CN106312070B - Metal matrix diamond tool burns pressure graphite jig carbon-based parting compound and preparation method thereof and application method - Google Patents

Metal matrix diamond tool burns pressure graphite jig carbon-based parting compound and preparation method thereof and application method Download PDF

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Publication number
CN106312070B
CN106312070B CN201610659766.XA CN201610659766A CN106312070B CN 106312070 B CN106312070 B CN 106312070B CN 201610659766 A CN201610659766 A CN 201610659766A CN 106312070 B CN106312070 B CN 106312070B
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powder
carbon
graphite
graphite jig
parting compound
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CN106312070A (en
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冯力
高亚龙
李文生
安国升
姜威
王磊
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Lanzhou University of Technology
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Lanzhou University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/1208Containers or coating used therefor

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The invention discloses a kind of metal matrix diamond tools to burn pressure graphite jig carbon-based parting compound and preparation method thereof and application method, which is prepared by the raw material of following mass percent:Graphite powder 65% 70%;CaCO3Powder 20% 22%;Na2CO3Powder 2.5% 3.5%;MgCO3Powder 2.5% 3.5%;Al2O3Powder 2.5% 3.0%;SiO2Powder 2.5% 3.0%;The sum of weight percent of each component is 100%, and graphite powder, CaCO3Powder, Na2CO3、MgCO3Powder, Al2O3Powder and SiO2The particle size range of powder is 0 40 μm.The carbon-based parting compound of gained of the invention has ideal high temperature resistance, ideal chemically-resistant reactivity worth, and easy-clear;It substantially increases the success rate of diamond abrasive tool making and increases the service life of graphite jig.

