CN106317930A - Novel floor substrate - Google Patents
Novel floor substrate Download PDFInfo
- Publication number
- CN106317930A CN106317930A CN201610704839.2A CN201610704839A CN106317930A CN 106317930 A CN106317930 A CN 106317930A CN 201610704839 A CN201610704839 A CN 201610704839A CN 106317930 A CN106317930 A CN 106317930A
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- Prior art keywords
- parts
- agent
- adhesive
- novel floor
- base material
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/003—Crosslinking of starch
- C08B31/006—Crosslinking of derivatives of starch
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
- E04F15/105—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials of organic plastics with or without reinforcements or filling materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
- E04F2290/045—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against fire
Abstract
The invention discloses a novel floor substrate. The novel floor substrate is made by adopting the following raw materials in parts by weight: 109-146 parts of smashed poplar powder, 17-24 parts of coal ash, 9-12 parts of waste rubber powder, 1-3 parts of curing agent, 1-2 parts of water-proofing agent, 2-3 parts of anti-flaming agent, 2-3 parts of smoke suppression agent, and 14-22 parts of adhesive. The physical and mechanical performances of the novel floor substrate disclosed by the invention exceed the LY/T1611-2003 requirement (fiberboard for floor substrate); the floor substrate can replace laminate floor made of the high/medium density fiberboard which wastes a great quantity of wood resources and causes serious free formaldehyde pollution; the floor substrate has good economy and environmental protection performance, and can be extensively popularized and applied.
Description
[technical field]
The invention belongs to floor preparing technical field, be specifically related to a kind of novel floor base material.
[background technology]
Floor base material typically uses medium and high density fibre panel to make, and needs to consume substantial amounts of timber.Along with forest can the amount of cutting down by
The fewest, timber the most increasingly seems precious.But being widely present junked tire on market to need to process, thermal power plant is also deposited
Need to process at a large amount of flyash, the waste material of above-mentioned serious environment pollution can be used, fill to floor, be to need
The problem urgently to solve.
Since entering for 21st century, domestic wood-based panel industry obtains unconventional fast development, increases by 22% every year, 2009
Wood-based plate yield consumes adhesive about 5,000,000 more than ten thousand stere more than 8000, year, becomes world's Wood-based Panel Production the first big country.
At present, binding agent main still Lauxite, phenolic resin, the melamino-formaldehyde tree that domestic and international wood-based plate manufacturing uses
Fat etc..In the adhesive of this type, free formaldehyde content is higher, slowly releases toxic formaldehyde gas, to human body during use
Damage.In order to reduce the discharge of formaldehyde gas, on the one hand domestic Research Thinking is the skill to original synthesis Lauxite
Art route is improved, it is intended to reduce the content of free formaldehyde.As added the fomol catcher such as carbamide, tripolycyanamide；The opposing party
It is that raw material prepares adhesive to replace formaldehyde system adhesive that face attempts to inexpensive biomass poly hydroxyl compound.Reported
Above-mentioned thinking in, the cost of starch-based glue stick is relatively low, is the one natural poly hydroxyl compound material having most application prospect.
Be widely used in the national conditions of corrugated board packing box in conjunction with domestic starch adhesive, starch adhesive forms sediment through new structure
The MOLECULE DESIGN of powder with control graft copolymerization after oxidative cleavage, crosslinking, solve adhesion strength and resistance to water, for industry of artificial boards
Economically consider it is feasible.Over the past two years, there have been exploratory development or the invention of part wood-based plate starch adhesive
Patent.But starch-based glue stick is for wood-based plate from the point of view of result of study, however it remains resistance to water, adhesive strength, solid content and
A difficult problem for bin stability etc..The wood-based plate technological development aspect that starch adhesive is applied also also has a lot of difficulty needs gram
Clothes.
