CN106277262A - A kind of environmental protection air supporting synergist for treatment of dyeing wastewater - Google Patents
A kind of environmental protection air supporting synergist for treatment of dyeing wastewater Download PDFInfo
- Publication number
- CN106277262A CN106277262A CN201610718672.5A CN201610718672A CN106277262A CN 106277262 A CN106277262 A CN 106277262A CN 201610718672 A CN201610718672 A CN 201610718672A CN 106277262 A CN106277262 A CN 106277262A
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- CN
- China
- Prior art keywords
- parts
- agent
- air supporting
- synergist
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002351 wastewater Substances 0.000 title claims abstract description 16
- 238000004043 dyeing Methods 0.000 title claims abstract description 14
- 230000007613 environmental effect Effects 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 69
- 239000007832 Na2SO4 Substances 0.000 claims abstract description 19
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 18
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 13
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229960003237 betaine Drugs 0.000 claims abstract description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011780 sodium chloride Substances 0.000 claims abstract description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 6
- 239000011707 mineral Substances 0.000 claims abstract description 6
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 10
- -1 olefin sulfonate Chemical class 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 9
- 238000005188 flotation Methods 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 5
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical class OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 238000005189 flocculation Methods 0.000 description 4
- 230000016615 flocculation Effects 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 229960004887 ferric hydroxide Drugs 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
Abstract
The invention discloses a kind of environmental protection air supporting synergist for treatment of dyeing wastewater, including the A agent 10 in terms of parts by weight~50 parts and B agent 50~90 parts, described A agent and B agent are formed by following parts by weight preparation of raw material respectively: A agent component is: dodecyl sodium sulfate 10~40 parts, α sodium olefin sulfonate 40~70 parts and glycine betaine 20~50 parts;B agent component is: inorganic villaumite 10~40 parts and mineral sulfates 60~80 parts;Described inorganic villaumite is one or both combination in KCl and NaCl;Described mineral sulfates is K2SO4And Na2SO4In one or both combination.
Description
Technical field
The present invention relates to a kind of environmental protection air supporting synergist for treatment of dyeing wastewater, belong to waste water in environmental conservation and process
The field of waste water treatment in field, especially dyeing.
Background technology
Air supporting is one of the most conventional water technology, as a kind of quick, efficient, solid-liquid separation skill of low energy consumption
Art, is not only suitable for the water purification that feeds water, is applicable to again the process of various wastewater, particularly to separating miscellaneous close to water of some proportions
Matter is more superior than general settling methods.Pneumatically supported principle is to produce substantial amounts of fine gas bubbles in water, at interfacial tension, bubble
Under the common effect of the many kinds of forces such as rising buoyancy and hydrostatic pressure difference, micro air bubble is promoted to stick to removed impurity particle
On, because adherend density floats to the water surface, so that impurities in water is separated removal less than water.
Dyeing waste water contains the granule of a large amount of different-grain diameters, including clay, antibacterial, virus, humic acid and protein
Deng.Commonly used air supporting method in printing-dyeing waste water treatment process at present, and its design has because water quality situation is different with field condition
Distinguished, be divided into the air supporting used by pretreatment and the air supporting used by end advanced treating after biochemistry before biochemistry.Both air supporting
Waste water in pond all contains the float of multiple different-grain diameter, and major part can use air supporting method to remove, but some because of
The bigger removal efficiency of proportion low (this is also the major reason causing air flotation effect the best).
The principal element of decision air flotation effect is the character of the fine gas bubbles in water, only small at acquisition diameter, density
Greatly, in the case of the good a large amount of fine gas bubbles of uniformity, just can obtain good air flotation effect, reason is:
1, bubble is little, and floating speed is fast, and the disturbance to water body is little, will not crash wadding grain, and can increase bubble and wadding grain collision
Probability.But not bubble is the thinnest more good, and bubble is meticulous to be affected ascent rate and increase size and the cost of flotation tank;
2, bubble diameter is the least, and in bubble, suffered additional pressure is the biggest, the interior collision probability to air molecule to bubble chamber film of bubble
The most, the most violent.Therefore to obtain stable fine bubble, air bubble intensity to ensure;
3, the number of contained microbubble in bubble density, i.e. unit volume outgassing water, determines bubble and the collision that suspends
Probability, density is the biggest, and collision probability is the biggest;
4, the uniformity of bubble, diameter difference and minor diameter bubble including largest air bubbles with minimum bubble account for bubble total amount ratio
Example, increasing of air pocket can reduce daf efficiency.
The research improving treatment of dyeing wastewater solid-liquid separation effect at present is concentrated mainly on the improvement to bubble generator
On, these achieve preferable effect, but often add more processing cost.The method improving solid-liquid separation effect is also wrapped
Include by adjusting the method that flocculant interpolation kind makes the flco proportion of generation reduce, as changed Ferric Salt Flocculants into PAC, PAM
Flocculant etc..Increase bubbles volume in addition with the surfactant adding a small amount of single kind, thus improve solid-liquid separation efficiency
Method.But the surfactant adding single kind is not easily controlled Air Bubble Size, density and uniformity, if add
Surfactant is not suitable for, and even can reduce air flotation effect.
