CN106297595A - A kind of building advertisement system structure - Google Patents
A kind of building advertisement system structure Download PDFInfo
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- CN106297595A CN106297595A CN201610626375.8A CN201610626375A CN106297595A CN 106297595 A CN106297595 A CN 106297595A CN 201610626375 A CN201610626375 A CN 201610626375A CN 106297595 A CN106297595 A CN 106297595A
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- Prior art keywords
- cellophane
- solution
- slurry
- system structure
- panel district
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F15/00—Boards, hoardings, pillars, or like structures for notices, placards, posters, or the like
- G09F15/0006—Boards, hoardings, pillars, or like structures for notices, placards, posters, or the like planar structures comprising one or more panels
- G09F15/0012—Boards, hoardings, pillars, or like structures for notices, placards, posters, or the like planar structures comprising one or more panels frames therefor
Abstract
The invention discloses a kind of building advertisement system structure, including base and support body；The top of described support body is provided with the first panel district, and the middle part of described support body is provided with Zhan Gequ, and the bottom of described support body is provided with the second panel district symmetrical with described first panel district；Described first panel district and described second surface, panel district are pasted with cellophane.
Description
Technical field
The present invention relates to technical field of advertisement, particularly relate to a kind of building advertisement system structure.
Background technology
Building advertisement system, owing to can directly pass information to the audient really needed, therefore suffers from more and more using
Liking of family.But, the building advertisement system used in correlation technique is substantially more expensive, and the most easy to clean.
Summary of the invention
It is desirable to provide a kind of building advertisement system structure, to solve above-mentioned technical problem.
Embodiments of the invention provide a kind of building advertisement system structure, including base and support body；Described support body
Top is provided with the first panel district, and the middle part of described support body is provided with Zhan Gequ, and the bottom of described support body is provided with and described
The second panel district that one panel district is symmetrical；Described first panel district and described second surface, panel district are pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Accompanying drawing explanation
Accompanying drawing herein is merged in description and constitutes the part of this specification, it is shown that meet the enforcement of the present invention
Example, and for explaining the principle of the present invention together with description.
Fig. 1 is the structural representation of the present invention.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.
Wherein: 1-the first panel district, 2-Zhan Ge district, 3-support body, 4-base, 5-the second panel district.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
In the description of the present application, it should be noted that unless otherwise prescribed and limit, term " is installed ", " being connected ",
" connect " and should be interpreted broadly, for example, it may be mechanically connected or electrical connection, it is also possible to be the connection of two element internals, can
Being to be joined directly together, it is also possible to be indirectly connected to by intermediary, for the ordinary skill in the art, can basis
Concrete condition understands the concrete meaning of above-mentioned term.
The invention will be further described with the following Examples.
Application scenarios 1
Fig. 1 is according to a kind of building advertisement system structure shown in an exemplary embodiment, as it is shown in figure 1,1, Yi Zhonglou
Space ad system structure, including base 4 and support body 3, the top of described support body 3 is provided with the first panel district 1, described support body 3
Middle part is provided with Zhan Ge district 2, and the bottom of described support body 3 is provided with and the second panel district 5 of described first panel district 1 symmetry；Institute
State the first panel district 1 and described second surface, panel district 5 and be pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Preferably, described cellophane sticks in described first panel district 1 and described second panel district 5 by pasting agent.
Preferably, pasting agent described in, to be that macromolecule is organic transparent paste agent.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.With reference to Fig. 2, the preparation method of described cellophane comprises the following steps:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000
～under the rotating speed of 10000rpm/min, stir 5min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour into point
Dissipate in pulp solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Use stretched dropper by
Dropping sodium hypochlorite enters and reacts 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixing slurry through reaction
Material solution obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；By oxygen
Slurrying is done homogenizing through microfluidizer with the pressure of 3000 psi and is processed, and obtains the dispersion of gelatinous nanofibrils cellulose
Body, preserves under conditions of nanofibrils cellulose dispersion is placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add
93～95ml ultra-pure waters use ultrasonic disperse 30min, takes CNT 80.0mg, add ultrasonic 30min in above-mentioned solution, take
Going out and be placed on magnetic stirring apparatus, adjust the temperature to 30～45 DEG C, mixing speed is 5000～8000rpm/min, adds two
Magnet rotor, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and it is antibacterial former that reaction 1h obtains CNT silver
Liquid；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose that will prepare in step S1 disperses
Body uses distilled water to be diluted to 0.1wt%, is then placed within magnetic stirring apparatus stirring with 1000rpm/min speed
30min；Being that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1% by mass dryness fraction, the fiber being sufficiently stirred for making wadding poly-fills
Dispersion；By standby after 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt%；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose divides
A prose style free from parallelism is mixed to form mixed solution, and above-mentioned mixed liquor is placed in evacuation in plastic bag, uses under the protection of nitrogen13Cs γ penetrates
Above-mentioned mixed liquor is radiated by beta radiation source, and the mixed solution after overshoot is poured in buchner funnel filtration, is formed
One layer of wet NFC layer the thinnest, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, should
Double-decker use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, by above-mentioned NFC
Duplex paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
Series of processes through above-mentioned steps is processed, and is made for a kind of cellophane with anti-microbial property.Use Lambda
Ultraviolet-uisible spectrophotometer and with reference to international standard the method provided by embodiments of the invention is prepared from transparent
Paper carries out the relative analysis of light transmission and anti-microbial property, the analysis found that, the cellophane light transmission of this enforcement preparation is
80～97.65%, and show excellent anti-microbial property.
