CN106283872A - Environment-friendlywallpaper wallpaper and preparation method thereof - Google Patents
Environment-friendlywallpaper wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106283872A CN106283872A CN201610806001.4A CN201610806001A CN106283872A CN 106283872 A CN106283872 A CN 106283872A CN 201610806001 A CN201610806001 A CN 201610806001A CN 106283872 A CN106283872 A CN 106283872A
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- Prior art keywords
- preparation
- consumption
- environment
- heat treatment
- wallpaper
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/30—Pretreatment of the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses the preparation method of a kind of Environment-friendlywallpaper wallpaper, the method includes: acetone, dispersant, polrvinyl chloride, melamine-formaldehyde resin, acrylic resin, carborundum, anti-foam agent and bamboo charcoal powder are mixed to prepare water-repellent paint by (1)；(2) paper is carried out the pre-heat treatment；(3) water-repellent paint is coated on the paper after preheated process, and heat, Environment-friendlywallpaper wallpaper is made in embossing；Wherein, the weight average molecular weight of polrvinyl chloride is 80,000 9 ten thousand.The Environment-friendlywallpaper wallpaper prepared by the method has fluid-tight characteristic, it is possible to play waterproof effect, and environmentally friendly.
Description
Technical field
The present invention relates to wallpaper, be specifically related to Environment-friendlywallpaper wallpaper and preparation method thereof.
Background technology
Wallpaper, be a kind of indoor hardware fitting for papering metope, is widely used in house, office, hotel, hotel
Interior decoration etc..Material is not limited to paper, also comprises other materials.Because having, color is various, pattern abundant, luxurious style, peace
The feature that other house decorative materials multiple such as loopful guarantor, easy construction, affordable are incomparable, thus be widely used.
Wallpaper is divided into a lot of class, such as overlay film wallpaper, coating wallpaper, embossing wallpaper etc..Generally produce body paper, then warp with bleached wood pulp
The processed of different operations, as be coated with, prints, emboss or surface being covered and moulded, the most cut, pack after dispatch from the factory.But, currently
Commercially available wallpaper uses multiple chemical products due to a large amount of, causes wallpaper not only poor air permeability to cause body of wall moist, it is often more important that
Wallpaper volatilization poisonous and harmful chemical composition harmful to human life and health itself.
Summary of the invention
An object of the present invention is to provide mild condition, the preparation method of Environment-friendlywallpaper wallpaper simple to operate.
It is a further object of the present invention to provide, by what said method was prepared from, there is impervious nature, it is possible to play waterproof
Effect, and environmentally friendly Environment-friendlywallpaper wallpaper.
The preparation method of Environment-friendlywallpaper wallpaper that the present invention provides includes: (1) by acetone, dispersant, polrvinyl chloride, melamine-
Formaldehyde resin, acrylic resin, carborundum, anti-foam agent and bamboo charcoal powder are mixed to prepare water-repellent paint；(2) paper is carried out at preheating
Reason；(3) water-repellent paint is coated on the paper after preheated process, and heat, Environment-friendlywallpaper wallpaper is made in embossing；Wherein, polychlorostyrene second
The weight average molecular weight of alkene is 80,000-9 ten thousand.
In the step (1) of above-mentioned preparation method, the concrete kind of dispersant can select, from cost in wide scope
Upper consideration, it is preferable that dispersant is in sodium hexameta phosphate, sodium pyrophosphate, triethyl group hexyl phosphoric acid and sodium lauryl sulphate
One or more.
In the step (1) of above-mentioned preparation method, the concrete kind of anti-foam agent can select in wide scope, but is
Improve the tensile strength of obtained wallpaper, it is preferable that anti-foam agent is polydimethylsiloxane, emulsified silicone oil and polyoxypropylene glyceryl
One or more in ether.
In the step (1) of above-mentioned preparation method, the particle diameter of bamboo charcoal powder can select in wide scope, but for increasing
The contact area of storeroom, improves composite rate, it is preferable that the particle diameter of bamboo charcoal powder is 200-300nm.
