CN106316306A - Foam concrete for wall filling and preparation method of foam concrete - Google Patents

Foam concrete for wall filling and preparation method of foam concrete Download PDF

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Publication number
CN106316306A
CN106316306A CN201610788669.0A CN201610788669A CN106316306A CN 106316306 A CN106316306 A CN 106316306A CN 201610788669 A CN201610788669 A CN 201610788669A CN 106316306 A CN106316306 A CN 106316306A
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China
Prior art keywords
water
foam concrete
foam
foaming agent
wall filling
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Application number
CN201610788669.0A
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Chinese (zh)
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CN106316306B (en
Inventor
蔡纯荣
陶冶
夏昕
池召坤
黄立语
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Wuhan fulotec Material Technology Co., Ltd
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Wuhan Yongxinmei Green Building New Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)

Abstract

The invention discloses foam concrete for wall filling and a preparation method of the foam concrete. The foam concrete is prepared from raw materials as follows: a cementing material, mixing water, a foaming agent, a water repellent, a foam stabilizer, a coagulant and a water reducing agent, wherein the cementing material is a mixture of Portland cement and aluminate cement, and the aluminate cement accounts for 10%-20% of the Portland cement by mass; the mixing water, the foaming agent, the water repellent, the foam stabilizer, the coagulant and the water reducing agent account for 38%-45%, 0.5%-1%, 1.5%, 0.05%-0.2%, 1%-3% and 0.6%-0.8% of the cementing material by mass respectively. The foam concrete has the characteristics of being light, short in setting time, high in strength, low in water absorption and low in shrinkage and is not prone to mold collapse and sinking, and the surface is not prone to pulverization.

