gram), acetone (7.5ml) mixture and sodium oleate (0.5 gram), K
2S
2O
8(0.4 gram), H
2The mixture of O (20 gram) continues reaction 2～2.5 hours, stops promptly to get the cross-linked core-shell copolymerized particle emulsion.
Above-mentioned emulsion is diluted to solid content about 5% through methyl alcohol, with 5% salt naphtenic acid, adds about 580 milliliters altogether, heating is changed 10～20 minutes with fixed attention, and precipitation is through methanol wash centrifugal settling, prior to 70 ℃ of forced air dryings, in 40 ℃ of vacuum-dryings 24 hours, promptly get fine-particle powder again.[embodiment 8]
Get 50 milliliters of toluene, chloroform is mixed in the beaker for 50 milliliters, adds core-shell copolymerized particle 1 gram that transparent polystyrene pellet 20 restrains, embodiment 1 makes, particle size 129nm.Low-grade fever to 40～50 ℃, treat solid dissolve fully mix after, removing desolvates promptly gets modification transparent polystyrene material.Get solution and handle in mercury upper berth film drying that to record light transmission be 87.5% (wavelength 700nm), shock strength is 6.05KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.9[embodiment 9]
Get 60 milliliters of toluene, chloroform is mixed in the beaker for 40 milliliters, adds core-shell copolymerized particle 1 gram that transparent polystyrene pellet 20 restrains, embodiment 2 makes, particle size 105nm.Low-grade fever to 40～50 ℃, treat solid dissolve fully mix after, removing desolvates promptly gets modification transparent polystyrene material.Light transmission is 88% (wavelength 700nm), and shock strength is 6.38KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.03 times.[embodiment 10]
Get new steaming vinylbenzene 90 grams and add the core-shell copolymerized particle that 10 gram embodiment 3 make, particle size 129nm.Add BPO0.3 and restrain in the heating in water bath dissolving, letting nitrogen in and deoxidizing, 80 ℃ of pre-polymerizations are cooled to 40 ℃ and pour into mould to certain viscosity, in 45 ℃ 5 hours, 50 ℃ 4 hours, 60 ℃ 3 hours, 70 ℃ 2 hours, 80 ℃ were heating and curing in 1 hour, again in 95 ℃ 0.5 hour, 100 ℃ of further thermal treatments in 1 hour.Cooling and demolding promptly gets modification transparent polystyrene material.Through machining is test bars, records light transmission 87.5% (wavelength 700nm), and shock strength is 6.05KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.9 times.[embodiment 11]
Get new steaming vinylbenzene 95 grams and add the core-shell copolymerized particle that 5 gram embodiment 4 make, particle size 129nm.Add BPO0.5 and restrain in the heating in water bath dissolving, letting nitrogen in and deoxidizing, 80 ℃ of pre-polymerizations are cooled to 40 ℃ and pour into mould to certain viscosity, in 45 ℃ 5 hours, 50 ℃ 4 hours, 60 ℃ 3 hours, 70 ℃ 2 hours, 80 ℃ were heating and curing in 1 hour, again in 95 ℃ 0.5 hour, 100 ℃ of further thermal treatments in 1 hour.Cooling and demolding promptly gets modification transparent polystyrene material, and through processing batten test light transmission 88% (wavelength 700nm), shock strength is 6.03KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.92 times.[embodiment 12]
Get new steaming vinylbenzene 97 grams and add the core-shell copolymerized particle that 3 gram embodiment 5 make, particle size 105nm.Add AIBN0.5 and restrain in the heating in water bath dissolving, letting nitrogen in and deoxidizing, 80 ℃ of pre-polymerizations are cooled to 40 ℃ and pour into mould to certain viscosity, in 45 ℃ 5 hours, 50 ℃ 4 hours, 60 ℃ 3 hours, 70 ℃ 2 hours, 80 ℃ were heating and curing in 1 hour, again in 95 ℃ 0.5 hour, 100 ℃ of further thermal treatments in 1 hour.Cooling and demolding promptly gets modification transparent polystyrene material.Through processing batten test light transmission 88.5% (wavelength 700nm), shock strength is 5.85KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.8 times.[embodiment 13]
Get new steaming vinylbenzene 98 grams and add the core-shell copolymerized particle that 2 gram embodiment 6 make, particle size 90nm.Add AIBN0.6 and restrain in the heating in water bath dissolving, letting nitrogen in and deoxidizing, 80 ℃ of pre-polymerizations are cooled to 40 ℃ and pour into mould to certain viscosity, in 45 ℃ 5 hours, 50 ℃ 4 hours, 60 ℃ 3 hours, 70 ℃ 2 hours, 80 ℃ were heating and curing in 1 hour, again in 100 ℃ of further thermal treatments in 1.5 hours.Cooling and demolding promptly gets modification transparent polystyrene material.Through processing batten test light transmission 88.3% (wavelength 700nm), shock strength is 6.45KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.05 times.[embodiment 14]
