CN106268277A - A kind of desulfurizer and technique - Google Patents
A kind of desulfurizer and technique Download PDFInfo
- Publication number
- CN106268277A CN106268277A CN201610901019.2A CN201610901019A CN106268277A CN 106268277 A CN106268277 A CN 106268277A CN 201610901019 A CN201610901019 A CN 201610901019A CN 106268277 A CN106268277 A CN 106268277A
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- Prior art keywords
- tower body
- interior
- tower
- spraying layer
- serosity
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/80—Semi-solid phase processes, i.e. by using slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/96—Regeneration, reactivation or recycling of reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a kind of desulfurizer and technique, this device is made up of outer tower body (1), middle tower body (2), interior tower body (3), top of tower (7), interior spraying layer (6), outer spraying layer (5) and demister (4);Described outer tower body sidewall is connected with smoke inlet, and the top of outer tower body sidewall is formed with top of tower and is tightly connected;Described inter-chamber tower body is positioned between outer tower body and tower body, and height is less than outer tower, open top;Described interior tower body is positioned at inter-chamber tower body portion, and top is formed with tower top and is tightly connected, and bottom is uncovered and is higher than bottom middle tower body, and higher than interior pond (8) Starch Level;If being provided with the outer spraying layer (5) of dried layer and demister (4) between outer tower body and middle tower body, for the thick desulfurization of flue gas;If interior tower body is internally installed has spraying layer and demister in dried layer, for the fine de-sulfur of flue gas.The present invention has that desulfuration efficiency is high, occupation area of equipment is little, the advantage of stable and reliable operation.
Description
Technical field
The present invention relates to a kind of desulfurizer and technique, belong to flue gases purification field.
Technical background
Domestic coal-burning boiler uses wet fuel gas desulfurizing technology mostly, is divided by nozzle/packing layer by the desulfurizing agent of alkalescence
After Saning, react with flue gas counter current contacting in absorption tower, reach to remove SO in flue gas2Purpose, the big multipotency of desulfuration efficiency
Reach 90% even 95%.Along with China's standard limit of smog release is gradually strict and the proposition of current " ultra-clean " discharge theory, coal-fired electricity
The requirement of desulfurizer operational efficiency is also improved constantly by factory, particularly the power plant user of burning high sulfur coal, and its desulfuration efficiency needs
Reach more than 99%.
Current portions power plant uses double tower Two-way Cycle technology to improve desulfuration efficiency, but this technology exist equipment investment high,
The problems such as floor space is big, the flue gas high-efficiency desulfurization how realizing lower cost under conditions of land limited is urgently to solve at present
One of problem certainly.
Summary of the invention
The present invention relates to a kind of high effective desulphurization device, described device is by outer tower body, middle tower body, interior tower body, top of tower, interior
Spraying layer, outer spraying layer and demister composition;
Described outer tower body sidewall is connected with smoke inlet, and the top of outer tower body sidewall is formed with top of tower and is tightly connected.
Described inter-chamber tower body is positioned between outer tower body and tower body, and height is less than outer tower, open top.
Described interior tower body is positioned at inter-chamber tower body portion, top is formed with tower top and is tightly connected, and bottom is uncovered and is higher than
Between bottom tower body.
If being provided with the outer spraying layer of dried layer and demister between outer tower body and middle tower body, for the thick desulfurization of flue gas.
If interior tower body is internally installed has spraying layer and demister in dried layer, for the fine de-sulfur of flue gas.
Use above-mentioned high effective desulphurization device, form mixed liquor after being mixed with interior pond serosity by fresh desulfurization slurry and be delivered to interior
Spraying layer, now plasm PH value is higher, to low concentration SO2Assimilation effect strong;
Spray rear slurry falls to interior pond bottom middle tower body, and pond serosity in being formed, interior pond serosity part internal circulation pump is defeated
Sending interior spraying layer back to, another part is delivered to outer spraying layer and mixes with outer circulation serosity;Now serosity not yet reacts complete, to cigarette
High concentration SO in gas2Assimilation effect is preferable;Spray rear slurry falls to outer pond bottom outer tower body, part outer circulation
Transport pump returns outer spraying layer and forms outer circulation serosity, and another part is expelled directly out as waste water.
