CN106280830A - A kind of preparation method of enhanced polymer cement waterproof paint - Google Patents
A kind of preparation method of enhanced polymer cement waterproof paint Download PDFInfo
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- CN106280830A CN106280830A CN201610672960.1A CN201610672960A CN106280830A CN 106280830 A CN106280830 A CN 106280830A CN 201610672960 A CN201610672960 A CN 201610672960A CN 106280830 A CN106280830 A CN 106280830A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses the preparation method of a kind of enhanced polymer cement waterproof paint, belong to polymer cement waterproof paint preparing technical field.The present invention, with butyl acrylate, methyl methacrylate, Hydroxypropyl methacrylate as raw material, prepares acrylate polymer emulsion with the auxiliary agent polyreaction such as sodium lauryl sulphate, adds the high speed shear-mixed such as ethylene glycol monobutyl ether, prepares mixing liquid material standby；Take desulfurated plaster to mill and sieve, and after mixing homogeneously with Portland cement etc., add polypropylene filaments and prepare mixed powder as reinforcing material, the discharging that mixing liquid material and mixed powder stirred obtains enhanced polymer cement waterproof paint, the invention has the beneficial effects as follows: preparation process of the present invention is simple, gained water-resistant coating is good, and under high temperature, its surface occurs without tacky phenomenon, extends 24～36 months service life.
Description
Technical field
The present invention relates to the preparation method of a kind of enhanced polymer cement waterproof paint, belong to polymer cement waterproof and be coated with
Material preparing technical field.
Background technology
Along with China's economy quickly increases, the living standard of the people is also constantly improving.This has promoted China's building row
Developing rapidly of industry, to meet the needs of economic construction and people's lives.And the development of building trade be unable to do without construction material
Innovation, the particularly innovation of architectural waterproof material.Buildings waterproof is as an importance of building, and its quality affects building
The use function of thing and service life.And as the material base of buildings waterproof, quality and the performance of architectural waterproof material then exist
It is largely fixed the quality of construction waterproofing engineering.In traditional waterproof technique, cement is used for rigid waterproofing, macromolecule
Material is used for flexible water, and often Weihe, footpath is clearly demarcated.Cement group water-proofing material good endurance, can be fully compatible with basic unit, but not
Adaptive deformation；Flexible waterproof material is the most numerous in variety, adaptive deformation, but with basic unit's poor compatibility, but also there is aging
The problem of energy difference, therefore polymer cement waterproof paint arises at the historic moment.
Polymer cement waterproof paint, is called for short JS water-repellent paint, and J refers to that polymer, S refer to cement, therefore JS is exactly polymer water
Mud water-repellent paint.Polymer cement waterproof paint is a kind of with polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion etc.
Organic liquid material of polymer emulsion and various additives composition, and the inorganic filler such as cement, quartz sand, light ground calcium carbonate and each
The inorganic powder that kind additive is formed is by rational proportion, compounded a kind of double-component, aqueous architectural water-repellent paint.But
At present polymer cement-base waterproof coating there is also poor water resistance, and high temperature lower surface is the most tacky, service life short problem.
Summary of the invention
The technical problem to be solved: for current polymer cement-base waterproof coating poor water resistance, under high temperature
Surface is the most tacky, the drawback that service life is short, it is provided that a kind of with butyl acrylate, methyl methacrylate, methacrylic acid
Hydroxypropyl acrylate is raw material, prepares acrylate polymer emulsion with the auxiliary agent polyreaction such as sodium lauryl sulphate, adds ethylene glycol
The high speed shear-mixed such as monobutyl ether, prepare mixing liquid material standby；Take desulfurated plaster to mill and sieve, and with Portland cement etc.
After mix homogeneously, add polypropylene filaments and prepare mixed powder as reinforcing material, mixing liquid material is stirred with mixed powder
Uniform discharge obtains the method for enhanced polymer cement waterproof paint.Preparation process of the present invention is simple, and gained water-resistant coating is good,
Under high temperature, its surface occurs without tacky phenomenon, and service life is long.
