CN106280605A - A kind of ultra-violet curing water paint - Google Patents
A kind of ultra-violet curing water paint Download PDFInfo
- Publication number
- CN106280605A CN106280605A CN201610634998.XA CN201610634998A CN106280605A CN 106280605 A CN106280605 A CN 106280605A CN 201610634998 A CN201610634998 A CN 201610634998A CN 106280605 A CN106280605 A CN 106280605A
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- China
- Prior art keywords
- parts
- ultra
- violet curing
- water paint
- levelling agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to paint field, especially a kind of ultra-violet curing water paint.Its raw material is calculated as by weight: watersoluble polyurethane acrylic acid fat 65～75 parts, 25wt% tea polyphenols solution 15～25 parts, acrylic acid ethylidene-urea ethyl ester 15～20 parts, spherical chitosan 5～10 parts, titanium-dioxide photo catalase 5～10 parts, light trigger 2～4 parts, levelling agent 0.3～0.6 part, cosolvent 5～10 parts, anti-settling agent 0.2～0.5 part, defoamer 1～1.5 parts, water 140～250 parts.Produce coating and can effectively absorb and decompose the harmful substances such as stupid, formaldehyde, toluene, dimethylbenzene, reduce the indoor content of harmful substance, safety and environmental protection.
Description
Technical field
The present invention relates to paint field, especially a kind of ultra-violet curing water paint.
Background technology
Solvent based coating, through long-run development, has high-decoration, durable protectiveness, multifunctional novel；But organic solvent
Volatilization, causes environmental pollution, majority to have and solvent is to people, animal, biology, even to plant poisonous and harmful.Along with people's environment
The enhancing of protective awareness, coatings industry also begins to develop along sustainability direction.Accordingly, it can be seen that it is increasing without molten
Agent coating or use the coating system of a small amount of VOC to occur.The exploitation gesture of the water paint of safe and low VOC
Must go, compared with conventional oil-based UV coating, waterborne UV coating has the advantage that
1. the cure shrinkage decreasing a large amount of use reactive diluent and cause, can be used for non-absorbing surface, such as the coating of coating；
2. can control rheological characteristic easily with cheap dilution water or thickening agent, make coating can be used for various application mode；
3. need not regulate viscosity for highly purified reactive diluent, decrease the problems such as toxicity and zest；
4. the organic solvent without volatilization, nonflammable, compares safety
5. can obtain very thin coating and reduce cost；
6. equipment and container easily clean.
Often there is the harmful substances such as substantial amounts of formaldehyde in newly-decorated room, the health of people is had bigger damage, need
The vacant long period just can move in.
Summary of the invention
The present invention is directed to appeal problem and propose a kind of ultra-violet curing water paint, it is possible to effectively removing indoor formaldehyde etc. has
Pest matter, shortens the vacant time
In order to reach to appeal purpose, the technical solution adopted in the present invention is: a kind of its raw material components of ultra-violet curing water paint
It is calculated as by weight: watersoluble polyurethane acrylic acid fat 65～75 parts, 25wt% tea polyphenols solution 15～25 parts, acrylic acid ethylidene
Urea ethyl ester 15～20 parts, spherical chitosan 5～10 parts, titanium-dioxide photo catalase 5～10 parts, light trigger 2～4 parts, levelling agent 0.3
～0.6 part, cosolvent 5～10 parts, anti-settling agent 0.2～0.5 part, defoamer 1～1.5 parts, water 140～250 parts.
Described levelling agent is alkyl-modified organosiloxane levelling agent, acrylate levelling agent or polyether-modified poly-diformazan
Radical siloxane levelling agent.
Described light trigger is 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, hexichol
One in base-(2,4,6-trimethylbenzoyl) oxygen phosphorus, benzophenone, 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester
Or it is several.
Described anti-settling agent is the N monomethyl ketopyrrolidine anti-settling agent of aerosil anti-settling agent or modified polyurea.
