CN106279798A - A kind of rubber tube material and preparation method thereof - Google Patents
A kind of rubber tube material and preparation method thereof Download PDFInfo
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- CN106279798A CN106279798A CN201610633754.XA CN201610633754A CN106279798A CN 106279798 A CN106279798 A CN 106279798A CN 201610633754 A CN201610633754 A CN 201610633754A CN 106279798 A CN106279798 A CN 106279798A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of rubber tube material, it includes the raw material of following weight portion: 30 60 parts of butadiene-styrene rubber, natural rubber 45 80 parts, nitrile rubber 15 35 parts, polyurethane 10 22 parts, vulcanizing agent 0.8 3.6 parts, accelerator 13 parts, 37 parts of age resistor, dispersant 14 parts, nano calcium oxide 2 10 parts, zinc oxide 3 12 parts, magnesium oxide 16 parts, Ammonium benzoate 28 parts, TDE 14 parts, AESA 16 parts, silica flour 8 16 parts, trimethicone 8 20 parts.The rubber tube material of the present invention has good wearability and anti-pressure ability, and its service life is long, greatly reduces use cost.
Description
Technical field
The present invention relates to a kind of packaging material, particularly relate to a kind of rubber tube material and preparation method thereof.
Background technology
Along with constantly popularizing of rubber, rubber all can obtain more use at a lot of aspects, especially in industry
The factors such as field, because it is with low cost, has bigger impact resistance, and environmental resistance is preferable so that it is be widely used in
In production equipment.Rubber tube is as one of common rubber, and it is the electric equipment such as electric injection device, turbo charging installation
And the important composition parts in automobile.At present, the rubber tube on market generally exists that anti-fatigue ability is poor, easy to wear etc. to be lacked
Point, thus high load cannot be born, develop a kind of rubber tube material gesture that can bear more top load, more high abrasion characteristic and exist
Must go.
Summary of the invention
It is an object of the invention to provide a kind of rubber tube material, it has, and bearing capacity is strong, wearability good and preparation method
The advantage such as simple.
For achieving the above object, the present invention provides following technical scheme:
A kind of rubber tube material, it includes the raw material of following weight portion: butadiene-styrene rubber 30-60 part, natural rubber 45-80
Part, nitrile rubber 15-35 part, polyurethane 10-22 part, vulcanizing agent 0.8-3.6 part, accelerator 1-3 part, age resistor 3-7 part, dispersion
Agent 1-4 part, nano calcium oxide 2-10 part, zinc oxide 3-12 part, magnesium oxide 1-6 part, Ammonium benzoate 2-8 part, TDE
1-4 part, AESA 1-6 part, silica flour 8-16 part, trimethicone 8-20 part.
Preferably, described rubber tube material includes the raw material of following weight portion: butadiene-styrene rubber 40-50 part, natural rubber
60-80 part, nitrile rubber 20-30 part, polyurethane 10-18 part, vulcanizing agent 1.2-3 part, accelerator 1-3 part, age resistor 3-7 part,
Dispersant 1-4 part, nano calcium oxide 3-8 part, zinc oxide 3-9 part, magnesium oxide 2-4 part, Ammonium benzoate 2-8 part, decabrominated dipheny second
Alkane 1-2 part, AESA 2-5 part, silica flour 10-14 part, trimethicone 12-16 part.
Preferably, described rubber tube material includes the raw material of following weight portion: 48 parts of butadiene-styrene rubber, natural rubber 70
Part, nitrile rubber 30 parts, polyurethane 16 parts, vulcanizing agent 2.4 parts, accelerator 1.5 parts, 5 parts of age resistor, dispersant 2.5 parts, nanometer
Calcium oxide 6 parts, zinc oxide 8 parts, magnesium oxide 5 parts, Ammonium benzoate 5 parts, TDE 2 parts, fatty alcohol-polyoxyethylene ether sulfur
Acid ammonium 3 parts, silica flour 10 parts, trimethicone 12 parts.