For solving above-mentioned technical problem, the present invention uses the technical scheme as described below to be:
(1) 3.2～3.5g sodium lauryl sulphates are weighed respectively, 4.0～4.5g fatty alcohol-polyoxyethylene ether, 1.0～1.2g ten
Dialkyl group mercaptan, 0.8～1.0g sodium bicarbonate, 100～120mL deionized waters add in reactor, stir with 300～400r/min
Mix mix homogeneously, be heated to 80～85 DEG C, be incubated 30～40min, then be separately added into 160～180mL butyl acrylate,
135～150mL methyl methacrylates, 11～14mL Hydroxypropyl methacrylates, under stirring, drip with 2～4mL/min
Adding 200mL mass fraction is 1% ammonium persulfate solution, continues stirring 2～3h, is cooled to room temperature, is 10% hydrogen-oxygen with mass fraction
Changing sodium solution regulation pH is 7.0～8.0, crosses 250 mesh drainage screens, discharging, obtains acrylate polymer emulsion；
(2) weigh 200～300g aforesaid propylene acid ester polymer emulsions, be sequentially added into 9～12g ethylene glycol monobutyl ethers wherein,
0.6～0.9g sodium hexameta phosphate, 2～3g sodium methyl silicates, stirring mixing 50～60min, obtain mixed emulsion, mixed emulsion is fallen
Enter in high-speed shearing machine, with 6000～8000r/min stirring mixing 30～40min, obtain mixing liquid material, standby；
(3) weigh 40～50g desulfurated plasters, put it in mill and mill, cross 400 mesh sieves, obtain desulfurated plaster powder, Xiang Qi
In be sequentially added into 90～100g Portland cements, 40～50g200 mesh quartz sands, 6～10g wollastonites, stirring makes it abundant
After mix homogeneously, obtain mixture, be added in batch mixer, then in batch mixer, add 5.0～7.5g chlorinated paraffins respectively,
0.1～0.2g a length of 2～3mm polypropylene filaments, 0.1～0.2g polycarboxylate water-reducer PC-201, with 500～600r/min
Stirring mixing 5～10min, obtains mixed powder；
(4) mixing liquid material standby for step (2) is added in above-mentioned gained mixed powder by 1:1 in mass ratio, obtains compound, with
500～600r/min stirrings without particle agglomeration, discharging, obtain enhanced polymer cement waterproof paint to compound.
The application process of the present invention: waterproof substrate surface oil removal will be needed clean, then its surface is polished flat,
The enhanced polymer cement waterproof paint present invention prepared subsequently is coated on the substrate surface after process, coats 2～4 times,
Every all over coating duration interval 6～8h, every is 0.4～0.5mm all over coating thickness, and coated weight is 7.5～8.2kg/m2, coating completes
After, solidify.This water-resistant coating is good, and strong with basic unit adhesion, ageing resistace is good, extends 24～36 service life
Month.
The present invention is compared with additive method, and Advantageous Effects is:
(1) preparation process of the present invention is simple, and gained water-resistant coating is good；
(2) under high temperature, its surface occurs without tacky phenomenon, extends 24～36 months service life.
Detailed description of the invention
The most respectively weigh 3.2～3.5g sodium lauryl sulphates, 4.0～4.5g fatty alcohol-polyoxyethylene ether, 1.0～
1.2g lauryl mercaptan, 0.8～1.0g sodium bicarbonate, 100～120mL deionized waters add in reactors, with 300～
400r/min is uniformly mixed, and is heated to 80～85 DEG C, is incubated 30～40min, then is separately added into 160～180mL third
Olefin(e) acid butyl ester, 135～150mL methyl methacrylates, 11～14mL Hydroxypropyl methacrylates, under stirring, with 2～
4mL/min dropping 200mL mass fraction is 1% ammonium persulfate solution, continues stirring 2～3h, is cooled to room temperature, uses mass fraction
Be 10% sodium hydroxide solution regulation pH be 7.0～8.0, cross 250 mesh drainage screens, discharging, obtain acrylate polymer emulsion；So
Rear weighing 200～300g aforesaid propylene acid ester polymer emulsion, is sequentially added into 9～12g ethylene glycol monobutyl ethers wherein, 0.6～
0.9g sodium hexameta phosphate, 2～3g sodium methyl silicates, stirring mixing 50～60min, obtain mixed emulsion, pour mixed emulsion into height
In speed cutter, with 6000～8000r/min stirring mixing 30～40min, obtain mixing liquid material, standby；Weigh 40～50g again to take off
Sulfur Gypsum Fibrosum, puts it in mill and mills, and crosses 400 mesh sieves, obtains desulfurated plaster powder, be sequentially added into 90～100g wherein general
Logical portland cement, 40～50g200 mesh quartz sands, 6～10g wollastonites, after stirring makes it be sufficiently mixed uniformly, obtain mixture,
It is added in batch mixer, then in batch mixer, adds 5.0～7.5g chlorinated paraffins, 0.1～0.2g a length of 2～3mm respectively
Polypropylene filaments, 0.1～0.2g polycarboxylate water-reducer PC-201, with 500～600r/min stirring mixing 5～10min, obtain mixed
Close powder；Standby mixing liquid material is added in above-mentioned gained mixed powder by last 1:1 in mass ratio, obtains compound, with 500～
600r/min stirring without particle agglomeration, discharging, obtains enhanced polymer cement waterproof paint to compound.