Description

Body of wall filling foam concrete and preparation method thereof
Technical field
The present invention relates to building material technical field, in particular it relates to a kind of body of wall filling foam concrete and system thereof Preparation Method.
Background technology
Cement based foam concrete is uniformly to be introduced in cement mortar by bubble, formed through molding and maintenance containing a large amount of gas The lightweight concrete in hole.Owing to it has the advantage such as light weight, good, the A level not combustion of thermal and insulating performance, it is widely used in The fields such as building heat preservation, wall barrier, Foundation treatment, bank protection process.Due to each field to the performance requirement of foam concrete not With, actual production can be controlled the density of foam concrete by the addition changing bubble, and by adding different merits Component can realize property.
Foam concrete is applied to materials for wall and is usually present some problems, and the foam as used normal silicate to prepare mixes Solidifying soil is longer for setting time, the phenomenon such as mould, sinking of collapsing easily occurs;And use foam concrete prepared by sulphate aluminium cement by Short setting time, aquation is fast, the problems such as the easy efflorescence in surface easily occurs.
Summary of the invention
The deficiency existed for prior art, the invention provides one and is difficult to collapse mould and sinking and surface is not pulverized easily Body of wall filling foam concrete and preparation method thereof.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
One, body of wall filling foam concrete, its raw material includes Binder Materials, mixing water, foaming agent, hydrophober, surely steeps Agent, coagulant and water reducer;Wherein:
Binder Materials is the mixture of portland cement and aluminate cement, and aluminate cement quality is silicate cement shale The 10%~20% of amount;Mixing water, foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer are respectively Binder Materials The 38% of quality~45%, 0.5%~1%, 1.5%, 0.05%~0.2%, 1%~3%, 0.6%~0.8%.
Further, foaming agent is animal protein foaming agent.
Further, hydrophober is calcium stearate.
Further, foam stabilizer is methyl hydroxyethylcellulose ether.
Further, coagulant is sodium aluminate.
Further, water reducer is polycarboxylate water-reducer, white sugar and the mixture of 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP), its In, the mass ratio of polycarboxylate water-reducer, white sugar and 1-hydroxy ethylidene-1,1-diphosphonic acid is 1:(0.1~0.2): (0.1~0.3), and diminishing The solid content of agent is 12%~15%.
Two, the preparation method of above-mentioned body of wall filling foam concrete, including:
Foam after foaming agent and water are mixed, it is thus achieved that foam;
Epoxy glue gel material, hydrophober, foam stabilizer and coagulant obtain mixture, add water reducer and mix in mixture Heshui, agitated acquisition slurry;
Mix-froth and slurry obtain foam concrete.
Further, in foaming after foaming agent and water being mixed, the mass ratio of foaming agent and water is 1:30.
In the present invention, Binder Materials is mixed in proportion by portland cement and aluminate cement and forms, and it reacts raw with water Become there is the Behavior of Hardened Cement Paste of some strength, provide skeleton for foam concrete.Retarder in coagulant and water reducer is as condensation Time adjusts component, can prevent slurry from occurring collapsing according to the setting time of ambient temperature adjustment foam concrete to suitable interval The phenomenon such as mould and sinking.Water reducer is mainly used to reduce the water-cement ratio of foam concrete, while reducing the generation of bleeding passage, Improve foam concrete intensity.Foaming agent is under mechanical external force effect, and formation hydrophobic group is outside, inside the stablizing of hydrophilic group Foam.Foam stabilizer can increase slurry viscosity, the most also can strengthen foamy body, improves foam stability in slurry, enters one Step reduces by lather collapse, excessive and collapse mould and the sinking of foam concrete that cause.Hydrophober not only can significantly reduce foam The water absorption rate of concrete, moreover it is possible to the stability of strengthening foam, plays steady bubble effect.
Compared to the prior art, the invention have the advantages that and beneficial effect:
Foam concrete of the present invention has that lightweight, high intensity, setting time be short, low water absorption, lower shrinkage, the mould that is difficult to collapse, Be difficult to, the feature that is not pulverized easily of surface.The dry density of gained foam concrete is 300~500kg/m3, intensity be 0.4~ 1.5MPa, setting time is 2~5 hours, and within 24 hours, water absorption rate is less than 10%;Pour after molding after 7 days, any depression does not occurs Phenomenon, through form removal sampling discovery body of wall upper and lower unit weight deviation less than 5%, fire-protection rating is A level, is the good of filling materials for wall body Select.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but is not limited solely to example below.
Embodiment 1
In the present embodiment raw material, in Binder Materials, aluminate cement quality is the 10% of portland cement quality, mixing water, Foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer be respectively the 45% of Binder Materials quality, 1%, 1.5%, 0.2%, 3%, 0.6%.Water reducer is the mixture of polycarboxylate water-reducer, white sugar and HEDP, polycarboxylate water-reducer, white sugar and The mass ratio of HEDP is 1:0.2:0.3, and its solid content is 15%.
Take each raw material according to said ratio and prepare foam concrete:
Binder Materials, foam stabilizer, hydrophober and coagulant are stirred 2 minutes in blender, obtains mixture.Mixture Pour blender into, and add mixing water and water reducer stirs 2 minutes, obtain slurry;Meanwhile, by foaming agent and water according to 1:30's Foam in foaming machine after mass ratio mixing, make stable and uniform blebbing by adjusting gas-liquid ratio.By foam and slurry Forced Mixing, forming wet density is 380kg/m3Foam concrete.Foam concrete is poured into body of wall, through blanks and moulding and conserving, will Place fog room standard curing after the test specimen demoulding that sampling is made, stand 28d.