The present invention relates to a kind of high effective desulphurization device and technique, its operation principle is: flue gas enters from outer tower body side,
Under the middle stop of tower body and the drag effect of top spraying layer, flue gas tower body outside is uniform with in the annular region of middle tower body
It is distributed and flows up, the desulfurization slurry generation chemical reaction with spraying, complete thick sweetening process;Thick flue gas after desulfurization warp
Cross demister and arrive outer top of tower, then be redirected back into interior tower from top, along the gap between middle tower body and interior tower body to dirty
Dynamic;Flue gas is changed direction after arriving interior tower bottom under the stop of slurry pool liquid level again, flows up in entering in tower body, and
Fine de-sulfur process is completed under the effect of interior spraying layer serosity;After fine de-sulfur, flue gas leaves desulfurizer through demister.
Compared with the prior art, a kind of high effective desulphurization device and the technique of the present invention has the advantage that
(1) by the way of inside and outside tower, twice counter current contacting process of flue gas and desulfurization slurry is defined, with double tower Two-way Cycle skill
Art compares floor space and the cost of investment decreasing desulphurization plant;
(2) efficiently utilized by the classification of desulfurization slurry, reduce the operating cost of desulfurizing tower.
Accompanying drawing explanation
Fig. 1 is a kind of high effective desulphurization device of the present invention.
Fig. 2 is the top view of Section A-A in Fig. 1.
Description of reference numerals
The outer tower body of 1-;Tower body in the middle of 2-;Tower body in 3-;4-demister;The outer spraying layer of 5-;Spraying layer in 6-;7-top of tower;8-
Interior pond;The outer pond of 9-.
Detailed description of the invention
For making the present invention apparent understandable, 1 adds respectively in terms of serum recycle and flow of flue gas two below in conjunction with the accompanying drawings
To describe in detail.
Serum recycle: fresh desulfurization slurry and interior loop slurry are delivered to interior spraying layer, and now plasm PH value is higher, to low
Concentration SO2Assimilation effect strong.Spray rear slurry falls to interior pond 8 bottom middle tower body, in part circulating pump is transmitted back to
Spraying layer forms interior loop slurry, and another part is delivered to outer spraying layer and mixes with outer circulation serosity.Now serosity not yet reacts
Completely, to high concentration SO in flue gas2Assimilation effect is preferable.Spray rear slurry falls to outer pond 9 bottom outer tower body, one
Demultiplexing circulating pump is transmitted back to outer spraying layer and forms outer circulation serosity, and another part directly leads out.Interior pond 8 does not connects with outer pond 9.
Flow of flue gas: flue gas enters from outer tower body side, middle tower body stop and above the drag effect of spraying layer
Under, flue gas tower body outside is uniformly distributed and flows up, with the desulfurization slurry sprayed in the annular region of middle tower body
Chemical reaction occurring, completes thick sweetening process, desulfuration efficiency is not less than 90%;Thick flue gas after desulfurization arrives outer tower through demister
Top, interior tower it is redirected back into from top, flow downward along the gap between middle tower body and interior tower body;Flue gas arrives at the bottom of interior tower
Again change direction under the stop of slurry pool liquid level behind portion, enter interior tower body and flow up, at the work of interior spraying layer serosity
Completing fine de-sulfur process under with, desulfuration efficiency is not less than 90%;After fine de-sulfur, flue gas leaves desulfurizer through demister.
By above-mentioned high effective desulphurization device and serum recycle technique, it is achieved that the desulfurization slurry of high PH absorbs low SO2Concentration
Re-absorption height SO after flue gas, serosity PH reduction2The substep sweetening process of concentration flue gas, total desulfuration efficiency is up to more than 99%.
Claims (2)
1. a desulfurizer, it is characterised in that: by outer tower body (1), middle tower body (2), interior tower body (3), top of tower (7), interior
Spraying layer (6), outer spraying layer (5) and demister (4) composition;Described outer tower body sidewall is connected with smoke inlet, outer tower body side
The top of wall is formed with top of tower and is tightly connected;Described inter-chamber tower body is positioned between outer tower body and tower body, and height is less than outward
Tower, open top;Described interior tower body is positioned at inter-chamber tower body portion, and top is formed with tower top and is tightly connected, and bottom is uncovered and high
Bottom middle tower body, and higher than interior pond (8) Starch Level;If being provided with the outer spraying layer of dried layer between outer tower body and middle tower body
(5) and demister (4), for the thick desulfurization of flue gas;If interior tower body is internally installed has spraying layer and demister in dried layer, for cigarette
The fine de-sulfur of gas.