Get new steaming vinylbenzene 92 grams and add the core-shell copolymerized particle that 8 gram embodiment 7 make, particle size 129nm.Add BPO0.4 and restrain in the heating in water bath dissolving, letting nitrogen in and deoxidizing, 80 ℃ of pre-polymerizations are cooled to 40 ℃ and pour into mould to certain viscosity, in 45 ℃ 5 hours, 50 ℃ 4 hours, 60 ℃ 3 hours, 70 ℃ 2 hours, 80 ℃ of 100 ℃ of further thermal treatments in 2 hours that are heating and curing in 1 hour.Cooling and demolding promptly gets modification transparent polystyrene material.Through processing batten test light transmission 88.7% (wavelength 700nm), shock strength is 6.42KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.05 times.[embodiment 15]
In 500 milliliters of there-necked flasks, add 200 milliliters of deionized waters, polyethylene of dispersing agent alcohol 2 grams, newly steam core-shell copolymerized particle 10 grams (particle size 129nm) and the initiator B PO0.5 gram that monomer styrene 90 grams, embodiment 1 make, stirring and dissolving is uniformly dispersed, letting nitrogen in and deoxidizing, be warming up to 85～90 ℃ of polymerizations 4 hours, the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.This material in 215 ℃ of injection moldings or in 200 ℃ hot-forming be test bars, be 90% (wavelength 700nm) through surveying light transmission, shock strength is 6.38KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.03 times.[embodiment 16]
200 milliliters of deionized waters of adding, dispersion agent carboxymethyl cellulose 2 restrain, newly steam core-shell copolymerized particle 5 grams (particle size 129nm) and the initiator B PO1 gram that monomer styrene 95 restrains, embodiment 3 makes in 500 milliliters of there-necked flasks, stirring and dissolving is uniformly dispersed, letting nitrogen in and deoxidizing, be warming up to 85～90 ℃ of polymerizations 4 hours, the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.Behind the processing batten, light transmission is 90% (wavelength 700nm), and shock strength is 6.30KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.03 times.[embodiment 17]
250 milliliters of deionized waters of adding, dispersion agent magnesiumcarbonate 3 restrain, newly steam core-shell copolymerized particle 5 grams (particle size 105nm) and the initiator A IBN1 gram that monomer styrene 95 restrains, embodiment 4 makes in 500 milliliters of there-necked flasks, stirring and dissolving is uniformly dispersed, letting nitrogen in and deoxidizing, be warming up to 85～90 ℃ of polymerizations 4 hours, the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.Behind the processing batten, light transmission is 89% (wavelength 700nm), and shock strength is 6.27KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.0 times.[embodiment 18]
150 milliliters of deionized waters of adding, dispersion agent lime carbonate 4 restrain, newly steam core-shell copolymerized particle 3 grams (particle size 90nm) and the initiator A IBN2 gram that monomer styrene 97 restrains, embodiment 5 makes in 500 milliliters of there-necked flasks, stirring and dissolving is uniformly dispersed, letting nitrogen in and deoxidizing, be warming up to 85～90 ℃ of polymerizations 4 hours, the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.Behind the processing batten, light transmission is 88% (wavelength 700nm), and shock strength is 6.0KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.9 times.[embodiment 19]
Add 200 milliliters of deionized waters, polyethylene of dispersing agent alcohol 2 grams in 500 milliliters of there-necked flasks, newly steam core-shell copolymerized particle 8 grams (particle size 105nm) and the initiator B PO1 gram that monomer styrene 92 restrains, embodiment 6 makes, stirring and dissolving is uniformly dispersed.Letting nitrogen in and deoxidizing is warming up to 85～90 ℃ of polymerizations 4 hours. and the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.Behind the processing batten, light transmission is 88.1% (wavelength 700nm), and shock strength is 6.04KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
21.92 times.[embodiment 20]