Preferably, each reaction temperature in step S1 is 23～27 DEG C；0.5%～2.0% starches dense TEMPO oxidation slurry
PH value is 8～15.
Preferably, in step S3, at a diameter of the 70～90mm of the filter paper that buchner funnel is placed, the quantity of filter paper is 2～3
, filter paper is also placed with 1～2 a diameter of 90mm, aperture is the PVDF filter membrane of 0.65 micron.
Experiment test:
(1) anti-microbial property test: using absorbance method, detection cellophane is to escherichia coli and the fungistatic effect of mycete.Knot
Fruit is as shown in Table 1 and Table 2.
Table 1 cellophane is to colibacillary antibacterial absorbance
| OD680 | |
| Blank | 8±0.01 |
| 0.5% | 7.5±0.05 |
| 0.75% | 6±0.08 |
| 1.0% | 0.22±0.08 |
| 1.5% | 0.03±0.02 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
The cellophane that row radiation is made after irradiating, has the anti-escherichia coli performance of excellence, after testing through 480h, and its antibacterial effect
Fruit and the 1h started do not have significant difference.
Use absorbance method, detect the cellophane fungistatic effect to mycete.Result is as shown in table 2.
The table 2 cellophane antibacterial absorbance to mycete
| OD680 | |
| Blank | 6±0.01 |
| 0.5% | 6±0.05 |
| 0.75% | 4±0.08 |
| 1.0% | 0.10±0.06 |
| 1.5% | 0.05±0.01 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
Row radiation irradiate after the cellophane made, there is the Anti-mildew capability of excellence, after testing through 480h, its antibacterial effect and
The 1h started does not has significant difference.
(2) test of efficiency of light absorption
Cellophane is pasted in substrate of glass, measures its efficiency of light absorption by optical detecting platform.By incident illumination with
The vertical angle initialization in cellophane surface is 90 °, will start to calculate scattering when the intensity of transmission light reaches the 5% of maximum intensity
Angle.By a branch of a diameter of 0.5cm, wavelength is that the red laser of 500nm irradiates cellophane, and laser is by after cellophane, in the back of the body
Scape defines the aperture of a diameter of 25.6cm.By above-mentioned light vertical irradiation in the substrate of glass being pasted with cellophane, its
Light absorption is reached 80～97.65%.
(3) hot strength test
Being tested by Compression and Expansion, the cellophane that is prepared from of method using the present embodiment to provide has and well draws
Stretch intensity (60～72MPa) and excellent ductility (elongation percentage is 45～50%), be in correlation technique conventional common the most again
13～18 times of raw cellulose membrane.
Test result indicate that: this cellophane has anti-microbial property, good light transmittance and the useful tensile property of excellence,
The light transmittance using the ad system structure that this cellophane makes greatly enhances；Making that the display of ad system structure is relatively sharp can
See, and be easy to cleaning.
Application scenarios 2
Fig. 1 is according to a kind of building advertisement system structure shown in an exemplary embodiment, as it is shown in figure 1,1, Yi Zhonglou
Space ad system structure, including base 4 and support body 3, the top of described support body 3 is provided with the first panel district 1, described support body 3
Middle part is provided with Zhan Ge district 2, and the bottom of described support body 3 is provided with and the second panel district 5 of described first panel district 1 symmetry；Institute
State the first panel district 1 and described second surface, panel district 5 and be pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Preferably, described cellophane sticks in described first panel district 1 and described second panel district 5 by pasting agent.