2. use the desulfurizer described in claim 1 to form corresponding technique, it is characterised in that:
Forming mixed liquor after being mixed with interior pond serosity by fresh desulfurization slurry and be delivered to interior spraying layer (6), now plasm PH value is relatively
Height, to low concentration SO2Assimilation effect strong;
Spray rear slurry falls to interior pond (8) bottom middle tower body, pond serosity, interior pond serosity part internal circulation pump in being formed
Being transmitted back to interior spraying layer (6), another part is delivered to outer spraying layer (5) and mixes with outer circulation serosity;Now serosity not yet reacts
Completely, to high concentration SO in flue gas2Assimilation effect is preferable;Spray rear slurry falls to outer pond (9) bottom outer tower body, and one
Part outer circulation transport pump returns outer spraying layer and forms outer circulation serosity, and another part is expelled directly out as waste water.
Priority Applications (1)
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CN201610901019.2A CN106268277A (en) | 2016-10-17 | 2016-10-17 | A kind of desulfurizer and technique |
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CN201610901019.2A CN106268277A (en) | 2016-10-17 | 2016-10-17 | A kind of desulfurizer and technique |
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CN106268277A true CN106268277A (en) | 2017-01-04 |
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CN201610901019.2A Pending CN106268277A (en) | 2016-10-17 | 2016-10-17 | A kind of desulfurizer and technique |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108434965A (en) * | 2018-05-29 | 2018-08-24 | 舟山嵊泗海光明电器有限公司 | Turbine exhaust processing unit |
CN113230870A (en) * | 2020-12-15 | 2021-08-10 | 岑顺彬 | Desulfurizing tower dual cycle wet process filtration system for chemical production |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101130154A (en) * | 2007-08-14 | 2008-02-27 | 湖南大学 | Pneumatic stirring, injecting, bubbling, desulfurizing and dust removing absorption tower |
CN102553430A (en) * | 2012-02-23 | 2012-07-11 | 中电投远达环保工程有限公司 | Bicyclic high-efficiency desulfurization absorption tower and desulfurization system employing tower |
RU2496559C1 (en) * | 2012-08-10 | 2013-10-27 | Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Сибирский Федеральный Университет" | Plant for trapping vapors of oil and oil products |
CN204412060U (en) * | 2015-01-05 | 2015-06-24 | 中节能六合天融环保科技有限公司 | A kind of double fluid is to high efficiency lower resistance desulfurizing tower |
CN206199001U (en) * | 2016-10-17 | 2017-05-31 | 上海锅炉厂有限公司 | A kind of desulfurizer |
-
2016
- 2016-10-17 CN CN201610901019.2A patent/CN106268277A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101130154A (en) * | 2007-08-14 | 2008-02-27 | 湖南大学 | Pneumatic stirring, injecting, bubbling, desulfurizing and dust removing absorption tower |
CN102553430A (en) * | 2012-02-23 | 2012-07-11 | 中电投远达环保工程有限公司 | Bicyclic high-efficiency desulfurization absorption tower and desulfurization system employing tower |
RU2496559C1 (en) * | 2012-08-10 | 2013-10-27 | Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Сибирский Федеральный Университет" | Plant for trapping vapors of oil and oil products |
CN204412060U (en) * | 2015-01-05 | 2015-06-24 | 中节能六合天融环保科技有限公司 | A kind of double fluid is to high efficiency lower resistance desulfurizing tower |
CN206199001U (en) * | 2016-10-17 | 2017-05-31 | 上海锅炉厂有限公司 | A kind of desulfurizer |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108434965A (en) * | 2018-05-29 | 2018-08-24 | 舟山嵊泗海光明电器有限公司 | Turbine exhaust processing unit |
CN108434965B (en) * | 2018-05-29 | 2020-09-15 | 舟山嵊泗海光明电器有限公司 | Turbine exhaust gas treatment device |
CN113230870A (en) * | 2020-12-15 | 2021-08-10 | 岑顺彬 | Desulfurizing tower dual cycle wet process filtration system for chemical production |
CN113230870B (en) * | 2020-12-15 | 2022-07-01 | 山东莱钢节能环保工程有限公司 | Desulfurizing tower dual cycle wet process filtration system for chemical production |
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Application publication date: 20170104 |