In the step (1) of above-mentioned preparation method, the concrete amount ratio of each material can select in wide scope, but
For improving the tensile strength of obtained wallpaper further, it is preferable that in parts by weight, relative to 10 parts of described bamboo charcoal powder, described
The consumption of acetone is 30-50 part, and the consumption of described dispersant is 5-10 part, and the consumption of described polrvinyl chloride is 5-15 part, described
The consumption of melamine-formaldehyde resin is 10-20 part, and the consumption of described acrylic resin is 40-50 part, the consumption of described carborundum
Consumption for 2-5 part, described anti-foam agent is 5-10 part.
In the step (2) of above-mentioned preparation method, the concrete grammar of the pre-heat treatment can select in wide scope, in order to
Reduce the strain of paper in subsequent technique, it is preferable that the pre-heat treatment includes the first the pre-heat treatment and the second the pre-heat treatment successively.
In the step (2) of above-mentioned preparation method, the actual conditions of the pre-heat treatment can select, equally in wide scope
In order to reduce the strain of paper in subsequent technique, it is ensured that the uniformity of coating coating, it is preferable that the first the pre-heat treatment meets following bar
Part: initial temperature is 20-25 DEG C, heating rate is 1-5 DEG C/min, and the heating-up time is 2-5min；The intensification of the second the pre-heat treatment
Speed is 6-10 DEG C/min, and the heating-up time is 1-5min.
In the step (3) of above-mentioned preparation method, the temperature and time of heating can select in wide scope, for ensureing
The water proofing property of obtained Environment-friendlywallpaper wallpaper, considers from energy-conserving and environment-protective angle, the temperature of heating is 110-130 DEG C simultaneously, heating time
Between be 30-50min.
Present invention also offers Environment-friendlywallpaper wallpaper, this wallpaper is to be prepared from by above-mentioned method.
By technique scheme, the present invention by first by acetone, dispersant, polrvinyl chloride, melamine-formaldehyde resin,
Acrylic resin, carborundum, anti-foam agent and bamboo charcoal powder are mixed to prepare water-repellent paint, and paper carry out secondary preheating process, finally
Water-repellent paint is coated on the paper after preheated process, and heat, Environment-friendlywallpaper wallpaper is made in embossing.In the process, acetone, point
It is waterproof that powder, polrvinyl chloride, melamine-formaldehyde resin, acrylic resin, carborundum, anti-foam agent and bamboo charcoal powder are mixed to prepare
Coating can play waterproof effect, is coated on paper the fire resistance characteristic being capable of paper；Additionally, the pre-heat treatment that paper is carried out
Can reduce or avoid the strain that paper occurs during coating water-repellent paint post-heating such that it is able to improve obtained environmental protection wall
The waterproof effect of paper, and the interaction of storeroom in a heated condition can be effectively improved obtained Environment-friendlywallpaper wallpaper toughness and
Tensile strength.The method is a kind of with low cost, mild condition, environmental protection and method simple to operate, prepared environmental protection wall
Paper has fluid-tight characteristic, it is possible to play waterproof effect, and environmentally friendly.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Embodiment 1
(1) by polychlorostyrene second that 32 pbw acetone, 6 weight portion sodium hexameta phosphate, 5 weight portion weight average molecular weight are 8.1 ten thousand
Alkene, 12 weight portion melamines-formaldehyde resin, 40 parts by weight propylene acid resins, 2 weight portion carborundums, 6 weight portion poly dimethyl silicon
Oxygen alkane and the bamboo charcoal powder that 10 weight portion particle diameters are 200nm are mixed to prepare water-repellent paint；
(2) by paper under the initial temperature of 20 DEG C with the heating rate intensification 3min of 2 DEG C/min to carry out at the first preheating
Reason；Then with the heating rate intensification 2min of 7 DEG C/min to carry out the second the pre-heat treatment；
(3) water-repellent paint is coated on the paper after preheated process, and at a temperature of 110 DEG C, heats 35min, embossing
Make Environment-friendlywallpaper wallpaper A1.