Preferably, pasting agent described in, to be that macromolecule is organic transparent paste agent.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.With reference to Fig. 2, the preparation method of described cellophane comprises the following steps:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000
～under the rotating speed of 10000rpm/min, stir 5min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour into point
Dissipate in pulp solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Use stretched dropper by
Dropping sodium hypochlorite enters and reacts 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixing slurry through reaction
Material solution obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；By oxygen
Slurrying is done homogenizing through microfluidizer with the pressure of 3000psi and is processed, and obtains gelatinous nanofibrils cellulose dispersion,
Preserve under conditions of nanofibrils cellulose dispersion is placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add
93～95ml ultra-pure waters use ultrasonic disperse 30min, take CNT 80.0mg, add ultrasonic 30min in above-mentioned solution,
Taking-up is placed on magnetic stirring apparatus, adjusts the temperature to 30～45 DEG C, and mixing speed is 5000～8000rpm/min, adds two
Individual magnet rotor, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and it is antibacterial that reaction 1h obtains CNT silver
Stock solution；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose that will prepare in step S1 disperses
Body uses distilled water to be diluted to 0.1wt%, is then placed within magnetic stirring apparatus stirring with 1000rpm/min speed
30min；Being that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1% by mass dryness fraction, the fiber being sufficiently stirred for making wadding poly-fills
Dispersion；By standby after 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt%；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose divides
A prose style free from parallelism is mixed to form mixed solution, and above-mentioned mixed liquor is placed in evacuation in plastic bag, uses under the protection of nitrogen13Cs γ penetrates
Above-mentioned mixed liquor is radiated by beta radiation source, and the mixed solution after overshoot is poured in buchner funnel filtration, is formed
One layer of wet NFC layer the thinnest, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, should
Double-decker use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, by above-mentioned NFC
Duplex paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
Series of processes through above-mentioned steps is processed, and is made for a kind of cellophane with anti-microbial property.Use Lambda
Ultraviolet-uisible spectrophotometer and with reference to international standard the method provided by embodiments of the invention is prepared from transparent
Paper carries out the relative analysis of light transmission and anti-microbial property, the analysis found that, the cellophane light transmission of this enforcement preparation is
80%, and show excellent anti-microbial property.
Preferably, each reaction temperature in step S1 is 23 DEG C；0.5%% pH value starching dense TEMPO oxidation slurry is 8.
Preferably, in step S3, at a diameter of 70mm of the filter paper that buchner funnel is placed, the quantity of filter paper is 2, in filter
Also being placed with 1 a diameter of 90mm on paper, aperture is the PVDF filter membrane of 0.65 micron.
Experiment test:
(1) anti-microbial property test: using absorbance method, detection cellophane is to escherichia coli and the fungistatic effect of mycete.Knot
Fruit is as shown in Table 1 and Table 2.
Table 1 cellophane is to colibacillary antibacterial absorbance
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
The cellophane that row radiation is made after irradiating, has the anti-escherichia coli performance of excellence, after testing through 480h, and its antibacterial effect
Fruit and the 1h started do not have significant difference.
Use absorbance method, detect the cellophane fungistatic effect to mycete.Result is as shown in table 2.
The table 2 cellophane antibacterial absorbance to mycete
| OD680 | |
| Blank | 6±0.01 |
| 0.5% | 6±0.03 |
| 0.75% | 4.5±0.08 |
| 1.0% | 0.12±0.06 |
| 1.5% | 0.06±0.01 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
Row radiation irradiate after the cellophane made, there is the Anti-mildew capability of excellence, after testing through 480h, its antibacterial effect and
The 1h started does not has significant difference.
(2) test of efficiency of light absorption
Cellophane is pasted in substrate of glass, measures its efficiency of light absorption by optical detecting platform.By incident illumination with
The vertical angle initialization in cellophane surface is 90 °, will start to calculate scattering when the intensity of transmission light reaches the 5% of maximum intensity
Angle.By a branch of a diameter of 0.5cm, wavelength is that the red laser of 500nm irradiates cellophane, and laser is by after cellophane, in the back of the body
Scape defines the aperture of a diameter of 26cm.By above-mentioned light vertical irradiation in the substrate of glass being pasted with cellophane, it is right
Light absorption reaches 80%.
(3) hot strength test
Being tested by Compression and Expansion, the cellophane that the method using the present embodiment to provide is prepared from has well stretching
Intensity (60MPa) and excellent ductility (elongation percentage is 45%), be common regenerated cellulose film conventional in correlation technique
12 times.
