Containing Thidiazuron and the plant growth regulator composition of super quick albumen
Technical field
The invention belongs to agriculture plant protection field, particularly relate to a kind of plant growth regulator having and improving performance
Compositions, concretely relates to a kind of compositions comprising Thidiazuron and super quick albumen pesticide.
Background technology
Super quick albumen (harpin protein) is that one can induce plant to produce defense response, strengthens growth and development of plants
The specific proteins of function, because of the mechanism of action of its uniqueness crops, fruit-bearing forest, flowers etc. are had raising immunity, strengthen anti-
Disease pest and growth regulation, improve crop quality, increasing both production and income function.It is that the albumen produced by plant pathogenetic bacteria excites
A kind of agricultural biological technical products that son is developed, dosage form is 3% microgranule, and it is that U.S. Cornell University doctor Wei Zhongmin exists
Research invention in 1992.Within 2000, obtained registration by Eden biotech company of the U.S. in the U.S.
Thidiazuron (pyraclostrobin) is new and effective plant growth regulator, after Thidiazuron is absorbed by plants, and can
Promote the chorista between petiole and stem, form nature and come off, can be widely used in pesticide, fertilizer.It has extremely strong
Biological activity, it induces plant cell division, much higher times of the general basic element of cell division of energy force rate of Callus formation.Improve
Crop ability, increases photosynthesis, thus reaches volume increase, increases excellent purpose.Can be used for all kinds of melon, fruits and vegetables, nursery stock, flower
The crops such as grass, grain, Nicotiana tabacum L., it may also be used for tissue culture, genetic engineering etc..Crop yield can be significantly improved on producing, change
Kind quality and have consumption few, pollution-free to ecological environment, to features such as people, animal, bird, Apis, natural enemy are nontoxic.
The plant growth regulator of commercial type is mainly based on single dose at present, and action effect is single.
Summary of the invention
It is an object of the invention to provide a plant growth regulators, to promote plant growth, improve disease-resistant, the work of crop
Produce amount and the quality improving crop.Inventor finds, super quick albumen and Thidiazuron are raw in regulation or promotion plant between the two
Long side has the most collaborative castering action.
It is a further object to provide and comprise two kinds of effective constituents A and the system of B plant growth regulator composition
Preparation Method and agriculture field regulation and promote crop growth application.
The purpose of the present invention can be reached by following measures:
A kind of plant growth regulator composition with potentiation, said composition comprises two kinds of active components of A and B,
Wherein active component A is Thidiazuron, and active component B is super quick albumen, and the weight ratio between two components is active component A and activity
The weight ratio of component B is 1:0.05~90.
In a kind of preferred version, the weight ratio of active component A and active component B is 1:0.05~85, for carrying further
High synergistic effect, the weight ratio of active component A and active component B is 1:0.05~80.
In a kind of preferred version, the weight ratio of active component A and active component B is 1:0.1~85.
In a kind of preferred version, the weight ratio of active component A and active component B is 1:1~80.
In a kind of preferred version, the weight ratio of active component A and active component B is 1:10~80.
In a kind of preferably scheme, the weight ratio between A and B two component can at random be entered in the range of following proportioning
Row sum-equal matrix: 1:0.05,1:0.051,1:0.052,1:0.055,1:0.054,1:0.055,1:0.056,1:0.057,1:
0.058,1:0.059,1:0.06,1:0.07,1:0.08,1:0.09,1:0.1,1:0.11,1:0.12,1:0.13,1:0.14,
1:0.15,1:0.16,1:0.17,1:0.18,1:0.19,1:0.2,1:0.3,1:0.4,1:0.5,1:0.6,1:0.7,1:0.8,
1:0.9,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,
1:17,1:18,1:19,1:20,1:25,1:30,1:35,1:40,1:45,1:50,1:55,1:60,1:65,1:70,1:75,1:
80,1:85,1:90, it is also possible to select in the range of two proportionings of any of the above are formed.
Inventor is found by experiment that, the compositions of the present invention is the growth for can preferably regulate crop, promotes
The health benefit of crop, improves the yield of crop, improves crop quality.
The invention provides the compositions comprising component A (Thidiazuron) and component B (super quick albumen) to regulate at agriculture field
The purposes of crop growth, particularly in terms of Oryza sativa L., Semen Maydis or fruit tree, regulating crop growth improves the aspects such as disease resisting effect
Purposes.