Example 1
Weigh 3.2g sodium lauryl sulphate, 4.0g fatty alcohol-polyoxyethylene ether, 1.0g lauryl mercaptan, 0.8g the most respectively
Sodium bicarbonate, 100mL deionized water adds in reactor, is uniformly mixed with 300r/min, is heated to 80 DEG C, insulation
30min, then it is separately added into 160mL butyl acrylate, 135mL methyl methacrylate, 11mL Hydroxypropyl methacrylate, is stirring
Mix under state, be 1% ammonium persulfate solution with 2mL/min dropping 200mL mass fraction, continue stirring 2h, be cooled to room temperature, use
Mass fraction be 10% sodium hydroxide solution regulation pH be 7.0, cross 250 mesh drainage screens, discharging, obtain acrylate polymer emulsion；
Then weigh 200g aforesaid propylene acid ester polymer emulsion, be sequentially added into 9g ethylene glycol monobutyl ether, 0.6g hexa metaphosphoric acid wherein
Sodium, 2g sodium methyl silicate, stirring mixing 50min, obtain mixed emulsion, mixed emulsion is poured in high-speed shearing machine, with 6000r/
Min stirring mixing 30min, obtains mixing liquid material, standby；Weigh 40g desulfurated plaster again, put it in mill and mill, cross 400
Mesh sieve, obtains desulfurated plaster powder, is sequentially added into 90g Portland cement wherein, 40g200 mesh quartz sand, 6g wollastonite,
After stirring makes it be sufficiently mixed uniformly, obtain mixture, be added in batch mixer, then in batch mixer, add 5.0g chlorination respectively
Paraffin, 0.1g a length of 2mm polypropylene filaments, 0.1g polycarboxylate water-reducer PC-201, with 500r/min stirring mixing 5min,
Obtain mixed powder；Standby mixing liquid material is added in above-mentioned gained mixed powder by last 1:1 in mass ratio, obtains compound, with
500r/min stirring without particle agglomeration, discharging, obtains enhanced polymer cement waterproof paint to compound.
Waterproof matrix surface and oil contaminant will be needed to remove clean, then its surface will be polished flat, the increasing subsequently present invention prepared
Strengthened polymer cement waterproof paint is coated on the substrate surface after process, coats 2 times, every time coating duration interval 6h, every time
Coating thickness is 0.4mm, and coated weight is 7.5kg/m2, after having coated, solidify.This water-resistant coating is good, ties with basic unit
Making a concerted effort strong, ageing resistace is good, and service life extends 24 months.