The product using the present invention to produce has the advantage that
1. polyurethane acrylic resin PARA FORMALDEHYDE PRILLS(91,95) has adsorption；Containing gallic acid-1-epicatechol and gallic acid table times in tea polyphenols
Catechols etc., react, with formaldehyde, the free formaldehyde that can catch in sheet material fast and effectively；
2. spherical chitosan monomer structure highly polar functional group special, multiple, can decompose free formaldehyde molecule, have natural
The feature of environmental protection, free from environmental pollution；
3. titanium-dioxide photo catalase is with sunlight, ultraviolet light, daylight lamp for the electronics (e in lamp source excitation valence band-) transit to
Conduction band, produces corresponding hole (h in valence band+), generate and there is the hydroxyl free radical of extremely strong Oxidation, super oxygen hydroxyl free
Base, Superoxide anion free radical, by the harmful organic substances such as formaldehyde, benzene,toluene,xylene, ammonia, TVOC, pollutant, foul smell, antibacterial,
The oxidation Decomposition such as virus become harmless CO2And H2O；
4. add acrylic acid ethylidene-urea ethyl ester, can be with formaldehyde adsorption.
Specific embodiments
By predetermined purpose and technological means and effect that the present invention reached is expanded on further, below in conjunction with embodiment, right
The present invention is described in detail.
Embodiment 1: a kind of its raw material components of ultra-violet curing water paint is calculated as by weight: watersoluble polyurethane acrylic acid fat
65 parts, 25wt% tea polyphenols solution 15 parts, acrylic acid ethylidene-urea ethyl ester 15 parts, spherical chitosan 5 parts, titanium-dioxide photo catalase 5
Part, 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 2 parts, alkyl-modified organosiloxane levelling agent 0.3 part, cosolvent 7
Part, aerosil anti-settling agent 0.3 part, defoamer 1 part, 140 parts of water.Produce coating can effectively absorb and decompose stupid,
Formaldehyde, the harmful substance such as toluene, dimethylbenzene, reduce the indoor content of harmful substance, safety and environmental protection.
Embodiment 2: a kind of its raw material components of ultra-violet curing water paint is calculated as by weight: watersoluble polyurethane acrylic acid fat
75 parts, 25wt% tea polyphenols solution 20 parts, acrylic acid ethylidene-urea ethyl ester 20 parts, spherical chitosan 8 parts, titanium-dioxide photo catalase 8
Part, 1-hydroxycyclohexyl phenyl ketone 4 parts, polyether-modified polydimethylsiloxane levelling agent 0.6 part, cosolvent 8 parts, modification gather
The N monomethyl ketopyrrolidine anti-settling agent 0.5 part of urea, defoamer 1.5 parts, 250 parts of water.Produce coating can effectively absorb and divide
Solve stupid, formaldehyde, the harmful substance such as toluene, dimethylbenzene, reduce the indoor content of harmful substance, safety and environmental protection.
Embodiment 3: a kind of its raw material components of ultra-violet curing water paint is calculated as by weight: watersoluble polyurethane acrylic acid fat
70 parts, 25wt% tea polyphenols solution 18 parts, acrylic acid ethylidene-urea ethyl ester 18 parts, spherical chitosan 5 parts, titanium-dioxide photo catalase 5
Part, 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 2 parts, 2 parts of 2-hydroxy-2-methyl-1-phenyl-1-acetone, acrylic acid
Ester levelling agent 0.5 part, cosolvent 10 parts, aerosil anti-settling agent 0.3 part, defoamer 1.2 parts, 220 parts of water.Produce coating
Can effectively absorb and decompose stupid, formaldehyde, the harmful substance such as toluene, dimethylbenzene, reduce the indoor content of harmful substance, peace
Loopful is protected.
Embodiment 4: a kind of its raw material components of ultra-violet curing water paint is calculated as by weight: watersoluble polyurethane acrylic acid fat
68 parts, 25wt% tea polyphenols solution 18 parts, acrylic acid ethylidene-urea ethyl ester 18 parts, spherical chitosan 10 parts, titanium-dioxide photo catalase 10
Part, 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 1 part, benzophenone 2 parts, acrylate levelling agent 0.5 part, cosolvent
10 parts, aerosil anti-settling agent 0.3 part, defoamer 1.4 parts, 170 parts of water.Produce coating can effectively absorb and decompose
The harmful substances such as stupid, formaldehyde, toluene, dimethylbenzene, reduce the indoor content of harmful substance, safety and environmental protection.
