CN106283687A - A kind of anti-soil cook clothes - Google Patents

A kind of anti-soil cook clothes Download PDF

Info

Publication number
CN106283687A
CN106283687A CN201610665125.5A CN201610665125A CN106283687A CN 106283687 A CN106283687 A CN 106283687A CN 201610665125 A CN201610665125 A CN 201610665125A CN 106283687 A CN106283687 A CN 106283687A
Authority
CN
China
Prior art keywords
emulsion
manufacture method
styrene
fabric
integer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610665125.5A
Other languages
Chinese (zh)
Inventor
张太平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610665125.5A priority Critical patent/CN106283687A/en
Publication of CN106283687A publication Critical patent/CN106283687A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/08—Copolymers of ethene
    • C09D123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09D123/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/145—Oleophobic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/146—Soilproof, soil repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2213/00—Others characteristics
    • D06N2213/03—Fibrous web coated on one side with at least two layers of the same polymer type, e.g. two coatings of polyolefin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

A kind of anti-soil cook clothes, it is characterised in that: use the sewing of grease proofing fabric to form.

Description

A kind of anti-soil cook clothes
Technical field
The present invention relates to a kind of anti-soil cook clothes, belong to functional clothing field.
Background technology
Oilproof fabric refers to through arranging, and makes garment material fabric fibre surface can repel, becomes estranged oil, water class I liquid I Jie Matter, thus reach neither to hinder ventilative comfortable, can effectively resist again the special type protection of the erosion of the internal clothing of this class I liquid I and human body Fabric.This product does not gets wet, oil-tight.The machine oil of 5 milliliters or diesel oil are placed on cloth cover, within 24 hours, can not pass through cloth, mainly For the industry that oily wastewater pollution is serious, such as industries such as oil recovery, flight-line maintenances.Oil resistant water repellent fabric is applicable to frequently contact profit and is situated between Labor protection under matter environment, have chance profit do not adhere to, impermeable, good air-moisture-permeable function.Be widely used in oil, The industries such as chemical industry, gas station, industrial and mineral, anti-soil cook clothes, repairing.The finishing technique of existing Oilproof fabric includes: 1, polytetrafluoro The oil resistant water repellency of ethylene (PTFE) film laminating laminated fabric is good, water-fastness, high water pressure resistant, but needs special lamination Equipment, one-time investment is relatively big, and cost is high.External preferably PTFE thin film mainly has the Gore Tex of Gao Er company of the U.S. thin Film and the Sympatex thin film of AKZO company of Holland；The domestic thin film mainly having General Logistics Department's quartermaster equipment exhibition area Research Institute.2, fluorine carbon Compound padding method arranges at present, fluorocarbons common on market mainly have du pont company zepe1588 and Telfon, the Oleo phobol series that Hensel steps, AG480 and AG710 of Japan AGC, the TG410 of big King Company, TG527, the EC50 etc. of solar corona.Although the performance of various fluorocarbons is different, but finishing technique is substantially the same, and general employing is such as Under roll baking process: pad fabric (pick-up 70%～80%) preliminary drying (80 100 DEG C of .5 10arin)-bake (150～ 170 DEG C, 2～3min) dressing liquid with glacial acetic acid regulation pH value to 3～7.3, top finish coating is to realize water repellent, water-proof finish Conventional means.Fabric coating finishing agent mainly has polyacrylate, polyurethane, elastomer silicone and polrvinyl chloride tree at present The types such as fat, wherein the application of soluble polyurethane type coating glue is relatively broad.Coating can significantly improve the resistance to hydrostatic pressure of fabric. But often affect vapor transfer rate and feel.In order to obtain preferable finishing effect, padding finishing can be used to tie mutually with top finish The technique closed.There is oil preventing performance and can not get both with ventilative, water vapour permeability in the method for prior art, after washing, grease proofness difference etc. are asked Topic.
Summary of the invention
