CN106281295A - A kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well and preparation method thereof - Google Patents
A kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well and preparation method thereof Download PDFInfo
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- CN106281295A CN106281295A CN201610640973.0A CN201610640973A CN106281295A CN 106281295 A CN106281295 A CN 106281295A CN 201610640973 A CN201610640973 A CN 201610640973A CN 106281295 A CN106281295 A CN 106281295A
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- Prior art keywords
- quaternary ammonium
- ammonium salt
- imidazoline quaternary
- acid
- oil well
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/72—Eroding chemicals, e.g. acids
- C09K8/74—Eroding chemicals, e.g. acids combined with additives added for specific purposes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/54—Compositions for in situ inhibition of corrosion in boreholes or wells
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/32—Anticorrosion additives
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- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well and preparation method thereof, it is made up of the raw material of following weight portion: 17 alkenyl amine ethyl imidazol(e) hyamines 10 15, Abietyl modified oleic acid base imidazoline quaternary ammonium salt 8 14, dimeric dibasic acid 47,1-hydroxy ethylidene-1,1-diphosphonic acid four sodium 58, three Phosphoric acid monohexadecyl ester 7 13, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether 69, epoxychloropropane diethanolamine copolymer 9 16, cocoyl Glycine sodium 79, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride 8 10, petroleum sodium sulfonate 57, water 70 80.The corrosion inhibiter that the present invention prepares has the corrosion inhibition of excellence, and acid-soluble good, heat-resistant stability, heat is not decomposed, and is the acidifying corrosion inhibitor for oil well host of a kind of function admirable.
Description
Technical field
The present invention relates to a kind of corrosion inhibiter and preparation method thereof, be specifically related to a kind of imidazoline quaternary ammonium salt oil well acidation inhibition
Agent and preparation method thereof.
Background technology
Since the seventies, probing that China Petroleum learning overseas is advanced and DP technology new technique, crude output by
Year significantly rises, and production development is very fast, carries out fracture acidizing as used big acid to measure high salt concentration acid solution, and steady output of oilwell increases production
Effect is the most notable.Although acidification of oil gas well operation adds oil recovery yield, but the acid solution used in acidization is to pipeline
Serious corrosion is all produced with equipment.Solving the most economical effective method of this difficult problem is exactly interpolation corrosion inhibiter in acidifying solution.
The appearance of acidification of oil gas well corrosion inhibiter solves a difficult problem for Oil/gas Well equipment corrosion just, just makes acidification of oil gas well technology obtain
Extensively application.On existing market, the Imidazoline Quatemary-ammonium-salt Corrosion Inhibitor for oil well acidation still suffers from undesirable the lacking of corrosion inhibition
Point, greatly limit its range of application.
Summary of the invention
For the deficiencies in the prior art, the problem to be solved in the present invention is to provide the imidazoline that a kind of corrosion inhibition is excellent
Quaternary ammonium salt acidifying corrosion inhibitor for oil well and preparation method thereof.
For solving prior art problem, the present invention provides following technical scheme:
A kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well, is made up of the raw material of following weight portion: 17 alkenyl amine ethyl imidazol(e)s
Hyamine 10-15, Abietyl modified oleic acid base imidazoline quaternary ammonium salt 8-14, dimeric dibasic acid 4-7,1-hydroxy ethylidene-1,1-diphosphonic acid four sodium 5-8,
Three Phosphoric acid monohexadecyl ester 7-13, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether 6-9, epoxychloropropane-diethanolamine copolymer 9-16, coconut palm
Oleoyl Glycine sodium 7-9, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride 8-10, petroleum sodium sulfonate 5-7, water
70-80。
The preparation method of a kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well, comprises the following steps: add water at a high speed
In blender, add dimeric dibasic acid, three Phosphoric acid monohexadecyl esters, cocoyl Glycine sodium, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether,
1500-2500rpm high-speed stirred 5-8min;Add epoxychloropropane-diethanolamine copolymer, 17 alkenyl amine ethyl imidazol(e) quinolines
Quaternary ammonium salt, Abietyl modified oleic acid base imidazoline quaternary ammonium salt, microwave treatment 15-20min, microwave power is 400-500W, 1000-
2000rpm high-speed stirred 6-12min;It is subsequently adding remaining raw material, 2000-3000rpm high-speed stirred 4-6min, ultrasonic vibration
10-15min, ultrasonic power is 600-700W, and supersonic frequency is 40-50KHz;Finally proceed in low-speed mixer, 200-
400rpm stirring at low speed 4-8min, gets product.
The method have the benefit that
The present invention with 17 alkenyl amine ethyl imidazol(e) hyamines, Abietyl modified oleic acid base imidazoline quaternary ammonium salt as primary raw material,
With dimeric dibasic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid four sodium, three Phosphoric acid monohexadecyl esters, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether, epoxychloropropane-
The adjuvants such as diethanolamine copolymer match, and the corrosion inhibiter prepared has the corrosion inhibition of excellence, acid-soluble good, Heat-resistant stable
Property, heat is not decomposed, and is the acidifying corrosion inhibitor for oil well host of a kind of function admirable.
