CN106283016B - A kind of resistance rust solution and preparation method thereof based on nano ceramic material - Google Patents
A kind of resistance rust solution and preparation method thereof based on nano ceramic material Download PDFInfo
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- CN106283016B CN106283016B CN201610666669.3A CN201610666669A CN106283016B CN 106283016 B CN106283016 B CN 106283016B CN 201610666669 A CN201610666669 A CN 201610666669A CN 106283016 B CN106283016 B CN 106283016B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/62—Treatment of iron or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/66—Treatment of aluminium or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
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Abstract
The invention discloses a kind of resistance rust solution and preparation method thereof based on nano ceramic material, the solution is the mixed liquor being formulated by various ingredients, and the quality of each component meets in grams in every 600 grams of mixed liquors：3- (2,3- the third oxygen of epoxy) propyl trimethoxy silicane, hydrolyzed silane solution, silester, metasilicate pentahydrate sodium, nano ceramics, silica solution, sodium carbonate, sodium gluconate, sodium citrate, isopropanol, surplus is deionized water.The present invention is by the way that nano ceramic material to be added in the resistance rust solution of silane, by the nano ceramic material of addition, forms one layer of hard layer on the surface that metal surface generates silanization composite membrane, improves inoxidizability, the abrasion resistance of the metal surface.
Description
Technical field
The invention belongs to field of metal surface treatment technology, become rusty and use more particularly to a kind of resistance based on nano ceramic material
Solution and preparation method thereof.
Background technique
Steel material has very high intensity and hardness, while having good plasticity and processability, and therefore, it is current
A kind of maximum structural material of world's usage amount.But no matter steel material uses or places for a long time in atmospheric environment, all
Chemical action or electrochemical action gradually can occur with surrounding medium, cause the corrosion on surface.Slight corrosion can be such that surface loses
Metallic luster is removed, precision is reduced, surface generates rust hole when serious, and deteriorate steel material Mechanical Properties of Products and is even broken, shadow
Ring its service life.It is reported that in industrially developed country, every year as the corrosion of steel and caused by loss account for national economy
The 1.5%~4.2% of total value；It is horizontal and different with the different economic development level in various countries and corrosion control.The whole world produces every year
Steel there is 10% to become iron rust, 30% steel equipment is damaged because of corrosion.
Organosilan aqueous solution is the process that main component is surface-treated metal or nonmetallic materials.At silanization
Reason has the advantages that following multiple compared with conventional phosphatizing：It is not phosphorous without harmful heavy metal ions, without heating.Silane treatment mistake
Journey does not generate sediment, short processing time, control simplicity.Processing step is few, can save table tune process, and tank liquor is reusable.Have
Effect improves paint to the adhesive force of substrate.It can a variety of substrates such as collineation processing iron plate, galvanized sheet, aluminium sheet.
Nano ceramic material refers in the microstructure of ceramic material, and crystal grain, crystal boundary and combination between them are all
Be in nanometer level (1~100nm) so that the intensity, toughness and superplasticity of material increase substantially, nano ceramics have compared with
Sintering can reach the superiority of densification under low temperature.
Summary of the invention
The purpose of the present invention is to provide a kind of resistance rust solution and preparation method thereof based on nano ceramic material, passes through
Nano ceramic material is added in the resistance rust solution of silane, by the nano ceramic material of addition, is generated in metal surface
The surface of silanization composite membrane forms one layer of hard layer, improves inoxidizability, the abrasion resistance of the metal surface.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions：
The present invention is a kind of resistance rust solution based on nano ceramic material, and the solution is formulated by various ingredients
Mixed liquor, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 12-15
Hydrolyzed silane solution 2-3.5
Silester 0.5-0.8
Metasilicate pentahydrate sodium 33-35
Nano ceramics 60-70
Silica solution 8-12
Sodium carbonate 2.5-2.8
Sodium gluconate 3-5
Sodium citrate 2-2.5
Isopropanol 100-105
Surplus is deionized water.
Further, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 13.5
Hydrolyzed silane solution 2.75
Silester 0.65
Metasilicate pentahydrate sodium 34
Nano ceramics 65
Silica solution 10
Sodium carbonate 2.65
Sodium gluconate 4
Sodium citrate 2.25
Isopropanol 102
Surplus is deionized water.