Preferably, described rubber tube material includes the raw material of following weight portion: 40 parts of butadiene-styrene rubber, natural rubber 76
Part, nitrile rubber 24 parts, polyurethane 12 parts, vulcanizing agent 2 parts, accelerator 1.6 parts, 5 parts of age resistor, dispersant 2.3 parts, nano oxygen
Change calcium 6 parts, zinc oxide 6 parts, magnesium oxide 2.5 parts, Ammonium benzoate 5 parts, TDE 1.2 parts, fatty alcohol-polyoxyethylene ether
3 parts of ammonium sulfate, silica flour 12 parts, trimethicone 14 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Compared with prior art, the invention has the beneficial effects as follows:
Rubber tube material in the present invention mainly add butadiene-styrene rubber, natural rubber, nitrile rubber, polyurethane, vulcanizing agent,
The raw materials such as accelerator, age resistor, nano calcium oxide, zinc oxide, each component raw material is mixed in proportion, melting forms, and it has and holds
Loading capability is strong, wearability good and the advantage such as length in service life.
Detailed description of the invention
Describe technical scheme in detail below in conjunction with embodiment, but protection domain is not limited thereto.
Embodiment one:
A kind of rubber tube material, it includes the raw material of following weight portion: 50 parts of butadiene-styrene rubber, natural rubber 70 parts, butyronitrile
Rubber 25 parts, polyurethane 18 parts, vulcanizing agent 2.3 parts, accelerator 1.3 parts, 5 parts of age resistor, dispersant 2.3 parts, nano calcium oxide 7
Part, zinc oxide 8 parts, magnesium oxide 4.5 parts, Ammonium benzoate 6 parts, TDE 2.3 parts, AESA
4 parts, silica flour 10 parts, trimethicone 16 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment two:
A kind of rubber tube material, it includes the raw material of following weight portion: 40 parts of butadiene-styrene rubber, natural rubber 65 parts, butyronitrile
Rubber 24 parts, polyurethane 13 parts, vulcanizing agent 3 parts, accelerator 2.1 parts, 6 parts of age resistor, dispersant 2.5 parts, nano calcium oxide 8
Part, zinc oxide 9 parts, magnesium oxide 4 parts, Ammonium benzoate 8 parts, TDE 4 parts, AESA 4 parts,
Silica flour 10 parts, trimethicone 14 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment three:
A kind of rubber tube material, it includes the raw material of following weight portion: 55 parts of butadiene-styrene rubber, natural rubber 50 parts, butyronitrile
Rubber 20 parts, polyurethane 20 parts, vulcanizing agent 1.8 parts, accelerator 1.7 parts, 4.5 parts of age resistor, dispersant 2.6 parts, nano oxidized
Calcium 6 parts, zinc oxide 7 parts, magnesium oxide 5 parts, Ammonium benzoate 6 parts, TDE 3 parts, AESA 5
Part, silica flour 12 parts, trimethicone 18 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment four:
A kind of rubber tube material, it includes the raw material of following weight portion: 48 parts of butadiene-styrene rubber, natural rubber 70 parts, butyronitrile
Rubber 30 parts, polyurethane 16 parts, vulcanizing agent 2.4 parts, accelerator 1.5 parts, 5 parts of age resistor, dispersant 2.5 parts, nano calcium oxide 6
Part, zinc oxide 8 parts, magnesium oxide 5 parts, Ammonium benzoate 5 parts, TDE 2 parts, AESA 3 parts,
Silica flour 10 parts, trimethicone 12 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment five:
A kind of rubber tube material, it includes the raw material of following weight portion: 40 parts of butadiene-styrene rubber, natural rubber 76 parts, butyronitrile
Rubber 24 parts, polyurethane 12 parts, vulcanizing agent 2 parts, accelerator 1.6 parts, 5 parts of age resistor, dispersant 2.3 parts, nano calcium oxide 6
Part, zinc oxide 6 parts, magnesium oxide 2.5 parts, Ammonium benzoate 5 parts, TDE 1.2 parts, AESA
3 parts, silica flour 12 parts, trimethicone 14 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment six:
A kind of rubber tube material, it includes the raw material of following weight portion: 35 parts of butadiene-styrene rubber, natural rubber 55 parts, butyronitrile