[summary of the invention]
The present invention provides a kind of novel floor base material, to solve existing starch-based glue stick for wood-based plate, however it remains water-fast
Property, adhesive strength, solid content and bin stability are poor；The problems such as forest reserves loss in a large number.The novel floor base material of the present invention
Physical mechanics property can exceed that LY/T1611-2003 (floor base material fibre board) requirement, and it can replace both having wasted a large amount of timber money
Source, height/medium density fibre board (MDF) that serious free formaldehyde pollutes can be caused to make consolidated floor again, have good economy and
The feature of environmental protection；The present invention can be that the recycling of flyash and waste old provides new way with saving timber resources.
For solve above technical problem, the present invention by the following technical solutions:
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 109-146 part, flyash 17-
24 parts, waste rubber powder 9-12 part, firming agent 1-3 part, waterproofing agent 1-2 part, fire retardant 2-3 part, smoke suppressant 2-3 part, adhesive
14-22 part；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.4-0.8 part, chlordene cyclododecane
0.2-0.5 part, 2-chloroethyl-2-bromoethyl carboxylate 0.2-0.5 part, molybdenum oxide 0.4-0.7 part, Oleum Verniciae fordii based alkyd 0.2-
0.5 part, POLYPROPYLENE GLYCOL 0.2-0.4 part, bentonite 0.4-0.6 part；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.6-1.2 part, zirconium hydroxide
0.6-1.2 part, Pulvis Talci 0.4-0.8 part, ferrum oxide 0.4-0.8 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 106-160 part, dimethyl malenate 14-
17 parts, N,N-dimethylacetamide 12-14 part, sodium hydroxide 2-5 part, epoxy chlorobutane 3-7 part, carbamide 2-5 part, coupling agent
0.3-0.7 part, initiator 0.1-0.4 part, catalyst 0.1-0.3 part, stabilizer 0.1-0.4 part, defoamer 0.5-1 part, plasticising
Agent 0.6-1.2 part, toughener 0.5-0.9 part, viscosifier 0.4-0.8 part；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 17-20Be ', pH value be 3.3-3.6 pea starch slurry I；
S2: starching addition concentration in I to the pea starch of step S1 is the dimethyl malenate of 1%-1.9%, N, N-dimethylacetamide
Amine, coupling agent, catalyst, be then 45-55 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3-under 60-80r/min
4h, prepares slurry II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.2-9.6, be subsequently added into epoxy chlorobutane,
Carbamide, initiator, plasticizer, toughener, viscosifier, be then 56-58 DEG C in temperature, and speed of agitator is under 50-100r/min
Carry out cross-linking reaction 1.5-2h, prepare slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 7.8-8.2, is warming up to 75-79 DEG C, gelatinizing 55-
60min, gelatinizing is down to 30-35 DEG C after terminating, is added defoamer, stirs 10-15min, prepare under rotating speed is 50-100r/min
Adhesive.
Further, described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-.
Further, described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester.
Further, described catalyst is platinum catalyst.
Further, described stabilizer is organic tin stabilizer.
Further, described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether.
Further, described plasticizer is citrate.
The method have the advantages that
(1) by increasing rubber powder, flyash in Traditional Wood fiberboard substrate, wood-based plate can be made to have significant bullet
Property；
(2) present invention can be that the recycling of flyash and waste old provides new way with saving timber resources；
(3) the novel floor substrate material physical mechanical property of the present invention is wanted more than LY/T1611-2003 (floor base material fibre board)
Ask, it can replace not only wasting a large amount of timber resources, but also height/medium density fibre board (MDF) that serious free formaldehyde can be caused to pollute make
Consolidated floor, has good economy and the feature of environmental protection；
(4) primary raw material that the adhesive of the present invention is used is pea starch, belongs to biological material, and price advantage is obvious,
Wide material sources, environmental protection, belong to the rational exploitation and utilization of renewable agricultural resource, the added value of agricultural product can be improved；
(5) in the process route that the adhesive of the present invention composes, any material containing formaldehyde, synthesized gluing are not added
Agent product free formaldehyde release reaches E0 grade standard (≤0.5mg/L), reduces the discharge of formaldehyde, to human body fanout free region, belongs to
Green adhesive；
(6) adhesive of the present invention has solid content high (46.7%-49.4%, higher than pollopas admittedly containing standard), water resistance
Good (75-79h), bonding strength high (7.78-8.24Mpa), hardening time fast (42-45s), storage phase length (>=208-210
My god), reaction condition gentleness, less energy consumption, the feature such as technique is simple, low cost, equipment are simple.