Embodiment 2
(1) by polychlorostyrene second that 50 pbw acetone, 9 weight portion sodium pyrophosphates, 15 weight portion weight average molecular weight are 8.8 ten thousand
Alkene, 18 weight portion melamines-formaldehyde resin, 50 parts by weight propylene acid resins, 5 weight portion carborundums, 9 weight portion emulsified silicone oils and
10 weight portion particle diameters are that the bamboo charcoal powder of 300nm is mixed to prepare water-repellent paint；
(2) by paper under the initial temperature of 25 DEG C with the heating rate intensification 5min of 5 DEG C/min to carry out at the first preheating
Reason；Then with the heating rate intensification 5min of 10 DEG C/min to carry out the second the pre-heat treatment；
(3) water-repellent paint is coated on the paper after preheated process, and at a temperature of 130 DEG C, heats 50min, embossing
Make Environment-friendlywallpaper wallpaper A2.
Embodiment 3
(1) by 40 pbw acetone, 8 weight portion sodium lauryl sulphates, 10 weight portion weight average molecular weight be 8.5 ten thousand poly-
Vinyl chloride, 15 weight portion melamines-formaldehyde resin, 45 parts by weight propylene acid resins, 3 weight portion carborundums, 7 weight portion polyoxies third
Alkene glycerin ether and the bamboo charcoal powder that 10 weight portion particle diameters are 250nm are mixed to prepare water-repellent paint；
(2) by paper under the initial temperature of 23 DEG C with the heating rate intensification 3min of 3 DEG C/min to carry out at the first preheating
Reason；Then with the heating rate intensification 3min of 8 DEG C/min to carry out the second the pre-heat treatment；
(3) water-repellent paint is coated on the paper after preheated process, and at a temperature of 120 DEG C, heats 40min, embossing
Make Environment-friendlywallpaper wallpaper A3.
Comparative example 1
Carry out preparing wallpaper B1 according to the method for embodiment 1, except that, step (2) is not carried out at the preheating to paper
Reason.
Comparative example 2
Carry out preparing wallpaper B2 according to the method for embodiment 2, except that, consumption 150 weight of acetone in step (1)
Amount part, consumption 10 weight portion of acrylic resin.
Detection example 1
The wallpaper that above-described embodiment and comparative example prepare is placed in pressure be 0.3MPa under water, keep 10 minutes, do not
Permeable experiment, observes with or without Seepage, and concrete outcome is shown in Table 1.
Detection example 2
The method that wallpaper above-described embodiment and comparative example prepared specifies according to GB18582-2008 standard is to relevant ginseng
Number detects, and concrete outcome is shown in Table 1.
Table 1
| A1 | A2 | A3 | B1 | B2 | |
| Waterproof experiment | Ne-leakage | Ne-leakage | Ne-leakage | Seepage | Seepage |
| Limit the use of solvent | Meet | Meet | Meet | Do not meet | Do not meet |
| VOC content | Meet | Meet | Meet | Do not meet | Meet |
| Free formaldehyde content | Meet | Meet | Meet | Do not meet | Do not meet |
| Benzene content | Meet | Meet | Meet | Meet | Meet |
Wherein, VOC represents VOC；By above-mentioned detection example, the wall prepared by above-described embodiment
Paper has fluid-tight characteristic, it is possible to plays waterproof effect, and meets GB18582-2008 standard, environmentally friendly.By upper
The testing result stating embodiment is learnt, the Environment-friendlywallpaper wallpaper that the present invention provides has fluid-tight characteristic, it is possible to play waterproof work
With, and environmentally friendly.Additionally, from the preparation process of the present invention it can be seen that the preparation method of Environment-friendlywallpaper wallpaper that provides of the present invention
Mild condition, simple to operate.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1. the preparation method of an Environment-friendlywallpaper wallpaper, it is characterised in that described method includes:
(1) by acetone, dispersant, polrvinyl chloride, melamine-formaldehyde resin, acrylic resin, carborundum, anti-foam agent and bamboo charcoal
Powder is mixed to prepare water-repellent paint；
(2) paper is carried out the pre-heat treatment；
(3) described water-repellent paint is coated on the described paper after preheated process, and heat, Environment-friendlywallpaper wallpaper is made in embossing；
Wherein, the weight average molecular weight of described polrvinyl chloride is 80,000-9 ten thousand.
