CN106281177A - A kind of monolithic type flame resistant glass PUR - Google Patents

A kind of monolithic type flame resistant glass PUR Download PDF

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Publication number
CN106281177A
CN106281177A CN201610807459.1A CN201610807459A CN106281177A CN 106281177 A CN106281177 A CN 106281177A CN 201610807459 A CN201610807459 A CN 201610807459A CN 106281177 A CN106281177 A CN 106281177A
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CN
China
Prior art keywords
parts
pur
resistant glass
flame resistant
type flame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610807459.1A
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Chinese (zh)
Inventor
李金平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610807459.1A priority Critical patent/CN106281177A/en
Publication of CN106281177A publication Critical patent/CN106281177A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of monolithic type flame resistant glass PUR, it is characterised in that by following composition according to the preparation synthesis of following weight portion: phthalic acid glycol copolymer 20 40 parts；APP 10 50 parts；Tripolycyanamide 58 parts；Softening agent 10 20 parts；Antioxidant 23 parts；Tackifying resin 18 parts.The present invention uses phthalic acid glycol copolymer as Main Ingredients and Appearance, and this polymer possesses the advantages such as adhesion strength is high, resistance to elevated temperatures is good, and by adding APP and tripolycyanamide, to be fused into Intumescent Retardant System, the cohesive energy of whole system is higher.After tested, whole PUR product system can resist 30min under 1000 DEG C of high temperature, has powerful high-temperature stability.

Description

A kind of monolithic type flame resistant glass PUR
Technical field
The present invention relates to adhesive field, be specifically related to a kind of monolithic type flame resistant glass PUR.
Background technology
Spreading or every cigarette of the flame resistant glass mainly control intensity of a fire, is the fire proofing material of a kind of measure type, and its fireproof is imitated Fruit is evaluated with fire resistance.Single-sheet fire-resistant glass is a kind of single-glass structural fire protection glass.Within the regular hour Keep fire integrity, the naked light blocking counter-fire face and poisonous, harmful gas.
The most existing flame resistant glass is all that monoblock produces, but in the face of large-scale flame resistant glass, such as office building exterior wall are prevented Flint glass, then need by bonding form thus reach purpose of design, then need to use binding agent.But, on existing market Flame resistant glass binding agent is normally due to self flameproof effect is the highest, so that depart between glass and glass when fire, and Good flameproof effect can not be reached.
Summary of the invention
In order to solve above technical problem, the present invention provides the monolithic type flame resistant glass hot melt that a kind of anti-fire intensity is high Glue.
A kind of monolithic type flame resistant glass PUR, it is characterised in that closed according to the preparation of following weight portion by following composition Become:
Phthalic acid-glycol copolymer 20-40 part；
APP 10-50 part；
Tripolycyanamide 5-8 part；
Softening agent 10-20 part；
Antioxidant 2-3 part；
Tackifying resin 1-8 part.
As one of preferred technical scheme, it is characterised in that described phthalic acid-glycol copolymer molecular weight exists Between 100000-30 ten thousand.
As one of preferred technical scheme, it is characterised in that described tackifying resin is Terpene-phenolic resin.
The invention has the beneficial effects as follows: the present invention use phthalic acid-glycol copolymer as Main Ingredients and Appearance, this polymerization Thing possesses the advantages such as adhesion strength is high, resistance to elevated temperatures is good, and by adding APP and tripolycyanamide, swollen to be fused into Swollen flame-retardant system, the cohesive energy of whole system is higher.After tested, whole PUR product system can be resisted under 1000 DEG C of high temperature 30min, has powerful high-temperature stability.
Detailed description of the invention
Below with reference to embodiment, the technique effect of the design of the present invention, concrete component and generation is carried out clear, complete Ground describes, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is the one of the present invention Section Example rather than all embodiment, based on embodiments of the invention, those skilled in the art is not paying creativeness Other embodiments obtained on the premise of work, belong to the scope of protection of the invention.
Embodiment 1: a kind of monolithic type flame resistant glass PUR, it is characterised in that by following composition according to following weight Part preparation synthesis:
Phthalic acid-glycol copolymer 40 parts；APP 30 parts；Tripolycyanamide 8 parts；Softening agent 15 parts；Antioxidant 3 Part；Tackifying resin 4 parts.
Embodiment 2: a kind of monolithic type flame resistant glass PUR, it is characterised in that by following composition according to following weight Part preparation synthesis:
Molecular weight 100,000-30 ten thousand M-phthalic acid-glycol copolymer 40 parts；APP 20 parts；Tripolycyanamide 5 parts； Softening agent 10 parts；Antioxidant 3 parts；Tackifying resin 4 parts.
Embodiment 3: a kind of monolithic type flame resistant glass PUR, it is characterised in that by following composition according to following weight Part preparation synthesis:
Phthalic acid-glycol copolymer 23 parts；APP 24 parts；Tripolycyanamide 8 parts；Softening agent 16 parts；Antioxidant 3 Part；Terpene-phenolic resin 4 parts.
Embodiment 4: a kind of monolithic type flame resistant glass PUR, it is characterised in that by following composition according to following weight Part preparation synthesis:
Phthalic acid-glycol copolymer 30 parts；APP 30 parts；Tripolycyanamide 8 parts；Softening agent 10 parts；Phenolic antioxidant 3 Part；Tackifying resin 4 parts.
Above the better embodiment of the present invention is illustrated, but the invention is not limited to described enforcement Example, those of ordinary skill in the art also can make all equivalent modifications on the premise of spirit of the present invention or replace Changing, modification or the replacement of these equivalents are all contained in the application claim limited range.

