CN106285774A - A kind of cyanogen-containing tailing innoxious paste body filling method - Google Patents
A kind of cyanogen-containing tailing innoxious paste body filling method Download PDFInfo
- Publication number
- CN106285774A CN106285774A CN201610669345.5A CN201610669345A CN106285774A CN 106285774 A CN106285774 A CN 106285774A CN 201610669345 A CN201610669345 A CN 201610669345A CN 106285774 A CN106285774 A CN 106285774A
- Authority
- CN
- China
- Prior art keywords
- cyanogen
- innoxious
- ore pulp
- paste body
- body filling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21F—SAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
- E21F15/00—Methods or devices for placing filling-up materials in underground workings
- E21F15/005—Methods or devices for placing filling-up materials in underground workings characterised by the kind or composition of the backfilling material
Abstract
The invention provides a kind of cyanogen-containing tailing innoxious paste body filling method, comprise the following steps: after deep cone concentrates, size mixing, two-stage nitration bores concentrations deeply, secondary is sized mixing, except cyanogen oxidation and concentration.Cyanogen-containing tailing provided by the present invention innoxious paste body filling method, the method using physics sedimentation and dilution desorption technique, chemical oxidation techniques and paste body filling technology to combine, comprehensively utilize again after sludge containing cyanogens is carried out harmless treatment.This method technological process is simple, and treatment effeciency is high, and operating cost is low, relieves the security context hidden danger of cyanogen-containing tailing.
Description
Technical field
The invention belongs to tailings glass field, be specifically related to a kind of cyanogen-containing tailing innoxious paste body filling method.
Background technology
Cyanidation gold-extracted being still current gold manufacturing enterprises and carry the prevailing technology of gold, but this technique can produce in process of production
Substantial amounts of containing cyanogen waste residue.The expansion along with golden production scale and production history is processed at present containing cyanogen waste residue many employings bin system
Prolongation, gold tailings accumulating amount increases year by year and does not only take up a large amount of soil, polluted surface water, subsoil water and soil, and very
Many Tailings Dams exceed the time limit or over loading uses, and make Tailings Dam there is very big potential safety hazard, and once break down leakage, it will the ring to surrounding
Border produces great pollution effect, and Tailings Dam is built and maintenance management also needs to put into substantial contribution simultaneously.Therefore, accelerate to advance Huang
Gold is smelted containing cyanogen Solid state fermentation and comprehensive utilization extremely urgent.
The harmless treatment approach of sludge containing cyanogens has two classes, a class to be to Tailings Slurry filter pressing, the dry heap of filtering residue, and filtrate is carried out
Integrated treatment, reuse or qualified discharge after process；Another kind of is that Tailings Slurry directly processes, and method is substantially destruction cyanide.Before
Person is easily processed due to mud-water separation, cyanide, technology maturation, controls simple, but owing to filter pressing cost is high, it is difficult at large ore
Mountain popularization and application.The development trend of gold industry is to develop towards extensive treating capacity, and corresponding, sludge containing cyanogens is harmless
The development trend that change processes is towards the direction progress directly processed.
Summary of the invention
In order to solve above technical problem, the invention provides a kind of cyanogen-containing tailing innoxious paste body filling method, including
Following steps:
(1) mine tailing ore pulp is after one section of deep cone concentrates, and supernatant fluid reuse, underflow adds new water under stirring and adjusts
Slurry；
(2) ore pulp after sizing mixing is after two-stage nitration bores concentration deeply, and supernatant fluid reuse, underflow adds new water under stirring and enters
Row secondary is sized mixing；
(3) after secondary is sized mixing, ore pulp control ph is in the range of 8～9, adds except cyanogen oxidant, reaction under stirring
30min～50min；
(4) concentrate except the ore pulp after cyanogen oxidation processes enters mastic thickener, make mass concentration 68%～70%
Mastic, mastic is used for mine down-hole filling.
2., in step described in (1), (2), deep cone concentrates end mass concentration flow control 55%～60%.