Further, 0.4-0.6 parts of the parts by weight of raw materials silester, 0.7-0.9 parts of metasilicate pentahydrate sodium, sodium carbonate
0.4-0.6 parts, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, 20-25 parts of composition silane hydrolyzates of deionized water
Liquid.
It further, further include 10-14 parts of isopropanol in the hydrolyzed silane solution, 15-18 parts of nano ceramics, anilinomethyl
5-7 parts and silica solution 8-9 parts of triethoxysilane.
A kind of preparation method of the resistance rust solution based on nano ceramic material, following steps：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following weight point：5-7 parts of anilinomethyl triethoxysilane, 0.4-0.6 parts of silester, five
It is 0.7-0.9 parts of water sodium metasilicate, 0.4-0.6 parts of sodium carbonate, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, different
10-14 parts of propyl alcohol, 20-25 parts of deionized water；
After raw material weighs, first by urea deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 removes the 3/5 of ion water inventory, is heated to 75-85 DEG C, and preliminary solution made from step 1 is added；Add
Enter 3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, sodium carbonate, sodium gluconate, lemon
Lemon acid sodium raw materials component reacts obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total amount made from step 2, is heated to 75-85 DEG C, and nano ceramics is added, stirs
After mixing 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-
10, resistance rust solution is made.
The invention has the advantages that：
1, containing there are two crucial functional group --- R ' and Si-OR in the solution of silane in the present invention.The structural formula of silane
For：R ' (CH2) nSi (OR) 3, wherein R ' is silane characteristic group, it can with paint etc. react and combined with；And Si-OR
It can hydrolyze and generate Si-OH, Si-OH can be condensed with the hydroxyls dehydrate of metal material surface and generate covalent bond.On the one hand：Silane film tool
There is certain corrosion-resisting function；On the other hand, silane does not improve metal surface performance, can with paint etc. corrosion-inhibiting coatings it is better
In conjunction with.
2, resistance rust of the invention of the invention is sprayed on metal surface with solution of silane beach and generates silanization composite membrane, the process
Including three steps：Firstly, Si-OR hydrolysis generates Si-OH；Secondly, the Me- on Si-OH and metal material surface in silane
OH forms hydrogen bond；Finally, heating fixed line, forms Si-O-Me key between silane and metal, self condensation reaction then occurs for Si-OH,
Si-O-Si key is generated, forms netted and fine and close film in metal surface.
3, nano ceramic material of the invention is added in the resistance rust solution of silane, passes through the nano ceramics material of addition
Material forms one layer of hard layer on the surface that metal surface generates silanization composite membrane, improves the inoxidizability, resistance to of the metal surface
It is abrasiveness.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, all other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment one
A kind of resistance rust solution based on nano ceramic material, the solution is the mixing being formulated by various ingredients
Liquid, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 13.5
Hydrolyzed silane solution 2.75
Silester 0.65
Metasilicate pentahydrate sodium 34
Nano ceramics 65
Silica solution 10
Sodium carbonate 2.65
Sodium gluconate 4
Sodium citrate 2.25
Isopropanol 102
Deionized water 363.2.
Wherein, parts by weight of raw materials silester 0.4-0.6 parts, 0.7-0.9 parts of metasilicate pentahydrate sodium, sodium carbonate 0.4-0.6
Part, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, 20-25 parts of composition hydrolyzed silane solutions of deionized water.
It wherein, further include 6-8 parts of hydrolyzed silane solution in hydrolyzed silane solution, 10-14 parts of isopropanol, 15-18 parts of nano ceramics,
5-7 parts and silica solution 8-9 parts of anilinomethyl triethoxysilane.
