CN106278325A - A kind of kiln vehicle surface castable - Google Patents

A kind of kiln vehicle surface castable Download PDF

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Publication number
CN106278325A
CN106278325A CN201610706477.0A CN201610706477A CN106278325A CN 106278325 A CN106278325 A CN 106278325A CN 201610706477 A CN201610706477 A CN 201610706477A CN 106278325 A CN106278325 A CN 106278325A
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CN
China
Prior art keywords
castable
vehicle surface
corundum
kiln vehicle
spinel
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CN201610706477.0A
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Chinese (zh)
Inventor
张静芬
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Individual
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Individual
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Priority to CN201610706477.0A priority Critical patent/CN106278325A/en
Publication of CN106278325A publication Critical patent/CN106278325A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The invention provides a kind of kiln vehicle surface castable, be made up of following parts by weighbf component: sub-high soil 5 15, nano-calcium carbonate nickel 35, synthesize strontium aluminate 38, NiFe_2O_4 spinel 5 10, leave alabaster 20 35, synthesize corundum 5 10, corundum 30 40, synthesizes magnesium zircon sand 10 15, aluminous cement 38;Additional dispersant 0.1 0.2, levelling agent 0.1.By the enforcement of whole technical scheme, improve the deficiency that current production exists, preferably meet the needs of current production, it is achieved that the technical purpose of the present invention.

Description

A kind of kiln vehicle surface castable
Technical field
The present invention relates to a kind of unshape refractory, especially a kind of kiln vehicle surface castable.
Background technology
At present, in heat treatment industry, need heavier Large Steel baslled iron body is placed directly on kiln vehicle surface, then Kiln car pushes in heat-treatment furnace, after treating that the workpiece heat time arrives, then forges before the workpiece of high temperature is transported to forging machine.With The heavy refractory material kiln car work top of high temperature absorption surface not only to bear weigh several tons or tens of tons of high temperature workpiece, Also want the reaction that can resist high-temperature steel baslled iron body with refractory material.Require that work top is at high temperature wanted at 1100 to 1400 DEG C There is preferable creep resistance, thermal shock resistance, high wearability, it is often more important that the opposing iron scale erosion to work top Destroy reaction.In the prior art, general employing high alumina castable and mullite castable carry out pouring into a mould work top. Although using both castables can meet certain high temperature requirement to a certain extent, but can not preferably resist iron scale Infiltration corrode, application property is poor, and wearability is poor, and creep resistance is poor, and globality is poor, and during use, table top produces big The crackle of amount, service life is extremely short, up to three or four months.The normal use of heating furnace kiln car, frequent dimension are had a strong impact on Repair, affect product quality, increase energy resource consumption.
Summary of the invention
For the defect during overcoming existing High-Alumina and mullite castable to use, the present invention provides one to have Antioxidation iron sheet corrodes, fire-resistant, wear-resisting and abrasion resistance is high, and creep resistance is preferable, and workability is preferable, can be greatly prolonged kiln The castable refractory in ride face service life.
The present invention solves above-mentioned technical problem and be the technical scheme is that a kind of work top castable, by following heavy Amount weighbf component composition: synthesis strontium aluminate 3-8, NiFe_2O_4 spinel 5-10, leave alabaster 20-35, synthesizes corundum 5-10, just Beautiful 30-40, synthesizes magnesium zircon sand 10-15, sub-high soil 5-15, nano-calcium carbonate nickel 3-5, aluminous cement 3-8;Additional dispersant 0.1- 0.2, levelling agent 0.1.
Further, described NiFe_2O_4 spinel is positive NiFe_2O_4 spinel.
Further, the weight content of described leave alabaster is more than 98%.
Further, described sub-high native mainly comprising as highly active anhydrous aluminium silicate and zirconium nitride, weight both it Amount ratio is 90:10.
Further, described dispersant is REFPAC®288, its true specific gravity is 2.60-2.70 gram every cubic centimetre, heap Long-pending density 1.15-1.30 gram every cubic centimetre, Exemplary chemical composition is (percentage by weight): aluminium oxide 62-64%, SiO2< 1.0%。
Further, the weight content of described nano-calcium carbonate nickel is more than 99%.
Further, the weight content of described synthesis magnesium zircon sand is more than 99%.
Further, the weight content of described synthesis corundum is more than 99%, and remaining impurity is mainly silicon dioxide.
Further, described levelling agent is polyether siloxane copolymer.
The preparation method of a kind of work top castable, comprises the following steps: in above-mentioned parts by weight ratio stirring mixing Uniformly, then add appropriate clean water during onsite application, be stirred with forced stirrer, when meeting construction requirement, stirring The castable mixed is put into inside the mould of work top, carries out vibrations with vibrating head and constructs.
Compared with the material of existing use, the invention has the beneficial effects as follows: 1, work top castable of the present invention has Higher elevated temperature strength, can undertake the weight of heating steel billet;The infiltration that can resist iron scale under high temperature is corroded, and improves Wearability, extends body of heater service life 2-3 times.2, castable good thermal shock of the present invention, not shrinkage cracking, globality Good, it is effectively protected the globality safety of work top.3, the present invention can in use step-reaction, sub-high soil and Aluminous cement has effect of plural gel, can suppress the alkalinization on castable surface simultaneously;Strontium aluminate, synthesizes Buddha's warrior attendant Sand, NiFe_2O_4 spinel, the material such as nano-calcium carbonate nickel is miscellaneous to entering into the steel billet iron sheet inside the fire-resistant liner body of work top in using Matter can play purification, substantially increases the high temperature overall performance of workbench castable;Due to the fact that and add efficiently Dispersant REFPAC®288, the rational grain size distribution of pyrophyllite and whole scheme obtains good the watering of a kind of workability Material feeding, solves the defect that current castable application property is bad.By the enforcement of whole technical scheme, improve current production and deposit Deficiency, preferably meet the needs of current production, it is achieved that the technical purpose of the present invention.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1
A kind of work top castable, is made up of following parts by weighbf component: synthesis strontium aluminate 5, NiFe_2O_4 spinel 10, leave Alabaster 20, synthesizes corundum 5, corundum 30, synthesizes magnesium zircon sand 10, sub-high soil 10, nano-calcium carbonate nickel 5, aluminous cement 5;Additional REFPAC®288,0.2, polyether siloxane copolymer 0.1.
Embodiment 2
A kind of work top castable, is made up of following parts by weighbf component: synthesis strontium aluminate 6, NiFe_2O_4 spinel 10, leave Alabaster 20, synthesizes corundum 5, corundum 30, synthesizes magnesium zircon sand 10, sub-high soil 9, nano-calcium carbonate nickel 3, aluminous cement 7;Additional REFPAC®288,0.16, polyether siloxane copolymer 0.1.
Embodiment 3
A kind of work top castable, is made up of following parts by weighbf component: synthesis strontium aluminate 7, NiFe_2O_4 spinel 10, leave Alabaster 20, synthesizes corundum 5, corundum 30, synthesizes magnesium zircon sand 10, sub-high soil 8, nano-calcium carbonate nickel 3, aluminous cement 7;Additional REFPAC®288,0.18, polyether siloxane copolymer 0.1.
Embodiment 4
A kind of work top castable, is made up of following parts by weighbf component: synthesis strontium aluminate 8, NiFe_2O_4 spinel 10, leave Alabaster 20, synthesizes corundum 5, corundum 30, synthesizes magnesium zircon sand 11, sub-high soil 9, nano-calcium carbonate nickel 3, aluminous cement 4;Additional REFPAC®288,0.16, polyether siloxane copolymer 0.1.
Embodiment 5
A kind of Silicon-magnesium fireproof wear-resistant composite castable, is made up of following parts by weighbf component: synthesis strontium aluminate 6, and ferronickel point is brilliant Stone 10, leave alabaster 20, synthesize corundum 5, corundum 30, synthesize magnesium zircon sand 10, sub-high soil 8, nano-calcium carbonate nickel 3, calcium aluminate water Mud 8;Additional REFPAC®288,0.15, polyether siloxane copolymer 0.1.
The preparation method of a kind of work top castable, comprises the following steps: in above-mentioned parts by weight ratio stirring mixing Uniformly, then add appropriate clean water during onsite application, be stirred with forced stirrer, when meeting construction requirement, The castable being stirred is put into inside the mould of work top, carries out vibrations with vibrating head and constructs.Above-described embodiment 1,2, 3,4,5 through using, and service life is current 2-3 times, and trolley surface is smooth, flawless, and antioxidation iron sheet aggressivity is good.
As described above, only presently preferred embodiments of the present invention, when not limiting, with this, the scope that the present invention implements, The present embodiment can be made any amendment by those skilled in the art after reading this specification as required, but as long as at this All protected by Patent Law in the right of invention.

