CN106290756B - A kind of method of harmful substance in field quick detection grape wine - Google Patents

A kind of method of harmful substance in field quick detection grape wine Download PDF

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Publication number
CN106290756B
CN106290756B CN201610940984.0A CN201610940984A CN106290756B CN 106290756 B CN106290756 B CN 106290756B CN 201610940984 A CN201610940984 A CN 201610940984A CN 106290756 B CN106290756 B CN 106290756B
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module
touch screen
sensor
circuit
liquid
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CN106290756A (en
Inventor
刘亚荣
谢晓兰
熊传信
沈卓君
李新
杨晓斐
施晓东
唐超尘
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Guilin University of Technology
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Guilin University of Technology
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/02Food
    • G01N33/14Beverages
    • G01N33/146Beverages containing alcohol
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/00584Control arrangements for automatic analysers

Abstract

The invention discloses a kind of methods of harmful substance in field quick detection grape wine.A kind of mancarried device, including quantitative sample extraction module, signal processing circuit module, single-chip microcomputer signal acquisition system, power module, touch screen module and on-line storage module are set.The wine samples of quantitative sample extraction module Extraction and determination, and pass through sensor sensing methanol therein and volatile acid, content information is converted into electric signal, be sent into signal processing circuit module be amplified, denoising and filtering, single-chip microcomputer signal acquisition system is inputted after the conversion of A/D conversion circuits, it is handled again through single-chip microcomputer signal acquisition system, it is shown on the touch screen in touch screen module, and measurement result is sent into online memory module and is stored or is exported, that is, realize harmful substance in field quick detection grape wine.The method of the present invention is simple and convenient, fundamentally solves the problems, such as methanol and volatile acid fast-field evaluation in grape wine, and greatly increase Site Detection speed.

