CN106273543A - A kind of carbon fibre composite moulding process - Google Patents

A kind of carbon fibre composite moulding process Download PDF

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Publication number
CN106273543A
CN106273543A CN201610945328.XA CN201610945328A CN106273543A CN 106273543 A CN106273543 A CN 106273543A CN 201610945328 A CN201610945328 A CN 201610945328A CN 106273543 A CN106273543 A CN 106273543A
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China
Prior art keywords
carbon fiber
heating
epoxide
moulding process
resin glue
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Pending
Application number
CN201610945328.XA
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Chinese (zh)
Inventor
张翼
王毅
马震宇
任淑红
党利
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Zhengzhou University of Aeronautics
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Zhengzhou University of Aeronautics
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Priority to CN201610945328.XA priority Critical patent/CN106273543A/en
Publication of CN106273543A publication Critical patent/CN106273543A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The invention discloses a kind of carbon fibre composite moulding process of carbon fiber forming technical field, including laying, impregnation, heat, solidify and quality inspection process step, described carbon fibre composite moulding process, specifically include following steps: S1: laying;S2: impregnation;S3: heating;S4: solidification;S5: quality inspection processes;Moulding process of the present invention is simple, efficiently, the raw material of carbon fiber can fully be used, do not result in the waste of material, improving production efficiency, carbon fiber product qualification rate is high, uses autoclave to solidify, airfelt and other auxiliary material stripeds of formation when shrinking can be effectively eliminated, and can guarantee that material smooth surface after hardening, no wrinkle, preferably improve product quality.