The present invention provides a kind of anti-soil cook clothes having waterproof and oilproof breathable moisture permeability concurrently, uses special fabrication processes system The grease proofing fabric sewing made forms, and improves the problems of existing Oilproof fabric greatly, and the manufacture method of grease proofing fabric is such as Under:
(1) composite oil-proof coating finishing agent is prepared: be 0.1-20wt%, preferably 1-15wt%, more preferably 5-by solid content Sol liquid 40-100g comprising Pulvis Talci, calcium carbonate or barium sulfate of 10wt% adds 200-400g and adds styrene-acrylic emulsion, second One or more in acrylic emulsion, silicone acrylic emulsion and fluorine carbon emulsion；
The chemical composition of described these four emulsion is respectively
1. styrene-acrylic emulsion: be styrene, butyl acrylate, methyl methacrylate, methacrylic acid quadripolymer latex (commodity Name LT-1 emulsion), or quadripolymer latex (the trade name LT-2 breast of butyl acrylate in ethyl acrylate replacement combinations thereof Liquid), or the ternary copolymer emulsion (trade name LT-3 emulsion) of styrene, ethyl acrylate, methacrylic acid, it is the so-called 1st A representative for coating emulsion；
2. vinyl acetate emulsion: be the copolymer emulsion of vinylacetate and acrylic monomer, be so-called 1st generation coating emulsion again One representative；
3. silicone acrylic emulsion: be the resin emulsion of acrylate monomer silicone functionalities's graft copolymerization；This is that the so-called second filial generation is coated with One representative of material emulsion, has good water-proof function because of silicone functionalities's hydrophobicity speciality, resistance to soiling after film forming Can significantly improve；This kind of emulsion combination property substantially exceeds common so-called first generation coating emulsion, phenylpropyl alcohol described above breast Liquid, vinyl acetate emulsion；
4. fluorine carbon emulsion: comprise perfluorocarbon emulsion and fluorine carbon emulsion two class；Perfluorocarbon emulsion system is by perfluorinated monomers, such as tetrafluoro second Alkene, carries out solution or the final perfluorocarbon polymer emulsion prepared of emulsion polymerization；Fluorine carbon emulsion system uses tetrafluoroethene, fluorine second One or more in the fluorochemical monomers such as alkene, CTFE, hexafluoropropene and non-fluorochemical monomer, as comprised vinyl (allyl Base) ether (ester) monomer of alkyl or aryl or unsaturated olefin(e) acid etc. be polymerized the final fluorine carbon poly prepared by solution or emulsion and close Thing emulsion；Fluorocarbon polymer have because of the high saturability of F-C covalent bond prominent chemical inertness and extremely low surface can, fluorine Oleophobic after carbon polymer emulsion film forming, hydrophobic, water proofing property and antistick characteristic, contaminated resistance highlight；This kind of emulsion combination property is bright Show and exceed above-mentioned so-called second filial generation coating emulsion, such as silicone acrylic emulsion.
The solvent that styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion and fluorine carbon emulsion are used is organic or inorganic solvent.Talcum Powder, calcium carbonate or barium sulfate use the nano-scale particle of 100-200nm.
(2) composite oil-proof coating finishing agent prepared by step (1) is coated on the surface of fabric, and coating thickness is ground floor 1-10mm, the second layer is 1-10mm, and convection oven 40 60 degrees Celsius dries 5-20min；
(3) by fluorine silicon organic compound solution spray gun spraying on the composite oil-proof coating finishing agent surface of step (2), microwave Stove 690-860W, heats 3-20min；
Fluorine silicon organic compound used is selected from one or more of compound with below general formula:
①(R1)3Si(OSi(Rf)(R2))nOSi(R1)3
Wherein n is the integer of 0～100；R1For alkyl, selected from methyl, ethyl or propyl group；R2For alkyl, hydroxyl or amido；RfFor CF3(CF2)p(CH2) q, wherein p and q is the integer of 0～20；
②CF3(CF2)m(CH2)nSi(OM)3
Wherein m and n is the integer of 0～20, and M is alkyl, selected from methyl, ethyl or propyl group；With
③CF3(CF2)m(CH2)nSiCl3-fRf
Wherein m and n is the integer of 0～20, and f is the integer of 0～3, and R is chlorine, bromine or alkyl, such as methyl, ethyl, propyl group；
Preferably fluorine silicon organic compound is selected from HO (Si (CH3)(CF3(CH2)2)O)nH、 CF3(CF2)7Si(OCH3)3、CF3 (CF2)7SiCl3One or more.
The solvent of described fluorine silicon organic compound adapted or disperse medium system are selected from alcohols, benzene class, ethers and hydro carbons.
Beneficial effects of the present invention