Description

A kind of method of harmful substance in field quick detection grape wine
Technical field
The invention belongs to technical field of analysis and detection, more particularly to harmful substance in a kind of field quick detection grape wine Method.
Background technology
Grape wine is fermented and be made using grape as raw material.In grape wine contain many nutriments, as carbohydrate, alcohols, Acids, inorganic salts, amino acid and various vitamins.Not only sweet flavor is pure and sweet, full of nutrition, and solid with bad courage is reduced Alcohol promotees digestion, salubrity, beauty and other effects, therefore is liked by numerous people.In recent years, with the continuous hair of social economy Exhibition and the continuous promotion of people's living standard, many family's selection self-control grape wine.Brewing grape wine is needed by sorting, clearly The links such as wash, dry, being crushed, fermenting, clarifying, it is every since grape wine is highly susceptible to living contaminants in brewing process A link is very strict to hygienic requirements.However, for family is from vintage wine, most people by rule of thumb and is felt to make entirely Grape wine is made, (is grape wine from literature methanol and volatile acid to the ingredient from vintage wine especially methanol and volatile acid Exceeded harmful substance is easiest in brewing process) whether the contents of these harmful substances is exceeded has no way of learning, it is therefore necessary to A kind of portable methanol and volatilizable sour detection device are designed, the content of methanol and volatilizable acid in grape wine is detected, to protect Hinder the life security of the people.
Methanol is also known as another name for, wood alcohol, colourless, volatile, toxicity is big, methanol excess intake can cause it is dizzy, weak, regard The poisoning symptoms such as power obstacle, severe patient are even dead.There is the measurement method of methanol in traditional grape wine:Head space, laser are drawn Graceful spectroscopic methodology, refraction process, gas chromatography, colorimetric method etc..Wherein Head space needs chromatography instrument;Raman spectroscopy curve Complexity is difficult to, and needs Raman spectroscopy instrument;Although refraction process is easy, influence factor is difficult to accurately measure more;And gas phase color Spectrometry needs expensive instrument, and instrument is not readily portable and field quick detection.These are not suitable for the methanol of domestic wine And volatile acid detection.Although currently, having portable methanol and volatile acid measuring instrument on the market, these instruments are can only Single harmful substance is measured, and there is the shortcomings of not portable, not quick, higher price, it is therefore necessary to be developed a kind of The method of harmful substance in new field quick detection grape wine is family and individual services.
Invention content
The purpose of the present invention is overcoming the shortcomings of existing method, harmful substance in a kind of field quick detection grape wine is provided Method.
The specific steps are:
(1) a kind of mancarried device, including quantitative sample extraction module, signal processing circuit module, microcontroller letter are set Number acquisition system, power module, touch screen module and on-line storage module.Quantitative sample extraction module includes sensor, liquid Inhalator handle, liquid inhaler and liquid flooded suction;Liquid inhaler handle is arranged on the top of liquid inhaler, and liquid is inhaled Enter the lower part that head is mounted on liquid inhaler, the intersection in liquid inhaler and liquid flooded suction is arranged in sensor;At signal It includes driver sensor circuit, filter amplification circuit and A/D conversion circuits to manage circuit module;Touch screen module includes touch screen electricity Road and touch screen;It is provided with USB data interface in on-line storage module;Quantitative sample extraction mould sensor in the block is connected to drive Filter amplification circuit is additionally coupled to while dynamic sensor circuit, filter amplification circuit is connected to A/D conversion circuits, A/D conversions Circuit is connected to single-chip microcomputer signal acquisition system, and single-chip microcomputer signal acquisition system is additionally coupled to while being connected to touch screen module On-line storage module;Power module includes charging circuit, rechargeable battery and output circuit, and charging circuit is provided with Micro-USB Charging interface, rechargeable battery pass through output circuit connection signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage Module and touch screen module.
The quantitative sample extraction module is used for the quantitative extraction of wine samples, when sampling, press liquid inhaler by Handle, liquid inhaler is just by the sample of liquid flooded suction Extraction and determination volume, and liquid flooded suction can be replaced, fast and easy Extract different samples;Sensor includes methanol sensor and volatilization acid sensor, and methanol sensor is used for the small of methanol Variation is converted into faint electric signal, and the minor change of volatile acid for being converted into faint electric signal by volatilization acid sensor.
The driver sensor circuit is used to provide working power for sensor, and filter amplification circuit is used for sensor Faint electric signal is amplified, denoising and filtering, A/D conversion circuits for that will amplify, denoising and filtered electric signal turn It changes digital signal into, then inputs single-chip microcomputer signal acquisition system.
The single-chip microcomputer signal acquisition system is made of programmable development board, and the system is for collecting signal processing electricity The digital signal of road module output, and the digital signal being collected into is handled, it is converted into touch screen energy in touch screen module The form enough shown, while providing interface for on-line storage module and supporting.
The touch screen is human-computer interaction interface, and operating personnel can carry out various functions behaviour by the software on touch screen Make, including measurement, preservation, return, export measurement result and comparison grape wine national standard limit value, touch screen circuitry are to touch Screen provides circuit and supports.
Measurement result can be stored in U by the on-line storage module for storing measurement result by USB data interface It in disk or exports, facilitates record, counts and summarize.
The charging circuit is provided with Micro-USB charging interfaces, is inserted into portable charger, for electric to charge Pond is charged, and rechargeable battery is signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module by output circuit And touch screen module is powered.
(2) circuit is opened to the mancarried device of step (1) setting, the rechargeable battery of power module is by output circuit Signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module and touch screen module are powered;Touch screen mould Touch screen circuitry in the block is powered for touch screen, and touch screen is in system initialization interface, and carries out key scan;Press liquid The liquid inhaler handle on inhalator top, will draw quantitative wine samples in liquid flooded suction, on point touching screen Measurement button, into measure interface, driver sensor circuit makes sensor start to work, sensor sensing to wine samples In methanol and volatile acid after, generate stable electric signal, the electric signal entering signal processing circuit module, filtered amplification electricity Road is amplified, denoising and is filtered, and is then converted through A/D conversion circuits, becomes single-chip microcomputer signal acquisition system institute The digital signal needed;The digital signal that single-chip microcomputer signal acquisition system inputs A/D conversion circuits is handled, and is transformed into survey Amount result is shown on the touch screen of touch screen module, while touching country's mark of methanol and volatile acid in screen display grape wine Quasi- limit value, to make methanol and the whether exceeded judgement of volatile acid automatically, then measurement result is led to by on-line storage module USB data interface is crossed to be stored on USB flash disk or export;When measuring next sample, liquid flooded suction is replaced, and touch screen is made to return To measure interface, duplicate measurements process is filled when electric quantity of rechargeable battery is smaller by the Micro-USB being arranged on charging circuit Electrical interface accesses portable charger, charges for rechargeable battery, is quickly carried out with ensureing to measure.