(7) the adhesive bonding strength of the present invention is high and resistance to water is strong, complies fully with relevant mark in GB/T14732-2006
Standard, the Strength of Plywood produced is considerably beyond national II class wood-based plate standard.Can be widely applied to wood-based plate, plywood, fibre
The industrial flow-line of dimension element plate produces, and replaces the use of " three aldehyde " glue, reduces the dependence to fossil resource.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following instance, these examples belong to protection scope of the present invention,
But it is not intended to protection scope of the present invention.
In an embodiment, described novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 109-
146 parts, flyash 17-24 part, waste rubber powder 9-12 part, firming agent 1-3 part, waterproofing agent 1-2 part, fire retardant 2-3 part, press down cigarette
Agent 2-3 part, adhesive 14-22 part, described novel floor base material is by after described raw material mix homogeneously, and mixture is passed through hot pressing
Mode suppress and form；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.4-0.8 part, chlordene cyclododecane
0.2-0.5 part, 2-chloroethyl-2-bromoethyl carboxylate 0.2-0.5 part, molybdenum oxide 0.4-0.7 part, Oleum Verniciae fordii based alkyd 0.2-
0.5 part, POLYPROPYLENE GLYCOL 0.2-0.4 part, bentonite 0.4-0.6 part；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.6-1.2 part, zirconium hydroxide
0.6-1.2 part, Pulvis Talci 0.4-0.8 part, ferrum oxide 0.4-0.8 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 106-160 part, dimethyl malenate 14-
17 parts, N,N-dimethylacetamide 12-14 part, sodium hydroxide 2-5 part, epoxy chlorobutane 3-7 part, carbamide 2-5 part, coupling agent
0.3-0.7 part, initiator 0.1-0.4 part, catalyst 0.1-0.3 part, stabilizer 0.1-0.4 part, defoamer 0.5-1 part, plasticising
Agent 0.6-1.2 part, toughener 0.5-0.9 part, viscosifier 0.4-0.8 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 17-20Be ', pH value be 3.3-3.6 pea starch slurry I；
S2: starching addition concentration in I to the pea starch of step S1 is the dimethyl malenate of 1%-1.9%, N, N-dimethylacetamide
Amine, coupling agent, catalyst, be then 45-55 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3-under 60-80r/min
4h, prepares slurry II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.2-9.6, be subsequently added into epoxy chlorobutane,
Carbamide, initiator, plasticizer, toughener, viscosifier, be then 56-58 DEG C in temperature, and speed of agitator is under 50-100r/min
Carry out cross-linking reaction 1.5-2h, prepare slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 7.8-8.2, is warming up to 75-79 DEG C, gelatinizing 55-
60min, gelatinizing is down to 30-35 DEG C after terminating, is added defoamer, stirs 10-15min, prepare under rotating speed is 50-100r/min
Adhesive.
Below by more specifically embodiment, the present invention will be described.