For giving full play to the advantageous effect of the present invention, the compositions of the present invention (such as antibacterial, can also be killed with other pesticide
Worm agent, herbicide, plant growth regulator), fertilizer etc. be used in mixed way, these are mixed therewith is often disclosed in prior art
Pesticide or fertilizer.
For improving using effect, the compositions of the present invention can be processed into the preparation of various dosage form, or and fertilizer with fertilizer
Jointly use or mixed.Suitably fertilizer includes: inorganic fertilizer or fertilizer, and concrete fertilizer is as containing in nitrogen, phosphorus, potassium etc.
Plant or several a great number of elements, or containing one or more trace element in copper, ferrum, manganese, zinc, boron, calcium, magnesium, sulfur etc., or contain
The mixture of at least one of the fertilizer such as humic acid, aminoacid, chitin.
The compositions of the present invention can be made, by active component and insecticides adjuvant, the dosage form allowed on pesticide.
Above-mentioned composition specifically can comprise insecticides adjuvant, such as carrier, solvent, dispersant, wetting agent, adhesive, thickening
One or more in agent, binding agent, surfactant or fertilizer etc., can mix conventional auxiliary agent during using.
Suitably auxiliary agent can be solid or liquid, the material that they are conventional during being typically formulation, such as sky
Mineral that is right or that regenerate, solvent, dispersant, wetting agent, adhesive, thickening agent, binding agent or fertilizer.
The application process of the present composition includes the aerial parts that the compositions of the present invention is used for plant growing, especially
It is leaf portion or blade face.Seed soaking can be selected or be applied in controlling object surface.Frequency and the amount of application used depend on crop
Growing state.
These compositionss can only comprise active component and be administered, it is also possible to mix together with additive (insecticides adjuvant)
Close and use.
The compositions of the present invention can be prepared as acceptable dosage form on pesticide, such as water preparation, suspending agent, solubility liquid
Agent, oil-suspending agent, encapsulated form, microemulsion, wettable powder etc..Character according to these compositionss and use compositions institute
Purpose to be reached and ambient conditions, can select compositions with spraying, atomizing, dust, broadcast sowing or sprinkle the side watered or the like
Method is used.
The encapsulated form being suitable for the present invention includes: microcapsule suspending agent, microcapsule suspension-suspendinagent agent, microcapsule suspension-aqueous emulsion
Deng, it is characterised in that in cyst wall, (i.e. capsule-core) comprises by the super quick albumen of effective ingredient and Thidiazuron mixing according to a certain percentage
Thing, both will be mixed and made into microencapsulation.Microencapsulation is stably disperseed using certain concentration, is suspended in as continuous phase
Water in formed microcapsule suspending agent.Or one of which effective ingredient is prepared as microcapsule suspending agent, another is effectively become
Divide and be prepared as emulsion, by two kinds of compositions of preparation in mixing, stirring, shake up and i.e. obtain microcapsule suspending agent-suspending agent or microcapsule suspension
Agent-aqueous emulsion.
The compositions of the present invention can be prepared as various dosage form by available known method, can by effective ingredient with help
Agent, such as solvent, solid carrier, can uniformly mix together with surfactant when needing, grind, be prepared as required agent
Type.
Above-mentioned solvent is selected from aromatic hydrocarbon, preferably containing 8-12 carbon atom, such as xylene mixture or substituted benzene, phthalein
Esters of gallic acid, such as Dibutyl phthalate or phthalandione two octanoic acid, fat hydrocarbon, such as thiacyclohexane or paraffin, alcohol and ethylene glycol and their ether
And ester, such as ethanol, ethylene glycol, ethylene glycol monomethyl;Ketone, such as cyclohexanone, highly polar solvent, such as N-methyl-2-pyrrolidine
Ketone, dimethyl sulfoxide or dimethylformamide, and vegetable oil or vegetable oil, such as soybean oil.
Above-mentioned solid carrier, as wettable powder and dispersible agent be typically natural mineral fillers, the most sliding
Stone, Kaolin, montmorillonite or active hargil.In order to manage the physical property of compositions, it is also possible to add polymolecularity silicic acid or
Polymolecularity adsorpting polymerization thing carrier, such as granulated adsorptive carriers or non-adsorbed carrier, suitable granulated adsorptive carriers is porous
Type, such as Pumex, Bentonite or bentonite;Suitably non-adsorbed carrier such as calcite or sand.Further, it is possible to use it is substantial amounts of inorganic
Character or organic nature be prefabricated into granular material as carrier, particularly dolomite.