A kind of preparation method of the resistance rust solution based on nano ceramic material, following steps：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following weight point：6 parts of anilinomethyl triethoxysilane, 0.5 part of silester, the inclined silicon of five water
0.8 part of sour sodium, 0.5 part of sodium carbonate, 2.0 parts of sodium gluconate, 1.6 parts of sodium citrate, 12 parts of isopropanol, 23 parts of deionized water；
After raw material weighs, first by urea deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 takes the 3/5 of 363.2g deionized water total amount, is heated to 75-85 DEG C, is added preliminary molten made from step 1
Liquid；3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, sodium carbonate, gluconic acid is added
Sodium, sodium citrate raw material components react obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total amount made from step 2, is heated to 75-85 DEG C, and nano ceramics is added, stirs
After mixing 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-
10, resistance rust solution is made.
Embodiment two
A kind of resistance rust solution based on nano ceramic material, the solution is the mixing being formulated by various ingredients
Liquid, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 12
Hydrolyzed silane solution 2
Silester 0.5
Metasilicate pentahydrate sodium 33
Nano ceramics 60
Silica solution 8
Sodium carbonate 2.5
Sodium gluconate 3
Sodium citrate 2
Isopropanol 100
Deionized water 377.
Wherein, parts by weight of raw materials silester 0.4-0.6 parts, 0.7-0.9 parts of metasilicate pentahydrate sodium, sodium carbonate 0.4-0.6
Part, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, 20-25 parts of composition hydrolyzed silane solutions of deionized water.
It wherein, further include 6-8 parts of hydrolyzed silane solution in hydrolyzed silane solution, 10-14 parts of isopropanol, 15-18 parts of nano ceramics,
5-7 parts and silica solution 8-9 parts of anilinomethyl triethoxysilane.
A kind of preparation method of the resistance rust solution based on nano ceramic material, following steps：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following weight point：6 parts of anilinomethyl triethoxysilane, 0.4 part of silester, the inclined silicon of five water
0.7 part of sour sodium, 0.5 part of sodium carbonate, 1.9 parts of sodium gluconate, 1.5 parts of sodium citrate, 10 parts of isopropanol, 25 parts of deionized water；
After raw material weighs, first by urea deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 removes the 3/5 of 377g ion water inventory, is heated to 75-85 DEG C, is added preliminary molten made from step 1
Liquid；3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, sodium carbonate, gluconic acid is added
Sodium, sodium citrate raw material components react obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total amount made from step 2, is heated to 75-85 DEG C, and nano ceramics is added, stirs
After mixing 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-
10, resistance rust solution is made.
Embodiment three
A kind of resistance rust solution based on nano ceramic material, the solution is the mixing being formulated by various ingredients
Liquid, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 15
Hydrolyzed silane solution 3.5
Silester 0.8
Metasilicate pentahydrate sodium 35
Nano ceramics 70
Silica solution 12
Sodium carbonate 2.8
Sodium gluconate 5
Sodium citrate 2.5
Isopropanol 105
Deionized water 348.4.
Wherein, parts by weight of raw materials silester 0.4-0.6 parts, 0.7-0.9 parts of metasilicate pentahydrate sodium, sodium carbonate 0.4-0.6
Part, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, 20-25 parts of composition hydrolyzed silane solutions of deionized water.
It wherein, further include 6-8 parts of hydrolyzed silane solution in hydrolyzed silane solution, 10-14 parts of isopropanol, 15-18 parts of nano ceramics,
5-7 parts and silica solution 8-9 parts of anilinomethyl triethoxysilane.
A kind of preparation method of the resistance rust solution based on nano ceramic material, following steps：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following weight point：7 parts of anilinomethyl triethoxysilane, 0.6 part of silester, the inclined silicon of five water
0.9 part of sour sodium, 0.6 part of sodium carbonate, 2.1 parts of sodium gluconate, 1.7 parts of sodium citrate, 14 parts of isopropanol, 20 parts of deionized water；
After raw material weighs, first by urea deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 removes the 3/5 of 348.4g ion water inventory, is heated to 75-85 DEG C, is added preliminary molten made from step 1
Liquid；3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, sodium carbonate, gluconic acid is added
Sodium, sodium citrate raw material components react obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total amount made from step 2, is heated to 75-85 DEG C, and nano ceramics is added, stirs
After mixing 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-
10, resistance rust solution is made.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment
All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification,
It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention
Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only
It is limited by claims and its full scope and equivalent.