This cellophane has anti-microbial property, good light transmittance and the useful tensile property of excellence, uses this cellophane
The light transmittance of the ad system structure made greatly enhances；The display making ad system structure is relatively sharp visible, and is easy to clear
Clean.
Application scenarios 3
Fig. 1 is according to a kind of building advertisement system structure shown in an exemplary embodiment, as it is shown in figure 1,1, Yi Zhonglou
Space ad system structure, including base 4 and support body 3, the top of described support body 3 is provided with the first panel district 1, described support body 3
Middle part is provided with Zhan Ge district 2, and the bottom of described support body 3 is provided with and the second panel district 5 of described first panel district 1 symmetry；Institute
State the first panel district 1 and described second surface, panel district 5 and be pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Preferably, described cellophane sticks in described first panel district 1 and described second panel district 5 by pasting agent.
Preferably, pasting agent described in, to be that macromolecule is organic transparent paste agent.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.With reference to Fig. 2, the preparation method of described cellophane comprises the following steps:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000
～under the rotating speed of 10000rpm/min, stir 5min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour into point
Dissipate in pulp solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Use stretched dropper by
Dropping sodium hypochlorite enters and reacts 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixing slurry through reaction
Material solution obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；By oxygen
Slurrying is done homogenizing through microfluidizer with the pressure of 3000psi and is processed, and obtains gelatinous nanofibrils cellulose dispersion,
Preserve under conditions of nanofibrils cellulose dispersion is placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add
93～95ml ultra-pure waters use ultrasonic disperse 30min, takes CNT 80.0mg, add ultrasonic 30min in above-mentioned solution, take
Going out and be placed on magnetic stirring apparatus, adjust the temperature to 30～45 DEG C, mixing speed is 5000～8000rpm/min, adds two
Magnet rotor, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and it is antibacterial former that reaction 1h obtains CNT silver
Liquid；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose that will prepare in step S1 disperses
Body uses distilled water to be diluted to 0.1wt%, is then placed within magnetic stirring apparatus with 1000 rpm/min speed stirrings
30min；Being that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1% by mass dryness fraction, the fiber being sufficiently stirred for making wadding poly-fills
Dispersion；By standby after 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt%；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose divides
A prose style free from parallelism is mixed to form mixed solution, and above-mentioned mixed liquor is placed in evacuation in plastic bag, uses under the protection of nitrogen13Cs γ penetrates
Above-mentioned mixed liquor is radiated by beta radiation source, and the mixed solution after overshoot is poured in buchner funnel filtration, is formed
One layer of wet NFC layer the thinnest, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, should
Double-decker use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, by above-mentioned NFC
Duplex paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
Series of processes through above-mentioned steps is processed, and is made for a kind of cellophane with anti-microbial property.Use Lambda
Ultraviolet-uisible spectrophotometer and with reference to international standard the method provided by embodiments of the invention is prepared from transparent
Paper carries out the relative analysis of light transmission and anti-microbial property, the analysis found that, the cellophane light transmission of this enforcement preparation is
90%, and show excellent anti-microbial property.
Preferably, each reaction temperature in step S1 is 24 DEG C；1.0% pH value starching dense TEMPO oxidation slurry is 10.
Preferably, in step S3, at a diameter of 80mm of the filter paper that buchner funnel is placed, the quantity of filter paper is 2～3,
Also being placed with 1～2 a diameter of 90mm on filter paper, aperture is the PVDF filter membrane of 0.65 micron.
Experiment test:
(1) anti-microbial property test: using absorbance method, detection cellophane is to escherichia coli and the fungistatic effect of mycete.Knot
Fruit is as shown in Table 1 and Table 2.
Table 1 cellophane is to colibacillary antibacterial absorbance
| OD680 | |
| Blank | 8±0.01 |
| 0.5% | 7.8±0.01 |
| 0.75% | 6.5±0.08 |
| 1.0% | 0.32±0.08 |
| 1.5% | 0.05±0.02 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
The cellophane that row radiation is made after irradiating, has the anti-escherichia coli performance of excellence, after testing through 480h, and its antibacterial effect
Fruit and the 1h started do not have significant difference.
Use absorbance method, detect the cellophane fungistatic effect to mycete.Result is as shown in table 2.
The table 2 cellophane antibacterial absorbance to mycete
| OD680 | |
| Blank | 6±0.01 |
| 0.5% | 6.5±0.05 |
| 0.75% | 4.0±0.08 |
| 1.0% | 0.15±0.06 |
| 1.5% | 0.08±0.01 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
Row radiation irradiate after the cellophane made, there is the Anti-mildew capability of excellence, after testing through 480h, its antibacterial effect and
The 1h started does not has significant difference.