Summary of the invention
For solving deficiency of the prior art, present invention aim at providing a kind of compound, low cost, nontoxic, efficient
Air supporting synergist, there is the generation amount dramatically increasing micro-bubble and the effect of stability, uniformity improving micro-bubble,
Water can be obviously enhanced process, the especially air flotation effect in printing-dyeing waste water treatment process and efficiency.
For achieving the above object, the technical scheme is that a kind of environmental protection air supporting potentiation for treatment of dyeing wastewater
Agent, including the A agent 10 in terms of parts by weight~50 parts and B agent 50~90 parts, described A agent and B agent are respectively by following parts by weight
Preparation of raw material forms:
A agent component is: dodecyl sodium sulfate 10~40 parts, α-sodium olefin sulfonate 40~70 parts and glycine betaine 20~50
Part;
B agent component is: inorganic villaumite 10~40 parts and mineral sulfates 60~80 parts;
Described inorganic villaumite is one or both combination in KCl and NaCl;Described mineral sulfates is K2SO4With
Na2SO4In one or both combination.
As preferably, described A agent component is: dodecyl sodium sulfate 20~40 parts, α-sodium olefin sulfonate 40~60 parts
With glycine betaine 20~30 parts;B agent component is: KCl 10~40 parts, Na2SO460~80 parts;Described A agent is 40 parts, and B agent is 60
Part.
As preferably, described A agent component is: dodecyl sodium sulfate 25~35 parts, α-sodium olefin sulfonate 45~55 parts
With glycine betaine 20~25 parts;B agent component is: NaCl 30 parts, Na2SO470 parts;Described A agent is 30 parts, and B agent is 70 parts.
As preferably, described A agent component is: dodecyl sodium sulfate 30 parts, α-sodium olefin sulfonate 50 parts and glycine betaine
20 parts;B agent component is: NaCl30 part, Na2SO4With K2SO470 parts of mixture, wherein Na2SO4With K2SO4Ratio be 1:1;
Described A agent is 25 parts, and B agent is 75 parts.
Beneficial effects of the present invention: the surfactant that A agent is compounding surfactant, relatively single kind of the present invention
Effect is more preferable, addition is few, can not only improve the foam performance of waste water, moreover it is possible to change the surface activity of suspended particles in water body.
The B agent of this invention is made up of inorganic salt, and it adds the effect of the water quality that can regulate foamed solution, makes surface tension further
Reduce, reduce the addition of A agent.
Detailed description of the invention
Embodiment 1.
Certain dye house effluents treating stations have employed air supporting and makees pretreatment, and flocculation medicament uses PAC and PAM, added 40 parts of A
Agent and 60 parts of B agent compositions:
A agent component is: 20 parts of dodecyl sodium sulfates, 50 parts of α-sodium olefin sulfonates and 30 parts of glycine betaines;
B agent component is: 30 parts of KCl and 70 parts of Na2SO4。
Compared with not adding air supporting synergist, solid-liquid separation effect dramatically increases, and COD clearance increases from 25%
50%, float (SS) clearance increases 75% from 60%, and chroma removal rate adds 5% simultaneously.
Embodiment 2.
In embodiment 1, dye house effluents treating stations have employed air supporting and makees pretreatment, and flocculation medicament uses PAC and PAM, adds
30 parts of A agent and 70 parts of B agent compositions:
A agent component is: 35 parts of dodecyl sodium sulfates, 45 parts of α-sodium olefin sulfonates and 20 parts of glycine betaines;
B agent component is: 30 parts of NaCl and 70 parts of Na2SO4。
Compared with not adding air supporting synergist, solid-liquid separation effect dramatically increases, and COD clearance increases from 25%
55%, float (SS) clearance increases 80% from 60%, and chroma removal rate adds 8% simultaneously.
Embodiment 3.
In embodiment 1, dye house effluents treating stations have employed air supporting and makees pretreatment, and flocculation medicament uses PAC and PAM, adds
25 parts of A agent and 75 parts of B agent compositions:
A agent component is: 30 parts of dodecyl sodium sulfates, 50 parts of α-sodium olefin sulfonates and 20 parts of glycine betaines;
B agent component is: B agent component is: 30 parts of NaCl, 70 parts of Na2SO4With K2SO4Mixture, wherein Na2SO4With K2SO4
Ratio be 1:1.
Compared with not adding air supporting synergist, solid-liquid separation effect dramatically increases, and COD clearance increases from 25%
58%, float (SS) clearance increases 83% from 60%, and chroma removal rate adds 10% simultaneously.
Embodiment 4.
Certain dye house effluents treating stations have employed air supporting and makees pretreatment, and flocculation medicament uses PAC and decolorising agent, added 25
Part A agent and 75 parts of B agent compositions:
A agent component is: 30 parts of dodecyl sodium sulfates, 50 parts of α-sodium olefin sulfonates and 20 parts of glycine betaines;
B agent component is: 30 parts of NaCl, 70 parts of Na2SO4With K2SO4Mixture, wherein Na2SO4With K2SO4Ratio be 1:
1。
Compared with not adding air supporting synergist, solid-liquid separation effect dramatically increases, and COD clearance increases from 30%
60%, float (SS) clearance increases 85% from 70%, and chroma removal rate adds 40% simultaneously.