After measured, the present embodiment gained foam concrete striking time is 4.5 hours, and dry density is 310kg/m3, 28d is strong Degree is 0.48MPa, and heat conductivity is 0.07W/ (m k), and within 24 hours, water absorption rate is 9.7%.
Embodiment 2
In the present embodiment raw material, in Binder Materials, aluminate cement quality is the 20% of portland cement quality, mixing water, Foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer be respectively the 38% of Binder Materials quality, 0.6%, 1.5%, 0.05%, 3%, 0.8%.Water reducer is the mixture of polycarboxylate water-reducer, white sugar and HEDP, polycarboxylate water-reducer, white sugar and The mass ratio of HEDP is 1:0.2:0.3, and its solid content is 15%.
Take each raw material according to said ratio and prepare foam concrete:
Binder Materials, foam stabilizer, hydrophober and coagulant are stirred 2 minutes in blender, obtains mixture.Mixture Pour blender into, and add mixing water and water reducer stirs 2 minutes, obtain slurry;Meanwhile, by foaming agent and water according to 1:30's Foam in foaming machine after mass ratio mixing, make stable and uniform blebbing by adjusting gas-liquid ratio.By foam and slurry Forced Mixing, forming wet density is 610kg/m3Foam concrete.Foam concrete is poured into body of wall, through blanks and moulding and conserving, will Place fog room standard curing after the test specimen demoulding that sampling is made, stand 28d.
After measured, the present embodiment gained foam concrete striking time is 2.1 hours, and dry density is 480kg/m3, 28d is strong Degree is 1.2MPa, and heat conductivity is 0.09W/ (m k), and within 24 hours, water absorption rate is 8.3%.
Embodiment 3
In the present embodiment raw material, in Binder Materials, aluminate cement quality is the 10% of portland cement quality, mixing water, Foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer be respectively the 38% of Binder Materials quality, 0.8%, 1.5%, 0.2%, 2%, 0.8%.Water reducer is the mixture of polycarboxylate water-reducer, white sugar and HEDP, polycarboxylate water-reducer, white sugar and The mass ratio of HEDP is 1:0.1:0.1, and its solid content is 12%.
Take each raw material according to said ratio and prepare foam concrete:
Binder Materials, foam stabilizer, hydrophober and coagulant are stirred 2 minutes in blender, obtains mixture.Mixture Pour blender into, and add mixing water and water reducer stirs 2 minutes, obtain slurry;Meanwhile, by foaming agent and water according to 1:30's Foam in foaming machine after mass ratio mixing, make stable and uniform blebbing by adjusting gas-liquid ratio.By foam and slurry Forced Mixing, forming wet density is 570kg/m3Foam concrete.Foam concrete is poured into body of wall, through blanks and moulding and conserving, will Place fog room standard curing after the test specimen demoulding that sampling is made, stand 28d.
After measured, the present embodiment gained foam concrete striking time is 4.2 hours, and dry density is 450kg/m3, 28d is strong Degree is 1.1MPa, and heat conductivity is 0.09W/ (m k), and within 24 hours, water absorption rate is 8.5%.
Embodiment 4
In the present embodiment raw material, in Binder Materials, aluminate cement quality is the 15% of portland cement quality, mixing water, Foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer be respectively the 40% of Binder Materials quality, 0.7%, 1.5%, 0.1%, 3%, 0.7%.Water reducer is the mixture of polycarboxylate water-reducer, white sugar and HEDP, polycarboxylate water-reducer, white sugar and The mass ratio of HEDP is 1:0.1:0.1, and its solid content is 12%.
Take each raw material according to said ratio and prepare foam concrete:
Binder Materials, foam stabilizer, hydrophober and coagulant are stirred 2 minutes in blender, obtains mixture.Mixture Pour blender into, and add mixing water and water reducer stirs 2 minutes, obtain slurry;Meanwhile, by foaming agent and water according to 1:30's Foam in foaming machine after mass ratio mixing, make stable and uniform blebbing by adjusting gas-liquid ratio.By foam and slurry Forced Mixing, forming wet density is 510kg/m3Foam concrete.Foam concrete is poured into body of wall, through blanks and moulding and conserving, will Place fog room standard curing after the test specimen demoulding that sampling is made, stand 28d.
After measured, the present embodiment gained foam concrete striking time is 2.6 hours, and dry density is 390kg/m3, 28d is strong Degree is 0.95MPa, and heat conductivity is 0.8W/ (m k), and within 24 hours, water absorption rate is 9.3%.
Embodiment 5
In the present embodiment raw material, in Binder Materials, aluminate cement quality is the 15% of portland cement quality, mixing water, Foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer be respectively the 41% of Binder Materials quality, 0.5%, 1.5%, 0.15%, 1%, 0.7%.Water reducer is the mixture of polycarboxylate water-reducer, white sugar and HEDP, polycarboxylate water-reducer, white sugar and The mass ratio of HEDP is 1:0.1:0.2, and its solid content is 13%.
Take each raw material according to said ratio and prepare foam concrete:
Binder Materials, foam stabilizer, hydrophober and coagulant are stirred 2 minutes in blender, obtains mixture.Mixture Pour blender into, and add mixing water and water reducer stirs 2 minutes, obtain slurry;Meanwhile, by foaming agent and water according to 1:30's Foam in foaming machine after mass ratio mixing, make stable and uniform blebbing by adjusting gas-liquid ratio.By foam and slurry Forced Mixing, forming wet density is 440kg/m3Foam concrete.Foam concrete is poured into body of wall, through blanks and moulding and conserving, will Place fog room standard curing after the test specimen demoulding that sampling is made, stand 28d.
After measured, it is 5 hours that the present embodiment measures gained foam concrete striking time, and dry density is 340kg/m3, 28d Intensity is 0.54MPa, and heat conductivity is 0.7W/ (m k), and within 24 hours, water absorption rate is 9.5%.
In embodiment 1~5, foaming agent uses animal protein foaming agent, and hydrophober uses calcium stearate, and foam stabilizer uses first Ethylhydroxyethylcellulose ether, coagulant uses sodium aluminate.

