CN106280153A - A kind of formula producing high heat resistant plastice building template - Google Patents
A kind of formula producing high heat resistant plastice building template Download PDFInfo
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- CN106280153A CN106280153A CN201610660040.8A CN201610660040A CN106280153A CN 106280153 A CN106280153 A CN 106280153A CN 201610660040 A CN201610660040 A CN 201610660040A CN 106280153 A CN106280153 A CN 106280153A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- General Chemical & Material Sciences (AREA)
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Abstract
The present invention relates to PVC board technical field, a kind of formula producing high heat resistant plastice building template.Described template is made up of the raw material of following weight portion: high heat-resistant PVC: 100 parts；Stabilizer: 1.5 3 parts；In-lubricant: 0.4 1.6 parts；External lubricant: 0.4 1.6 parts；Impact modifier: 28 parts；Modifier: 16 parts；Age resister: 0.2 2 parts；Filler: 5 40 parts, wherein said high heat-resistant PVC be chlorination modified after PVC or be made up of the PVC after chlorination modified and common PVC.Solve that existing plastic formwork heat resisting temperature is low, weatherability is poor, the shortcoming of loss of properties on aging, it is high that the high heat resistant plastice building template produced according to described formula has heat resisting temperature, weatherability is strong, the feature that ageing resistace is good, the building template that can use under the conditions of preparing different regions, Different climate according to customer requirement.
Description
Technical field
The invention belongs to building materials technical field, a kind of formula producing high heat resistant plastice building template.
Background technology
In recent years, the most newly-built 2,000,000,000 square metres of buildings of China, it is contemplated that at the bottom of the year two thousand twenty, whole nation house architectural area will
Newly-increased 40,000,000,000 square metres, its asd number and construction speed broadly fall in world architecture development history unprecedented.Build in building
During making and using, owing to the building structure of China is based on cast-in-place concrete structure.At Cast-in-situ Concrete Structural Engineering
In construction, building template is requisite important tool.Form work engineering typically constitute from the 30% of concrete structure engineering cost with
On, account for the 35% of the Structural Engineering amount of labour used, account for the duration about 55%.Building template technology directly influence architectural engineering quality,
Progress and cost.Use any material to make building template and be related to the utilization of resource, the production cost of template and to building
Construction cost and cause the influence degree to environment.
At present, the template that building industry mainly uses has steel form, plank sheathing, Bamboo Formwork, PVC plastic template.Patent
CN102359221A describes panel of a kind of combined PVC building formwork and preparation method thereof.Described building template is with PVC tree
Fat be primary raw material make solve existing steel form than great, maintenance cost is high in-convenience in use shortcoming, overcome existing
Plank sheathing, Bamboo Formwork are not durable, the inferior position that repeat usage is low, have easy to use, corrosion-resistant, turnover many excellent of access times
Gesture.But, along with a large amount of uses, existing plastic formwork also occurs in that certain deficiency, most typical shortcoming are exactly heat resisting temperature
Problem that is low, that be easier temperature distortion occurs.Xinjiang Uygur Autonomous Regions's product quality supervision and inspection academy Zhang little Wei, Lu
In article " research of PVC sill plastic building mould and the production " literary composition that hypo et al. is delivered, research tests wood plastic building mould
Performance, article is pointed out its template researched and produced, its vicat softening temperature is 76 DEG C.Summer sun-drenched area such as
In Turfan In Xinjiang, the sunshine-duration is long, sunny, and maximum temperature reaches 45 DEG C, and surface temperature is up to more than 80 DEG C, right
In this type of area, apply existing plastic building template, it may appear that template is the most aging, use the time short, asking of temperature distortion
Topic.For NORTHWEST CHINA area, not only summer is sunny, and temperature is high, and winter is cold weather equally, for this kind of gas
Wait the area changed greatly, due to the problem of existing building template weatherability, it is impossible to meet the needs of life-time service.
Therefore, in building trade, in order to overcome, existing plastic formwork heat resisting temperature is low, weatherability is poor, ageing-resistant performance
The problem of difference, in the urgent need to a kind of template, it must possess high heat-resisting, and weatherability is strong, the feature that ageing resistance is strong, it is possible to meets
Building trade has enough to meet the need use for a long time, to improve quality and the progress of construction project, reducings the construction costs, and reduces steel, timber etc.
The consumption of natural resources.