Description

Metal matrix diamond tool burns pressure graphite jig carbon-based parting compound and its preparation side Method and application method
Technical field
The present invention relates to chemical fields, and in particular to a kind of metal matrix diamond tool burns pressure graphite jig with carbon-based point Type agent and preparation method thereof and application method.
Background technology
The realization of diamond abrasive industrialized production is known as the breakthrough with milestone significance acquired by Abrasive Industry Property achievement, being machined into one and have ready conditions the epoch of high-efficiency and precision operation may be implemented from this material.Almost start to walk from this, Various countries by high-efficiency and precision process for the purpose of each diamond-like concretion abrasive tool also begin to flourish.
And it is main to make metallic bond used in diamond abrasive tool to mostly use bronze, iron, cobalt, nickel alloy greatly Bond material, used method are mostly sintering process.Basically the making of diamond tool is by powder forming and sintering Two procedures composition, under special circumstances, forming process is not important, but sintering circuit or the high temperature work for being equivalent to sintering Sequence is indispensable.Sintering is also last one of master operation of diamond tool production process, to the performance of final products It plays a decisive role, because waste product caused by sintering can not be saved by subsequent handling, sintering plays " checking on " product quality Effect.
But during burning pressure, due to burning pressure graphite jig used and the close contact of diamond abrasive tool, in high temperature The metallic bond part of lower low melting point is melted, and is immersed in the slight void of graphite jig, be bonded with graphite jig generation, die sinking Parting can cause diamond tool the defects of fracture, deformation occur, reduce the success rate for making diamond abrasive tool, simultaneously Reduce the service life of graphite jig.
Then, there is parting compound, but also occur many problems, such as high score when using currently used parting compound The son amount typical defect of parting compound is exactly that parting number is undesirable, continuous parting is not up to standard;Metal mold parting compound when in use can There is bonding, carbon deposition phenomenon etc., it is undesirable that the main problem of the above common parting compound can be summarized as high temperature resistance, resistance to Chemical reactivity is not high enough, not easy-clear.
Invention content
To solve the above problems, the present invention provides a kind of metal matrix diamond tools to burn pressure graphite jig with carbon-based point Type agent and preparation method thereof and application method.
To achieve the above object, the technical solution that the present invention takes is:
Metal matrix diamond tool burns the pressure carbon-based parting compound of graphite jig, is prepared by the raw material of following mass percent It forms:
Carbon dust (graphite) 65%-70%;CaCO3Powder 20%-22%;Na2CO3Powder 2.5%-3.5%;MgCO3Powder 2.5%- 3.5%;Al2O3Powder 2.5%-3.0%;SiO2Powder 2.5%-3.0%;The sum of weight percent of each component is 100%, and carbon Powder (graphite), CaCO3Powder, Na2CO3、MgCO3Powder, Al2O3Powder and SiO2The particle size range of powder is 0-40 μm.
Above-mentioned metal matrix diamond tool burns the preparation method of the pressure carbon-based parting compound of graphite jig, including walks as follows Suddenly:
After each raw material being weighed by above-mentioned formula, ball milling mixing, you can obtain metal powder and burn pressure graphite jig with carbon-based point Type agent.
Gained metal matrix diamond tool burns the application method of the pressure carbon-based parting compound of graphite jig, including walks as follows Suddenly:
S1, by graphite mold surface deashing;
S2, carbon-based parting compound is taken uniformly to brush in graphite mold surface using banister brush is viscous;
S3, the sintering of metal matrix diamond tool;
S4, cooling parting;Then step S1-S4 is repeated.
The invention has the advantages that:
The carbon-based parting compound of gained of the invention has ideal high temperature resistance, ideal chemically-resistant reactivity worth, and easily It removes;Use the carbon-based parting compound obtained by the present invention that can make graphite jig that there is good detach with diamond abrasive tool Property, it substantially increases the success rate of diamond abrasive tool making and increases the service life of graphite jig;It is thick when use Degree can regulate and control and can store for a long time, to substantially increase economic benefit.
Description of the drawings
Fig. 1 is the back scattering that metal matrix diamond tool of the embodiment of the present invention burns the pressure carbon-based parting compound of graphite jig Figure.
Fig. 2 diamond ultra-thins saw blade is adhered cross section microscopic appearance figure with graphite jig.
Fig. 3 graphite jigs are adhered the microscopic appearance figure after transversal mirror polish with metal matrix diamond saw blade.
Specific implementation mode
In order to make objects and advantages of the present invention be more clearly understood, the present invention is carried out with reference to embodiments further It is described in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this hair It is bright.
An embodiment of the present invention provides a kind of metal matrix diamond tool burn pressure the carbon-based parting compound of graphite jig, by with The raw material of lower mass percent is prepared:
Carbon dust (graphite) 65%-70%;CaCO3Powder 20%-22%;Na2CO3Powder 2.5%-3.5%;MgCO3Powder 2.5%- 3.5%;Al2O3Powder 2.5%-3.0%;SiO2Powder 2.5%-3.0%;The sum of weight percent of each component is 100%, and carbon Powder (graphite), CaCO3Powder, Na2CO3、MgCO3Powder, Al2O3Powder and SiO2The particle size range of powder is 0-40 μm.
The embodiment of the present invention additionally provides above-mentioned metal matrix diamond tool and burns the pressure carbon-based parting compound of graphite jig Preparation method includes the following steps:
After each raw material being weighed by above-mentioned formula, ball milling mixing, you can obtain metal powder and burn pressure graphite jig with carbon-based point Type agent.
Gained metal matrix diamond tool burns the application method of the pressure carbon-based parting compound of graphite jig, including walks as follows Suddenly:
S1, by graphite mold surface deashing;
S2, carbon-based parting compound is taken uniformly to brush in graphite mold surface using banister brush is viscous;
S3, the sintering of metal matrix diamond tool;
S4, cooling parting;Then step S1-S4 is repeated.
This specific implementation has good electric conductivity (will not be to graphite jig and gold due to containing a large amount of carbon dust in formula The electric conductivity belonged between carcass diamond tool has a negative impact), while its lubricity well makes graphite jig and diamond Abrasive material tools have good separation property, eliminate fracture, deformation etc. that diamond tool occurs when without using carbon-based parting compound Defect substantially increases the success rate of diamond abrasive tool making.Meanwhile metal matrix diamond tool burns pressure graphite jig With carbon dust, the Na in carbon-based parting agent prescription2CO3Powder, MgCO3Powder, Al2O3Powder, SiO2Powder and CaCO3Powder is filled in graphite table It in the slight void in face, does not react with graphite jig, does not also react with metallic bond, less occur with diamond Reaction.Therefore stronger mechanical snap power will not be formed.
In this specific implementation each component there is it specifically to act on (carbon dust i.e. graphite-phase is led for other parting compounds Electrically preferable and its heat-resisting quantity is good, simultaneously because its lubricity is good, makes graphite jig and diamond tool separation property very It is good;Na2CO3Powder and MgCO3Powder have cementability, so that parting compound is preferably sticked to die surface, will not molding sintering before from Graphite mold surface is fallen;CaCO3Powder keeps the parting compound being laid on graphite jig uniform, while and Al2O3Powder and SiO2Powder has There is supporting role)
The particle size range of each component is 0-40 μm in this specific implementation formula, and the thickness that when use smears can arbitrarily regulate and control, It need to only be selected according to working condition, and not influence the mouldability of diamond tool.
Carbon-based parting compound obtained by this specific implementation can be stored for a long time, make succinctly, only need parting compound each component according to the ratio Ball milling mixing is carried out after weighing to be obtained, when use with banister brush by the carbon-based parting compound brushing prepared in graphite surface.
Metal matrix diamond tool provided by the invention burns back scattering Fig. 1 institutes of the pressure carbon-based parting compound of graphite jig Show.
Fig. 2 is when not burning pressure slim diamond blade using carbon-based parting compound, and saw blade is adhered cross section with graphite jig Microscopic appearance figure, the right black portions are graphite jigs, and left side light-colored part is metal matrix diamond ultra-thin saw blade.We It can see graphite mold surface and rough from figure, internal not fine and close have crackle and gap.It is flowed when metal matrix high temperature Property it is good, invade in graphite jig, form more close mechanical bond after cooling meat, can not parting take out saw blade, if by force Open form processed can cause saw blade and burn failure.
Fig. 3 is saw blade and graphite jig in no burning pressure super thin metal carcass diamond saw blade using carbon-based parting compound The pattern being adhered after fracture polishing.Intermediate light-colored part is super thin metal carcass diamond saw blade in figure, and both sides black portions are Graphite jig.The metal of low melting point is molten in hot conditions part in metal matrix diamond saw blade as we can clearly see from the figure Change, soaks in the minim gap of people's graphite jig to generate close mechanical bond with graphite jig.This phenomenon will lead to stone Black mold can not open form take out saw blade, can mold damage and diamond saw blade if open form by force;Reduce metal matrix Buddha's warrior attendant The production efficiency and economic benefit of lapicide's tool.
With specific function, (carbon dust, that is, graphite is with well during burning is molded for each component in this specific implementation Electric conductivity, while its lubricity is good, electric conductivity have ensured the conductive heater burnt during pressure, lubricity be easy to graphite jig with The separation of diamond tool;Na2CO3Powder and MgCO3Powder has preferable surface-active, and parting compound is enable preferably to be sticked to graphite Die surface;CaCO3Powder can make parting compound powder evenly laid out in graphite mold surface, while and Al2O3Powder and SiO2Powder is being burnt Pressure during play certain supporting role), so that graphite jig is detached with metal matrix diamond tool perfection, be not on The fracture apperance in face.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (3)