Embodiment 5.
Certain dye house effluents treating stations have employed air supporting and makees end advanced treating, and front technique is that the waste water after biochemical treatment makes
Residual organic substances is aoxidized, containing ferric hydroxide precipitate and biochemical sludge in water outlet by Fenton method.25 parts of A agent have been added before air supporting
With 75 parts of B agent compositions:
A agent component is: 30 parts of dodecyl sodium sulfates, 50 parts of α-sodium olefin sulfonates and 20 parts of glycine betaines;
B agent component is: B agent component is: 30 parts of NaCl, 70 parts of Na2SO4With K2SO4Mixture, wherein Na2SO4With K2SO4
Ratio be 1:1.
Compared with not adding air supporting synergist, solid-liquid separation effect dramatically increases, and COD clearance increases from 5%
15%, float (SS) content is reduced to 45mg/L from 100mg/L, and chroma removal rate adds 5% simultaneously.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent or the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (4)
1. for an environmental protection air supporting synergist for treatment of dyeing wastewater, including the A agent 10 in terms of parts by weight~50 parts and B agent
50~90 parts, it is characterised in that described A agent and B agent are formed by following parts by weight preparation of raw material respectively:
A agent component is: dodecyl sodium sulfate 10~40 parts, α-sodium olefin sulfonate 40~70 parts and glycine betaine 20~50 parts;
B agent component is: inorganic villaumite 10~40 parts and mineral sulfates 60~80 parts;
Described inorganic villaumite is one or both combination in KCl and NaCl;Described mineral sulfates is K2SO4And Na2SO4In
One or both combination.
A kind of environmental protection air supporting synergist for treatment of dyeing wastewater the most according to claim 1, it is characterised in that described
A agent component be: dodecyl sodium sulfate 20~40 parts, α-sodium olefin sulfonate 40~60 parts and glycine betaine 20~30 parts;B agent group
It is divided into: KCl 10~40 parts, Na2SO460~80 parts;Described A agent is 40 parts, and B agent is 60 parts.
A kind of environmental protection air supporting synergist for treatment of dyeing wastewater the most according to claim 1, it is characterised in that described
A agent component be: dodecyl sodium sulfate 25~35 parts, α-sodium olefin sulfonate 45~55 parts and glycine betaine 20~25 parts;B agent group
It is divided into: NaCl 30 parts, Na2SO470 parts;Described A agent is 30 parts, and B agent is 70 parts.
A kind of environmental protection air supporting synergist for treatment of dyeing wastewater the most according to claim 1, it is characterised in that described
A agent component be: dodecyl sodium sulfate 30 parts, α-sodium olefin sulfonate 50 parts and glycine betaine 20 parts;B agent component is: NaCl30
Part, Na2SO4With K2SO470 parts of mixture, wherein Na2SO4With K2SO4Ratio be 1:1;Described A agent is 25 parts, and B agent is
75 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610718672.5A CN106277262A (en) | 2016-08-24 | 2016-08-24 | A kind of environmental protection air supporting synergist for treatment of dyeing wastewater |
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Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610718672.5A CN106277262A (en) | 2016-08-24 | 2016-08-24 | A kind of environmental protection air supporting synergist for treatment of dyeing wastewater |
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Publication Number | Publication Date |
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CN106277262A true CN106277262A (en) | 2017-01-04 |
Family
ID=57616317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610718672.5A Pending CN106277262A (en) | 2016-08-24 | 2016-08-24 | A kind of environmental protection air supporting synergist for treatment of dyeing wastewater |
Country Status (1)
Country | Link |
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CN (1) | CN106277262A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111470571A (en) * | 2020-04-18 | 2020-07-31 | 浙江伊诺环保科技股份有限公司 | Air floatation auxiliary agent and sewage treatment process applying same |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4772425A (en) * | 1985-12-23 | 1988-09-20 | Colgate-Palmolive Company | Light duty liquid dishwashing composition containing abrasive |
US5308499A (en) * | 1989-05-22 | 1994-05-03 | Commonwealth Scientific And Industrial Research Organisation | Effluent treatment |
-
2016
- 2016-08-24 CN CN201610718672.5A patent/CN106277262A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4772425A (en) * | 1985-12-23 | 1988-09-20 | Colgate-Palmolive Company | Light duty liquid dishwashing composition containing abrasive |
US5308499A (en) * | 1989-05-22 | 1994-05-03 | Commonwealth Scientific And Industrial Research Organisation | Effluent treatment |
Non-Patent Citations (1)
Title |
---|
柳姝等: "混凝-微气泡气浮法处理含藻废水的研究", 《环境工程学报》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111470571A (en) * | 2020-04-18 | 2020-07-31 | 浙江伊诺环保科技股份有限公司 | Air floatation auxiliary agent and sewage treatment process applying same |
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