Embodiment 1
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 130 parts, 20 parts of flyash, useless
Abandon rubber powder 10 parts, 2 parts of firming agent, waterproofing agent 1.5 parts, fire retardant 2.5 parts, smoke suppressant 2.5 parts, adhesive 18 parts, described newly
Type floor base material is by after described raw material mix homogeneously, is suppressed by mixture and form by the way of hot pressing；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.6 part, chlordene cyclododecane 0.4 part,
2-chloroethyl-2-bromoethyl carboxylate 0.4 part, molybdenum oxide 0.6 part, Oleum Verniciae fordii based alkyd 0.4 part, POLYPROPYLENE GLYCOL 0.3 part, swollen
0.5 part of profit soil；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.9 part, zirconium hydroxide 0.9
Part, Pulvis Talci 0.6 part, ferrum oxide 0.6 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 132 parts, dimethyl malenate 15 parts, N,
N-dimethyl acetylamide 13 parts, sodium hydroxide 4 parts, epoxy chlorobutane 5 parts, 4 parts of carbamide, coupling agent 0.5 part, initiator 0.3 part,
Catalyst 0.2 part, stabilizer 0.3 part, defoamer 0.8 part, plasticizer 0.9 part, toughener 0.8 part, viscosifier 0.6 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 18Be ', pH value be 3.4 pea starch slurry I；
S2: starch to the pea starch of step S1 add in I dimethyl malenate that concentration is 1.5%, N,N-dimethylacetamide,
Coupling agent, catalyst, be then 50 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3.5h under 70r/min, prepares slurry
Material II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.4, be subsequently added into epoxy chlorobutane, carbamide,
Initiator, plasticizer, toughener, viscosifier, be then 57 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction under 80r/min
1.8h, prepares slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 8, is warming up to 78 DEG C, and gelatinizing 58min, gelatinizing terminates
After be down to 32 DEG C, add defoamer, under rotating speed is 80r/min stir 12min, prepare adhesive.
Embodiment 2
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 109 parts, 17 parts of flyash, useless
Abandon rubber powder 9 parts, 2 parts of firming agent, waterproofing agent 1 part, fire retardant 2 parts, smoke suppressant 2 parts, adhesive 18 parts, described novel floor base
Material is by after described raw material mix homogeneously, is suppressed by mixture and form by the way of hot pressing；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.4 part, chlordene cyclododecane 0.2 part,
2-chloroethyl-2-bromoethyl carboxylate 0.2 part, molybdenum oxide 0.4 part, Oleum Verniciae fordii based alkyd 0.2 part, POLYPROPYLENE GLYCOL 0.2 part, swollen
0.4 part of profit soil；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.6 part, zirconium hydroxide 0.6
Part, Pulvis Talci 0.4 part, ferrum oxide 0.4 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 106 parts, dimethyl malenate 14 parts, N,
N-dimethyl acetylamide 12 parts, sodium hydroxide 2 parts, epoxy chlorobutane 3 parts, 2 parts of carbamide, coupling agent 0.3 part, initiator 0.1 part,
Catalyst 0.1 part, stabilizer 0.1 part, defoamer 0.5 part, plasticizer 0.6 part, toughener 0.5 part, viscosifier 0.4 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 17Be ', pH value be 3.3 pea starch slurry I；
S2: starch to the pea starch of step S1 and add dimethyl malenate that concentration is 1%, N,N-dimethylacetamide, idol in I
Connection agent, catalyst, be then 45 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 4h under 60r/min, prepares slurry
Ⅱ；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.2, be subsequently added into epoxy chlorobutane, carbamide,
Initiator, plasticizer, toughener, viscosifier, be then 56 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction under 50r/min
2h, prepares slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 7.8, is warming up to 75 DEG C, gelatinizing 60min, and gelatinizing is tied
It is down to 30 DEG C after bundle, adds defoamer, under rotating speed is 50r/min, stirs 15min, prepares adhesive.