3., in step described in (3), after secondary is sized mixing, ore pulp mass concentration controls 39%～42%, addition except cyanogen aoxidize
Agent is calcium hypochlorite, and calcium hypochlorite dosage is relevant with ore pulp cyanide content, the calcium hypochlorite that cyanide content height then adds
Many, cyanide content is low, and the calcium hypochlorite added is few.
The invention provides a kind of cyanogen-containing tailing innoxious paste body filling method, use physics sedimentation and dilution desorbing skill
The method that art, chemical oxidation techniques and paste body filling technology combine, the most comprehensive after sludge containing cyanogens is carried out harmless treatment
Utilize.This method technological process is simple, and treatment effeciency is high, and operating cost is low, relieves the security context hidden danger of cyanogen-containing tailing.
Accompanying drawing explanation
Fig. 1 is cyanogen-containing tailing provided by the present invention innoxious paste body filling method flow schematic diagram.
Detailed description of the invention
Embodiment 1:
Sludge containing cyanogens concentration 40%, pH is 11.21, cyanide content 235.18mg/L.
(1) mine tailing ore pulp is after one section of deep cone concentrates, and obtains the underflow of pulp density 55%, supernatant fluid reuse, underflow
Under stirring, add new water size mixing；
(2) ore pulp after sizing mixing is after two-stage nitration bores concentration deeply, to the underflow of mass percent 60%, and supernatant fluid reuse,
Underflow adds new water under stirring and carries out secondary and size mixing；
(3) after secondary is sized mixing, pulp density controls 42%, in the range of pH value 8～9, adds such as hypochlorous acid under stirring
Calcium 0.3Kg/t, reacts 30min；
(4) the ore pulp entrance mastic thickener after oxidation processes concentrates, and makes the mastic of mass concentration 70%, by cream
Body is used for mine down-hole filling.
Mastic after harmless treatment, after Cyanide Leaching test differentiates, cyanide is less than 1.0mg/L, belongs to general
Trade waste.
Embodiment 2:
Sludge containing cyanogens concentration 37%, pH is 11.40, cyanide content 276.03mg/L.
(1) mine tailing ore pulp is after one section of deep cone concentrates, and obtains the underflow of ore pulp mass concentration 60%, supernatant fluid reuse,
Underflow adds new water under stirring and sizes mixing；
(2) ore pulp after sizing mixing is after two-stage nitration bores concentration deeply, to the underflow of mass percent 58%, and supernatant fluid reuse,
Underflow adds new water under stirring and carries out secondary and size mixing；
(3) after secondary is sized mixing, pulp density controls 40%, in the range of pH value 8～9, adds such as hypochlorous acid under stirring
Calcium 0.35Kg/t, reacts 40min；
(4) the ore pulp entrance mastic thickener after oxidation processes concentrates, and makes the mastic of mass concentration 69%, by cream
Body is used for mine down-hole filling.
Mastic after harmless treatment, after Cyanide Leaching test differentiates, cyanide is less than 1.0mg/L, belongs to general
Trade waste.
Embodiment 3:
Sludge containing cyanogens concentration 39%, pH is 11.47, cyanide content 302.31/L.
(1) mine tailing ore pulp is after one section of deep cone concentrates, and obtains the underflow of ore pulp mass concentration 57%, supernatant fluid reuse,
Underflow adds new water under stirring and sizes mixing；
(2) ore pulp after sizing mixing is after two-stage nitration bores concentration deeply, to the underflow of mass percent 55%, and supernatant fluid reuse,
Underflow adds new water under stirring and carries out secondary and size mixing；
(3) after secondary is sized mixing, pulp density controls 42%, in the range of pH value 8～9, adds such as hypochlorous acid under stirring
Calcium 0.41Kg/t, reacts 50min；
(4) the ore pulp entrance mastic thickener after oxidation processes concentrates, and makes the mastic of mass concentration 68%, by cream
Body is used for mine down-hole filling.
Mastic after harmless treatment, after Cyanide Leaching test differentiates, cyanide is less than 1.0mg/L, belongs to general
Trade waste.