(2) test of efficiency of light absorption
Cellophane is pasted in substrate of glass, measures its efficiency of light absorption by optical detecting platform.By incident illumination with
The vertical angle initialization in cellophane surface is 90 °, will start to calculate scattering when the intensity of transmission light reaches the 5% of maximum intensity
Angle.By a branch of a diameter of 0.5cm, wavelength is that the red laser of 500nm irradiates cellophane, and laser is by after cellophane, in the back of the body
Scape defines the aperture of a diameter of 27cm.By above-mentioned light vertical irradiation in the substrate of glass being pasted with cellophane, it is right
Light absorption reaches 90%.
(3) hot strength test
Being tested by Compression and Expansion, the cellophane that the method using the present embodiment to provide is prepared from has well stretching
Intensity (68MPa) and excellent ductility (elongation percentage is 46%), be common regenerated cellulose film conventional in correlation technique
15 times.
This cellophane has anti-microbial property, good light transmittance and the useful tensile property of excellence, uses this cellophane
The light transmittance of the ad system structure made greatly enhances；The display making ad system structure is relatively sharp visible, and is easy to clear
Clean.
Application scenarios 4
Fig. 1 is according to a kind of building advertisement system structure shown in an exemplary embodiment, as it is shown in figure 1,1, Yi Zhonglou
Space ad system structure, including base 4 and support body 3, the top of described support body 3 is provided with the first panel district 1, described support body 3
Middle part is provided with Zhan Ge district 2, and the bottom of described support body 3 is provided with and the second panel district 5 of described first panel district 1 symmetry；Institute
State the first panel district 1 and described second surface, panel district 5 and be pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Preferably, described cellophane sticks in described first panel district 1 and described second panel district 5 by pasting agent.
Preferably, pasting agent described in, to be that macromolecule is organic transparent paste agent.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.With reference to Fig. 2, the preparation method of described cellophane comprises the following steps:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000
～under the rotating speed of 10000rpm/min, stir 5min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour into point
Dissipate in pulp solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Use stretched dropper by
Dropping sodium hypochlorite enters and reacts 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixing slurry through reaction
Material solution obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；By oxygen
Slurrying is done homogenizing through microfluidizer with the pressure of 3000psi and is processed, and obtains gelatinous nanofibrils cellulose dispersion,
Preserve under conditions of nanofibrils cellulose dispersion is placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add
93～95ml ultra-pure waters use ultrasonic disperse 30min, takes CNT 80.0mg, add ultrasonic 30min in above-mentioned solution, take
Going out and be placed on magnetic stirring apparatus, adjust the temperature to 30～45 DEG C, mixing speed is 5000～8000rpm/min, adds two
Magnet rotor, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and it is antibacterial former that reaction 1h obtains CNT silver
Liquid；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose that will prepare in step S1 disperses
Body uses distilled water to be diluted to 0.1wt%, is then placed within magnetic stirring apparatus stirring with 1000rpm/min speed
30min；Being that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1% by mass dryness fraction, the fiber being sufficiently stirred for making wadding poly-fills
Dispersion；By standby after 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt%；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose divides
A prose style free from parallelism is mixed to form mixed solution, and above-mentioned mixed liquor is placed in evacuation in plastic bag, uses under the protection of nitrogen13Cs γ penetrates
Above-mentioned mixed liquor is radiated by beta radiation source, and the mixed solution after overshoot is poured in buchner funnel filtration, is formed
One layer of wet NFC layer the thinnest, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, should
Double-decker use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, by above-mentioned NFC
Duplex paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
Series of processes through above-mentioned steps is processed, and is made for a kind of cellophane with anti-microbial property.Use Lambda
Ultraviolet-uisible spectrophotometer and with reference to international standard the method provided by embodiments of the invention is prepared from transparent
Paper carries out the relative analysis of light transmission and anti-microbial property, the analysis found that, the cellophane light transmission of this enforcement preparation is
92%, and show excellent anti-microbial property.
Preferably, each reaction temperature in step S1 is 25 DEG C；1.5% pH value starching dense TEMPO oxidation slurry is 12.
Preferably, in step S3, at a diameter of 85mm of the filter paper that buchner funnel is placed, the quantity of filter paper is 2～3,
Also being placed with 1～2 a diameter of 90mm on filter paper, aperture is the PVDF filter membrane of 0.65 micron.
Experiment test:
(1) anti-microbial property test: using absorbance method, detection cellophane is to escherichia coli and the fungistatic effect of mycete.Knot
Fruit is as shown in Table 1 and Table 2.
