CN106280820A - A kind of fluorine silicon acrylate paint - Google Patents

A kind of fluorine silicon acrylate paint Download PDF

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Publication number
CN106280820A
CN106280820A CN201610596579.1A CN201610596579A CN106280820A CN 106280820 A CN106280820 A CN 106280820A CN 201610596579 A CN201610596579 A CN 201610596579A CN 106280820 A CN106280820 A CN 106280820A
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CN
China
Prior art keywords
fluorine silicon
acrylate
silicon acrylate
parts
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610596579.1A
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Chinese (zh)
Inventor
郭凯
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Shanghai Jufeng Chemical Co Ltd
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Shanghai Jufeng Chemical Co Ltd
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Publication date
Application filed by Shanghai Jufeng Chemical Co Ltd filed Critical Shanghai Jufeng Chemical Co Ltd
Priority to CN201610596579.1A priority Critical patent/CN106280820A/en
Publication of CN106280820A publication Critical patent/CN106280820A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of fluorine silicon acrylate paint, be made up of following composition by weight: fluorine silicon acrylate 30 45 parts, filler 30 45 parts, solvent 10 25 parts, auxiliary agent 5 15 parts, bioantifouling agent 5 10 parts.Chemically modified and physical modification two angles are set out, chemically angle is set out the acrylate resin coating of copolymerization fluorine silicon, and add the bioantifouling agent to marine environment nonhazardous effect from physical angle, obtain preferable resistance to soiling, be particularly suited for marine antifouling coating.

Description

A kind of fluorine silicon acrylate paint
Technical field
The present invention relates to coating, specifically refer to a kind of fluorine silicon acrylate paint.
Background technology
Acrylate resin coating is because of the ultraviolet aging resistance of its excellence, film property, the advantage such as environment friendly and pollution-free, the most Through being widely used in every field, its modification is become the focus of research.Ship or underwater installation in ocean all can Be stained by halobiontic, for they performance, service life etc. cause negative impact.Marine antifouling coating meet the tendency and Raw.The marine antifouling coating of present stage to reach antifouling effect, and main by two approach, the first is killed, passed through toxicity Material directly kills the absorption marine organisms on surface, and existing poisoning type marine antifouling coating is owing to depositing marine environment after release At potential hazard, the most disabled or limit the use of, environmentally friendly bioantifouling agent replaces.It two is that low-surface-energy is antifouling, Prevent marine organisms at surface enrichment by hydro-oleophobicity surface coating, mainly have organosilicon and the big class of Organic fluoride two.At present Prior art about the antifouling aspect of ocean low-surface-energy is a lot, but organosilicon, Organic fluoride, acrylate and bioantifouling agent Not, resistance to soiling is further improved four technology combined.
Summary of the invention
The problem to be solved in the present invention is to provide a kind of fluorine silicon acrylate paint, and soil resistance is good, it is adaptable to ocean is prevented Dirt, has resistance to soiling good, pollutes few feature.
In order to solve above-mentioned technical problem, the present invention adopts the following technical scheme that a kind of fluorine silicon acrylate paint, by Following composition by weight forms: fluorine silicon acrylate 30-45 part, filler 30-45 part, solvent 10-25 part, auxiliary agent 5-15 Part, bioantifouling agent 5-10 part.
As preferably, described auxiliary agent is one or more groups in defoamer, levelling agent, thickening agent, wetting dispersing agent Close.
As preferably, described solvent is the one in dimethyl phthalate, butyl acetate, ethylenediamine or many Plant combination.
As preferably, described filler be in zeolite, organobentonite, titanium dioxide, Kaolin, mica powder any one or Person's multiple combination.
As preferably, described bioantifouling agent is the one in capsaicin, osthole, elatol and protease Or multiple combination.
As preferably, the polymerization of described fluorine silicon acrylate is as follows: by fluoro-acrylate monomer, siliceous third Acrylic monomer and acrylate main monomer add in solvent, add initiator and are polymerized, and polymerization gained resin is fluorine-containing Si acrylate resin.Wherein fluoro-acrylate monomer be methacrylic acid ten trifluoro monooctyl ester, ethylacrylic acid ten trifluoro monooctyl ester, At least one in methyl base acrylic acid ten fluorine butyl ester.Wherein silyl acrylate monomer is vinyl silane triisopropoxide, second At least one in thiazolinyl triethoxysilane.Wherein acrylate main monomer is acrylic acid methyl ester., ethyl acrylate, acrylic acid In butyl ester, 2-EHA, methoxyethyl acrylate, ethoxyethyl acrylate, methoxyethyl butyl ester At least one.Wherein initiator is dibenzoyl peroxide, azodiisobutyronitrile, potassium peroxydisulfate, Ammonium Persulfate 98.5, hydrogen oxide-Asia One in iron salt, any two kinds or the most two or more mixture.
After using technique scheme, present invention have the advantage that chemically modified and physical modification two angles go out Sending out, chemically angle is set out the acrylate resin coating of copolymerization fluorine silicon, and adds nontoxic to marine environment from physical angle The bioantifouling agent of evil effect, obtains preferable resistance to soiling, is particularly suited for marine antifouling coating.
Detailed description of the invention
Embodiment 1
A kind of fluorine silicon acrylate paint, includes following raw materials according by weight: fluorine silicon acrylate 30 parts, boiling 20 parts of stone, organobentonite 25 parts, butyl acetate 15 parts, auxiliary agent 5 parts, capsaicin 5 parts.
Embodiment 2
A kind of fluorine silicon acrylate paint, includes following raw materials according by weight: fluorine silicon acrylate 45 parts, titanium 15 parts of white lead, mica powder 15 parts, dimethyl phthalate 7 parts, butyl acetate 8 parts, auxiliary agent 5 parts, osthole 5 parts.
Embodiment 3
A kind of fluorine silicon acrylate paint, includes following raw materials according by weight: fluorine silicon acrylate 40 parts, high 30 parts of ridge soil, solvent 10 parts, ethylenediamine 10 parts, elatol 10 parts.
Embodiment 4
A kind of fluorine silicon acrylate paint, includes following raw materials according by weight: fluorine silicon acrylate 35 parts, boiling 10 parts of stone, organobentonite 10 parts, titanium dioxide 10 parts, dimethyl phthalate 15 parts, auxiliary agent 12 parts, proteinase 8 part.
Additionally needing explanation, the fluorine silicon acrylate polymerization methods in 4 embodiments is identical, and concrete mode is: Fluoro-acrylate monomer, silyl acrylate monomer and acrylate main monomer are added in solvent, adds initiator and gather Closing, polymerization gained resin is fluorine silicon acrylate.Wherein fluoro-acrylate monomer is that methacrylic acid ten trifluoro is pungent At least one in ester, ethylacrylic acid ten trifluoro monooctyl ester, methyl base acrylic acid ten fluorine butyl ester.Wherein silyl acrylate monomer is At least one in vinyl silane triisopropoxide, VTES.Wherein acrylate main monomer is propylene Acid methyl ester, ethyl acrylate, butyl acrylate, 2-EHA, methoxyethyl acrylate, ethioxy second At least one in ester, methoxyethyl butyl ester.Wherein initiator is dibenzoyl peroxide, azodiisobutyronitrile, over cure One in acid potassium, Ammonium Persulfate 98.5, hydrogen oxide-ferrous salt, any two kinds or the most two or more mixture.
With reference to national standard " anti-fouling paint model shallow sea soak test method " (GB/T 5370-2007), the inspection present invention is real Execute the example antifouling usefulness in sea area, Shanghai.(seeing table 1) shown in the board experiment result of sea area, natural sea area link plate 12 months After, the biodeterioration on embodiment surface is substantially less than blank model and commercially available lacquer coat plate, shows that bioantifouling agent tool is good Good anti-fouling effect.
Table 1
In addition to above preferred embodiment, the present invention also has other embodiment, and those skilled in the art can be according to this Invention is variously modified, and without departing from the spirit of the present invention, all should belong to model defined in claims of the present invention Enclose.

Claims (6)

1. a fluorine silicon acrylate paint, is characterized in that, is made up of following composition by weight: fluorine silicon acrylate 30-45 part, filler 30-45 part, solvent 10-25 part, auxiliary agent 5-15 part, bioantifouling agent 5-10 part.
Fluorine silicon acrylate paint the most according to claim 1, is characterized in that: described auxiliary agent be defoamer, levelling agent, One or more combinations in thickening agent, wetting dispersing agent.
Fluorine silicon acrylate paint the most according to claim 1, is characterized in that: described solvent is phthalic acid two One or more combinations in methyl ester, butyl acetate, ethylenediamine.
Fluorine silicon acrylate paint the most according to claim 1, is characterized in that: described filler is zeolite, organic swelling Any one or multiple combination in soil, titanium dioxide, Kaolin, mica powder.
Fluorine silicon acrylate paint the most according to claim 1, is characterized in that: described bioantifouling agent is Fructus Capsici One or more combinations in element, osthole, elatol and protease.
Fluorine silicon acrylate paint the most according to claim 1, is characterized in that, described fluorine silicon acrylate Polymerization is as follows: fluoro-acrylate monomer, silyl acrylate monomer and acrylate main monomer is added in solvent, adds Initiator is polymerized, and polymerization gained resin is fluorine silicon acrylate.
CN201610596579.1A 2016-07-27 2016-07-27 A kind of fluorine silicon acrylate paint Pending CN106280820A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610596579.1A CN106280820A (en) 2016-07-27 2016-07-27 A kind of fluorine silicon acrylate paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610596579.1A CN106280820A (en) 2016-07-27 2016-07-27 A kind of fluorine silicon acrylate paint

Publications (1)

Publication Number Publication Date
CN106280820A true CN106280820A (en) 2017-01-04

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106905780A (en) * 2017-04-17 2017-06-30 云南宏绿辣素有限公司 A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof
CN109819986A (en) * 2019-03-13 2019-05-31 浙江省农业科学院 A kind of insecticide containing capsaicine
CN109852111A (en) * 2017-11-30 2019-06-07 佛山市朗泰建材有限公司 A kind of resistant UV coating and preparation method thereof, technique for applying
CN110358396A (en) * 2019-08-09 2019-10-22 江苏海晟涂料有限公司 A kind of long-acting controlled release marine antifouling coating
CN112521822A (en) * 2020-12-02 2021-03-19 韦琪燕 Polyacrylate composition, water-based paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1810903A (en) * 2006-02-23 2006-08-02 南通科兴化工有限公司 Anti-fouling ship paint with low biological surface energy
WO2008066319A1 (en) * 2006-11-28 2008-06-05 Woo-Jae Lee Inorganic pigments composition having high hardness
CN101570587A (en) * 2009-05-08 2009-11-04 厦门大学 Fluorine-silicon modified acrylic copolymer resin and preparation method thereof
CN102337063A (en) * 2011-08-15 2012-02-01 东莞上海大学纳米技术研究院 Preparation method of low-surface-energy ship antifouling paint capable of releasing silicone oil, paint and construction method
CN103819983A (en) * 2013-12-11 2014-05-28 青岛海洋新材料科技有限公司 Novel ocean antifouling paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1810903A (en) * 2006-02-23 2006-08-02 南通科兴化工有限公司 Anti-fouling ship paint with low biological surface energy
WO2008066319A1 (en) * 2006-11-28 2008-06-05 Woo-Jae Lee Inorganic pigments composition having high hardness
CN101570587A (en) * 2009-05-08 2009-11-04 厦门大学 Fluorine-silicon modified acrylic copolymer resin and preparation method thereof
CN102337063A (en) * 2011-08-15 2012-02-01 东莞上海大学纳米技术研究院 Preparation method of low-surface-energy ship antifouling paint capable of releasing silicone oil, paint and construction method
CN103819983A (en) * 2013-12-11 2014-05-28 青岛海洋新材料科技有限公司 Novel ocean antifouling paint

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106905780A (en) * 2017-04-17 2017-06-30 云南宏绿辣素有限公司 A kind of capsicim environmental protection type anti-pollution paint and preparation method thereof
CN109852111A (en) * 2017-11-30 2019-06-07 佛山市朗泰建材有限公司 A kind of resistant UV coating and preparation method thereof, technique for applying
CN109819986A (en) * 2019-03-13 2019-05-31 浙江省农业科学院 A kind of insecticide containing capsaicine
CN109819986B (en) * 2019-03-13 2021-03-23 浙江省农业科学院 Pesticide containing capsaicin
CN110358396A (en) * 2019-08-09 2019-10-22 江苏海晟涂料有限公司 A kind of long-acting controlled release marine antifouling coating
CN112521822A (en) * 2020-12-02 2021-03-19 韦琪燕 Polyacrylate composition, water-based paint and preparation method thereof
CN112521822B (en) * 2020-12-02 2022-04-05 山西天宁新材料有限公司 Polyacrylate composition, water-based paint and preparation method thereof

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Application publication date: 20170104