According to the chemical property of the effective ingredient in the compositions of the present invention, suitable surfactant is sulfomethylated lignin
Acid, LOMAR PWA EINECS 246-676-2, phenolsulfonic acid, alkali salt or amine salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, fat
Alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, the also condensation substance of sulfonated naphthalene and naphthalene derivatives and formaldehyde, naphthalene or
LOMAR PWA EINECS 246-676-2 and phenol and the condensation substance of formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol,
Alkylaryl polyglycol ether, tributyl benzene polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol,
Ethoxylated castor oil, polyoxyethylene alkyl ether, ethylene oxide condensation substance, ethoxylation polyoxypropylene, lauric acid Polyethylene Glycol
Ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
In the compositions of the present invention, the mass content of active component is 1~80%, preferably 1~50%, further preferred 2
~30%.
Plant in the present invention includes but not limited to Fructus Fragariae Ananssae or Fructus Pruni pseudocerasi.
In the compositions of the present invention, two kinds of effective ingredient show as synergistic effect, and the specific activity of said composition uses individualized
The activity expection summation of compound, and the independent activity of individualized compound is the most notable.Showing of the compositions of the present invention
Other feature mainly shows themselves in that 1, the compositions mixture of the present invention has obvious synergistic function;2, the combination of the present invention
Thing can good regulating crop growth, improve disease-resistant resistance, promote crop health benefit, improve crop quality, improve crop
Yield.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit
Determine the present invention, all any amendment, equivalent and improvement etc. made within the spirit and principles in the present invention, should be included in
Within protection scope of the present invention.
In all formula of following example, percentage ratio is all weight percentage (folding hundred).The various preparation of the present composition
Processing technique is prior art, can be varied from according to different situations.
One, dosage form prepares embodiment
(1) processing of suspending agent and embodiment
By super for active component quick albumen and Thidiazuron, press formula with each components such as dispersant, wetting agent, thickening agent and water
Ratio mix homogeneously, after sand milling and/or high speed shear, obtains semi-finished product, adds water mix homogeneously and filter and i.e. obtain into after analysis
Product.
The super quick protein suspending agent of embodiment 1:20.25% Thidiazuron
Thidiazuron 0.25%, super quick protein 20 %, xanthan gum 4%, glycerol 2%, Kaolin 5%, Magnesiumaluminumsilicate 5%,
Sodium lignin sulfonate 5%, water complements to 100%.
The super quick protein suspending agent of embodiment 2:30.6% Thidiazuron
Thidiazuron 0.6%, super quick albumen 30%, bentonite 7%, ethylene glycol 3%, methyl naphthalene sulfonate formaldehyde condensate
5%, water complements to 100%.
The super quick protein suspending agent of embodiment 3:5.25% Thidiazuron
Thidiazuron 5%, super quick albumen 0.25%, white carbon 5%, glycerol 6%, sodium benzoate 3%, fatty alcohol polyoxy second
Alkene ether phosphate 5%, water complements to 100%.
(2) processing of microcapsule and embodiment
By effective ingredient Thidiazuron and super quick albumen mixture according to a certain percentage, both miniature glue will be mixed and made into
Capsule.Microencapsulation is stably disperseed using certain concentration, is suspended in the water of continuous phase formation microcapsule suspending agent.Or
One of which effective ingredient is prepared as microcapsule suspending agent, another effective ingredient is prepared as emulsion, by two kinds of preparation
Composition, in mixing, stirring, shakes up and i.e. obtains microcapsule suspending agent-suspending agent or microcapsule suspending agent-aqueous emulsion.
The super quick albumen microcapsule suspending agent of embodiment 4:14.2% Thidiazuron
Thidiazuron 0.2%, super quick protein 14 %, rosinweed oil 12%, glyceride lactate 4%, emulsifier polyoxyethylene
Oleum Ricini 3%, stabilizer triphenyl phosphite 3.5%, toluene di-isocyanate(TDI) 15%, acrylic acid and acrylic ester copolymers
5%, dipropylene glycol 3%, preservative sodium benzoate 1%, thickening agent xanthan gum 2.1%, water complements to 100%.
The super quick albumen microcapsule suspension-suspendinagent agent of embodiment 5:24.8% Thidiazuron
Thidiazuron 0.8%, super quick protein 24 %, methyl ester Oleum Cocois 15%, polyoxyethylene monopalmitate 5%, BHT5%,
Attractant aminoacid 2%, sodium benzoate 5%, ethylene glycol 5%, poly (vinyl acetate) emulsions 4%, xanthan gum 2%, water complements to
100%.