Summary of the invention
In order to solve, existing plastic formwork heat resisting temperature is low, weatherability is poor, the shortcoming of loss of properties on aging, and the present invention provides one
Planting the formula producing high heat resistant plastice building template, concrete technical scheme is as follows:
Described template includes that the raw material of following weight portion is made: high heat-resistant PVC: 100 parts；Stabilizer: 1.5-3 part；Interior profit
Lubrication prescription: 0.4-1.6 part；External lubricant: 0.4-1.6 part；Impact modifier: 2-8 part；Modifier: 1-6 part；Age resister:
0.2-2 part；Filler: 5-40 part, wherein said high heat-resistant PVC be chlorination modified after PVC or include chlorination modified after PVC
With common PVC form, described chlorination modified after PVC chlorinity be not less than 60%.
A kind of formula producing high heat resistant plastice building template, described stabilizer includes that complex lead salt is stable
At least one in agent, calcium-zinc composite stabilizing agent, barium zinc complex stabilizer, organic tin stabilizer, rare earth composite stabilizer etc., institute
State lead salt stabilizer and include at least one in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate etc., described
Machine stannum stabilizer includes at least one in Methyl stannum mercaptide, butanethiol stannum, octyl mercaptan stannum etc..
A kind of formula producing high heat resistant plastice building template, described in-lubricant includes stearic acid, oxygen
Change at least one in Tissuemat E, chlorinated paraffin, calcium stearate, barium stearate, the rudimentary alcohol ester of fatty acid etc..
A kind of formula producing high heat resistant plastice building template, external lubricant include paraffin, Tissuemat E,
At least one in OPE, low-molecular polyethylene wax etc..
A kind of formula producing high heat resistant plastice building template, described impact modifier include CPE, MBS,
At least one in ABS, SBS, EVA, ACR etc..
A kind of formula producing high heat resistant plastice building template, described modifier includes acrylic compounds
At least one in resin, SAN etc..
A kind of formula producing high heat resistant plastice building template, described age resister includes titanium dioxide, UV-
At least one in 531 grades.
A kind of formula producing high heat resistant plastice building template, described filler includes calcium carbonate, potter's clay, wood
At least one in powder, barium sulfate, calcium sulfate etc..
It is high that the high heat resistant plastice building template that formula produces as mentioned above has heat resisting temperature, and weatherability is strong, ageing resistance
The feature that energy is good, the building template that can use under the conditions of preparing different regions, Different climate according to customer requirement.
Of the present invention a kind of produce the formula of high heat resistant plastice building template compared with prior art, its beneficial effect
It is:
1. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, and it is high heat-resisting by application
PVC, the heat resisting temperature of described template is higher, overcomes the PVC plastic building template drawback in the temperature distortion of summer high temperature area.
2. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, by high heat-resistant PVC
Application, it is waterproof, and decay resistance is obviously improved.
3. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, in conjunction with high heat-resistant PVC
Self-characteristic, coordinate and add the related auxiliaries such as age resister, the aging resistance of described template, weather resistance are obviously improved, outdoor
Using ageing-resistant more than 30 years, solve existing PVC plastic building template sufficient in some illumination, summer, hot area was the most aging
Shortcoming.
4. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, passes through impact modifier
Use according to a certain ratio with modifier, substantially increase the pressure performance of anti-impact of template goods.
5. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, passes through inside and outside lubricant agent
Using according to a certain ratio, described template surface is smooth, cleaning, and template uses complete the most easily dismounting.
6. a kind of described in produces the formula of high heat resistant plastice building template compared with prior art, fully have studied various
Processing aid and the proportioning of raw material, during manufacture, formula is flexible, it is possible to make under the conditions of preparing Different climate according to customer requirement
Building template.
Detailed description of the invention
Embodiment 1
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Complex lead salt stabilizer: 3 parts；Stearic acid: 1.6 parts；Paraffin: 1.6 parts；CPE:8 part；Acrylic resin: 6
Part；Titanium dioxide: 2 parts；Calcium carbonate: 30 parts.Described high heat-resistant PVC be chlorination modified after PVC, its chlorinity is 60%.
Embodiment 2
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Lead sulfate tribasic: 3 parts；OPE: 1.6 parts；Tissuemat E: 1.6 parts；MBS:8 part；Benzene second
Alkene-acrylonitrile copolymer: 6 parts；UV-531:2 part；Potter's clay: 30 parts.Described high heat-resistant PVC be chlorination modified after PVC, its chlorine
Content is 60%.