In 500 milliliters of there-necked flasks, add 200 milliliters of deionized waters, polyethylene of dispersing agent alcohol 3 grams, newly steam core-shell copolymerized particle 5 grams (particle size 129nm) and the initiator B PO0.8 gram that monomer styrene 95 grams, embodiment 7 make, stirring and dissolving is uniformly dispersed, letting nitrogen in and deoxidizing, be warming up to 85～90 ℃ of polymerizations 4 hours, the control stirring velocity is in the hope of obtaining suitable particle size in the polymerization process.Product is drying to obtain pearl modification transparent polystyrene through separation.Behind the processing batten, light transmission is 89.3% (wavelength 700nm), and shock strength is 6.38KJ/m
2, be pure polystyrene shock strength 3.14KJ/m
22.03 times.[comparative example]
Behind pure polystyrene processing batten, measuring its light transmission is 88～89% (wavelength 700nm), and shock strength is 3.14KJ/m
2
Claims (8)
1. transparent core-shell particle toughened polystyrene material, comprise core-shell particle and polystyrene, in parts by weight, core-shell particle content is 1～20 part, and polystyrene content is 80～99 parts, core-shell particle comprises nuclear, shell, nuclear contains alkenyl arene segment, acrylate segment and linking agent, and shell is the segment that contains alkenyl arene, and the segment of shell links by an end and the nuclear phase of linking agent, the core-shell particle particle diameter is 60～150 nanometers, and nuclear is 1: 1.279～1.830 with the weight ratio of shell.
2. according to the described transparent core-shell particle toughened polystyrene material of claim 1, it is characterized in that core-shell particle content is 3～10 parts in parts by weight.
3. according to the described transparent core-shell particle toughened polystyrene material of claim 1, it is characterized in that alkenyl arene is vinylbenzene, alpha-methyl styrene, p-methylstyrene.
4. according to the described transparent core-shell particle toughened polystyrene material of claim 3, it is characterized in that alkenyl arene is a vinylbenzene.
5. according to the described transparent core-shell particle toughened polystyrene material of claim 1, it is characterized in that linking agent is two methacryloxypropyl phenyl-propanes, polyethersulfone diene macromonomer or its mixture.
6. according to the described transparent core-shell particle toughened polystyrene material of claim 1, it is characterized in that acrylate is methyl acrylate, ethyl propenoate, propyl acrylate, butyl acrylate.
7,, it is characterized in that acrylate is a butyl acrylate according to the described transparent core-shell particle toughened polystyrene material of claim 6.
8,, it is characterized in that the core-shell particle particle diameter is 80～120 nanometers according to the described transparent core-shell particle toughened polystyrene material of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97106352A CN1063193C (en) | 1997-04-03 | 1997-04-03 | Transparent core-shell particle toughened polystyrene material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97106352A CN1063193C (en) | 1997-04-03 | 1997-04-03 | Transparent core-shell particle toughened polystyrene material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1194994A CN1194994A (en) | 1998-10-07 |
| CN1063193C true CN1063193C (en) | 2001-03-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97106352A Expired - Fee Related CN1063193C (en) | 1997-04-03 | 1997-04-03 | Transparent core-shell particle toughened polystyrene material |
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| Country | Link |
|---|---|
| CN (1) | CN1063193C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863735B (en) * | 2012-09-27 | 2015-05-13 | 上海锦湖日丽塑料有限公司 | Preparation method for styrene based mixed reclaimed material |
| CN102888072B (en) * | 2012-09-27 | 2014-12-17 | 上海锦湖日丽塑料有限公司 | Styrene mixed recycled material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4684696A (en) * | 1986-03-14 | 1987-08-04 | General Electric Company | Impact modified polyphenylene compositions |
| EP0465792A2 (en) * | 1990-05-11 | 1992-01-15 | Takeda Chemical Industries, Ltd. | Multi-layer polymer, thermoplastic resin composition containing the same, and shaped article produced using the composition |
-
1997
- 1997-04-03 CN CN97106352A patent/CN1063193C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4684696A (en) * | 1986-03-14 | 1987-08-04 | General Electric Company | Impact modified polyphenylene compositions |
| EP0465792A2 (en) * | 1990-05-11 | 1992-01-15 | Takeda Chemical Industries, Ltd. | Multi-layer polymer, thermoplastic resin composition containing the same, and shaped article produced using the composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1194994A (en) | 1998-10-07 |
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