(3) step (2) is completed, that is, realizes harmful substance in field quick detection grape wine.
The method of the present invention is simple and convenient, and mancarried device used is easy to use, fast response time, measurement accuracy High, simple in structure, small, light-weight, waterproof, explosion-proof, easy to maintain, this method fundamentally solves methanol in grape wine And the problem of volatile acid fast-field evaluation, and greatly increase Site Detection speed.
Description of the drawings
Fig. 1 is the general frame of the mancarried device used in the present invention.
Fig. 2 is the appearance front elevation of the mancarried device used in the embodiment of the present invention.
Fig. 3 is the appearance back view of the mancarried device used in the embodiment of the present invention.
Fig. 4 is the outside drawing of the quantitative sample extraction module of the mancarried device used in the embodiment of the present invention.
It is marked in figure:1-Micro-USB charging interfaces;2-USB data-interfaces;3- power switches;4- liquid inhalers are pressed Handle;5- liquid inhalers;6- sensors;7- liquid flooded suctions;8- touch screens;9-Home keys;10- return keys.
Fig. 5 is the main program flow chart of software used in the embodiment of the present invention.
Specific implementation mode
Embodiment:
(1) as shown in Figure 1, a kind of mancarried device is arranged, including quantitative sample extraction module, signal processing circuit mould Block, single-chip microcomputer signal acquisition system, power module, touch screen module and on-line storage module;Quantifying sample extraction module includes Sensor 6, liquid inhaler handle 4, liquid inhaler 5 and liquid flooded suction 7;The setting of liquid inhaler handle 4 is inhaled in liquid Enter the top of device 5, liquid flooded suction 7 is mounted on the lower part of liquid inhaler 5, and sensor 6 is arranged in liquid inhaler 5 and liquid The intersection of flooded suction 7;Signal processing circuit module includes driver sensor circuit, filter amplification circuit and A/D conversion circuits; Touch screen module includes touch screen circuitry and touch screen 8;USB data interface 2 is provided in on-line storage module;Quantitative sample carries Modulus sensor 6 in the block is additionally coupled to filter amplification circuit, filter amplification circuit while being connected to driver sensor circuit A/D conversion circuits are connected to, A/D conversion circuits are connected to single-chip microcomputer signal acquisition system, the connection of single-chip microcomputer signal acquisition system On-line storage module is additionally coupled to while to touch screen module;Power module includes charging circuit, rechargeable battery and output electricity Road, charging circuit are provided with Micro-USB charging interfaces 1, and rechargeable battery passes through output circuit connection signal processing circuit mould Block, single-chip microcomputer signal acquisition system, on-line storage module and touch screen module.As shown in Fig. 2,3 and 4, the portable field is fast Power switch 3, Home key 9 and return key 10 are additionally provided on speed detector.
The quantitative sample extraction module is used for the quantitative extraction of wine samples, when sampling, press liquid inhaler by Handle 4, liquid inhaler 5 is just by the sample of 7 Extraction and determination volume of liquid flooded suction, and liquid flooded suction 7 can be replaced, convenient The different sample of rapid extraction;Sensor 6 includes methanol sensor and volatilization acid sensor, and methanol sensor is used for methanol Minor change is converted into faint electric signal, and the minor change of volatile acid for being converted into faint telecommunications by volatilization acid sensor Number.
The driver sensor circuit is used to provide working power for sensor 6, and filter amplification circuit is used for sensor 6 Upper faint electric signal is amplified, denoising and filtering, A/D conversion circuits for that will amplify, denoising and filtered electric signal It is converted into digital signal, then inputs single-chip microcomputer signal acquisition system.
The single-chip microcomputer signal acquisition system is made of programmable development board, and the system is for collecting signal processing electricity The digital signal of road module output, and the digital signal being collected into is handled, it is converted into 8 energy of touch screen in touch screen module The form enough shown, while providing interface for on-line storage module and supporting.
The touch screen 8 is human-computer interaction interface, and operating personnel can carry out various functions by the software on touch screen 8 Operation, including measurement, preservation, return, export measurement result and comparison grape wine national standard limit value, touch screen circuitry is tactile It touches screen 8 and circuit support is provided.
Measurement result can be stored in by the on-line storage module for storing measurement result by USB data interface 2 It in USB flash disk or exports, facilitates record, counts and summarize.
The Micro-USB charging interfaces 1 have access to portable charger, for charging for rechargeable battery, charging electricity Pond is signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module and touch screen module by output circuit It is powered.
(2) 3 are turned on the power switch, the rechargeable battery of power module is signal processing circuit module, list by output circuit Piece machine signal acquiring system, on-line storage module and touch screen module are powered.Touch screen circuitry in touch screen module is Touch screen 8 is powered, and touch screen 8 is made to be in system initialization interface, carries out key scan.Press 5 top of liquid inhaler Liquid inhaler handle 4 will draw quantitative wine samples in liquid flooded suction 7, the measurement button on point touching screen 8, Into measure interface, driver sensor circuit makes sensor 6 start to work, and thin electrolyte layers are added in the electrode surface layer of sensor 6, and Surface increases the pin hole of capillary-type, to improve measurement accuracy.Sensor 6 senses methanol and volatile acid in wine samples Afterwards, chemical change occurs, generates stable electric signal, the electric signal entering signal processing circuit module, filtered amplifying circuit It is amplified, denoising and is filtered, then converted, become needed for single-chip microcomputer signal acquisition system through A/D conversion circuits The digital signal wanted.The digital signal that single-chip microcomputer signal acquisition system inputs A/D conversion circuits is handled, and is transformed into measurement As a result it is shown on the touch screen 8 of touch screen module, while showing country's mark of methanol and volatile acid in grape wine on touch screen 8 Quasi- limit value, to make methanol and the whether exceeded judgement of volatile acid automatically, then measurement result is led to by on-line storage module USB data interface 2 is crossed to be stored on USB flash disk.When measuring next sample, liquid flooded suction 7 is replaced, is directly returned by Home key 9 It to measure interface, or repeats to gradually resume measure interface by return key 10, when electric quantity of rechargeable battery is smaller, passes through the electricity that charges Road setting Micro-USB charging interfaces 1 access portable charger, for rechargeable battery charge, with ensure measure quickly into Row.
(3) step (2) is completed, that is, realizes harmful substance in field quick detection grape wine.
The flow chart of the main program of the software used in the present embodiment is as shown in figure 5, the software development uses Keil4 for ARM, programming language are C language.Keil develops software and provides C language, assembler language compiler, and provides abundant library letter Number and powerful Integrated Development debugging acid, the full interfaces Windows.Easy meeting easy to learn, it is easy to operate.