1. metal matrix diamond tool burns the pressure carbon-based parting compound of graphite jig, which is characterized in that by following mass percent Raw material be prepared:
Graphite powder 65%-70%;CaCO3Powder 20%-22%;Na2CO3Powder 2.5%-3.5%;MgCO3Powder 2.5%-3.5%; Al2O3Powder 2.5%-3.0%;SiO2Powder 2.5%-3.0%;The sum of weight percent of each component is 100%, and graphite powder, CaCO3Powder, Na2CO3、MgCO3Powder, Al2O3Powder and SiO2The particle size range of powder is 0-40 μm.
2. metal matrix diamond tool as described in claim 1 burns the preparation method of the pressure carbon-based parting compound of graphite jig, It is characterised in that it includes following steps:
After formula as described in claim 1 weighs each raw material, ball milling mixing, you can obtain metal powder and burn pressure graphite jig carbon Base parting compound.
3. metal matrix diamond tool as described in claim 1 burns the application method of the pressure carbon-based parting compound of graphite jig, It is characterised in that it includes following steps:
S1, by graphite mold surface deashing;
S2, carbon-based parting compound is taken uniformly to brush in graphite mold surface using banister brush is viscous;
S3, the sintering of metal matrix diamond tool;
S4, cooling parting;Then step S1-S4 is repeated.
CN201610659766.XA 2016-08-09 2016-08-09 Metal matrix diamond tool burns pressure graphite jig carbon-based parting compound and preparation method thereof and application method Active CN106312070B (en)

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* Cited by examiner, † Cited by third party
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FR2773728B1 (en) * 1998-01-16 2000-03-17 Pechiney Electrometallurgie POWDER PRODUCT FOR THE PROTECTION OF CENTRIFUGAL CAST MOLDS FROM CAST IRON AND POTENTIAL PREPARATION METHOD
CN101036933A (en) * 2007-04-11 2007-09-19 华中科技大学 Powderlike mold-releasing agent for die-casing
CN102039367A (en) * 2009-10-09 2011-05-04 韦加伟 Application technology of novel release agent in centrifugal casting of cylinder liner
CN102009121B (en) * 2010-12-31 2012-07-25 攀枝花钢城集团有限公司 Releasing agent for pig machine and preparation and application methods thereof
CN105127364B (en) * 2015-08-25 2018-10-09 苏州热工研究院有限公司 The mould wash and its brushing method of centrifugal casting casting

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