Embodiment 3
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 146 parts, 24 parts of flyash, useless
Abandon rubber powder 12 parts, 3 parts of firming agent, waterproofing agent 2 parts, fire retardant 3 parts, smoke suppressant 3 parts, adhesive 22 parts, described novel floor
Base material is by after described raw material mix homogeneously, is suppressed by mixture and form by the way of hot pressing；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.8 part, chlordene cyclododecane 0.5 part,
2-chloroethyl-2-bromoethyl carboxylate 0.5 part, molybdenum oxide 0.7 part, Oleum Verniciae fordii based alkyd 0.5 part, POLYPROPYLENE GLYCOL 0.4 part, swollen
0.6 part of profit soil；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 1.2 parts, zirconium hydroxide 1.2
Part, Pulvis Talci 0.8 part, ferrum oxide 0.8 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 160 parts, dimethyl malenate 17 parts, N,
N-dimethyl acetylamide 14 parts, sodium hydroxide 5 parts, epoxy chlorobutane 7 parts, 5 parts of carbamide, coupling agent 0.7 part, initiator 0.4 part,
Catalyst 0.3 part, stabilizer 0.4 part, defoamer 1 part, plasticizer 1.2 parts, toughener 0.9 part, viscosifier 0.8 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 20Be ', pH value be 3.6 pea starch slurry I；
S2: starch to the pea starch of step S1 add in I dimethyl malenate that concentration is 1.9%, N,N-dimethylacetamide,
Coupling agent, catalyst, be then 55 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3h under 80r/min, prepares slurry
Ⅱ；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.6, be subsequently added into epoxy chlorobutane, carbamide,
Initiator, plasticizer, toughener, viscosifier, be then 58 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction under 100r/min
1.5h, prepares slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 8.2, is warming up to 79 DEG C, gelatinizing 55min, and gelatinizing is tied
It is down to 35 DEG C after bundle, adds defoamer, under rotating speed is 100r/min, stirs 10min, prepares adhesive.
Embodiment 4
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 120 parts, 18 parts of flyash, useless
Abandon rubber powder 11 parts, 2 parts of firming agent, waterproofing agent 2 parts, fire retardant 2 parts, smoke suppressant 2 parts, adhesive 16 parts, described novel floor
Base material is by after described raw material mix homogeneously, is suppressed by mixture and form by the way of hot pressing；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.5 part, chlordene cyclododecane 0.3 part,
2-chloroethyl-2-bromoethyl carboxylate 0.3 part, molybdenum oxide 0.5 part, Oleum Verniciae fordii based alkyd 0.3 part, POLYPROPYLENE GLYCOL 0.2 part, swollen
0.4 part of profit soil；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.7 part, zirconium hydroxide 0.7
Part, Pulvis Talci 0.5 part, ferrum oxide 0.5 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 120 parts, dimethyl malenate 15 parts, N,
N-dimethyl acetylamide 13 parts, sodium hydroxide 3 parts, epoxy chlorobutane 4 parts, 3 parts of carbamide, coupling agent 0.4 part, initiator 0.2 part,
Catalyst 0.2 part, stabilizer 0.2 part, defoamer 0.6 part, plasticizer 0.8 part, toughener 0.6 part, viscosifier 0.5 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 18Be ', pH value be 3.4 pea starch slurry I；
S2: starch to the pea starch of step S1 add in I dimethyl malenate that concentration is 1.2%, N,N-dimethylacetamide,
Coupling agent, catalyst, be then 48 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3.8h under 65r/min, prepares slurry
Material II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.3, be subsequently added into epoxy chlorobutane, carbamide,
Initiator, plasticizer, toughener, viscosifier, be then 57 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction under 60r/min
1.9h, prepares slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 7.9, is warming up to 76 DEG C, gelatinizing 57min, and gelatinizing is tied
It is down to 32 DEG C after bundle, adds defoamer, under rotating speed is 60/min, stirs 14min, prepares adhesive.