Claims (4)

1. a monolithic type flame resistant glass PUR, it is characterised in that by following composition according to the preparation synthesis of following weight portion:
Phthalic acid-glycol copolymer 20-40 part；
APP 10-50 part；
Tripolycyanamide 5-8 part；
Softening agent 10-20 part；
Antioxidant 2-3 part；
Tackifying resin 1-8 part.
Monolithic type flame resistant glass PUR the most according to claim 1, it is characterised in that described phthalic acid-second Diol copolymer molecular weight is between 100,000-30 ten thousand.
Monolithic type flame resistant glass PUR the most according to claim 1, it is characterised in that described tackifying resin is terpene Alkene-phenolic resin.
Monolithic type flame resistant glass PUR the most according to claim 1, it is characterised in that described antioxidant is phenol Kind antioxidant.
CN201610807459.1A 2016-09-07 2016-09-07 A kind of monolithic type flame resistant glass PUR Withdrawn CN106281177A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610807459.1A CN106281177A (en) 2016-09-07 2016-09-07 A kind of monolithic type flame resistant glass PUR

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610807459.1A CN106281177A (en) 2016-09-07 2016-09-07 A kind of monolithic type flame resistant glass PUR

Publications (1)

Publication Number Publication Date
CN106281177A true CN106281177A (en) 2017-01-04

Family

ID=57709697

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610807459.1A Withdrawn CN106281177A (en) 2016-09-07 2016-09-07 A kind of monolithic type flame resistant glass PUR

Country Status (1)

Country Link
CN (1) CN106281177A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107954612A (en) * 2017-12-04 2018-04-24 滕州市耀海玻雕有限公司 A kind of manufacturing process of vacuum glass
CN109722200A (en) * 2018-12-27 2019-05-07 东莞市澳中电子材料有限公司 A kind of hot melt adhesive and Hot melt adhesive tape of excellent heat resistance

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250575A (en) * 2011-05-20 2011-11-23 北京理工大学 Halogen-free flame retardant PES (Polyether Sulfone) natural color hot melt adhesive and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250575A (en) * 2011-05-20 2011-11-23 北京理工大学 Halogen-free flame retardant PES (Polyether Sulfone) natural color hot melt adhesive and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107954612A (en) * 2017-12-04 2018-04-24 滕州市耀海玻雕有限公司 A kind of manufacturing process of vacuum glass
CN107954612B (en) * 2017-12-04 2020-08-28 滕州市耀海玻雕有限公司 Manufacturing process of vacuum glass
CN109722200A (en) * 2018-12-27 2019-05-07 东莞市澳中电子材料有限公司 A kind of hot melt adhesive and Hot melt adhesive tape of excellent heat resistance

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PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
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Application publication date: 20170104