Embodiment 3
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Calcium-zinc composite stabilizing agent, Methyl stannum mercaptide: 3 parts；Tissuemat E, OPE: 1.6 parts；Paraffin, poly-
Ethylene waxes: 1.6 parts；ABS, SBS, EVA:8 part；Acrylic resin, SAN: 6 parts；Titanium dioxide, UV-
531:2 part；Wood powder, barium sulfate, calcium sulfate: 30 parts.Described high heat-resistant PVC be chlorination modified after PVC, its chlorinity is 60%.
Embodiment 4
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Barium zinc complex stabilizer: 1.5 parts；Calcium stearate: 0.4 part；Low-molecular polyethylene wax: 0.4 part；ACR:2 part；
SAN: 1 part；Age resister: 0.2 part；Wood powder: 5 parts.Described high heat-resistant PVC is that chlorination modified rear chlorine contains
The PVC weight portion 60 parts of amount 65% and common PVC weight portion 40 parts composition.
Embodiment 5
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Butanethiol stannum: 1.5 parts；The rudimentary alcohol ester of fatty acid: 0.4 part；OPE: 0.4 part；EVA:2 part；
Acrylic resin: 1 part；UV-531:0.2 part；Calcium carbonate, potter's clay: 5 parts.Described high heat-resistant PVC is chlorination modified rear chlorinity
The PVC weight portion of 65% 60 parts and common PVC weight portion 40 parts composition.
Embodiment 6
A kind of formula producing high heat resistant plastice building template, described template includes that the raw material of following weight portion is made: high
Heat-resistant PVC: 100 parts；Complex lead salt stabilizer, butanethiol stannum: 1.5 parts；The rudimentary alcohol ester of chlorinated paraffin, fatty acid: 0.4 part；
Paraffin, Tissuemat E, OPE: 0.4 part；MBS, ABS:2 part；SAN: 1 part；Titanium dioxide,
UV-531:0.2 part；Potter's clay: 5 parts.Described high heat-resistant PVC is that the PVC weight portion 60 parts of chlorination modified rear chlorinity 65% is with common
PVC weight portion 40 parts composition.
Embodiment 7
A kind of formula producing high heat resistant plastice building template, described template includes that the raw material of following weight portion is made: high
Heat-resistant PVC: 100 parts；Organic tin stabilizer: 2 parts；Barium stearate: 0.8 part；Tissuemat E: 0.8 part；SBS:6 part；Styrene-
Acrylonitrile copolymer: 4 parts；Titanium dioxide: 1.2 parts；Calcium carbonate: 20 parts.Described high heat-resistant PVC is chlorination modified rear chlorinity 70%
PVC weight portion 40 parts and common PVC weight portion 60 parts composition.
Embodiment 8
A kind of formula producing high heat resistant plastice building template, described template is made up of the raw material of following weight portion: high resistance to
Hot PVC:100 part；Methyl stannum mercaptide: 2 parts；The rudimentary alcohol ester of fatty acid: 0.8 part；OPE: 0.8 part；MBS:6 part；Benzene
Ethylene-propylene lonitrile copolymer: 4 parts；Titanium dioxide, UV-531:1.2 part；Barium sulfate: 20 parts.Described high heat-resistant PVC is chlorination modified
The PVC weight portion of rear chlorinity 70% 40 parts and common PVC weight portion 60 parts composition.
Embodiment 9
A kind of formula producing high heat resistant plastice building template, described template includes that the raw material of following weight portion is made: high
Heat-resistant PVC: 100 parts；Complex lead salt stabilizer, dibasic lead phosphite, Methyl stannum mercaptide: 2 parts；Stearic acid, oxidic polyethylene
The rudimentary alcohol ester of wax, fatty acid: 0.8 part；Paraffin, Tissuemat E: 0.8 part；SBS, EVA:6 part；SAN: 4
Part；Titanium dioxide: 1.2 parts；Calcium carbonate, potter's clay: 20 parts.Described high heat-resistant PVC is the PVC weight of chlorination modified rear chlorinity 70%
Part 40 parts and common PVC weight portion 60 parts composition.
Claims (10)
1. the formula producing high heat resistant plastice building template, it is characterised in that described template includes the former of following weight portion
Material preparation is made:
High heat-resistant PVC: 100 parts；
Stabilizer: 1.5-3 part；
In-lubricant: 0.4-1.6 part；
External lubricant: 0.4-1.6 part；
Impact modifier: 2-8 part；
Modifier: 1-6 part；
Age resister: 0.2-2 part；
Filler: 5-40 part.
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that described height is resistance to
Hot PVC be chlorination modified after PVC or include chlorination modified after PVC and common PVC composition, described chlorination modified after
PVC chlorinity is not less than 60%.
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that described stable
Agent includes complex lead salt stabilizer, calcium-zinc composite stabilizing agent, barium zinc complex stabilizer, organic tin stabilizer, rare earth stable composition
At least one in agent etc..
4. according to the arbitrary described a kind of formula producing high heat resistant plastice building template of claim 1 or 3, it is characterised in that
Described lead salt stabilizer includes at least one in lead sulfate tribasic, dibasic lead phosphite, dibasic lead stearate etc.；Institute
State organic tin stabilizer and include at least one in Methyl stannum mercaptide, butanethiol stannum, octyl mercaptan stannum etc..
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that in-lubricant
In including stearic acid, OPE, chlorinated paraffin, calcium stearate, barium stearate, the rudimentary alcohol ester of fatty acid etc. at least one
Kind.
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that external lubricant
At least one in including paraffin, Tissuemat E, OPE, low-molecular polyethylene wax etc..
A kind of formula producing high heat resistant plastice building template the most according to claim 1, its feature, impact modifier bag
Include at least one in CPE, MBS, ABS, SBS, EVA, ACR etc..
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that processing modified
Agent includes at least one in acrylic resin, SAN etc..
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that age resister
Include at least one in titanium dioxide, UV-531 etc..
A kind of formula producing high heat resistant plastice building template the most according to claim 1, it is characterised in that filler bag
Include at least one in calcium carbonate, potter's clay, wood powder, barium sulfate, calcium sulfate etc..
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| CN201610660040.8A CN106280153A (en) | 2016-08-12 | 2016-08-12 | A kind of formula producing high heat resistant plastice building template |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928594A (en) * | 2017-03-27 | 2017-07-07 | 苏州大友汽车配套件有限公司 | A kind of PVC inlet vent of bus plate |
| CN107057230A (en) * | 2017-05-12 | 2017-08-18 | 青岛赛诺新材料有限公司 | A kind of Tissuemat E of high-melting-point, high rigidity |
| CN107556648A (en) * | 2017-08-21 | 2018-01-09 | 安徽省康宇水电机械成套设备有限公司 | A kind of corrosion-resistant inexpensive mold material of revetment brick shaping |
| CN108586982A (en) * | 2018-05-07 | 2018-09-28 | 彭跃荣 | A kind of strong template of Modified plastic-steel steel alloy and preparation method thereof |
| CN109762269A (en) * | 2019-01-10 | 2019-05-17 | 广东中塑高新技术股份有限公司 | A kind of PVC board stake and preparation method thereof |
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|---|---|---|---|---|
| CN101880429A (en) * | 2010-08-11 | 2010-11-10 | 聊城大学 | High-tenacity heat-resisting ageing-resisting chlorinated polyvinyl chloride alloy material and preparation method thereof |
| CN104927261A (en) * | 2015-05-21 | 2015-09-23 | 青岛科凯达橡塑有限公司 | Corrosion-resistant electric conduction and heat conduction chlorinated polyvinyl chloride resin material and preparation method and application thereof |
-
2016
- 2016-08-12 CN CN201610660040.8A patent/CN106280153A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101880429A (en) * | 2010-08-11 | 2010-11-10 | 聊城大学 | High-tenacity heat-resisting ageing-resisting chlorinated polyvinyl chloride alloy material and preparation method thereof |
| CN104927261A (en) * | 2015-05-21 | 2015-09-23 | 青岛科凯达橡塑有限公司 | Corrosion-resistant electric conduction and heat conduction chlorinated polyvinyl chloride resin material and preparation method and application thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928594A (en) * | 2017-03-27 | 2017-07-07 | 苏州大友汽车配套件有限公司 | A kind of PVC inlet vent of bus plate |
| CN107057230A (en) * | 2017-05-12 | 2017-08-18 | 青岛赛诺新材料有限公司 | A kind of Tissuemat E of high-melting-point, high rigidity |
| CN107556648A (en) * | 2017-08-21 | 2018-01-09 | 安徽省康宇水电机械成套设备有限公司 | A kind of corrosion-resistant inexpensive mold material of revetment brick shaping |
| CN108586982A (en) * | 2018-05-07 | 2018-09-28 | 彭跃荣 | A kind of strong template of Modified plastic-steel steel alloy and preparation method thereof |
| CN109762269A (en) * | 2019-01-10 | 2019-05-17 | 广东中塑高新技术股份有限公司 | A kind of PVC board stake and preparation method thereof |
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Application publication date: 20170104 |