Example 2
Weigh 3.4g sodium lauryl sulphate, 4.3g fatty alcohol-polyoxyethylene ether, 1.1g lauryl mercaptan, 0.9g the most respectively
Sodium bicarbonate, 110mL deionized water adds in reactor, is uniformly mixed with 350r/min, is heated to 83 DEG C, insulation
35min, then it is separately added into 170mL butyl acrylate, 138mL methyl methacrylate, 12mL Hydroxypropyl methacrylate, is stirring
Mix under state, be 1% ammonium persulfate solution with 3mL/min dropping 200mL mass fraction, continue stirring 3h, be cooled to room temperature, use
Mass fraction be 10% sodium hydroxide solution regulation pH be 7.5, cross 250 mesh drainage screens, discharging, obtain acrylate polymer emulsion；
Then weigh 250g aforesaid propylene acid ester polymer emulsion, be sequentially added into 10g ethylene glycol monobutyl ether, 0.7g hexa metaphosphoric acid wherein
Sodium, 3g sodium methyl silicate, stirring mixing 55min, obtain mixed emulsion, mixed emulsion is poured in high-speed shearing machine, with 7000r/
Min stirring mixing 35min, obtains mixing liquid material, standby；Weigh 45g desulfurated plaster again, put it in mill and mill, cross 400
Mesh sieve, obtains desulfurated plaster powder, is sequentially added into 95g Portland cement wherein, 45g200 mesh quartz sand, 8g wollastonite,
After stirring makes it be sufficiently mixed uniformly, obtain mixture, be added in batch mixer, then in batch mixer, add 6.2g chlorination respectively
Paraffin, 0.2g a length of 3mm polypropylene filaments, 0.2g polycarboxylate water-reducer PC-201, with 550r/min stirring mixing 8min,
Obtain mixed powder；Standby mixing liquid material is added in above-mentioned gained mixed powder by last 1:1 in mass ratio, obtains compound, with
550r/min stirring without particle agglomeration, discharging, obtains enhanced polymer cement waterproof paint to compound.
Waterproof matrix surface and oil contaminant will be needed to remove clean, then its surface will be polished flat, the increasing subsequently present invention prepared
Strengthened polymer cement waterproof paint is coated on the substrate surface after process, coats 3 times, every time coating duration interval 7h, every time
Coating thickness is 0.5mm, and coated weight is 7.8kg/m2, after having coated, solidify.This water-resistant coating is good, ties with basic unit
Making a concerted effort strong, ageing resistace is good, and service life extends 30 months.
Example 3
Weigh 3.5g sodium lauryl sulphate, 4.5g fatty alcohol-polyoxyethylene ether, 1.2g lauryl mercaptan, 1.0g the most respectively
Sodium bicarbonate, 120mL deionized water adds in reactor, is uniformly mixed with 400r/min, is heated to 85 DEG C, insulation
40min, then it is separately added into 180mL butyl acrylate, 150mL methyl methacrylate, 14mL Hydroxypropyl methacrylate, is stirring
Mix under state, be 1% ammonium persulfate solution with 4mL/min dropping 200mL mass fraction, continue stirring 3h, be cooled to room temperature, use
Mass fraction be 10% sodium hydroxide solution regulation pH be 8.0, cross 250 mesh drainage screens, discharging, obtain acrylate polymer emulsion；
Then weigh 300g aforesaid propylene acid ester polymer emulsion, be sequentially added into 12g ethylene glycol monobutyl ether, 0.9g hexa metaphosphoric acid wherein
Sodium, 3g sodium methyl silicate, stirring mixing 60min, obtain mixed emulsion, mixed emulsion is poured in high-speed shearing machine, with 8000r/
Min stirring mixing 40min, obtains mixing liquid material, standby；Weigh 50g desulfurated plaster again, put it in mill and mill, cross 400
Mesh sieve, obtains desulfurated plaster powder, is sequentially added into 100g Portland cement, 50g200 mesh quartz sand, 10g silicon ash wherein
Stone, after stirring makes it be sufficiently mixed uniformly, obtains mixture, is added in batch mixer, then adds 7.5g respectively in batch mixer
Chlorinated paraffin, 0.2g a length of 3mm polypropylene filaments, 0.2g polycarboxylate water-reducer PC-201, with 600r/min stirring mixing
10min, obtains mixed powder；Standby mixing liquid material is added in above-mentioned gained mixed powder by last 1:1 in mass ratio, obtains mixing
Material, with 600r/min stirring to compound without particle agglomeration, discharging, obtains enhanced polymer cement waterproof paint.
Waterproof matrix surface and oil contaminant will be needed to remove clean, then its surface will be polished flat, the increasing subsequently present invention prepared
Strengthened polymer cement waterproof paint is coated on the substrate surface after process, coats 4 times, every time coating duration interval 8h, every time
Coating thickness is 0.5mm, and coated weight is 8.2kg/m2, after having coated, solidify.This water-resistant coating is good, ties with basic unit
Making a concerted effort strong, ageing resistace is good, and service life extends 36 months.