The super quick albumen microcapsule suspension-aqueous emulsion of embodiment 6:2.2% Thidiazuron
Thidiazuron 2%, super quick albumen 0.2%, gelatin 15%, ethanol 4%, ethylenediamine 5%, methyl naphthalene sulfonic acid sodium formaldehyde
Condensation substance 5%, water complements to 100%.
(3) processing of soluble powder and embodiment
By effective ingredient Thidiazuron and super quick albumen mixture according to a certain percentage, surfactant, auxiliary agent, filler,
It is placed in still, is sufficiently stirred for, obtain soluble powder.
The super quick albumen soluble powder of embodiment 7:9.1% Thidiazuron
Thidiazuron 0.1%, super quick albumen 9%, sodium alkyl benzene sulfonate 5%, Kaolin complements to 100%.
The super quick albumen soluble powder of embodiment 8:18.3% Thidiazuron
Thidiazuron 0.3%, super quick protein 18 %, alkylphenol polyoxyethylene polyethenoxy ether 2%, bentonite complements to
100%
The super quick albumen soluble powder of embodiment 9:2% Thidiazuron
Thidiazuron 1%, super quick albumen 1%, benzyl dimethyl phenol polyethenoxy ether 4%, ammonium sulfate complements to 100%.
(4) processing of water preparation and embodiment
Adding effective ingredient and auxiliary agent in a kettle., surplus water is supplied, and is stirred, and i.e. can get Thidiazuron
Super quick albumen water preparation.
The super quick albumen water preparation of embodiment 10:20.2% Thidiazuron
Thidiazuron 0.2%, super quick protein 20 %, ethanol 5% mixes, and stirs 20 minutes, adds super quick protein 28 %, stirs
Mix 30 minutes and be completely dissolved to super quick albumen;Adding 8% alkylol sodium sulfate, surplus water is supplied.
The super quick albumen water preparation of embodiment 11:2.1% Thidiazuron
Add Thidiazuron 0.1% and ethanol 8% in a kettle., stir 20 minutes;Add super quick albumen 2%, stirring
Within 30 minutes, it is completely dissolved to super quick albumen;Adding 10% fatty alcohol-polyoxyethylene ether, surplus water is supplied.
The super quick albumen water preparation of embodiment 12:10.2% Thidiazuron
Add Thidiazuron 0.2% and ethanol 5% in a kettle., stir 20 minutes;Add super quick protein 10 %, stirring
Within 30 minutes, it is completely dissolved to super quick albumen;Adding 5% fatty alcohol-polyoxyethylene ether, surplus water is supplied.
(5) processing of aqueous emulsion and embodiment
By super for active component quick albumen and Thidiazuron, press with each components such as solvent, emulsifying agent, dispersant, antifreeze and water
The ratio mixing of formula is placed in reactor, is sufficiently stirred for, i.e. can get aqueous emulsion.
The super quick albumen aqueous emulsion of embodiment 13:12.9% Thidiazuron
Thidiazuron 0.15%, super quick protein 12 .75%, dodecylbenzene sodium sulfonate 10%, toluene 10%, polyvinyl alcohol
5%, glycerol 5%, organic silicon defoamer 1%, water complements to 100%.
The super quick albumen aqueous emulsion of embodiment 14:20.5% Thidiazuron
Thidiazuron 0.5%, super quick protein 20 %, dimethylbenzene 10%, polyvinyl alcohol 5%, glycerol 5%, organosilicon froth breaking
Agent 1%, water complements to 100%.
The super quick albumen aqueous emulsion of embodiment 15:2.2% Thidiazuron
Thidiazuron 0.2%, super quick albumen 2%, dodecylbenzene sodium sulfonate 10%, methanol 10%, polyvinyl alcohol 5%, third
Triol 5%, organic silicon defoamer 1%, water complements to 100%.
The super quick albumen aqueous emulsion of embodiment 16:1.3% Thidiazuron
Thidiazuron 1%, super quick albumen 0.3%, alkylphenol polyoxyethylene 10%, toluene 10%, glycerol 5%, organic
Silicon defoaming agent 1%, water complements to 100%.
Two, drug effect checking test
(1) Assays Example
1, Thidiazuron is compounding with super quick albumen tests Fructus Fragariae Ananssae growth regulating synthesis measuring
Thidiazuron is diluted according to finite concentration with super quick albumen acetone, crop is carried out stem and leaf spraying, survey between garden
The impact that strawberry fruit is grown by each concentration fixed, including to the petiole of Fructus Fragariae Ananssae, single fruit weight, disease-resistant situation, fruit quality, and
Output condition etc. carry out overall merit.