Claims (3)
1. a cyanogen-containing tailing innoxious paste body filling method, it is characterised in that comprise the following steps:
(1) mine tailing ore pulp is after one section of deep cone concentrates, and supernatant fluid reuse, underflow adds new water under stirring and sizes mixing；
(2) ore pulp after sizing mixing is after two-stage nitration bores concentration deeply, and supernatant fluid reuse, underflow adds new water under stirring and carries out two
Secondary size mixing；
(3) after secondary is sized mixing, ore pulp control ph is in the range of 8～9, adds except cyanogen oxidant, reaction under stirring
30min～50min；
(4) concentrate except the ore pulp after cyanogen oxidation processes enters mastic thickener, make the cream of mass concentration 68%～70%
Body, carries out mine down-hole filling with described mastic.
Cyanogen-containing tailing the most according to claim 1 innoxious paste body filling method, it is characterised in that described step (1),
(2), in, deep cone concentrates underflow mass concentration and controls 55%～60%.
Cyanogen-containing tailing the most according to claim 1 innoxious paste body filling method, it is characterised in that in described step (3),
After secondary is sized mixing, ore pulp mass concentration controls 39%～42%, described except cyanogen oxidant be calcium hypochlorite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669345.5A CN106285774A (en) | 2016-08-15 | 2016-08-15 | A kind of cyanogen-containing tailing innoxious paste body filling method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669345.5A CN106285774A (en) | 2016-08-15 | 2016-08-15 | A kind of cyanogen-containing tailing innoxious paste body filling method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106285774A true CN106285774A (en) | 2017-01-04 |
Family
ID=57671052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610669345.5A Pending CN106285774A (en) | 2016-08-15 | 2016-08-15 | A kind of cyanogen-containing tailing innoxious paste body filling method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106285774A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108298718A (en) * | 2018-01-31 | 2018-07-20 | 辽宁工程技术大学 | A kind of integrated conduct method of sludge containing cyanogens |
| CN108503248A (en) * | 2018-04-16 | 2018-09-07 | 贵州紫金矿业股份有限公司 | A method of doing aggregate using superfine granule lightweight calcium and magnesium gelling ointment material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215975A (en) * | 2008-01-09 | 2008-07-09 | 云南驰宏锌锗股份有限公司 | Whole tailings depth controllable homogeneous concentration method |
| CN101444660A (en) * | 2008-12-30 | 2009-06-03 | 吴正建 | Innocent treatment of cyanide and fluoride in solid waste residues and recycling process thereof |
| CN103239828A (en) * | 2013-05-31 | 2013-08-14 | 吴正建 | Harmless production process of program-control and manual-control electrolytic aluminum overhaul residues |
| CN104944639A (en) * | 2015-06-09 | 2015-09-30 | 长春黄金研究院 | Comprehensive utilization method for cyanogen-containing tailing slurry |
| CN204689778U (en) * | 2015-05-14 | 2015-10-07 | 长春黄金研究院 | A kind of sludge containing cyanogens utilization system |
| CN105498952A (en) * | 2016-02-02 | 2016-04-20 | 大连地拓重工有限公司 | Gold tailing processing system and method |
| CN105709920A (en) * | 2016-02-02 | 2016-06-29 | 大连地拓重工有限公司 | Comprehensive recovery method for copper and iron in copper tailings |
-
2016
- 2016-08-15 CN CN201610669345.5A patent/CN106285774A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215975A (en) * | 2008-01-09 | 2008-07-09 | 云南驰宏锌锗股份有限公司 | Whole tailings depth controllable homogeneous concentration method |
| CN101444660A (en) * | 2008-12-30 | 2009-06-03 | 吴正建 | Innocent treatment of cyanide and fluoride in solid waste residues and recycling process thereof |
| CN103239828A (en) * | 2013-05-31 | 2013-08-14 | 吴正建 | Harmless production process of program-control and manual-control electrolytic aluminum overhaul residues |