Description

A kind of carbon fibre composite moulding process
Technical field
The present invention relates to carbon fiber forming technical field, be specially a kind of carbon fibre composite moulding process.
Background technology
Carbon fiber, is the tencel material of a kind of phosphorus content high intensity more than 95%, high modulus fibre.It is by The organic fibers such as flake graphite crystallite are piled up along fiber axial direction and are formed, the microlite obtained through carbonization and graphitization processing Ink material.Carbon fiber " soft outside but hard inside ", quality is lighter than metallic aluminium, but intensity is higher than iron and steel, and has corrosion-resistant, high-modulus Characteristic, be all important materials at defence and military and civilian aspect.It not only has the intrinsic intrinsic property of material with carbon element, has both again The soft machinability of textile fabric, is a new generation's reinforcing fiber.Carbon fiber has many premium properties, carbon fiber axially strong Degree and modulus are high, and density is low, higher than performance, and without creep, superhigh temperature resistant under non-oxidizing atmosphere, fatigue durability is good, specific heat and conduction Property is between nonmetal and metal, and thermal coefficient of expansion is little and has anisotropy, good corrosion resistance, and X-ray transparent is good.Good Electrical and thermal conductivity performance well, electromagnetic wave shielding are good.
Existing carbon fiber forming technique in molding more uses airfelt and other auxiliary materials, and these materials are adding Rear carbon fiber can form the phenomenon of fold and striped, affects the smoothness of outward appearance, thus affects the total quality of carbon fiber, for This, we have invented a kind of carbon fibre composite moulding process and come into operation, to solve the problems referred to above.
Summary of the invention
It is an object of the invention to provide a kind of carbon fibre composite moulding process, to solve above-mentioned background technology carries The problem that the conventional molding process gone out there will be fold and fringe phenomena.
For achieving the above object, the present invention provides following technical scheme: a kind of carbon fibre composite moulding process, including Laying, impregnation, heat, solidify and quality inspection process step, described carbon fibre composite moulding process, specifically include following step Rapid:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, wherein Carbon fiber axially with the ratio of the number of plies radially for 3:2;
S2: impregnation: be stretched to inside gumming device by carbon fiber by haulage gear, is completely immersed in impregnation dress with carbon fiber Put in interior epoxide-resin glue and be as the criterion, simultaneously haulage gear synchronous operation, continue to draw carbon fiber, and by spreading roller by carbon The epoxide-resin glue extrusion that fiber surface is unnecessary;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue Stickiness reduce, and carbon fiber is slowly pulled out by haulage gear;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 5--8bar, maintains 1.2--1.5h so that it is Gu Change;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 2.8--4.2bar.
Preferably, in described step S1, the size of preforming tool is 4--8mm width, 0.6--1.2m length, and 3--6mm is thick, Dies cavity is provided with wearing layer, and wearing layer outer wall polishes smooth.
Preferably, in described step S2, the temperature of epoxide-resin glue is maintained at 35--50 DEG C, and carbon fiber is at epoxide-resin glue Middle infiltrating time 10--15min, the pressure of spreading roller is 2--5bar.
Preferably, in described step S3, heating-up temperature 140--180 DEG C, stop heating, traction machine after heating 30--40min The pultrusion speed of structure is 3--8m/min.
Preferably, in described step S4, solidification process is carried out in autoclave, and autoclave uses stainless steel welded, in it Portion's pressure-bearing 1.5--3MPa.
Preferably, in described step S5, the epoxide-resin glue that the carbon fiber surface after solidification is unnecessary is heated to 40--60 DEG C, make unnecessary epoxide-resin glue again melt, and utilize frictioning to be rooted out.
Compared with prior art, the invention has the beneficial effects as follows: moulding process of the present invention is simple, efficiently, carbon fiber former Material can fully be used, and does not results in the waste of material, improves production efficiency, and carbon fiber product qualification rate is high, uses Autoclave solidifies, it is possible to effectively eliminates airfelt and other auxiliary material stripeds of formation when shrinking, and can guarantee that Material smooth surface after hardening, no wrinkle, preferably improves product quality.
Accompanying drawing explanation
Fig. 1 is present invention process flow chart.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Describe, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments wholely.Based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under not making creative work premise Embodiment, broadly falls into the scope of protection of the invention.
Embodiment one
A kind of carbon fibre composite moulding process, including laying, impregnation, heats, solidify and quality inspection process step, described Carbon fibre composite moulding process, specifically includes following steps:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, wherein Carbon fiber axially with the ratio of the number of plies radially for 3:2, the size of preforming tool is 4mm width, 0.6m length, and 3mm is thick, and dies cavity sets There is wearing layer, and wearing layer outer wall polishes smooth;
S2: impregnation: be stretched to inside gumming device by carbon fiber by haulage gear, is completely immersed in impregnation dress with carbon fiber Put in interior epoxide-resin glue and be as the criterion, simultaneously haulage gear synchronous operation, continue to draw carbon fiber, and by spreading roller by carbon The epoxide-resin glue extrusion that fiber surface is unnecessary, the temperature of epoxide-resin glue is maintained at 35 DEG C, and carbon fiber is in epoxide-resin glue Infiltrating time 10min, the pressure of spreading roller is 2bar;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue Stickiness reduce, and carbon fiber is slowly pulled out by haulage gear, heating-up temperature 140 DEG C, after heating 30min, stops heating, The pultrusion speed of haulage gear is 3m/min;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 5bar, maintains 1.2h so that it is solidification, solidification Process is carried out in autoclave, and autoclave uses stainless steel welded, its internal pressure-bearing 1.5MPa;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 2.8bar, and the epoxide-resin glue that the carbon fiber surface after solidification is unnecessary is heated to 40 DEG C, make unnecessary epoxide-resin glue again melt, and utilize frictioning to be rooted out.