Claims (1)

1. a kind of method of harmful substance in field quick detection grape wine, it is characterised in that the specific steps are:
(1) a kind of mancarried device is set, including quantitative sample extraction module, signal processing circuit module, single-chip microcomputer signal are adopted Collecting system, power module, touch screen module and on-line storage module;Quantitative sample extraction module includes sensor, liquid sucking Device handle, liquid inhaler and liquid flooded suction;Liquid inhaler handle is arranged in the top of liquid inhaler, liquid flooded suction Mounted on the lower part of liquid inhaler, the intersection in liquid inhaler and liquid flooded suction is arranged in sensor;Signal processing electricity Road module includes driver sensor circuit, filter amplification circuit and A/D conversion circuits;Touch screen module include touch screen circuitry and Touch screen;It is provided with USB data interface in on-line storage module;Quantitative sample extraction mould sensor in the block is connected to driving and passes Filter amplification circuit is additionally coupled to while sensor circuit, filter amplification circuit is connected to A/D conversion circuits, A/D conversion circuits It is connected to single-chip microcomputer signal acquisition system, single-chip microcomputer signal acquisition system is additionally coupled to online while being connected to touch screen module Memory module;Power module includes charging circuit, rechargeable battery and output circuit, and charging circuit is provided with Micro-USB chargings Interface, rechargeable battery pass through output circuit connection signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module And touch screen module;
The quantitative sample extraction module is used for the quantitative extraction of wine samples, when sampling, presses liquid inhaler handle, liquid Body inhalator is just by the sample of liquid flooded suction Extraction and determination volume, and liquid flooded suction can be replaced, fast and easy extraction Different samples;Sensor includes methanol sensor and volatilization acid sensor, and methanol sensor is used for the minor change of methanol It is converted into faint electric signal, the minor change of volatile acid for being converted into faint electric signal by volatilization acid sensor;
The driver sensor circuit is used to provide working power for sensor, and filter amplification circuit is used for will be faint on sensor Electric signal be amplified, denoising and filtering, A/D conversion circuits for that will amplify, denoising and filtered electric signal are converted into Then digital signal inputs single-chip microcomputer signal acquisition system;
The single-chip microcomputer signal acquisition system is made of programmable development board, which is used for collecting signal processing circuit mould The digital signal of block output, and the digital signal being collected into is handled, being converted into touch screen in touch screen module can show The form shown, while providing interface for on-line storage module and supporting;
The touch screen is human-computer interaction interface, and operating personnel can carry out various functions operation by the software on touch screen, Including measurement, preservation, return, export measurement result and comparison grape wine national standard limit value, touch screen circuitry is touch screen Circuit is provided to support;
Measurement result can be stored in by USB data interface in USB flash disk by the on-line storage module for storing measurement result Or export, facilitate record, count and summarize;
The charging circuit is provided with Micro-USB charging interfaces, is inserted into portable charger, for being filled for rechargeable battery Electricity, rechargeable battery are signal processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module by output circuit and touch Panel module is touched to be powered;
(2) circuit opened to the mancarried device of step (1) setting, the rechargeable battery of power module is signal by output circuit Processing circuit module, single-chip microcomputer signal acquisition system, on-line storage module and touch screen module are powered;In touch screen module Touch screen circuitry be touch screen power supply, touch screen is in system initialization interface, and carries out key scan;Press liquid sucking The liquid inhaler handle on device top will draw quantitative wine samples, the survey on point touching screen in liquid flooded suction Button is measured, into measure interface, driver sensor circuit makes sensor start to work, in sensor sensing to wine samples After methanol and volatile acid, generate stable electric signal, the electric signal entering signal processing circuit module, filtered amplifying circuit into Row amplification and is filtered denoising, is then converted, is become required for single-chip microcomputer signal acquisition system through A/D conversion circuits Digital signal;The digital signal that single-chip microcomputer signal acquisition system inputs A/D conversion circuits is handled, and is transformed into measurement knot Fruit is shown on the touch screen of touch screen module, while touching the national standard of methanol and volatile acid in screen display grape wine and limiting Definite value, to make methanol and the whether exceeded judgement of volatile acid automatically, then measurement result passes through USB by on-line storage module Data-interface is stored on USB flash disk or exports;When measuring next sample, liquid flooded suction is replaced, and touch screen is made to return to survey Interface is measured, duplicate measurements process passes through the Micro-USB chargings being arranged on charging circuit when electric quantity of rechargeable battery is smaller Mouth access portable charger, charges for rechargeable battery, to ensure that measurement quickly carries out;
(3) step (2) is completed, that is, realizes harmful substance in field quick detection grape wine.
CN201610940984.0A 2016-10-26 2016-10-26 A kind of method of harmful substance in field quick detection grape wine Active CN106290756B (en)