1. Pulvis Talci, calcium carbonate or the barium sulfate ultramicron sol liquid that the present invention uses, with the evaporation of moisture, colloid molecules Increasing so that after it is coated on fabric, film is fine and close, does not produce electrostatic, and in air, various dust are difficult to adhere to and organic Contamination resistance is stronger.The trickleest granule, has stronger penetration to fabric, can be by capillary percolation to fabric Portion, forms good washability.
2. Pulvis Talci, calcium carbonate or barium sulfate ultramicron sol liquid and styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion Or fluorine carbon emulsion characteristic is complementary to one another, the organic and inorganic composite coating of function admirable can be made.
Composite oil-proof coating finishing agent the most of the present invention uses frivolous two-layer coating, and air blast is dried, the completeest In the case of entirely hardening, the fluorine silicon organic compound with rear spraying can suitably blend, and improves the durability of oil-repellent, And breathability.
4. fluorine silicon organic compound uses and sprays and non-impregnated mode so that coating uniform is frivolous, and microwave heating Avoiding composite oil-proof finishing agent and the structural deterioration of fluorine silicon organic compound, it is good grease proofing durable that the fabric of manufacture refuses oil Property and ventilative, poisture-penetrability.
Detailed description of the invention
Embodiment 1:
(1) composite oil-proof coating finishing agent is prepared: by sol liquid 50g comprising 100nm calcium carbonate that solid content is 15wt% Join in 280g styrene-acrylic emulsion.
(2) composite oil-proof coating finishing agent prepared by step (1) is coated on the surface of fabric, and coating thickness is ground floor 4mm, the second layer is 6mm, and convection oven 60 degrees Celsius dries 13min；
(3) by HO (Si (CH3)(CF3(CH2)2)O)8H fluorine silicon organic compound solution spray gun spraying being combined in step (2) On oil-repellent finishing agent surface, coating thickness is 13mm, microwave 690W, heats 10min.
Anti-soil cook clothes are made with the fabric after arranging.
Embodiment 2:
(1) composite oil-proof coating finishing agent is prepared: by sol liquid 90g comprising 120nm barium sulfate that solid content is 20wt% Add in 290g fluorine carbon emulsion；
(2) composite oil-proof coating finishing agent prepared by step (1) is coated on the surface of fabric, and coating thickness is ground floor 7mm, The second layer is 6mm, and convection oven 40 degrees Celsius dries 12min；
(3) by CF3(CF2)7Si(OCH3)3Fluorine silicon organic compound solution spray gun spraying is in the composite oil-proof coating of step (2) On finishing agent surface, coating thickness is 8mm, microwave 700W, heats 20min.
Anti-soil cook clothes are made with the fabric after arranging.
Comparative example 1:
Use the zepe1588 fluorocarbons of du pont company, roll baking process as follows: pad fabric (pick-up 70%) One preliminary drying (80 DEG C of .10min)-bake (170 DEG C, 2～3min), dressing liquid glacial acetic acid regulates pH value to 6.
Anti-soil cook clothes are made with the fabric after arranging.
Comparative example 2:
Calcium carbonate sol liquid in embodiment 1 is replaced to silicon dioxide gel liquid (i.e. generally described Ludox), its Remaining operation is identical.Anti-soil cook clothes are made with the fabric after arranging.
Comparative example 3:
By the AG480 fluorine silicon organic compound solution of Japan AGC with spray gun spraying on the surface of the fabric, coating thickness is 8mm, microwave 700W, heat 20min.Anti-soil cook clothes are made with the fabric after arranging.
Embodiment 1-2 providing the present invention and the anti-soil cook clothes of comparative example 1-3 are tested.
Index:
5 grades (the highest), instrument test result is after tested: web surface is not stained with any oil stain or water mark；
4 grades, test result is: web surface speckles with a small amount of or oil stain of trace or water mark, but impermeable, trembles and will fall；
3 grades, test result is: web surface speckles with a small amount of oil stain or water mark, trembles and can fall, but web surface still has the most residual Stay；
2 grades, test result is: web surface has substantially to be stained with oil or gets wet, and has infiltration；
1 grade, test result is: have substantially infiltration.
Normal less than 3 grades is defective
Table 1 testing result
Embodiment 1-2 is resistant to machine oil, diesel oil topples, and the grease proofing time is about 30-more than 150min, the comparative example 1-3 grease proofing time 50min。