Embodiment 5
A kind of novel floor base material, in units of weight portion, including following raw material: broken Poplar Powder 140 parts, 22 parts of flyash, useless
Abandon rubber powder 11 parts, 3 parts of firming agent, waterproofing agent 2 parts, fire retardant 3 parts, smoke suppressant 3 parts, adhesive 20 parts, described novel floor
Base material is by after described raw material mix homogeneously, is suppressed by mixture and form by the way of hot pressing；
Described broken Poplar Powder, smashes more than 30 mesh including poplar sawdust, wood shavings, wood fragments material；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.7 part, chlordene cyclododecane 0.4 part,
2-chloroethyl-2-bromoethyl carboxylate 0.4 part, molybdenum oxide 0.6 part, Oleum Verniciae fordii based alkyd 0.4 part, POLYPROPYLENE GLYCOL 0.3 part, swollen
0.5 part of profit soil；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 1 part, zirconium hydroxide 1 part, cunning
Stone powder 0.7 part, ferrum oxide 0.7 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 150 parts, dimethyl malenate 16 parts, N,
N-dimethyl acetylamide 13 parts, sodium hydroxide 4 parts, epoxy chlorobutane 6 parts, 4 parts of carbamide, coupling agent 0.6 part, initiator 0.3 part,
Catalyst 0.3 part, stabilizer 0.3 part, defoamer 0.9 part, plasticizer 1 part, toughener 0.8 part, viscosifier 0.7 part；
Described coupling agent is 2,5-dimethyl-2, double (benzoyl the peroxide)-hexane of 5-；
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester；
Described catalyst is platinum catalyst；
Described stabilizer is organic tin stabilizer；
Described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether；
Described plasticizer is citrate；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 19Be ', pH value be 3.5 pea starch slurry I；
S2: starch to the pea starch of step S1 add in I dimethyl malenate that concentration is 1.6%, N,N-dimethylacetamide,
Coupling agent, catalyst, be then 52 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3.2h under 75r/min, prepares slurry
Material II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.5, be subsequently added into epoxy chlorobutane, carbamide,
Initiator, plasticizer, toughener, viscosifier, be then 57 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction under 90r/min
1.6h, prepares slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 8.1, is warming up to 78 DEG C, gelatinizing 56min, and gelatinizing is tied
It is down to 34 DEG C after bundle, adds defoamer, under rotating speed is 90r/min, stirs 12min, prepares adhesive.
The adhesive of the present invention is tested according to GB/T 14732-2006 defined method, and test specimen is put into 63 ± 3 DEG C
Hot water in impregnate 3h, then test specimen is lain in the air convection drying case of 63 ± 3 DEG C be dried 1h, after taking-up at room temperature
Cooling 10min, then carry out bonding strength test.The adhesive bonding strength of the present invention, resistance to water all in meet national II class glue
Plywood relevant criterion.
Table 1 below is that the performance test results and the pollopas gluing agent country mark of the adhesive of embodiment 1-5 (accurate are called for short mark
Value) comparison.
Table 1
Reference standard GB/T17657-1999 (test methods of evaluating the properties of wood-based panels and surface decorated wood-based panels), testing example 1-5
The Physical and mechanical properties of novel floor base material, result is as shown in table 2.