Embodiment two
A kind of carbon fibre composite moulding process, including laying, impregnation, heats, solidify and quality inspection process step, described Carbon fibre composite moulding process, specifically includes following steps:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, wherein Carbon fiber axially with the ratio of the number of plies radially for 3:2, the size of preforming tool is 5mm width, 0.8m length, and 4mm is thick, and dies cavity sets There is wearing layer, and wearing layer outer wall polishes smooth;
S2: impregnation: be stretched to inside gumming device by carbon fiber by haulage gear, is completely immersed in impregnation dress with carbon fiber Put in interior epoxide-resin glue and be as the criterion, simultaneously haulage gear synchronous operation, continue to draw carbon fiber, and by spreading roller by carbon The epoxide-resin glue extrusion that fiber surface is unnecessary, the temperature of epoxide-resin glue is maintained at 40 DEG C, and carbon fiber is in epoxide-resin glue Infiltrating time 12min, the pressure of spreading roller is 3bar;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue Stickiness reduce, and carbon fiber is slowly pulled out by haulage gear, heating-up temperature 150 DEG C, after heating 34min, stops heating, The pultrusion speed of haulage gear is 4m/min;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 6bar, maintains 1.3h so that it is solidification, solidification Process is carried out in autoclave, and autoclave uses stainless steel welded, its internal pressure-bearing 2MPa;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 3.4bar, and the epoxide-resin glue that the carbon fiber surface after solidification is unnecessary is heated to 45 DEG C, make unnecessary epoxide-resin glue again melt, and utilize frictioning to be rooted out.
Embodiment three
A kind of carbon fibre composite moulding process, including laying, impregnation, heats, solidify and quality inspection process step, described Carbon fibre composite moulding process, specifically includes following steps:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, wherein Carbon fiber axially with the ratio of the number of plies radially for 3:2, the size of preforming tool is 8mm width, 1.2m length, and 6mm is thick, and dies cavity sets There is wearing layer, and wearing layer outer wall polishes smooth;
S2: impregnation: be stretched to inside gumming device by carbon fiber by haulage gear, is completely immersed in impregnation dress with carbon fiber Put in interior epoxide-resin glue and be as the criterion, simultaneously haulage gear synchronous operation, continue to draw carbon fiber, and by spreading roller by carbon The epoxide-resin glue extrusion that fiber surface is unnecessary, the temperature of epoxide-resin glue is maintained at 50 DEG C, and carbon fiber is in epoxide-resin glue Infiltrating time 15min, the pressure of spreading roller is 5bar;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue Stickiness reduce, and carbon fiber is slowly pulled out by haulage gear, heating-up temperature 180 DEG C, after heating 40min, stops heating, The pultrusion speed of haulage gear is 8m/min;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 8bar, maintains 1.5h so that it is solidification, solidification Process is carried out in autoclave, and autoclave uses stainless steel welded, its internal pressure-bearing 3MPa;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 4.2bar, and the epoxide-resin glue that the carbon fiber surface after solidification is unnecessary is heated to 60 DEG C, make unnecessary epoxide-resin glue again melt, and utilize frictioning to be rooted out.
Described in comprehensive above example, the most preferred embodiment of a kind of carbon fibre composite moulding process that the present invention provides For a kind of carbon fibre composite moulding process, including laying, impregnation, heat, solidify and quality inspection processes step, described carbon fibre Dimension composite material process planning, specifically includes following steps:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, wherein Carbon fiber axially with the ratio of the number of plies radially for 3:2, the size of preforming tool is 7mm width, 1m length, and 5mm is thick, and dies cavity is provided with Wearing layer, and wearing layer outer wall polishes smooth;
S2: impregnation: be stretched to inside gumming device by carbon fiber by haulage gear, is completely immersed in impregnation dress with carbon fiber Put in interior epoxide-resin glue and be as the criterion, simultaneously haulage gear synchronous operation, continue to draw carbon fiber, and by spreading roller by carbon The epoxide-resin glue extrusion that fiber surface is unnecessary, the temperature of epoxide-resin glue is maintained at 45 DEG C, and carbon fiber is in epoxide-resin glue Infiltrating time 14min, the pressure of spreading roller is 4bar;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue Stickiness reduce, and carbon fiber is slowly pulled out by haulage gear, heating-up temperature 160 DEG C, after heating 38min, stops heating, The pultrusion speed of haulage gear is 5m/min;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 7bar, maintains 1.4h so that it is solidification, solidification Process is carried out in autoclave, and autoclave uses stainless steel welded, its internal pressure-bearing 2.5MPa;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 3.8bar, and the epoxide-resin glue that the carbon fiber surface after solidification is unnecessary is heated to 55 DEG C, make unnecessary epoxide-resin glue again melt, and utilize frictioning to be rooted out.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, permissible Understand and these embodiments can be carried out multiple change without departing from the principles and spirit of the present invention, revise, replace And modification, the scope of the present invention be defined by the appended.