Preparation method the most according to claim 1, wherein, in step (1), described dispersant is sodium hexameta phosphate, Jiao
One or more in sodium phosphate, triethyl group hexyl phosphoric acid and sodium lauryl sulphate.
Preparation method the most according to claim 1, wherein, in step (1), described anti-foam agent is polydimethylsiloxanes
One or more in alkane, emulsified silicone oil and polypropylene glycerol aether.
Preparation method the most according to claim 1, wherein, in step (1), the particle diameter of described bamboo charcoal powder is 200-
300nm。
5. according to the preparation method according to any one of claim 1-4, wherein, in step (1), in parts by weight, relatively
In 10 parts of described bamboo charcoal powder, the consumption of described acetone is 30-50 part, and the consumption of described dispersant is 5-10 part, described polychlorostyrene second
The consumption of alkene is 5-15 part, and the consumption of described melamine-formaldehyde resin is 10-20 part, and the consumption of described acrylic resin is 30-
45 parts, the consumption of described carborundum is 2-5 part, and the consumption of described anti-foam agent is 5-10 part.
The most according to claim 1 or 5, preparation method, wherein, in step (2), described the pre-heat treatment includes successively
One the pre-heat treatment and the second the pre-heat treatment.
Preparation method the most according to claim 6, wherein, in step (2), described first the pre-heat treatment meets following bar
Part: initial temperature is 20-25 DEG C, heating rate is 1-5 DEG C/min, and the heating-up time is 2-5min；Described second the pre-heat treatment
Heating rate is 6-10 DEG C/min, and the heating-up time is 1-5min.
Preparation method the most according to claim 7, wherein, in step (3), the temperature of described heating is 110-130 DEG C,
The time of heating is 30-50min.
9. an Environment-friendlywallpaper wallpaper, it is characterised in that described wallpaper is prepared by the method described in any one in claim 1-8
Form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610806001.4A CN106283872A (en) | 2016-09-07 | 2016-09-07 | Environment-friendlywallpaper wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610806001.4A CN106283872A (en) | 2016-09-07 | 2016-09-07 | Environment-friendlywallpaper wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106283872A true CN106283872A (en) | 2017-01-04 |
Family
ID=57709717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610806001.4A Pending CN106283872A (en) | 2016-09-07 | 2016-09-07 | Environment-friendlywallpaper wallpaper and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07122236B2 (en) * | 1990-12-13 | 1995-12-25 | 日本製紙株式会社 | Exterior wallpaper backing paper |
| CN104179068A (en) * | 2014-07-23 | 2014-12-03 | 佛山市三水灏诚合成树脂有限公司 | Environment-friendly wallpaper polystyrene foam and preparation method thereof as well as wallpaper |
| CN105111653A (en) * | 2015-07-31 | 2015-12-02 | 桂林威迈壁纸有限公司 | Wallpaper foaming slurry |
| CN105155804A (en) * | 2015-10-09 | 2015-12-16 | 广东玉兰集团股份有限公司 | Local relief embossing wall paper and preparing method of local relief embossing wall paper |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105462442A (en) * | 2015-12-28 | 2016-04-06 | 浙江港流高分子科技有限公司 | Environment-friendly epoxy resin coating, environment-friendly coiled material and preparation method thereof |
-
2016
- 2016-09-07 CN CN201610806001.4A patent/CN106283872A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07122236B2 (en) * | 1990-12-13 | 1995-12-25 | 日本製紙株式会社 | Exterior wallpaper backing paper |
| CN104179068A (en) * | 2014-07-23 | 2014-12-03 | 佛山市三水灏诚合成树脂有限公司 | Environment-friendly wallpaper polystyrene foam and preparation method thereof as well as wallpaper |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105111653A (en) * | 2015-07-31 | 2015-12-02 | 桂林威迈壁纸有限公司 | Wallpaper foaming slurry |
| CN105155804A (en) * | 2015-10-09 | 2015-12-16 | 广东玉兰集团股份有限公司 | Local relief embossing wall paper and preparing method of local relief embossing wall paper |
| CN105462442A (en) * | 2015-12-28 | 2016-04-06 | 浙江港流高分子科技有限公司 | Environment-friendly epoxy resin coating, environment-friendly coiled material and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20170104 |