Claims (1)
1. the preparation method of an enhanced polymer cement waterproof paint, it is characterised in that concrete preparation process is:
(1) 3.2～3.5g sodium lauryl sulphates are weighed respectively, 4.0～4.5g fatty alcohol-polyoxyethylene ether, 1.0～1.2g ten
Dialkyl group mercaptan, 0.8～1.0g sodium bicarbonate, 100～120mL deionized waters add in reactor, stir with 300～400r/min
Mix mix homogeneously, be heated to 80～85 DEG C, be incubated 30～40min, then be separately added into 160～180mL butyl acrylate,
135～150mL methyl methacrylates, 11～14mL Hydroxypropyl methacrylates, under stirring, drip with 2～4mL/min
Adding 200mL mass fraction is 1% ammonium persulfate solution, continues stirring 2～3h, is cooled to room temperature, is 10% hydrogen-oxygen with mass fraction
Changing sodium solution regulation pH is 7.0～8.0, crosses 250 mesh drainage screens, discharging, obtains acrylate polymer emulsion；
(2) weigh 200～300g aforesaid propylene acid ester polymer emulsions, be sequentially added into 9～12g ethylene glycol monobutyl ethers wherein,
0.6～0.9g sodium hexameta phosphate, 2～3g sodium methyl silicates, stirring mixing 50～60min, obtain mixed emulsion, mixed emulsion is fallen
Enter in high-speed shearing machine, with 6000～8000r/min stirring mixing 30～40min, obtain mixing liquid material, standby；
(3) weigh 40～50g desulfurated plasters, put it in mill and mill, cross 400 mesh sieves, obtain desulfurated plaster powder, Xiang Qi
In be sequentially added into 90～100g Portland cements, 40～50g200 mesh quartz sands, 6～10g wollastonites, stirring makes it abundant
After mix homogeneously, obtain mixture, be added in batch mixer, then in batch mixer, add 5.0～7.5g chlorinated paraffins respectively,
0.1～0.2g a length of 2～3mm polypropylene filaments, 0.1～0.2g polycarboxylate water-reducer PC-201, with 500～600r/min
Stirring mixing 5～10min, obtains mixed powder；
(4) mixing liquid material standby for step (2) is added in above-mentioned gained mixed powder by 1:1 in mass ratio, obtains compound, with
500～600r/min stirrings without particle agglomeration, discharging, obtain enhanced polymer cement waterproof paint to compound.
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| CN201610672960.1A CN106280830A (en) | 2016-08-16 | 2016-08-16 | A kind of preparation method of enhanced polymer cement waterproof paint |
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| CN201610672960.1A CN106280830A (en) | 2016-08-16 | 2016-08-16 | A kind of preparation method of enhanced polymer cement waterproof paint |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718652A (en) * | 2005-07-21 | 2006-01-11 | 王立华 | Fiber reinforced type polymer cement waterproof paint |
| CN101402517A (en) * | 2008-10-23 | 2009-04-08 | 马鞍山市天锦云漆业有限公司 | Waterproof coating material for water-proof buildings |
| CN101429401A (en) * | 2007-11-06 | 2009-05-13 | 董善刚 | High-performance waterproof coating material of cement based polymer |
| CN103242007A (en) * | 2013-05-22 | 2013-08-14 | 陕西科技大学 | Preparation method of graphene oxide modified polymer cement waterproof coating |
-
2016
- 2016-08-16 CN CN201610672960.1A patent/CN106280830A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718652A (en) * | 2005-07-21 | 2006-01-11 | 王立华 | Fiber reinforced type polymer cement waterproof paint |
| CN101429401A (en) * | 2007-11-06 | 2009-05-13 | 董善刚 | High-performance waterproof coating material of cement based polymer |
| CN101402517A (en) * | 2008-10-23 | 2009-04-08 | 马鞍山市天锦云漆业有限公司 | Waterproof coating material for water-proof buildings |
| CN103242007A (en) * | 2013-05-22 | 2013-08-14 | 陕西科技大学 | Preparation method of graphene oxide modified polymer cement waterproof coating |
Non-Patent Citations (1)
| Title |
|---|
| 陈嘉林等: ""脱硫石膏作为惰性填料在聚合物水泥防水涂料中的应用研究"", 《中国建筑防水》 * |
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