Rubber 35 parts, polyurethane 22 parts, vulcanizing agent 2 parts, accelerator 3 parts, 5 parts of age resistor, dispersant 2.5 parts, nano calcium oxide 9 parts,
Zinc oxide 9 parts, magnesium oxide 5 parts, Ammonium benzoate 5 parts, TDE 2 parts, AESA 3 parts, stone
10 parts of English powder, trimethicone 14 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment seven:
A kind of rubber tube material, it includes the raw material of following weight portion: 38 parts of butadiene-styrene rubber, natural rubber 60 parts, butyronitrile
Rubber 18 parts, polyurethane 22 parts, vulcanizing agent 3 parts, accelerator 2.3 parts, 4.8 parts of age resistor, dispersant 2.6 parts, nano calcium oxide 6
Part, zinc oxide 11 parts, magnesium oxide 4.3 parts, Ammonium benzoate 7 parts, TDE 2.5 parts, fatty alcohol-polyoxyethylene ether sulphuric acid
Ammonium 3 parts, silica flour 10 parts, trimethicone 15 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment eight:
A kind of rubber tube material, it includes the raw material of following weight portion: 55 parts of butadiene-styrene rubber, natural rubber 55 parts, butyronitrile
Rubber 32 parts, polyurethane 12 parts, vulcanizing agent 2.5 parts, accelerator 2.3 parts, 5.5 parts of age resistor, dispersant 2.3 parts, nano oxidized
Calcium 7 parts, zinc oxide 11 parts, magnesium oxide 5.5 parts, Ammonium benzoate 4.5 parts, TDE 2.2 parts, fatty alcohol-polyoxyethylene ether
3.5 parts of ammonium sulfate, silica flour 10 parts, trimethicone 16 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Embodiment nine:
A kind of rubber tube material, it includes the raw material of following weight portion: 60 parts of butadiene-styrene rubber, natural rubber 75 parts, butyronitrile
Rubber 18 parts, polyurethane 13 parts, vulcanizing agent 2 parts, accelerator 2.3 parts, 4.5 parts of age resistor, dispersant 2.5 parts, nano calcium oxide 9
Part, zinc oxide 7 parts, magnesium oxide 4 parts, Ammonium benzoate 8 parts, TDE 2.6 parts, AESA 4
Part, silica flour 16 parts, trimethicone 20 parts.
The preparation method of described rubber tube material, comprises the following steps:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano oxidized
Calcium, zinc oxide and magnesium oxide add banbury, and melting temperature is set to 140-200 DEG C, carries out mixing, obtain mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, poly alkyl alcohol again
Oxygen vinyl Ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
Finally illustrating, above example is only in order to illustrate technical scheme and unrestricted, although with reference to relatively
The present invention has been described in detail by good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent, and without deviating from objective and the scope of the technical program, it all should be contained in the present invention
Right in the middle of.
Claims (5)
1. a rubber tube material, it is characterised in that include the raw material of following weight portion: butadiene-styrene rubber 30-60 part, natural rubber
45-80 part, nitrile rubber 15-35 part, polyurethane 10-22 part, vulcanizing agent 0.8-3.6 part, accelerator 1-3 part, age resistor 3-7
Part, dispersant 1-4 part, nano calcium oxide 2-10 part, zinc oxide 3-12 part, magnesium oxide 1-6 part, Ammonium benzoate 2-8 part, ten bromines two
Vinylbenzene 1-4 part, AESA 1-6 part, silica flour 8-16 part, trimethicone 8-20 part.
Rubber tube material the most according to claim 1, it is characterised in that include the raw material of following weight portion: butadiene-styrene rubber
40-50 part, natural rubber 60-80 part, nitrile rubber 20-30 part, polyurethane 10-18 part, vulcanizing agent 1.2-3 part, accelerator 1-3
Part, age resistor 3-7 part, dispersant 1-4 part, nano calcium oxide 3-8 part, zinc oxide 3-9 part, magnesium oxide 2-4 part, Ammonium benzoate 2-
8 parts, TDE 1-2 part, AESA 2-5 part, silica flour 10-14 part, trimethicone
12-16 part.