Claims (8)

1. anti-soil cook clothes, it is characterised in that: use the sewing of grease proofing fabric to form.
2. the manufacture method of anti-soil cook as claimed in claim 1 clothes, it is characterised in that the grease proofing fabric manufacturer of use Method is as follows:
(1) prepare composite oil-proof coating finishing agent: by solid content be 0.1-20wt% comprise Pulvis Talci, calcium carbonate or barium sulfate Sol liquid 40-100g add 200-400g styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion and fluorine carbon emulsion one or more In；
The chemical composition of described these four emulsion is respectively
1. styrene-acrylic emulsion: be styrene, butyl acrylate, methyl methacrylate, methacrylic acid quadripolymer latex, or Ethyl acrylate replaces the quadripolymer latex of butyl acrylate in combinations thereof, or styrene, ethyl acrylate, methyl-prop The ternary copolymer emulsion of olefin(e) acid；
2. vinyl acetate emulsion: be the copolymer emulsion of vinylacetate and acrylic monomer；
3. silicone acrylic emulsion: be the resin emulsion of acrylate monomer silicone functionalities's graft copolymerization；
4. fluorine carbon emulsion: perfluorocarbon emulsion or fluorine carbon emulsion；Perfluorocarbon emulsion system, by fluorothene, carries out solution or emulsion is polymerized The perfluorocarbon polymer emulsion prepared eventually；Fluorine carbon emulsion system uses tetrafluoroethene, fluorothene, CTFE, hexafluoropropene etc. One or more in fluorochemical monomer and non-fluorochemical monomer, i.e. comprise ether (ester) monomer of vinyl (pi-allyl) alkyl or aryl Or unsaturation olefin(e) acid is by solution or the final fluorocarbon polymer emulsion prepared of emulsion polymerization；
(2) composite oil-proof coating finishing agent prepared by step (1) is coated on the surface of fabric, and coating thickness is ground floor 1- 10mm, the second layer is 1-10mm, and convection oven 40 60 degrees Celsius dries 5-20min；
(3) by fluorine silicon organic compound solution spray gun spraying on the composite oil-proof coating finishing agent surface of step (2), microwave 690-860W heats 3-20min；
Fluorine silicon organic compound used is selected from one or more of compound with below general formula:
①(R1)3Si(OSi(Rf)(R2))nOSi(R1)3
Wherein n is the integer of 0～100；R1For alkyl, selected from methyl, ethyl or propyl group；R2For alkyl, hydroxyl or amido；RfFor CF3(CF2)p(CH2) q, wherein p and q is the integer of 0～20；
②CF3(CF2)m(CH2)nSi(OM)3
Wherein m and n is the integer of 0～20, and M is alkyl, selected from methyl, ethyl or propyl group；With
③CF3(CF2)m(CH2)nSiCl3-fRf
Wherein m and n is the integer of 0～20, and f is the integer of 0～3, and R is chlorine, bromine or alkyl.
3. manufacture method as claimed in claim 2, it is characterised in that styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion and fluorine carbon breast The solvent that liquid is used is organic or inorganic solvent.
4. manufacture method as claimed in claim 2, it is characterised in that: the solvent of described fluorine silicon organic compound adapted or dispersion Medium system is selected from alcohols, benzene class, ethers and hydro carbons.
5. manufacture method as claimed in claim 2, it is characterised in that: fluorine silicon organic compound is selected from HO (Si (CH3)(CF3 (CH2)2)O)nH、 CF3(CF2)7Si(OCH3)3、CF3(CF2)7SiCl3In one or more.
6. manufacture method as claimed in claim 2, it is characterised in that: solid content is 1-15wt%.
7. manufacture method as claimed in claim 6, it is characterised in that: solid content is 5-10wt%.
8. manufacture method as claimed in claim 2, it is characterised in that: Pulvis Talci, calcium carbonate or barium sulfate use 100-200nm Nano-scale particle.
CN201610665125.5A 2016-08-12 2016-08-12 A kind of anti-soil cook clothes Pending CN106283687A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610665125.5A CN106283687A (en) 2016-08-12 2016-08-12 A kind of anti-soil cook clothes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610665125.5A CN106283687A (en) 2016-08-12 2016-08-12 A kind of anti-soil cook clothes