Table 1 cellophane is to colibacillary antibacterial absorbance
| OD680 | |
| Blank | 8±0.01 |
| 0.5% | 7.5±0.08 |
| 0.75% | 6.5±0.09 |
| 1.0% | 0.28±0.08 |
| 1.5% | 0.04±0.02 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
The cellophane that row radiation is made after irradiating, has the anti-escherichia coli performance of excellence, after testing through 480h, and its antibacterial effect
Fruit and the 1h started do not have significant difference.
Use absorbance method, detect the cellophane fungistatic effect to mycete.Result is as shown in table 2.
The table 2 cellophane antibacterial absorbance to mycete
| OD680 | |
| Blank | 6±0.01 |
| 0.5% | 5.6±0.05 |
| 0.75% | 4.9±0.08 |
| 1.0% | 0.15±0.06 |
| 1.5% | 0.05±0.04 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
Row radiation irradiate after the cellophane made, there is the Anti-mildew capability of excellence, after testing through 480h, its antibacterial effect and
The 1h started does not has significant difference.
(2) test of efficiency of light absorption
Cellophane is pasted in substrate of glass, measures its efficiency of light absorption by optical detecting platform.By incident illumination with
The vertical angle initialization in cellophane surface is 90 °, will start to calculate scattering when the intensity of transmission light reaches the 5% of maximum intensity
Angle.By a branch of a diameter of 0.5cm, wavelength is that the red laser of 500nm irradiates cellophane, and laser is by after cellophane, in the back of the body
Scape defines the aperture of a diameter of 25.6cm.By above-mentioned light vertical irradiation in the substrate of glass being pasted with cellophane, its
Light absorption is reached 92%.
(3) hot strength test
Being tested by Compression and Expansion, the cellophane that the method using the present embodiment to provide is prepared from has well stretching
Intensity (70MPa) and excellent ductility (elongation percentage is 48%), be common regenerated cellulose film conventional in correlation technique
15 times.
This cellophane has anti-microbial property, good light transmittance and the useful tensile property of excellence, uses this cellophane
The light transmittance of the ad system structure made greatly enhances；The display making ad system structure is relatively sharp visible, and is easy to clear
Clean.
Application scenarios 5
Fig. 1 is according to a kind of building advertisement system structure shown in an exemplary embodiment, as it is shown in figure 1,1, Yi Zhonglou
Space ad system structure, including base 4 and support body 3, the top of described support body 3 is provided with the first panel district 1, described support body 3
Middle part is provided with Zhan Ge district 2, and the bottom of described support body 3 is provided with and the second panel district 5 of described first panel district 1 symmetry；Institute
State the first panel district 1 and described second surface, panel district 5 and be pasted with cellophane.
The structure of a kind of building advertisement system structure that the above embodiment of the present invention provides is arranged rationally, thus solves
Above-mentioned technical problem.
Preferably, described cellophane sticks in described first panel district 1 and described second panel district 5 by pasting agent.
Preferably, pasting agent described in, to be that macromolecule is organic transparent paste agent.
Fig. 2 is the preparation method of the cellophane according to a kind of building advertisement system structure shown in an exemplary embodiment
Process chart.With reference to Fig. 2, the preparation method of described cellophane comprises the following steps:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000
～under the rotating speed of 10000rpm/min, stir 5min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour into point
Dissipate in pulp solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Use stretched dropper by
Dropping sodium hypochlorite enters and reacts 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixing slurry through reaction
Material solution obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；By oxygen
Slurrying is done homogenizing through microfluidizer with the pressure of 3000psi and is processed, and obtains gelatinous nanofibrils cellulose dispersion,
Preserve under conditions of nanofibrils cellulose dispersion is placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add
93～95ml ultra-pure waters use ultrasonic disperse 30min, takes CNT 80.0mg, add ultrasonic 30min in above-mentioned solution, take
Going out and be placed on magnetic stirring apparatus, adjust the temperature to 30～45 DEG C, mixing speed is 5000～8000rpm/min, adds two
Magnet rotor, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and it is antibacterial former that reaction 1h obtains CNT silver
Liquid；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose that will prepare in step S1 disperses
Body uses distilled water to be diluted to 0.1wt%, is then placed within magnetic stirring apparatus stirring with 1000rpm/min speed
30min；Being that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1% by mass dryness fraction, the fiber being sufficiently stirred for making wadding poly-fills
Dispersion；By standby after 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt%；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose divides
A prose style free from parallelism is mixed to form mixed solution, and above-mentioned mixed liquor is placed in evacuation in plastic bag, uses under the protection of nitrogen13Cs γ penetrates
Above-mentioned mixed liquor is radiated by beta radiation source, and the mixed solution after overshoot is poured in buchner funnel filtration, is formed
One layer of wet NFC layer the thinnest, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, should
Double-decker use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, by above-mentioned NFC
Duplex paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
Series of processes through above-mentioned steps is processed, and is made for a kind of cellophane with anti-microbial property.Use Lambda
Ultraviolet-uisible spectrophotometer and with reference to international standard the method provided by embodiments of the invention is prepared from transparent
Paper carries out the relative analysis of light transmission and anti-microbial property, the analysis found that, the cellophane light transmission of this enforcement preparation is
97.65%, and show excellent anti-microbial property.
Preferably, each reaction temperature in step S1 is 27 DEG C；2.0% pH value starching dense TEMPO oxidation slurry is 15.
Preferably, in step S3, at a diameter of 90mm of the filter paper that buchner funnel is placed, the quantity of filter paper is 3, in filter
Also being placed with 2 a diameter of 90mm on paper, aperture is the PVDF filter membrane of 0.65 micron.
Experiment test:
(1) anti-microbial property test: using absorbance method, detection cellophane is to escherichia coli and the fungistatic effect of mycete.Knot
Fruit is as shown in Table 1 and Table 2.
Table 1 cellophane is to colibacillary antibacterial absorbance
| OD680 | |
| Blank | 8±0.01 |
| 0.5% | 7.7±0.05 |
| 0.75% | 6.7±0.08 |
| 1.0% | 0.32±0.08 |
| 1.5% | 0.03±0.04 |
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
The cellophane that row radiation is made after irradiating, has the anti-escherichia coli performance of excellence, after testing through 480h, and its antibacterial effect
Fruit and the 1h started do not have significant difference.
Use absorbance method, detect the cellophane fungistatic effect to mycete.Result is as shown in table 2.
The table 2 cellophane antibacterial absorbance to mycete
Test shows, with the addition of the CNT antibacterial stock solution of silver and use13Above-mentioned mixed liquor is entered by Cs gamma-ray radiation source
Row radiation irradiate after the cellophane made, there is the Anti-mildew capability of excellence, after testing through 480h, its antibacterial effect and
The 1h started does not has significant difference.
(2) test of efficiency of light absorption
Cellophane is pasted in substrate of glass, measures its efficiency of light absorption by optical detecting platform.By incident illumination with
The vertical angle initialization in cellophane surface is 90 °, will start to calculate scattering when the intensity of transmission light reaches the 5% of maximum intensity
Angle.By a branch of a diameter of 0.5cm, wavelength is that the red laser of 500nm irradiates cellophane, and laser is by after cellophane, in the back of the body
Scape defines the aperture of a diameter of 29cm.By above-mentioned light vertical irradiation in the substrate of glass being pasted with cellophane, it is right
Light absorption reaches 97.65%.
(3) hot strength test
Being tested by Compression and Expansion, the cellophane that the method using the present embodiment to provide is prepared from has well stretching
Intensity (72MPa) and excellent ductility (elongation percentage is 50%), be common regenerated cellulose film conventional in correlation technique
18 times.
This cellophane has anti-microbial property, good light transmittance and the useful tensile property of excellence, uses this cellophane
The light transmittance of the ad system structure made greatly enhances；The display making ad system structure is relatively sharp visible, and is easy to clear
Clean.
Last it should be noted that, above example is only in order to illustrate technical scheme, rather than the present invention is protected
Protecting the restriction of scope, although having made to explain to the present invention with reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, technical scheme can be modified or equivalent, without deviating from the reality of technical solution of the present invention
Matter and scope.
Claims (6)
1. a building advertisement system structure, including base and support body, it is characterised in that the top of described support body is provided with first
Panel district, the middle part of described support body is provided with Zhan Gequ, and the bottom of described support body is provided with symmetrical with described first panel district
Second panel district；Described first panel district and described second surface, panel district are pasted with cellophane.
A kind of building advertisement system structure the most according to claim 1, it is characterised in that described cellophane is by pasting agent
Stick in described first panel district and described second panel district.
A kind of building advertisement system structure the most according to claim 2, it is characterised in that described to paste agent be high score
Son is organic transparent pastes agent.