Rubber tube material the most according to claim 1, it is characterised in that include the raw material of following weight portion: butadiene-styrene rubber
48 parts, natural rubber 70 parts, nitrile rubber 30 parts, polyurethane 16 parts, vulcanizing agent 2.4 parts, accelerator 1.5 parts, 5 parts of age resistor,
Dispersant 2.5 parts, nano calcium oxide 6 parts, zinc oxide 8 parts, magnesium oxide 5 parts, Ammonium benzoate 5 parts, TDE 2 parts, fat
3 parts of fat polyoxyethylenated alcohol ammonium sulfate, silica flour 10 parts, trimethicone 12 parts.
Rubber tube material the most according to claim 2, it is characterised in that include the raw material of following weight portion: butadiene-styrene rubber
40 parts, natural rubber 76 parts, nitrile rubber 24 parts, polyurethane 12 parts, vulcanizing agent 2 parts, accelerator 1.6 parts, 5 parts of age resistor, point
Powder 2.3 parts, nano calcium oxide 6 parts, zinc oxide 6 parts, magnesium oxide 2.5 parts, Ammonium benzoate 5 parts, TDE 1.2 parts,
AESA 3 parts, silica flour 12 parts, trimethicone 14 parts.
5. according to the preparation method of the rubber tube material according to any one of claim 1-4, it is characterised in that include following step
Rapid:
(1) each raw material components is weighed according to ratio of weight and number;
(2) by butadiene-styrene rubber, natural rubber, nitrile rubber, vulcanizing agent, accelerator, age resistor, dispersant, nano calcium oxide, oxygen
Changing zinc and magnesium oxide adds banbury, melting temperature is set to 140-200 DEG C, carries out mixing, obtains mixing raw material;
(3) the mixing raw material in step (2) adds polyurethane, Ammonium benzoate, TDE, fatty alcohol polyoxy second again
Alkene ether ammonium sulfate, silica flour, trimethicone, continue mixing;
(4) by the raw material in step (3) through heat refining molding, vulcanizing treatment, rubber tube material product is obtained.
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CN201610633754.XA CN106279798A (en) | 2016-08-04 | 2016-08-04 | A kind of rubber tube material and preparation method thereof |
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CN201610633754.XA CN106279798A (en) | 2016-08-04 | 2016-08-04 | A kind of rubber tube material and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109181022A (en) * | 2018-08-08 | 2019-01-11 | 付照君 | A kind of rubber hose preparation method |
CN112245777A (en) * | 2020-10-12 | 2021-01-22 | 彭建 | Traditional Chinese medicine gynecological suppository administration device |
CN113214546A (en) * | 2021-05-31 | 2021-08-06 | 七彩新型材料集团有限公司 | Novel heat-insulating flame-retardant rubber material |
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CN104893217A (en) * | 2015-05-28 | 2015-09-09 | 芜湖风雪橡胶有限公司 | Preparation method of oil-resistant rubber material composition and oil-resistant rubber |
CN105254934A (en) * | 2015-08-19 | 2016-01-20 | 苏州国泰科技发展有限公司 | Rubber hose material for vehicle and preparation method thereof |
CN105419029A (en) * | 2015-12-14 | 2016-03-23 | 安徽都邦电器有限公司 | Heat-resistant and aging-resistant chloroprene rubber tube |
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CN102108268A (en) * | 2011-01-11 | 2011-06-29 | 太仓金煜电子材料有限公司 | Environment-friendly halogen-free inflaming retarding adhesive tape and production process thereof |
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CN112245777A (en) * | 2020-10-12 | 2021-01-22 | 彭建 | Traditional Chinese medicine gynecological suppository administration device |
CN113214546A (en) * | 2021-05-31 | 2021-08-06 | 七彩新型材料集团有限公司 | Novel heat-insulating flame-retardant rubber material |
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Application publication date: 20170104 |