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CN107995599B (en) * 2017-11-10 2020-07-31 桂林理工大学 Natural rubber acquisition monitoring method based on spectrum sensing technology
CN107991247A (en) * 2017-12-08 2018-05-04 尹大路 A kind of food inspection device and its detection method

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CN1243230C (en) * 2003-11-20 2006-02-22 华中科技大学 Method for checking pesticide residue and portable detecting instrument thereof
CN101226166B (en) * 2008-01-31 2013-08-14 浙江大学 Low-power consumption hand-hold electric nasus system for testing on-site
CN102288658A (en) * 2011-08-18 2011-12-21 天津市汉漠尔电子科技有限公司 Portable electrochemical detection analysis device
CN203046900U (en) * 2012-12-21 2013-07-10 陕西理工学院 Automobile driver alcohol concentration detection device
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CN103558252A (en) * 2013-11-07 2014-02-05 周琼 Method for classifying grape wines based on electronic nose technology
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CN105911228B (en) * 2016-06-21 2018-01-09 重庆大学 A kind of portable electric nose system and its control method

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Application publication date: 20170104

Assignee: Guangxi Taiyao Technology Co.,Ltd.

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Contract record no.: X2023980044021

Denomination of invention: A method for rapid on-site detection of harmful substances in wine

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Denomination of invention: A method for rapid on-site detection of harmful substances in wine

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