As it has been described above, only present pre-ferred embodiments, therefore appoint all without departing from this programme technology contents, according to this
Above example is made any simple change, equivalent variations and modification by bright technical spirit, all still falls within the technology of the present invention
The scope of scheme.
Claims (4)
1. a ultra-violet curing water paint, it is characterised in that its raw material is calculated as by weight: watersoluble polyurethane acrylic acid fat 65
～75 parts, 25wt% tea polyphenols solution 15～25 parts, acrylic acid ethylidene-urea ethyl ester 15～20 parts, spherical chitosan 5～10 parts, two
Photocatalytic titanium oxide catalase 5～10 parts, light trigger 2～4 parts, levelling agent 0.3～0.6 part, cosolvent 5～10 parts, anti-settling agent 0.2～
0.5 part, defoamer 1～1.5 parts, water 140～250 parts.
A kind of ultra-violet curing water paint the most according to claim 1, it is characterised in that: levelling agent is alkyl-modified organic
Siloxanes levelling agent, acrylate levelling agent or polyether-modified polydimethylsiloxane levelling agent.
A kind of ultra-violet curing water paint the most according to claim 1, it is characterised in that: light trigger is 1-hydroxy cyclohexylphenyl
Base phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, diphenyl-(2,4,6-trimethylbenzoyl) oxygen phosphorus, hexichol first
One or more in ketone, 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester.
A kind of ultra-violet curing water paint the most according to claim 1, it is characterised in that: anti-settling agent is aerosil
The N monomethyl ketopyrrolidine anti-settling agent of anti-settling agent or modified polyurea.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610634998.XA CN106280605A (en) | 2016-08-05 | 2016-08-05 | A kind of ultra-violet curing water paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610634998.XA CN106280605A (en) | 2016-08-05 | 2016-08-05 | A kind of ultra-violet curing water paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106280605A true CN106280605A (en) | 2017-01-04 |
Family
ID=57665160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610634998.XA Withdrawn CN106280605A (en) | 2016-08-05 | 2016-08-05 | A kind of ultra-violet curing water paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106280605A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108159877A (en) * | 2017-12-29 | 2018-06-15 | 深圳市嘉达高科产业发展有限公司 | It is a kind of aqueous except formaldehyde formulations and preparation method thereof |
| CN109627963A (en) * | 2018-12-17 | 2019-04-16 | 湖南邦弗特新材料技术有限公司 | A kind of super abrasive automatic cleaning coating and preparation method thereof |
| CN112625482A (en) * | 2020-12-25 | 2021-04-09 | 惠州市韵点新材料科技股份有限公司 | High-ductility UV (ultraviolet) curing water-based paint |
| CN112662307A (en) * | 2020-12-25 | 2021-04-16 | 惠州市韵点新材料科技股份有限公司 | UV-cured water-based vacuum sputtering coating |
-
2016
- 2016-08-05 CN CN201610634998.XA patent/CN106280605A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108159877A (en) * | 2017-12-29 | 2018-06-15 | 深圳市嘉达高科产业发展有限公司 | It is a kind of aqueous except formaldehyde formulations and preparation method thereof |
| CN109627963A (en) * | 2018-12-17 | 2019-04-16 | 湖南邦弗特新材料技术有限公司 | A kind of super abrasive automatic cleaning coating and preparation method thereof |
| CN112625482A (en) * | 2020-12-25 | 2021-04-09 | 惠州市韵点新材料科技股份有限公司 | High-ductility UV (ultraviolet) curing water-based paint |
| CN112662307A (en) * | 2020-12-25 | 2021-04-16 | 惠州市韵点新材料科技股份有限公司 | UV-cured water-based vacuum sputtering coating |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170104 |
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| WW01 | Invention patent application withdrawn after publication |