Detailed description of the invention
Embodiment
A kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well, is made up of the raw material of following weight (kg): 17 alkenyl amine second
Base imidazoline quaternary ammonium salt 12, Abietyl modified oleic acid base imidazoline quaternary ammonium salt 10, dimeric dibasic acid 6,1-hydroxy ethylidene-1,1-diphosphonic acid four sodium 7, three
Phosphoric acid monohexadecyl ester 11, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether 8, epoxychloropropane-diethanolamine copolymer 12, cocoyl are sweet
Propylhomoserin sodium 8, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride 9, petroleum sodium sulfonate 6, water 75.
The preparation method of a kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well, comprises the following steps: add water at a high speed
In blender, add dimeric dibasic acid, three Phosphoric acid monohexadecyl esters, cocoyl Glycine sodium, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether,
2000rpm high-speed stirred 6min;Add epoxychloropropane-diethanolamine copolymer, 17 alkenyl amine ethyl imidazol(e) hyamines,
Abietyl modified oleic acid base imidazoline quaternary ammonium salt, microwave treatment 18min, microwave power is 450W, 1500rpm high-speed stirred 9min;
Being subsequently adding remaining raw material, 2500rpm high-speed stirred 5min, ultrasonic vibration 12min, ultrasonic power is 650W, and supersonic frequency is
45KHz;Finally proceed in low-speed mixer, 300rpm stirring at low speed 6min, get product.
The above-mentioned imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well prepared can make N-80 steel at 90 DEG C, the hydrochloric acid of 20%
In corrosion rate drop to 0.84g/ (m2H), SY/T540521996 set quota it is far superior to.
Claims (2)
1. an imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well, it is characterised in that be made up of the raw material of following weight portion: 17 alkene
Base amine ethyl imidazol(e) hyamine 10-15, Abietyl modified oleic acid base imidazoline quaternary ammonium salt 8-14, dimeric dibasic acid 4-7, hydroxy ethylidene two
Phosphonic acids four sodium 5-8, three Phosphoric acid monohexadecyl ester 7-13, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether 6-9, epoxychloropropane-diethanolamine
Copolymer 9-16, cocoyl Glycine sodium 7-9, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride 8-10, oil
Sodium sulfonate 5-7, water 70-80.
The preparation method of a kind of imidazoline quaternary ammonium salt acidifying corrosion inhibitor for oil well the most according to claim 1, it is characterised in that
Comprise the following steps: add water in homogenizer, add dimeric dibasic acid, three Phosphoric acid monohexadecyl esters, the sweet ammonia of cocoyl
Acid sodium, Adeps Bovis seu Bubali amino propylamine polyethenoxy ether, 1500-2500rpm high-speed stirred 5-8min;Add epoxychloropropane-diethanol
Amine copolymer thing, 17 alkenyl amine ethyl imidazol(e) hyamines, Abietyl modified oleic acid base imidazoline quaternary ammonium salt, microwave treatment 15-
20min, microwave power is 400-500W, 1000-2000rpm high-speed stirred 6-12min;It is subsequently adding remaining raw material, 2000-
3000rpm high-speed stirred 4-6min, ultrasonic vibration 10-15min, ultrasonic power is 600-700W, and supersonic frequency is 40-50KHz;
Finally proceed in low-speed mixer, 200-400rpm stirring at low speed 4-8min, get product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107142481A (en) * | 2017-06-22 | 2017-09-08 | 西南石油大学 | A kind of method that ginkgo leaf compounding prepares corrosion inhibiter |
CN109371401A (en) * | 2018-12-21 | 2019-02-22 | 陕西省石油化工研究设计院 | A kind of polyoxyethylene ether imidazoline sulfonate corrosion inhibiter and preparation method thereof |
CN109440115A (en) * | 2018-10-31 | 2019-03-08 | 中国石油天然气集团公司 | A kind of amidophosphate water-soluble corrosion inhibitor and preparation method |
Citations (1)
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CN104233310A (en) * | 2014-07-25 | 2014-12-24 | 西安和泰化工有限公司 | Compound type imidazoline-quaternary ammonium salt corrosion inhibitor and preparation method thereof |
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2016
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104233310A (en) * | 2014-07-25 | 2014-12-24 | 西安和泰化工有限公司 | Compound type imidazoline-quaternary ammonium salt corrosion inhibitor and preparation method thereof |
Non-Patent Citations (2)
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李柏林 等: "环氧氯丙烷-二乙醇胺共聚物合成研究", 《化学与生物工程》 * |
陈冠荣 等: "《化工百科全书 第3卷》", 31 March 1999, 化学工业出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107142481A (en) * | 2017-06-22 | 2017-09-08 | 西南石油大学 | A kind of method that ginkgo leaf compounding prepares corrosion inhibiter |
CN109440115A (en) * | 2018-10-31 | 2019-03-08 | 中国石油天然气集团公司 | A kind of amidophosphate water-soluble corrosion inhibitor and preparation method |
CN109371401A (en) * | 2018-12-21 | 2019-02-22 | 陕西省石油化工研究设计院 | A kind of polyoxyethylene ether imidazoline sulfonate corrosion inhibiter and preparation method thereof |
CN109371401B (en) * | 2018-12-21 | 2021-03-23 | 陕西省石油化工研究设计院 | Polyoxyethylene ether imidazoline sulfonate corrosion inhibitor and preparation method thereof |
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