Publications (1)

Publication Number Publication Date
CN106283687A true CN106283687A (en) 2017-01-04

Family

ID=57670777

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610665125.5A Pending CN106283687A (en) 2016-08-12 2016-08-12 A kind of anti-soil cook clothes

Country Status (1)

Country Link
CN (1) CN106283687A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1446869A (en) * 2003-04-09 2003-10-08 高明南星涂料科技有限公司 Colored heat insulation anti soak coating material
CN1944348A (en) * 2006-02-06 2007-04-11 霍镰泉 Method for preparing silicon dioxide anti-pollution layer of polished glazed tile surface
CN101258284A (en) * 2005-04-12 2008-09-03 因维斯塔技术有限公司 Fabric treated with durable stain repel and stain release finish and method of industrial laundering to maintain durability of finish

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1446869A (en) * 2003-04-09 2003-10-08 高明南星涂料科技有限公司 Colored heat insulation anti soak coating material
CN101258284A (en) * 2005-04-12 2008-09-03 因维斯塔技术有限公司 Fabric treated with durable stain repel and stain release finish and method of industrial laundering to maintain durability of finish
CN1944348A (en) * 2006-02-06 2007-04-11 霍镰泉 Method for preparing silicon dioxide anti-pollution layer of polished glazed tile surface

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
姜英涛: "《涂料基础》", 31 January 2004, 化学工业出版社 第2版 *

Similar Documents

Publication Publication Date Title
CN1085962C (en) Flexible water and oil resistant composites
US5539072A (en) Fabric laminates
US8088445B2 (en) Process to increase the oleophobicity of PTFE, and resulting oleophobic articles
CA2319003C (en) Porous membrane structure and method
AU617310B2 (en) Protective surface treatment
US3203919A (en) Acrylic/siloxane copolymer, polysiloxane composition containing same, and article coated with the composition
CN106283688A (en) A kind of grease proofing fabric and manufacture method thereof
EP0829514A2 (en) Hydrophobic-oleophobic fluoropolymer compositions
US3385812A (en) Finishing composition comprising a fluorochemical and a polyorganosiloxane
CA2609327C (en) Aqueous delivery system for low surface energy structures
CN108137961A (en) Hydrophobicity incremental agent in fluorinated surface effect coatings
JP2006347180A6 (en) Flexible, water and oil resistant composite material
JPH0559827B2 (en)
JP2013095135A (en) Oleophobic membrane structure containing porous polymer coating
JP2009500494A (en) Polymer extender for surface effects
CN101173093A (en) Multifunctional mixture, teflon film and method for producing the same
WO2013058333A1 (en) Surface treatment agent composition, and use thereof
KR20130103392A (en) Superhydrophobic surface body and method for fabricating superhydrophobic surface body using icvd
CN108824007B (en) Processing method of durable antistatic, friction-resistant, waterproof, moisture-permeable and anti-water-seepage jacket fabric
CN106113833A (en) Wear-resisting pore type polyurethane composite membrane
US2407668A (en) Fire resistant coating compsition
CN106283687A (en) A kind of anti-soil cook clothes
EP0125955A2 (en) Novel reinforced fluoropolymer composite and method for making same
CA2209376A1 (en) Gas permeable fabric
JP4206714B2 (en) Fluororesin aqueous dispersion, fluororesin aqueous composition, coating and film

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170104