CN106317825A - Electroplating PC-ABS alloy material high in yield and preparation method thereof - Google Patents
Electroplating PC-ABS alloy material high in yield and preparation method thereof Download PDFInfo
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- CN106317825A CN106317825A CN201610696500.2A CN201610696500A CN106317825A CN 106317825 A CN106317825 A CN 106317825A CN 201610696500 A CN201610696500 A CN 201610696500A CN 106317825 A CN106317825 A CN 106317825A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention relates to an electroplating PC-ABS alloy material high in yield and a preparation method thereof. The electroplating PC-ABS alloy material comprises, by weight, 20-70 parts of PC resin, 10-50 parts of small-particle-size ABS resin, 10-50 parts of large-particle-size ABS resin, 5-10 parts of nano calcium carbonate and 0.2-2 parts of auxiliaries. The electroplating PC-ABS alloy material high in yield and the preparation method thereof have the advantages that the PC-ABS alloy material is prepared by the nano calcium carbonate and the ABS resin of different particle sizes, and the prepared alloy material is easy in electroplating and high in electroplating binding force; in addition, the preparation method is simple, practical and high in yield.
Description
Technical field
The present invention relates to polymer blended, Polymer Processing technical field, particularly relate to the electricity of a kind of rate of good quality rate
Plating PC-ABS alloy material and preparation method thereof.
Background technology
Plating PC-ABS alloy material is due to thermostability, toughness and the endurance life of its excellence and plating performance, by extensively
In general application and automobile interior exterior trim, such as inner-outer door handle, vehicle nameplate, wheel clamshell, grid, ornamental strip etc..Galvanizer
In skill, the performance of coarsening process and material is closely bound up.
For PC-ABS material, owing to PC cannot electroplate, the butadiene rubber B in ABS impart material can electricity
Plating performance.After roughening, material surface forms equally distributed hole, and chemical nickel reaches coating by these holes and material is tied
The effect closed.
Owing to product structure is different, cause material surface stress different, be roughened the final plating yields of influential effect；
The level difference of plating producer also can affect plating yields.The roughening window widening plating on material is conducive to improving plating
The yields of PC-ABS.
Summary of the invention
It is an object of the invention to propose the plating PC-ABS alloy material of a kind of rate of good quality rate, component uses nano-calcium carbonate
Calcium and the ABS resin of different-grain diameter, it is thus achieved that the feature that alloy material has easily plating, plating adhesion is high.It addition, nanometer
Calcium carbonate is little due to particle diameter, is easily plated liquid etching, improves the ability that material is easily plated.
It is an object of the invention to propose the preparation method of the plating PC-ABS alloy material of a kind of rate of good quality rate, method letter
Single easy, it is thus achieved that high yields.
For reaching this purpose, the present invention by the following technical solutions:
A kind of plating PC-ABS alloy material of rate of good quality rate, including the component of following parts by weight:
PC resin 20-70 part,
Small particle ABS resin 10-50 part,
Big particle diameter ABS resin 10-50 part,
Nano-calcium carbonate 5-10 part.
Further description, the particle diameter of described small particle ABS resin is 0.1-0.7 μm, described big particle diameter ABS resin
Particle diameter is 1.0-1.5 μm.
Further description, described small particle ABS resin is the graft copolymerization of acrylonitrile-butadiene-styrene (ABS) composition
Thing.The relative molecular weight of described small particle ABS resin is 130000～250000g/mol, and wherein butadiene percentage by weight contains
Amount is 10～60%, and acrylonitrile weight percent content is 15～32%, and styrene weight percent content is 20～40%.
Further description, the ABS resin of described big particle diameter is that the grafting of acrylonitrile-butadiene-styrene (ABS) composition is total to
Polymers.The relative molecular weight of described big particle diameter ABS resin is 100000～180000g/mol, wherein butadiene percentage by weight
Content is 10～30%, and acrylonitrile weight percent content is 15～32%, and styrene weight percent content is 40～60%.
Further description, described nano-calcium carbonate particle diameter is 100～500nm.
Further description, also includes the recipe ingredient of following parts by weight: antioxidant 0.1～1 part, lubricant 0.1
～1 part.
Further description, described antioxidant is the double [β-(3-tertiary butyl-4-hydroxy-5-methylbenzene of triethylene-glycol
Base) propionic ester] (i.e. antioxidant 245), four [β-(3,5-di-t-butyl 4-hydroxy phenyl) propanoic acid] pentaerythritol ester (i.e. antioxidant
1010), three (2,4-di-tert-butyl-phenyl) phosphite ester (i.e. irgasfos 168), double stearyl alcohol tetramethylolmethane diphosphorous acid
The mixing of one or more in ester (i.e. antioxidant 618).