Table 2
Above content it cannot be assumed that the present invention is embodied as being confined to these explanations, general for the technical field of the invention
For logical technical staff, without departing under present inventive concept premise, it is also possible to make some simple deduction or replace, all should regard
By belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (7)
1. a novel floor base material, it is characterised in that in units of weight portion, including following raw material: broken Poplar Powder 109-146
Part, flyash 17-24 part, waste rubber powder 9-12 part, firming agent 1-3 part, waterproofing agent 1-2 part, fire retardant 2-3 part, smoke suppressant
2-3 part, adhesive 14-22 part；
Described firming agent is diethyl amino propylamine；
Described waterproofing agent is higher fatty acids waterproofing agent；
Described fire retardant is in units of weight portion, including following raw material: antimony oxide 0.4-0.8 part, chlordene cyclododecane
0.2-0.5 part, 2-chloroethyl-2-bromoethyl carboxylate 0.2-0.5 part, molybdenum oxide 0.4-0.7 part, Oleum Verniciae fordii based alkyd 0.2-
0.5 part, POLYPROPYLENE GLYCOL 0.2-0.4 part, bentonite 0.4-0.6 part；
Described smoke suppressant is in units of weight portion, including following raw material: dibutyl tin laurate 0.6-1.2 part, zirconium hydroxide
0.6-1.2 part, Pulvis Talci 0.4-0.8 part, ferrum oxide 0.4-0.8 part；
Described adhesive, in units of weight portion, including following raw material: pea starch 106-160 part, dimethyl malenate 14-
17 parts, N,N-dimethylacetamide 12-14 part, sodium hydroxide 2-5 part, epoxy chlorobutane 3-7 part, carbamide 2-5 part, coupling agent
0.3-0.7 part, initiator 0.1-0.4 part, catalyst 0.1-0.3 part, stabilizer 0.1-0.4 part, defoamer 0.5-1 part, plasticising
Agent 0.6-1.2 part, toughener 0.5-0.9 part, viscosifier 0.4-0.8 part；
Described toughener is poly-propylene diene rubber；
Described viscosifier are propyl trimethoxy silicane；
The preparation method of described adhesive, comprises the following steps:
S1: compound concentration be 17-20Be ', pH value be 3.3-3.6 pea starch slurry I；
S2: starching addition concentration in I to the pea starch of step S1 is the dimethyl malenate of 1%-1.9%, N, N-dimethylacetamide
Amine, coupling agent, catalyst, be then 45-55 DEG C in temperature, and speed of agitator is to carry out cross-linked graft reaction 3-under 60-80r/min
4h, prepares slurry II；
S3: in the slurry II of step S2 add sodium hydroxide, regulation pH value be 9.2-9.6, be subsequently added into epoxy chlorobutane,
Carbamide, initiator, plasticizer, toughener, viscosifier, be then 56-58 DEG C in temperature, and speed of agitator is under 50-100r/min
Carry out cross-linking reaction 1.5-2h, prepare slurry III；
S4: will add stabilizer in the slurry III of step S3, regulation pH value is 7.8-8.2, is warming up to 75-79 DEG C, gelatinizing 55-
60min, gelatinizing is down to 30-35 DEG C after terminating, is added defoamer, stirs 10-15min, prepare under rotating speed is 50-100r/min
Adhesive.
Novel floor base material the most according to claim 1, it is characterised in that described coupling agent is 2,5-dimethyl-2,5-
Double (benzoyl peroxide)-hexane.
Novel floor base material the most according to claim 1, it is characterised in that described initiator is azo two isopropylformic acid. (third
Olefin(e) acid ethylene glycol) ester.
Novel floor base material the most according to claim 1, it is characterised in that described catalyst is platinum catalyst.
Novel floor base material the most according to claim 4, it is characterised in that described stabilizer is organic tin stabilizer.
Novel floor base material the most according to claim 1, it is characterised in that described defoamer is polyoxyethylene polyoxypropylene
Tetramethylolmethane ether.
Novel floor base material the most according to claim 1, it is characterised in that described plasticizer is citrate.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610704839.2A CN106317930A (en) | 2016-08-22 | 2016-08-22 | Novel floor substrate |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610704839.2A CN106317930A (en) | 2016-08-22 | 2016-08-22 | Novel floor substrate |
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| CN106317930A true CN106317930A (en) | 2017-01-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020173173A1 (en) * | 2019-02-28 | 2020-09-03 | 扬州富铭新材料有限公司 | Environmentally-friendly floor and production method therefor |
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| CN104002355A (en) * | 2014-05-28 | 2014-08-27 | 安徽德翔人造板有限公司 | Environment-friendly laminate floor board substrate |
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| WO2020173173A1 (en) * | 2019-02-28 | 2020-09-03 | 扬州富铭新材料有限公司 | Environmentally-friendly floor and production method therefor |
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Application publication date: 20170111 |