Petiole length increase rate=(the petiole length of petiole length-clear water comparison after process)/clear water comparison petiole length *
100%
Setting increase rate=(percentage of fertile fruit of percentage of fertile fruit-clear water comparison after process)/clear water comparison percentage of fertile fruit * 100%
The disease index * of preventive effect=(disease index after the disease index-process of clear water comparison)/clear water comparison
100%
The single fruit weight * of single fruit weight increase rate=(single fruit weight of the single fruit weight after process-clear water comparison)/clear water comparison
100%
Per mu yield * 100% of sugary increase rate=(sugar content of the sugar content after process-clear water comparison)/clear water comparison
Table 1. Thidiazuron is compounding with super quick albumen to Fructus Fragariae Ananssae growth regulating synthesis measuring summary sheet
Note: " surpassing " in form is " super quick albumen " abbreviation, and " thiophene " is the abbreviation of " Thidiazuron ".Dispenser period: at the beginning of the early flowering season
Phase, this stage Fructus Fragariae Ananssae starts powdery mildew.Spraying times: 1 time;Insecticide-applying way: stem and leaf is sprayed;Investigation period: grass
The certain kind of berries period of maturation;In this test, the index such as petiole length, disease index, single fruit weight, content amount is the meansigma methods of each process.
Found that by experiment inventor there is between Thidiazuron and super quick albumen very well collaborative castering action, Thidiazuron with
Super quick albumen mixture is under different ratio, and relative Thidiazuron, super quick albumen single dose, and clear water comparison, the growth to Fructus Fragariae Ananssae is adjusted
Joint effect is obvious, is mainly manifested in: 1, the present invention can be effectively increased the petiole length of Fructus Fragariae Ananssae;2, Thidiazuron is using as single dose
Time plant growing had certain disease-resistant degeneration-resistant effect, and super quick albumen is a kind of high bioactivity material, to crop pest
There is certain immunity, jointly use between super quick albumen and Thidiazuron and there is good synergism, permissible from upper table analysis
Finding out, between Thidiazuron with super quick albumen, the preventive effect of powdery mildew of strawberry is compareed by synergism relative to single dose and clear water,
There is good preventive effect;3, due to the synergism of Thidiazuron Yu super quick albumen, promote Fructus Fragariae Ananssae nutrition conduction, disease-resistant
Degeneration-resistant, the single fruit weight of Fructus Fragariae Ananssae is obviously improved effect;4, the method can significantly improve Fructus Fragariae Ananssae sugar content, thus improve fruit
Kind;4, Thidiazuron and super quick albumen are in proportioning 1:(0.05~90) between time, synergistic function effect is obvious, works as Thidiazuron
With the ratio of super quick albumen when less than 1:90 or more than 1:0.05, both show as summation action.
(2) field efficacy checking test
1, Thidiazuron and super quick albumen mixture are to Fructus Pruni pseudocerasi crop growth regulation and the field compbined test of disease-resistant yield-increasing
Dispenser period: Fructus Pruni pseudocerasi initial bloom stage.
Spraying times: 1 time.The example of formulations utilizing the present invention sprays, three repetitions, results averaged.
Table 2 Thidiazuron and the field Comprehensive Experiment to Fructus Pruni pseudocerasi growth regulation of the super quick albumen mixture
Showing from table 2 experimental data, the product of the present invention is used at Fructus Pruni pseudocerasi initial bloom stage, can effectively regulate the health of Fructus Pruni pseudocerasi
Growth.At Thidiazuron and super quick albumen in proportioning 1:(0.05~90) between time, mainly show themselves in that 1, be remarkably improved Fructus Pruni pseudocerasi seat
Really rate, raising yield;2, scalable Cherry Grown autoimmune resistance, the disease-resistant anti-adversity ability of the highest Fructus Pruni pseudocerasi, reduces Fructus Pruni pseudocerasi brown
Maize ear rot disease index;3, the present invention can increase the single weight of Fructus Pruni pseudocerasi;4, the compositions of the present invention can improve the sugar content of Fructus Pruni pseudocerasi, fall
The acidity of low Fructus Pruni pseudocerasi, sugar-acid ratio significantly improves, and can promote the raising of Fructus Pruni pseudocerasi mouthfeel;5, embodiment 10, embodiment 12, embodiment
16, i.e. Thidiazuron: super quick albumen proportioning less than 1:90 or or more than 1:0.05 time, relative to single dose comparison and other embodiments,
Synergistic action effect is inconspicuous, shows as summation action.