Further description, described lubricant is silane polymer, hard paraffin, liquid paraffin, soap, tristearin
The mixing of one or more in acid calcium fatty acid amide, calcium stearate, zinc stearate, stearic amide.
Further description, the relative molecular weight of described PC resin is 10000～30000g/mol.
The method of the plating PC-ABS alloy material preparing above-mentioned rate of good quality rate that the present invention proposes, comprises the following steps:
A, by PC resin, small particle ABS resin, big particle diameter ABS resin, nano-calcium carbonate, adjuvant add mix and blend
Machine mixes；
B, by step a gained mixture extruding pelletization, obtain the plating PC-ABS alloy particle of rate of good quality rate.
Further description, the mixture of step b gained is blended pelletize by double screw extruder, wherein extrusion temperature
For 200-260 DEG C, screw speed is 200～600rpm.
Compared with prior art, the device have the advantages that into: the preparation method of the present invention is simple, nano-sized carbon
Acid calcium is etched when plating roughening, improve can the volume fraction of etched portions, the ABS resin of different-grain diameter is compounding simultaneously obtains
Obtain the roughening etching point of different depth, by these 2 process windows that improve plating PC-ABS, it is thus achieved that high yields.
Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.
The PC L-1250WS of Di Ren Asahi Chemical Industry selected in following example and comparative example, small particle ABS resin is selected
The petrochemical P/D190 in Korea S's brocade lake, particle diameter is 0.1-0.7 μm, and big particle diameter ABS resin selects the AT-08 of A&L company, particle diameter
For 1.0-1.5 μm；Antioxidant is the Irganox 1010 of Ciba company, Irganox 168, Irganox 618, Irganox
245；Lubricant is commercially available tetramethylolmethane stearic acid.
Comparative example 1
A kind of plating PC-ABS alloy material and preparation method thereof, comprises the following steps:
(1) each component is weighed by weight: PC resin: 50 parts, small particle ABS resin: 50 parts, antioxidant 1010: 0.1
Part, irgasfos 168: 0.1 part, lubricant 0.3 part；
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Comparative example 2
A kind of plating PC-ABS alloy material and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 70 parts, big particle diameter ABS resin: 30 parts, antioxidant 1010: 0.1
Part, irgasfos 168: 0.1 part, lubricant 0.3 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 1
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 20 parts, small particle ABS resin: 50 parts, small particle ABS resin: 20
Part, nano-calcium carbonate: 10 parts；Antioxidant 1010: 0.1 part, irgasfos 168: 0.1 part, lubricant 0.3 part；
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 2
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 55 parts, small particle ABS resin: 30 parts, big particle diameter ABS resin: 10
Part, nano-calcium carbonate: 5 parts；Antioxidant 1010: 0.1 part, irgasfos 168: 0.1 part, lubricant 0.3 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 3
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 58 parts, small particle ABS resin: 10 parts, big particle diameter ABS resin: 25
Part, nano-calcium carbonate: 7 parts；Antioxidant 1010: 0.1 part, irgasfos 168: 0.1 part, lubricant 0.3 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 4
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 58 parts, small particle ABS resin: 10 parts, big particle diameter ABS resin: 25
Part, nano-calcium carbonate: 10 parts；Antioxidant 1010: 0.1 part, irgasfos 168: 0.1 part, lubricant 0.3 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Implementation result comparison
It is molded into the high tabula rasa of 140mm*90mm*3mm, electroplates in Shanghai Electroplate Factory.In the coarsening solution of plating, concentrated sulphuric acid
Being 400g/L with the concentration of chromic acid, Coarsening Temperature is 68 DEG C.
Plating adhesion is carried out according to GMW14668-2010 standard, and draw speed is 100mm/min, and angle is 90 °；
Notch impact strength is carried out according to ASTM D256 standard, and temperature is 23 DEG C.
Test result is as shown in table 1:
Table 1 comparative example 1,2 and the product coarsening time of embodiment 1～4 and test result
As shown in Table 1, embodiment 2 has the impact property of excellence, no matter is roughened 13min or 11min, electroplates adhesion
The highest, electroplate window width, improve the yields of product.Visible nano-calcium carbonate is etched when plating roughening, improves
Can the volume fraction of etched portions, the ABS resin of different-grain diameter compounds the roughening etching point obtaining different depth simultaneously, passes through
These 2 process windows that improve plating PC-ABS, it is thus achieved that high yields.Further description, nano-calcium carbonate due to
Particle diameter is little, is easily plated liquid etching, improves the ability that material is easily plated.