Claims (6)

1. a carbon fibre composite moulding process, including laying, impregnation, heat, solidify and quality inspection process step, its feature It is: described carbon fibre composite moulding process, specifically includes following steps:
S1: laying: in preforming tool, lays carbon fiber winding with axially and radially two kinds of laying directions, and wherein carbon is fine Dimension axially with the number of plies radially ratio for 3:2;
S2: impregnation: be stretched to, inside gumming device, be completely immersed in gumming device with carbon fiber by carbon fiber by haulage gear Epoxide-resin glue in be as the criterion, haulage gear synchronous operation simultaneously, continue by carbon fiber draw, and by spreading roller by carbon fiber The epoxide-resin glue extrusion of excess surface;
S3: heating: utilize heating plate by the carbon fiber heating after impregnation, along with the rising of heating-up temperature, epoxide-resin glue glutinous Property reduce, and carbon fiber is slowly pulled out by haulage gear;
S4: solidification: to the carbon fiber persistent pressure after heating, and be forced into 5--8bar, maintains 1.2--1.5h so that it is solidification;
S5: quality inspection processes: carbon fiber there will be fold and fringe phenomena after hardening, uses pressurized equipment repressurization extremely Composite lay block is compressed by 2.8--4.2bar.
A kind of carbon fibre composite moulding process the most according to claim 1, it is characterised in that: in described step S1, The size of preforming tool is 4--8mm width, 0.6--1.2m length, and 3--6mm is thick, and dies cavity is provided with outside wearing layer, and wearing layer Wall polishes smooth.
A kind of carbon fibre composite moulding process the most according to claim 1, it is characterised in that: in described step S2, The temperature of epoxide-resin glue is maintained at 35--50 DEG C, and carbon fiber is infiltrating time 10--15min in epoxide-resin glue, spreading roller Pressure is 2--5bar.
A kind of carbon fibre composite moulding process the most according to claim 1, it is characterised in that: in described step S3, Heating-up temperature 140--180 DEG C, stops heating after heating 30--40min, and the pultrusion speed of haulage gear is 3--8m/min.
A kind of carbon fibre composite moulding process the most according to claim 1, it is characterised in that: in described step S4, Solidification process is carried out in autoclave, and autoclave uses stainless steel welded, its internal pressure-bearing 1.5--3MPa.
A kind of carbon fibre composite moulding process the most according to claim 1, it is characterised in that: in described step S5, The epoxide-resin glue that carbon fiber surface after solidification is unnecessary is heated to 40--60 DEG C, makes unnecessary epoxide-resin glue again melt Change, and utilize frictioning to be rooted out.
CN201610945328.XA 2016-10-26 2016-10-26 A kind of carbon fibre composite moulding process Pending CN106273543A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107488914A (en) * 2017-08-22 2017-12-19 西安工程大学 A kind of carbon fibre composite heald frame of lamination global formation
CN108426760A (en) * 2018-04-03 2018-08-21 威海拓展纤维有限公司 The method for preparing carbon fibre composite interlaminar shear strength batten
CN109940908A (en) * 2017-12-21 2019-06-28 宜兴市宜泰碳纤维织造有限公司 A kind of moulding process of carbon fiber and phenolic resin composite
CN109940903A (en) * 2017-12-21 2019-06-28 宜兴市宜泰碳纤维织造有限公司 A kind of carbon fiber composite board moulding process
CN110076927A (en) * 2019-04-04 2019-08-02 惠州永翊复合材料科技有限公司 A kind of novel cured stamen molding carbon fiber forming technology
CN110193961A (en) * 2019-05-05 2019-09-03 常州神鹰碳塑复合材料有限公司 A kind of carbon fibre composite jacquard weave machine broaching tool and manufacturing method
CN110271172A (en) * 2019-05-22 2019-09-24 惠州龙腾运动器材有限公司 A kind of carbon fiber bicycle part seamless pipe moulding process
CN113564840A (en) * 2021-07-23 2021-10-29 东莞市超强运动器材有限公司 Carbon fiber cloth production process
CN113998012A (en) * 2021-10-14 2022-02-01 上海瓴荣材料科技有限公司 Carbon fiber composite material doorsill stiffening beam and manufacturing method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107488914A (en) * 2017-08-22 2017-12-19 西安工程大学 A kind of carbon fibre composite heald frame of lamination global formation
CN109940908A (en) * 2017-12-21 2019-06-28 宜兴市宜泰碳纤维织造有限公司 A kind of moulding process of carbon fiber and phenolic resin composite
CN109940903A (en) * 2017-12-21 2019-06-28 宜兴市宜泰碳纤维织造有限公司 A kind of carbon fiber composite board moulding process
CN108426760A (en) * 2018-04-03 2018-08-21 威海拓展纤维有限公司 The method for preparing carbon fibre composite interlaminar shear strength batten
CN110076927A (en) * 2019-04-04 2019-08-02 惠州永翊复合材料科技有限公司 A kind of novel cured stamen molding carbon fiber forming technology
CN110193961A (en) * 2019-05-05 2019-09-03 常州神鹰碳塑复合材料有限公司 A kind of carbon fibre composite jacquard weave machine broaching tool and manufacturing method
CN110271172A (en) * 2019-05-22 2019-09-24 惠州龙腾运动器材有限公司 A kind of carbon fiber bicycle part seamless pipe moulding process
CN113564840A (en) * 2021-07-23 2021-10-29 东莞市超强运动器材有限公司 Carbon fiber cloth production process
CN113998012A (en) * 2021-10-14 2022-02-01 上海瓴荣材料科技有限公司 Carbon fiber composite material doorsill stiffening beam and manufacturing method thereof

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Application publication date: 20170104