Claims (4)
1. a kind of resistance rust solution based on nano ceramic material, which is characterized in that the solution be by various ingredients prepare and
At mixed liquor, the quality of each component meets in grams in every 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 12-15
Hydrolyzed silane solution 2-3.5
Silester 0.5-0.8
Metasilicate pentahydrate sodium 33-35
Nano ceramics 60-70
Silica solution 8-12
Sodium carbonate 2.5-2.8
Sodium gluconate 3-5
Sodium citrate 2-2.5
Isopropanol 100-105
Surplus is deionized water；
Hinder the preparation step of rust solution：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following parts by weight：5-7 parts of anilinomethyl triethoxysilane, 0.4-0.6 parts of silester, five water are inclined
0.7-0.9 parts of sodium metasilicate, 0.4-0.6 parts of sodium carbonate, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, isopropanol
10-14 parts, 20-25 parts of deionized water；
After raw material weighs, first by sodium citrate deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 removes the 3/5 of ion water inventory, is heated to 75-85 DEG C, and preliminary solution made from step 1 is added；3- is added
(the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, isopropanol, sodium carbonate, gluconic acid
Sodium, sodium citrate raw material components react obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total weight made from step 2, is heated to 75-85 DEG C, and nano ceramics, stirring is added
After 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-10,
Resistance rust solution is made.
2. a kind of resistance rust solution based on nano ceramic material according to claim 1, which is characterized in that described every
The quality of each component meets in grams in 600 grams of mixed liquors：
3- (the third oxygen of 2,3- epoxy) propyl trimethoxy silicane 13.5
Hydrolyzed silane solution 2.75
Silester 0.65
Metasilicate pentahydrate sodium 34
Nano ceramics 65
Silica solution 10
Sodium carbonate 2.65
Sodium gluconate 4
Sodium citrate 2.25
Isopropanol 102
Surplus is deionized water.
3. a kind of resistance rust solution based on nano ceramic material according to claim 1, which is characterized in that the raw material
5-7 parts of parts by weight anilinomethyl triethoxysilane, 0.4-0.6 parts of silester, 0.7-0.9 parts of metasilicate pentahydrate sodium, carbonic acid
0.4-0.6 parts of sodium, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, 10-14 parts of isopropanol, deionized water 20-25
Part composition hydrolyzed silane solution.
4. such as a kind of preparation method of the resistance rust solution based on nano ceramic material according to claim 1 to 3,
It is characterized by comprising the following steps：
Step 1 prepares hydrolyzed silane solution；
Raw material is weighed based on following parts by weight：5-7 parts of anilinomethyl triethoxysilane, 0.4-0.6 parts of silester, five water are inclined
0.7-0.9 parts of sodium metasilicate, 0.4-0.6 parts of sodium carbonate, 1.9-2.1 parts of sodium gluconate, 1.5-1.7 parts of sodium citrate, isopropanol
10-14 parts, 20-25 parts of deionized water；
After raw material weighs, first by sodium citrate deionized water dissolving, it is heated to 90-100 DEG C, adds anilinomethyl three
Ethoxysilane, metasilicate pentahydrate sodium, sodium carbonate, silester, isopropanol are stirred to react 40-60 minutes, are cooled to 60-70
DEG C, sodium gluconate is added, is stirred to react 30-45 minutes and preliminary solution is made；
Step 2 removes the 3/5 of ion water inventory, is heated to 75-85 DEG C, and preliminary solution made from step 1 is added；3- is added
(the third oxygen of 2,3- epoxy) propyl trimethoxy silicane, metasilicate pentahydrate sodium, silester, isopropanol, sodium carbonate, gluconic acid
Sodium, sodium citrate raw material components react obtained intermediate solution to abundant in stirring 1-2 hours；
Step 3 takes 2/3 of intermediate solution total weight made from step 2, is heated to 75-85 DEG C, and nano ceramics, stirring is added
After 40-60 minutes；Add silica solution；Stirring was cooled to 60-70 DEG C after 40-60 minutes；
Step 4 is added remaining intermediate solution, stirs 40-60 minutes, end solution is made；
The deionized water constant volume of surplus is added in step 5 in the solution of end, is uniformly mixed, and adjusting pH with sodium carbonate is 9-10,
Resistance rust solution is made.
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