Claims (4)

1. a kiln vehicle surface castable, is made up of following parts by weighbf component: synthesis strontium aluminate 3-8, NiFe_2O_4 spinel 5- 10, leave alabaster 20-35, synthesize corundum 5-10, corundum 30-40, synthesizes magnesium zircon sand 10-15, sub-high soil 5-15, nano-calcium carbonate Nickel 3-5, aluminous cement 3-8;Additional dispersant 0.1-0.2, levelling agent 0.1.
2. a kind of kiln vehicle surface castable as claimed in claim 1, it is characterised in that: described NiFe_2O_4 spinel is positive ferronickel Spinelle.
3. kiln vehicle surface castable as claimed in claim 1 a kind of, it is characterised in that: described sub-high soil mainly comprise for Highly active anhydrous aluminium silicate and zirconium nitride, part by weight both it is 90:10.
4. a kind of kiln vehicle surface castable as claimed in claim 1, it is characterised in that: the weight content of described leave alabaster It is more than 98%.
CN201610706477.0A 2016-08-23 2016-08-23 A kind of kiln vehicle surface castable Pending CN106278325A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610706477.0A CN106278325A (en) 2016-08-23 2016-08-23 A kind of kiln vehicle surface castable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610706477.0A CN106278325A (en) 2016-08-23 2016-08-23 A kind of kiln vehicle surface castable

Publications (1)

Publication Number Publication Date
CN106278325A true CN106278325A (en) 2017-01-04

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07291747A (en) * 1994-04-26 1995-11-07 Nippon Steel Corp Heat insulating monolithic refractory
CN102203033A (en) * 2008-10-24 2011-09-28 新日本制铁株式会社 Binder for unshaped refractory, and unshaped refractory

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07291747A (en) * 1994-04-26 1995-11-07 Nippon Steel Corp Heat insulating monolithic refractory
CN102203033A (en) * 2008-10-24 2011-09-28 新日本制铁株式会社 Binder for unshaped refractory, and unshaped refractory

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
朱新伟等: "电熔镁锆砂加入量对RH精炼炉用刚玉-尖晶石浇注料性能的影响", 《耐火材料》 *
贾江议等: "铝酸钙水泥对硅酸铝质浇注料性能的影响", 《陶瓷》 *
金国泉等: "添加NiCO3对常压浸出除铁效果的探讨", 《新疆有色金属》 *

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