Claims (9)

1. body of wall filling foam concrete, is characterized in that:
Described foam concrete, its raw material include Binder Materials, mixing water, foaming agent, hydrophober, foam stabilizer, coagulant and Water reducer;Wherein:
Binder Materials is the mixture of portland cement and aluminate cement, and aluminate cement quality is portland cement quality 10%~20%;Mixing water, foaming agent, hydrophober, foam stabilizer, coagulant, the quality of water reducer are respectively Binder Materials quality 38%~45%, 0.5%~1%, 1.5%, 0.05%~0.2%, 1%~3%, 0.6%~0.8%.
2. body of wall filling foam concrete as claimed in claim 1, is characterized in that:
Described foaming agent is animal protein foaming agent.
3. body of wall filling foam concrete as claimed in claim 1, is characterized in that:
Described hydrophober is calcium stearate.
4. body of wall filling foam concrete as claimed in claim 1, is characterized in that:
Described foam stabilizer is methyl hydroxyethylcellulose ether.
5. body of wall filling foam concrete as claimed in claim 1, is characterized in that:
Described coagulant is sodium aluminate.
6. body of wall filling foam concrete as claimed in claim 1, is characterized in that:
Described water reducer is the mixture of polycarboxylate water-reducer, white sugar and 1-hydroxy ethylidene-1,1-diphosphonic acid, wherein, and polycarboxylic acids diminishing The mass ratio of agent, white sugar and 1-hydroxy ethylidene-1,1-diphosphonic acid is 1:(0.1~0.2): (0.1~0.3).
7. body of wall filling foam concrete as claimed in claim 6, is characterized in that:
The solid content of described water reducer is 12%~15%.
8. the preparation method of the body of wall filling foam concrete described in claim 1, is characterized in that, including:
Foam after foaming agent and water are mixed, it is thus achieved that foam;
Epoxy glue gel material, hydrophober, foam stabilizer and coagulant obtain mixture, add water reducer and mix in mixture Water, agitated acquisition slurry;
Mix-froth and slurry obtain foam concrete.
9. the preparation method of body of wall filling foam concrete as claimed in claim 8, is characterized in that:
In foaming after foaming agent and water being mixed, the mass ratio of foaming agent and water is 1:30.
CN201610788669.0A 2016-08-31 2016-08-31 Wall filling foam concrete and preparation method thereof Active CN106316306B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546037A (en) * 2018-05-09 2018-09-18 吴伟 A kind of low-density foamed waterproof packing material and preparation method thereof
CN108623270A (en) * 2018-05-31 2018-10-09 宁波联城住工科技有限公司 A kind of waterproof foam concrete formula and preparation method thereof
CN113173729A (en) * 2021-04-12 2021-07-27 山东交通学院 Anti-collapse liquid coagulant special for foam concrete cast-in-place wall

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101182158A (en) * 2007-11-26 2008-05-21 江苏博特新材料有限公司 High-temperature retarders suitable for polycarboxylate concrete dehydragent and method for making same
CN105218044A (en) * 2015-09-07 2016-01-06 李启金 A kind of lightweight high bond strength cement insulation board and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101182158A (en) * 2007-11-26 2008-05-21 江苏博特新材料有限公司 High-temperature retarders suitable for polycarboxylate concrete dehydragent and method for making same
CN105218044A (en) * 2015-09-07 2016-01-06 李启金 A kind of lightweight high bond strength cement insulation board and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546037A (en) * 2018-05-09 2018-09-18 吴伟 A kind of low-density foamed waterproof packing material and preparation method thereof
CN108623270A (en) * 2018-05-31 2018-10-09 宁波联城住工科技有限公司 A kind of waterproof foam concrete formula and preparation method thereof
CN113173729A (en) * 2021-04-12 2021-07-27 山东交通学院 Anti-collapse liquid coagulant special for foam concrete cast-in-place wall

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