Embodiment 5
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 20 parts, small particle ABS resin: 10 parts, big particle diameter ABS resin: 10
Part, nano-calcium carbonate: 5 parts；Antioxidant 618: 0.1 part, irgasfos 168: 0.1 part, lubricant 0.3 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 240 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 6
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 70 parts, small particle ABS resin: 50 parts, big particle diameter ABS resin: 30
Part, nano-calcium carbonate: 10 parts；Antioxidant 618: 0.5 part, antioxidant 245:0.5 part, lubricant 1 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 260 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 7
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 70 parts, small particle ABS resin: 10 parts, big particle diameter ABS resin: 50
Part, nano-calcium carbonate: 10 parts；Antioxidant 1010: 0.5 part, antioxidant 245:0.5 part, lubricant 1 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 250 DEG C, and through melt extruding, pelletize i.e. obtains product.
Embodiment 8
A kind of plating PC-ABS alloy material of rate of good quality rate and preparation method thereof, the method comprises the following steps:
(1) each component is weighed by weight: PC resin: 50 parts, small particle ABS resin: 10 parts, big particle diameter ABS resin: 20
Part, nano-calcium carbonate: 8 parts；Antioxidant 1010: 0.2 part, antioxidant 245:0.2 part, lubricant 0.5 part.
(2) (a) will mix in all raw materials addition mixing and blending machine；B step a gained mixture is passed through double spiral shells by ()
Bar extruder is blended pelletize, and extrusion temperature is 200 DEG C, and through melt extruding, pelletize i.e. obtains product.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain the present invention's
Principle, and limiting the scope of the invention can not be construed to by any way.Based on explanation herein, the technology of this area
Personnel need not pay performing creative labour can associate other detailed description of the invention of the present invention, and these modes fall within
Within protection scope of the present invention.
Claims (10)
1. the plating PC-ABS alloy material of a rate of good quality rate, it is characterised in that: include the recipe ingredient of following parts by weight:
PC resin 20-70 part,
Small particle ABS resin 10-50 part,
Big particle diameter ABS resin 10-50 part,
Nano-calcium carbonate 5-10 part.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 1, it is characterised in that: described granule
The particle diameter of footpath ABS resin is 0.1-0.7 μm, and the particle diameter of described big particle diameter ABS resin is 1.0-1.5 μm.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 2, it is characterised in that: described granule
Footpath ABS resin is the graft copolymer of acrylonitrile-butadiene-styrene (ABS) composition.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 3, it is characterised in that: described granule
The relative molecular weight of footpath ABS resin is 130000～250000g/mol, wherein butadiene weight percent content be 10～
60%, acrylonitrile weight percent content is 15～32%, and styrene weight percent content is 20～40%.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 2, it is characterised in that: described big grain
The ABS resin in footpath is the graft copolymer of acrylonitrile-butadiene-styrene (ABS) composition.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 5, it is characterised in that: described big grain
The relative molecular weight of footpath ABS resin is 100000～180000g/mol, wherein butadiene weight percent content be 10～
30%, acrylonitrile weight percent content is 15～32%, and styrene weight percent content is 40～60%.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 1, it is characterised in that: described receives
Rice calcium carbonate particle diameter is 100～500nm.
The plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 1, it is characterised in that: also include as
The recipe ingredient of lower parts by weight: antioxidant 0.1～1 part, lubricant 0.1～1 part.
9. the method for the plating PC-ABS alloy material of rate of good quality rate described in any one in preparation right 1-8 to be required, its
It is characterised by: comprise the following steps:
A, PC resin, small particle ABS resin, big particle diameter ABS resin, nano-calcium carbonate, adjuvant are added in mixing and blending machine
Mix；
B, by step a gained mixture extruding pelletization, obtain the plating PC-ABS alloy particle of rate of good quality rate.
The preparation method of the plating PC-ABS alloy material of a kind of rate of good quality rate the most according to claim 9, its feature exists
In: the mixture of step b gained is blended pelletize by double screw extruder, and wherein extrusion temperature is 200-260 DEG C, screw speed
It is 200～600rpm.
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Cited By (4)
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| CN107541045A (en) * | 2017-09-06 | 2018-01-05 | 万华化学集团股份有限公司 | One kind plating PC/ABS alloy materials and its production and use |
| CN108003557A (en) * | 2017-12-29 | 2018-05-08 | 嘉兴市中孚塑业有限公司 | One kind plating lamp door and preparation method thereof |
| CN111073251A (en) * | 2019-12-23 | 2020-04-28 | 宁波帅特龙集团有限公司 | High-yield high-strength electroplating PC/ABS alloy and preparation method thereof |
| CN111393820A (en) * | 2019-11-29 | 2020-07-10 | 东风汽车有限公司 | Electroplating material |
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| Publication number | Publication date |
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| CN106317825B (en) | 2018-11-09 |
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