A kind of building advertisement system structure the most according to claim 1, it is characterised in that described cellophane is by following step
Suddenly it is prepared from:
S1, prepares dispersed paste solution: add the distilled water of 200ml in 50mg slurry, with homogenizer with 8000～
Stir 5min under the rotating speed of 10000rpm/min, obtain dispersed paste solution；
S2, preparation TEMPO oxidation slurry: dissolve 10mg sodium chloride and 5mg TEMPO catalyst with ultra-pure water respectively, pour dispersion pulp into
In material solution, under 50～1000KPa negative pressure, stir 2min obtain mixed slurry solution；Stretched dropper is used dropwise to drip
Add sodium hypochlorite and enter reaction 30min in mixed slurry solution；Ultra-pure water is used to clean the above-mentioned mixed slurry through reaction molten
Liquid obtains clean slurry, takes 2ml cleaning slurry ultra-pure water configuration 0.5%～2.0% slurry dense TEMPO oxidation slurry；Oxidation is starched
Do homogenizing through microfluidizer with the pressure of 3000psi to process, obtain gelatinous nanofibrils cellulose dispersion, will receive
Rice Fibrillated fibers element dispersion is preserved under conditions of being placed on 4～10 DEG C；
S3, prepares the CNT antibacterial stock solution of silver: weigh 5～7mg carbamide and 5～6mg dodecylbenzene sodium sulfonate add 93～
95ml ultra-pure water uses ultrasonic disperse 30min, takes CNT 80.0mg, add ultrasonic 30min in above-mentioned solution, after taking-up
Being placed on magnetic stirring apparatus, adjust the temperature to 30～45 DEG C, mixing speed is 5000～8000rpm/min, adds two magnetic and turns
Son, adds 3～5mg sodium chloride, is added thereto to AgCl solution while stirring, and reaction 1h obtains the CNT antibacterial stock solution of silver；
S4, prepares NFC dispersion and lumber fibre mixed liquor: the nanofibrils cellulose dispersion prepared in step S1 made
It is diluted to 0.1wt% with distilled water, is then placed within magnetic stirring apparatus stirring 30min with 1000rpm/min speed；Will
Mass dryness fraction is that 15.0wt% bleached sulphate softwood pulp is diluted with water to 1%, and the fiber being sufficiently stirred for making wadding poly-is fully dispersed；Will
After 0.1wt%NFC dispersion and the lumber fibre mix and blend 10min of 1wt% standby；
S5, cellophane molding: take the 2ml CNT antibacterial stock solution of silver and 200ml gel nanofibers cellulose dispersion
It is mixed to form mixed solution, above-mentioned mixed liquor is placed in evacuation in plastic bag, use under the protection of nitrogen13Cs gamma-rays spoke
Above-mentioned mixed liquor is radiated by source of penetrating, and the mixed solution after overshoot is poured in buchner funnel filtration, forms one layer
The thinnest wet NFC layer, is repeated twice13Cs gamma Rays irradiates and filter process, forms NFC layer double-decker, by this bilayer
Structure use active paper sucks it and is more than moisture, makes moisture be maintained between 5%～6%；Finally, above-mentioned NFC is double-deck
Paper be placed in squeezer the pressure with 500～4000Pa cellophane is carried out squeezing be dried.
A kind of building advertisement system structure the most according to claim 4, it is characterised in that each reaction temperature in step S1
Degree is 23～27 DEG C；0.5%～2.0% pH value starching dense TEMPO oxidation slurry is 8～15.
A kind of building advertisement system structure the most according to claim 4, it is characterised in that in step S3, at buchner funnel
Place filter paper a diameter of 70～90mm, the quantity of filter paper is 2～3, filter paper is also placed with 1～2 a diameter of
90mm, aperture is the PVDF filter membrane of 0.65 micron.
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| CN201610626375.8A CN106297595A (en) | 2016-07-30 | 2016-07-30 | A kind of building advertisement system structure |
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| CN201610626375.8A CN106297595A (en) | 2016-07-30 | 2016-07-30 | A kind of building advertisement system structure |
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| CN102066654A (en) * | 2008-04-30 | 2011-05-18 | 希乐克公司 | Paper product and method and system for manufacturing the same |
| CN201285640Y (en) * | 2008-08-29 | 2009-08-05 | 余志伟 | Multifunctional advertisement machine |
| CN202145371U (en) * | 2011-06-24 | 2012-02-15 | 陈笑波 | Building DM advertisement exhibit rack |
| CN102702889A (en) * | 2012-06-01 | 2012-10-03 | 安徽省金盾涂料有限责任公司 | Anti-bacterial water-based paint and preparation method thereof |
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Application publication date: 20170104 |