| CN204689778U (en) * | 2015-05-14 | 2015-10-07 | 长春黄金研究院 | A kind of sludge containing cyanogens utilization system |
| CN104944639A (en) * | 2015-06-09 | 2015-09-30 | 长春黄金研究院 | Comprehensive utilization method for cyanogen-containing tailing slurry |
| CN105498952A (en) * | 2016-02-02 | 2016-04-20 | 大连地拓重工有限公司 | Gold tailing processing system and method |
| CN105709920A (en) * | 2016-02-02 | 2016-06-29 | 大连地拓重工有限公司 | Comprehensive recovery method for copper and iron in copper tailings |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108298718A (en) * | 2018-01-31 | 2018-07-20 | 辽宁工程技术大学 | A kind of integrated conduct method of sludge containing cyanogens |
| CN108503248A (en) * | 2018-04-16 | 2018-09-07 | 贵州紫金矿业股份有限公司 | A method of doing aggregate using superfine granule lightweight calcium and magnesium gelling ointment material |
| CN108503248B (en) * | 2018-04-16 | 2020-12-18 | 贵州紫金矿业股份有限公司 | Method for using ultrafine-grained light calcium-magnesium gelled paste material as aggregate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105268737B (en) | Heavy metal contaminated soil remediation equipment and remediation process thereof | |
| CN104923557A (en) | Cyanide contaminated soil restoring method | |
| CN104984992B (en) | A kind of method that heavy-metal contaminated soil press filtration elution is repaired | |
| CN105858958B (en) | A kind of cyanogen mine wastewater treatment method of antimony containing arsenic | |
| WO2019076061A1 (en) | Disposal method for gold mine cyanide tailing paste | |
| CN104475261A (en) | Method for recovering low-grade copper-zinc mineral from cyanidation tailings | |
| Salo et al. | Integrated acid leaching and biological sulfate reduction of phosphogypsum for REE recovery | |
| CN105399237B (en) | Copper-bearing gold ore cyanide wastewater processing method | |
| CN101767904A (en) | Process for treating polluted groundwater of retired mining area of acid in-situ leaching uranium mine by using microbial method | |
| CN104846195A (en) | Method for recovering low-grade precious metal from mineral dressing tailings | |
| Xie et al. | Leaching process and kinetics of manganese in low-grade manganese ore | |
| CN206965905U (en) | A kind of innocuity disposal system containing cyanogen golden mine tailing | |
| CN108249480A (en) | A kind of comprehensive recovering process of Copper making arsenic sulfide slag, flue dust leachate arsenic | |
| CN103831165A (en) | Harmless treatment method of gold cyanidation tailings highly containing arsenic | |
| CN104841565A (en) | Method for recycling gold from gold floatation tailings | |
| CN105498952B (en) | Gold tailing processing system and method | |
| CN106285774A (en) | A kind of cyanogen-containing tailing innoxious paste body filling method | |
| CN103899353B (en) | A kind of device and method of mine washing mine tailing bashing | |
| CN107460336A (en) | A kind of processing method of golden cyanide residue | |
| CN110898995A (en) | Flotation method for heavy metals in fly ash | |
| CN105127181B (en) | A kind of gold tailing ponds in-situ immobilization processing method | |
| CN103194613B (en) | Method for extracting gold from high basic gangue containing arsenic and carbon | |
| CN109182789A (en) | A kind of method of Oxidation Leaching processing mercury tailing | |
| CN105174527B (en) | Method for carrying out selective oxidation treatment on beneficiation wastewater | |
| CN107746965A (en) | A kind of method of germanium vacuum distillation slag recovery indium germanium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170831 Address after: 116200 Zhenxing street, Pulandian Bay Industrial Zone, Dalian, Liaoning, China, No. 16 Applicant after: Dalian Earth Environment Technology Co., Ltd. Address before: 116299 Zhenxing street, Pulandian Bay Industrial Zone, Dalian, Liaoning, China, No. 16 Applicant before: DALIAN DITUO HEAVY INDUSTRY CO., LTD. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |