CN106280738A - A kind of water-repellent paint and preparation method thereof - Google Patents
A kind of water-repellent paint and preparation method thereof Download PDFInfo
- Publication number
- CN106280738A CN106280738A CN201610667292.3A CN201610667292A CN106280738A CN 106280738 A CN106280738 A CN 106280738A CN 201610667292 A CN201610667292 A CN 201610667292A CN 106280738 A CN106280738 A CN 106280738A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- emulsion
- super hydrophobic
- hydrophobic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of water-repellent paint and preparation method thereof, coating includes two parts: component A super hydrophobic material and component B polymerized emulsion, by mass fraction ratio, component A is super-hydrophobic by Graphene 35 50 parts, silester 2.5 6 parts, silane coupler 5 12 parts, dehydrated alcohol 55 75 parts, ammonia 0.8 2 parts and deionized water 8 15 parts composition, component B polymerized emulsion is by hard monomer 35 55 parts, soft monomer 35 55 parts, function monomer 25 parts, super hydrophobic material 2 10 parts, coalescents 15 parts, plasticizer 15 parts, emulsifying agent 0.8 1.5 parts, dispersant 0.5 1 parts, preservative 0.5 1 parts, defoamer 0.05 1 parts and initiator 0.05 0.1 parts are formulated.The present invention obtains surface by modified graphene and has the super hydrophobic material of micro-nano structure, and process mixes for twice with emulsion, is distributed evenly in dope layer, imparts the water resistance that dope layer is the best.
Description
Technical field
Patent of the present invention belongs to technical field of coatings, particularly relates to a kind of water-repellent paint and preparation method thereof.
Background technology
Existing building water-proof paint mainly has polyurethane water-proof paint, polymer cement waterproof paint, and Colophonium class is waterproof
Coating and modified emulsifying asphalt class water-repellent paint, waterproof paint of polymer and asphalt, silicon rubber waterproof coating etc..Wherein polyurethane is prevented
Water paint, has certain toxicity, and construction basic unit face must be dried, and bi-component has certain proportioning, and construction requirement is strict.Drip
Blue or green class water-repellent paint, after film forming, tensile strength and fracture elongation are relatively low, are easily generated secondary pollution.Polymer cement waterproof paint
It is to compare the environment protection type high-strength water-repellent paint praised highly at present, but a large amount of of cement use the low-carbon (LC) carried out at present with China
Policy deviates from mutually.
Summary of the invention
It is an object of the invention to, in place of overcoming the deficiencies in the prior art, it is provided that a kind of water-repellent paint and preparation method thereof,
The Graphene added in coating, has the highest specific surface area, and superficial attractive forces is strong, and surface can be big, can be when coating is dried
Form network structure, enhance the adsorption between polymer coating and base material, make coating finer and close, strengthen coating to base
The adhesive force of material, improves the impact resistance of dope layer；It addition, after collosol and gel modification, graphenic surface is composed
Giving micro-nano structure, have higher water resistance, process mixes for twice with emulsion, is distributed evenly in dope layer, gives
The water resistance that dope layer is the best.
For the problems referred to above, the invention provides a kind of water-repellent paint and preparation method thereof, coating includes that component A is super-hydrophobic
Material and component B polymerized emulsion, based on mass fraction ratio, raw material respectively becomes to be grouped into as follows:
Component A super hydrophobic material:
Graphene 35-50 part
Silester 2.5-6 part
Silane coupler 5-12 part
Dehydrated alcohol 55-75 part
Ammonia 0.8-2 part
Deionized water 8-15 part
Component B polymerized emulsion:
Hard monomer 35-55 part
Soft monomer 35-55 part
Function monomer 2-5 part
Super hydrophobic material 2-10 part
Coalescents 1-5 part
Plasticizer 1-5 part
Emulsifying agent 0.8-1.5 part
Dispersant 0.5-1 part
Preservative 0.5-1 part
Defoamer 0.05-1 part
Initiator 0.05-0.1 part
The preparation of described water-repellent paint includes the preparation of (one) component A super hydrophobic material, the preparation of (two) component B polymerized emulsion and
(3) component A super hydrophobic material and the mixing of component B polymerized emulsion, specifically comprise the following steps that
(1) preparation of component A super hydrophobic material:
1.1 use deionized water ultrasonic waves for cleaning Graphene 25-40min, then are placed in the drying baker of constant temperature 45-80 DEG C dry
4.5-6h；
1.2, by the dehydrated alcohol mixing of 0.8-2 part ammonia, 8-15 part deionized water and total amount 3/4ths, stirring, obtain uniformly
Solution；
1.3, by 2.5-6 part silester and residue dehydrated alcohol mixing, stirring, obtain uniform liquid；
The uniform liquid of 1.3 is poured in the uniform liquid of 1.2 by 1.4, adds 5-12 part silane coupler while stirring, obtains place
Reason liquid；
The Graphene of 1.1 is joined in treatment fluid by 1.5, stirs 4.5-6h, take out Graphene, with anhydrous at constant temperature 20-35 DEG C
Ethanol purge is vacuum drying 6h at 6.8-7.2, then 60 DEG C to pH, obtains the component A super hydrophobic material based on Graphene；
(2) preparation of component B polymerized emulsion:
35-55 part hard monomer, 35-55 part soft monomer, 2-5 part functional monomer and 0.8-1.5 part emulsifying agent are joined by 2.1
In ionized water, homogenizing stir process 20-35min prepares pre-emulsion；
2.2 add deionized water in the reactor equipped with agitating device, condensing unit, nitrogen protection device and feeding device,
Opening agitating device, pour in reactor by the initiator of 1/5 pre-emulsion, 1/5 consumption, be warming up to 80 DEG C, stirring, reaction is to obtaining
To the emulsion of band blueness gloss, starting dropping residue pre-emulsion and initiator, pre-emulsion controls to drip off at 2.5-3.5h,
Initiator controls to drip off at 3.5h-4h, and temperature is maintained at 80-85 DEG C, and speed of agitator controls at 100r/min, after initiator drips off
Insulation 30min, continuously add 1-5 part coalescents, 1-5 part plasticizer, the dispersant of total amount half, 0.05-1 part defoamer and
0.5-1 part preservative, speed of agitator is 80r/min, and mixing time is 15-30min, filters discharging；
Super hydrophobic material in step 1.3 is joined in the mixing liquid material described in step 2.2 by 2.3, uses ultrasound wave to disperse
Processing, described ultrasonic Treatment frequency is 20 ~ 130KHz, and the process time is 3-5min, obtains component B polymerized emulsion；
(3) component A super hydrophobic material and the mixing of component B polymerized emulsion:
Polymerized emulsion in 2.3 is stood 25-30min by 3.1, joins in agitator, mechanical agitation 0.5-1.5min, simultaneously
Adding whole super hydrophobic materials in remaining dispersant and step 1.5, continue stirring 15-20min, speed of agitator controls
100r/min；
3.2 stop stirring, are positioned in ultrasonic dispersing machine by the A/B initial mixture in 3.1 and disperse, ultrasonic power
For 300W, jitter time is 8-12min, and dispersion temperature is 18-25 DEG C；
After 3.3 ultrasonic disperse terminate, taking out A/B mixture, room temperature stands 35-45min, obtains described water-repellent paint.
Described Graphene is two be made up of with ABC stacking with benzene ring structure periodically closelypacked carbon atom 3-10 layer
Dimension material with carbon element, described silane coupler is in vinyl silanes, Ethoxysilane, amino silane and methacryloxypropyl silane
One or more, the mass fraction of described ammonia is 25%.
Described soft monomer is one or more in butyl acrylate, ethyl acrylate and Isooctyl acrylate monomer；Described firmly
Monomer is in styrene, methyl methacrylate, vinyl acetate, acrylonitrile, acrylic acid methyl ester., acrylic acid and acrylamide
Plant or several；Described functional monomer is n-methylolacrylamide and acrylic acid；Described initiator is Ammonium persulfate. or persulfuric acid
Potassium；Described emulsifying agent is sodium lauryl sulphate, polyoxyethylene carboxylate, alkyl phenol polyethoxy ether ammonium sulfate, SPAN system
One or more in row and TWEEN Series.
Compared with prior art, the useful achievement of the present invention is as follows:
The Graphene added in coating, has the highest specific surface area, and superficial attractive forces is strong, and surface can be big, can do at coating
Form network structure time dry, enhance the adsorption between polymer coating and base material, make coating finer and close, enhance painting
The material adhesive force to base material, improves the impact resistance of dope layer；It addition, after collosol and gel modification, Graphene
Surface has been assigned micro-nano structure, has higher water resistance, and process mixes for twice with emulsion, is distributed evenly in coating
In Ceng, impart the water resistance that dope layer is the best.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, not limitation of the present invention, every according to this
The equivalent of any this area that disclosure of the invention content is carried out, belongs to protection scope of the present invention.
Embodiment one
A kind of water-repellent paint and preparation method thereof, coating includes component A super hydrophobic material and component B polymerized emulsion, by mass parts
Number is than meter, and raw material respectively becomes to be grouped into as follows:
Component A super hydrophobic material: Graphene 40 parts, tetraethyl orthosilicate 3 parts, methacryloxypropyl silane 8 parts, dehydrated alcohol 60
Part, ammonia 1.2 parts and deionized water 12 parts；
Component B polymerized emulsion: styrene 40 parts, butyl acrylate 35 parts, 5 parts of acrylic acid, modified graphene 5 parts, propylene glycol fourth
2 parts of ether, dibutyl phthalate 1.5 parts, fatty alcohol-polyoxyethylene ether 0.8 part, polyacrylamide 0.8 part, 1,2-benzisoxa
Thiazoline-3-ketone (BIT) 0.5 part, polysiloxanes-many alkoxyls ether copolymer 0.05 part and Ammonium persulfate. 0.05 part；
Preparation process is as follows:
(1) preparation of component A super hydrophobic material:
1.1 use deionized water ultrasonic waves for cleaning Graphene 30min, then are placed in the drying baker of constant temperature 60 DEG C dry 4.5h；
1.2, by 1.2 parts of ammonia, 12 parts of deionized waters and 45 parts of dehydrated alcohol mixing, stirrings, obtain homogeneous solution；
1.3, by 3 parts of tetraethyl orthosilicates and residue 15 parts of dehydrated alcohol mixing, stirrings, obtain uniform liquid；
The uniform liquid of 1.3 is poured in the uniform liquid of 1.2 by 1.4, adds methacryloxypropyl silane 8 parts while stirring,
Obtain treatment fluid；
The Graphene of 1.1 is joined in treatment fluid by 1.5, stirs 4.5h, take out Graphene, use dehydrated alcohol at constant temperature 25 DEG C
Cleaning to pH is vacuum drying 6h at 6.8, then 60 DEG C, obtains the component A super hydrophobic material based on Graphene；
(2) preparation of component B polymerized emulsion:
2.1 styrene 40 parts, butyl acrylate 35 parts, 5 parts of acrylic acid and fatty alcohol-polyoxyethylene ether 0.8 part joined from
In sub-water, homogenizing stir process 25min prepares pre-emulsion；
2.2 add deionized water in the reactor equipped with agitating device, condensing unit, nitrogen protection device and feeding device,
Open agitating device, the Ammonium persulfate. of 1/5 pre-emulsion, 1/5 consumption that is 0.01 part is poured in reactor, is warming up to 80 DEG C, stirs
Mixing, react to the emulsion obtaining band blueness gloss, start dropping residue pre-emulsion and Ammonium persulfate., pre-emulsion controls
2.5h drips off, and Ammonium persulfate. controls to drip off at 3.5h, and temperature is maintained at 80-85 DEG C, and speed of agitator controls at 100r/min, causes
Agent is incubated 30min after dripping off, and continuously adds propandiol butyl ether 2 parts, dibutyl phthalate 1.5 parts, polyacrylamide 0.4
Part, BIT (BIT) 0.5 part, polysiloxanes-many alkoxyls ether copolymer 0.05 part, speed of agitator is
80r/min, mixing time is 20min, filters discharging；
Super hydrophobic material in step 1.3 is joined in the mixing liquid material described in step 2.2 by 2.3, uses ultrasound wave to disperse
Processing, described ultrasonic Treatment frequency is 80KHz, and the process time is 3min, obtains component B polymerized emulsion；
(3) component A super hydrophobic material and the mixing of component B polymerized emulsion:
Polymerized emulsion in 2.3 is stood 25min by 3.1, joins in agitator, and mechanical agitation 1min is simultaneously introduced residue 0.4
Whole super hydrophobic materials in part polyacrylamide and step 1.5, continue stirring 18min, and speed of agitator controls at 100r/min；
3.2 stop stirring, are positioned in ultrasonic dispersing machine by the A/B initial mixture in 3.1 and disperse, ultrasonic power
For 300W, jitter time is 8min, and dispersion temperature is 20 DEG C；
After 3.3 ultrasonic disperse terminate, taking out A/B mixture, room temperature stands 40min, obtains described water-repellent paint.
Through inspection, in this example, each index of film is as follows:
| Standard-required | Assay | |
| Hot strength (after immersion) | ≥1.5/1.2/1.0MPa | 2.1MPa |
| Fracture elongation (after immersion) | >=300%/200%/100% | 243% |
| Adhesion strength (after immersion) | ≥1.0/0.8/0.6 MPa | 1.2MPa |
| Impermeability (hydraulic pressure 0.3Mpa, 30min) | Waterproof | Waterproof |
| Impervious (back side) | ≥0.6/0.8MPa | 0.97MPa |
| Lower temperature resistance (-40 DEG C ± 2 DEG C, 2h) | Do not peel off, flawless | Do not peel off, flawless |
Claims (3)
1. the preparation method of a water-repellent paint, it is characterised in that described water-repellent paint includes component A super hydrophobic material and component
B polymerized emulsion, based on mass fraction ratio, raw material respectively becomes to be grouped into as follows:
Component A super hydrophobic material:
Graphene 35-50 part
Silester 2.5-6 part
Silane coupler 5-12 part
Dehydrated alcohol 55-75 part
Ammonia 0.8-2 part
Deionized water 8-15 part
Component B polymerized emulsion:
Hard monomer 35-55 part
Soft monomer 35-55 part
Function monomer 2-5 part
Super hydrophobic material 2-10 part
Coalescents 1-5 part
Plasticizer 1-5 part
Emulsifying agent 0.8-1.5 part
Dispersant 0.5-1 part
Preservative 0.5-1 part
Defoamer 0.05-1 part
Initiator 0.05-0.1 part
The preparation of described water-repellent paint includes the preparation of (one) component A super hydrophobic material, the preparation of (two) component B polymerized emulsion and
(3) component A super hydrophobic material and the mixing of component B polymerized emulsion, specifically comprise the following steps that
(1) preparation of component A super hydrophobic material:
Use deionized water ultrasonic waves for cleaning Graphene 25-40min, then be placed in the drying baker of constant temperature 45-80 DEG C dry 4.5-
6h；
The dehydrated alcohol of 0.8-2 part ammonia, 8-15 part deionized water and total amount 3/4ths is mixed, stirs, obtain homogeneous solution；
By 2.5-6 part silester and residue dehydrated alcohol mixing, stirring, obtain uniform liquid；
The uniform liquid of 1.3 is poured in the uniform liquid of 1.2, add 5-12 part silane coupler while stirring, obtain treatment fluid；
The Graphene of 1.1 is joined in treatment fluid, stirs 4.5-6h at constant temperature 20-35 DEG C, take out Graphene, use dehydrated alcohol
Cleaning to pH is vacuum drying 6h at 6.8-7.2, then 60 DEG C, obtains the component A super hydrophobic material based on Graphene；
(2) preparation of component B polymerized emulsion:
35-55 part hard monomer, 35-55 part soft monomer, 2-5 part functional monomer and 0.8-1.5 part emulsifying agent are joined by 2.1
In ionized water, homogenizing stir process 20-35min prepares pre-emulsion；
2.2 add deionized water in the reactor equipped with agitating device, condensing unit, nitrogen protection device and feeding device,
Opening agitating device, pour in reactor by the initiator of 1/5 pre-emulsion, 1/5 consumption, be warming up to 80 DEG C, stirring, reaction is to obtaining
To the emulsion of band blueness gloss, starting dropping residue pre-emulsion and initiator, pre-emulsion controls to drip off at 2.5-3.5h,
Initiator controls to drip off at 3.5h-4h, and temperature is maintained at 80-85 DEG C, and speed of agitator controls at 100r/min, after initiator drips off
Insulation 30min, continuously add 1-5 part coalescents, 1-5 part plasticizer, the dispersant of total amount half, 0.05-1 part defoamer and
0.5-1 part preservative, speed of agitator is 80r/min, and mixing time is 15-30min, filters discharging；
Super hydrophobic material in step 1.3 is joined in the mixing liquid material described in step 2.2 by 2.3, uses ultrasound wave to disperse
Processing, described ultrasonic Treatment frequency is 20 ~ 130KHz, and the process time is 3-5min, obtains component B polymerized emulsion；
(3) component A super hydrophobic material and the mixing of component B polymerized emulsion:
Polymerized emulsion in 2.3 is stood 25-30min by 3.1, joins in agitator, and mechanical agitation 0.5-1.5min adds simultaneously
Entering whole super hydrophobic materials in remaining dispersant and step 1.5, continue stirring 15-20min, speed of agitator controls at 100r/
min；
3.2 stop stirring, are positioned in ultrasonic dispersing machine by the A/B initial mixture in 3.1 and disperse, ultrasonic power
For 300W, jitter time is 8-12min, and dispersion temperature is 18-25 DEG C；
After 3.3 ultrasonic disperse terminate, taking out A/B mixture, room temperature stands 35-45min, obtains described water-repellent paint.
The preparation method of a kind of water-repellent paint the most according to claim 1, it is characterised in that described Graphene is by 3-10
Layer is with the benzene ring structure Two-dimensional Carbon material that periodically closelypacked carbon atom is constituted with ABC stacking, and described silane coupler is
One or more in vinyl silanes, Ethoxysilane, amino silane and methacryloxypropyl silane, the matter of described ammonia
Amount mark is 25%.
The preparation method of a kind of water-repellent paint the most according to claim 1, it is characterised in that described soft monomer is acrylic acid
One or more in butyl ester, ethyl acrylate and Isooctyl acrylate monomer；Described hard monomer is styrene, methyl methacrylate
One or more in ester, vinyl acetate, acrylonitrile, acrylic acid methyl ester., acrylic acid and acrylamide；Described functional monomer is
N-methylolacrylamide and acrylic acid；Described initiator is Ammonium persulfate. or potassium peroxydisulfate；Described emulsifying agent is dodecyl sulfur
One or several in acid sodium, polyoxyethylene carboxylate, alkyl phenol polyethoxy ether ammonium sulfate, SPAN series and TWEEN Series
Kind.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610667292.3A CN106280738B (en) | 2016-08-15 | 2016-08-15 | A kind of water-repellent paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610667292.3A CN106280738B (en) | 2016-08-15 | 2016-08-15 | A kind of water-repellent paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106280738A true CN106280738A (en) | 2017-01-04 |
| CN106280738B CN106280738B (en) | 2018-08-24 |
Family
ID=57670435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610667292.3A Active CN106280738B (en) | 2016-08-15 | 2016-08-15 | A kind of water-repellent paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106280738B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108822667A (en) * | 2018-06-04 | 2018-11-16 | 合肥语林装饰工程有限公司 | A kind of decorative engineering water-repellent paint and preparation method thereof |
| CN109280120A (en) * | 2018-08-28 | 2019-01-29 | 武汉轻工大学 | A kind of graphite/styrene copolymerized composite pellets and preparation method thereof of silica solution cladding |
| CN109504200A (en) * | 2018-10-11 | 2019-03-22 | 中国皮革制鞋研究院有限公司 | Composite paint and preparation method thereof |
| CN109695332A (en) * | 2019-01-26 | 2019-04-30 | 温州乐成装饰设计有限公司 | A kind of dry-type hot water heating floor |
| CN114560703A (en) * | 2022-03-25 | 2022-05-31 | 山东百川智能科技有限公司 | Process for sintering silicon carbide ceramic through gel casting reaction |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104513579A (en) * | 2014-12-24 | 2015-04-15 | 常州大学 | Super-hydrophobic coating and preparation method thereof |
| JP2015218199A (en) * | 2014-05-14 | 2015-12-07 | 株式会社シミズ | Electrodeposition coating composition, electrodeposition coating method and fluorine-containing coating film |
-
2016
- 2016-08-15 CN CN201610667292.3A patent/CN106280738B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015218199A (en) * | 2014-05-14 | 2015-12-07 | 株式会社シミズ | Electrodeposition coating composition, electrodeposition coating method and fluorine-containing coating film |
| CN104513579A (en) * | 2014-12-24 | 2015-04-15 | 常州大学 | Super-hydrophobic coating and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108822667A (en) * | 2018-06-04 | 2018-11-16 | 合肥语林装饰工程有限公司 | A kind of decorative engineering water-repellent paint and preparation method thereof |
| CN109280120A (en) * | 2018-08-28 | 2019-01-29 | 武汉轻工大学 | A kind of graphite/styrene copolymerized composite pellets and preparation method thereof of silica solution cladding |
| CN109504200A (en) * | 2018-10-11 | 2019-03-22 | 中国皮革制鞋研究院有限公司 | Composite paint and preparation method thereof |
| CN109695332A (en) * | 2019-01-26 | 2019-04-30 | 温州乐成装饰设计有限公司 | A kind of dry-type hot water heating floor |
| CN114560703A (en) * | 2022-03-25 | 2022-05-31 | 山东百川智能科技有限公司 | Process for sintering silicon carbide ceramic through gel casting reaction |
| CN114560703B (en) * | 2022-03-25 | 2023-03-21 | 山东百川智能科技有限公司 | Process for sintering silicon carbide ceramic through gel casting reaction |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106280738B (en) | 2018-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106280738A (en) | A kind of water-repellent paint and preparation method thereof | |
| CN106348675B (en) | A kind of water proof type cement base coating and preparation method thereof | |
| CN110078867A (en) | Exterior coating core-shell all acrylic emulsion and its preparation method and application | |
| CN101575398B (en) | Organosilicon-modified acrylate emulsion and preparation method of coating agent for powder-free gloves | |
| CN106366228A (en) | Polyacrylic emulsion transparent waterproof glue and preparation method thereof | |
| CN109666360B (en) | Preparation method of graphene oxide modified polymer cement-based anticorrosive paint | |
| CN105906264B (en) | A kind of crack resistance type waterproofing slurry and preparation method thereof for low temperature environment | |
| CN105837763A (en) | Silane polycarboxylate water-reducing agent and preparation method thereof | |
| CN107815188A (en) | A kind of polymer cement waterproof paint and preparation method thereof | |
| CN109628028A (en) | A kind of ceramic tile gum lotion and preparation method thereof | |
| CN106083189B (en) | A kind of curing compound | |
| CN107488244A (en) | A kind of POSS modifying cinepazid emulsions copolymer, preparation method and application | |
| CN106278041B (en) | A kind of super-hydrophobic JS water-repellent paint and preparation method thereof | |
| CN108546482A (en) | A kind of polymer cement waterproof paint and preparation method thereof using modified sericite in powder | |
| CN104059446A (en) | Environment-friendly hydrophilic elastic fluorocarbon building emulsion and preparation method thereof | |
| CN103553426A (en) | Preparation method of polymer and cement composite waterproof coating | |
| CN102911580B (en) | Crosslinked acrylic emulsion for waterproofing paints and preparation method thereof | |
| CN106752606A (en) | A kind of aqueous fluorine silica acrylic acid coating and preparation method thereof | |
| JP4491313B2 (en) | Method for painting decorative surface and decorative laminate | |
| CN112321765B (en) | Waterproof coating based on self-crosslinking modified styrene-acrylic emulsion and preparation method and application thereof | |
| CN102199258A (en) | Polyether modified silicon acrylic flexible resin and preparation method thereof | |
| CN106336761A (en) | Biomass waterproof coating and preparation method thereof | |
| CN106189556B (en) | A kind of ultra-hydrophobic conductive coating and preparation method thereof | |
| CN106189633A (en) | A kind of high ferro water-repellent paint and preparation method thereof | |
| CN109504200A (en) | Composite paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 252200 Guo Kou village, bridge town, Dong'e County, Liaocheng, Shandong Applicant after: Shandong Tianhui waterproof Limited by Share Ltd Address before: 252200 Dong'e County Bridge Town, Liaocheng, Shandong Applicant before: SHANDONG TECWAY WATERPROOF MATERIALS CO., LTD. |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |