CN106252612B - A kind of zinc-silver oxide cell negative plate drying process - Google Patents

A kind of zinc-silver oxide cell negative plate drying process Download PDF

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Publication number
CN106252612B
CN106252612B CN201610884726.5A CN201610884726A CN106252612B CN 106252612 B CN106252612 B CN 106252612B CN 201610884726 A CN201610884726 A CN 201610884726A CN 106252612 B CN106252612 B CN 106252612B
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China
Prior art keywords
plate
pole plate
drying
zinc
negative plate
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CN106252612A (en
Inventor
张阳
田伟龙
李楠
郑清清
仇振安
包睿
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Henan New Taihang Power Ltd By Share Ltd
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Henan New Taihang Power Ltd By Share Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • H01M4/244Zinc electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • H01M4/26Processes of manufacture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention discloses a kind of zinc-silver oxide cell negative plate drying process, it is put into rinse bath cleaning washing after negative plate chemical conversion, is taken out from rinse bath, moisture extra on pole plate is blotted with filter paper, pole plate is put into the zine plate of object containing zinc 99.9% again, pole plate is wrapped with filter paper, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 200 DEG C ~ 400 DEG C, and drying time controls between 40min ~ 60min, waits for that pole plate temperature is down to room temperature after the completion of drying, is put into dry vessel and preserves.The beneficial effects of the invention are as follows:1, it effectively prevent negative plate that oxidation reaction occurs in air, improves pole plate electric discharge quality;2, after pole plate drying, polar board surface flatness is better than normal process production level;3, pole plate drying time is improved, the production cycle is shortened, improves product quality, reduce production cost.

Description

A kind of zinc-silver oxide cell negative plate drying process
Technical field
The present invention relates to a kind of techniques in the making of zinc-silver oxide cell negative plate, especially a kind of to be suitable for zinc-silver oxide cell cathode Drying process when plate is processed.
Background technology
Zinc-silver reserve battery has specific energy, energy density per unit volume high;Specific power very it is high can with high rate discharge, and Capacity declines few when heavy-current discharge;Cell discharge voltage is steady, and self discharge is small and has many advantages, such as good mechanical strength, It remains to be widely used in certain occasions, startup is especially can be used as in military technology and aerospace flight technology and answers urgent telegram Source, in military technology, since the rated weight of the particularity battery of occasion is more relatively high than energy requirement, condition is harsh, this Battery electrical property is needed to perform to ultimate attainment, the electrical property of especially negative plate directly influences the electric discharge index of whole battery, Especially quickly activation becomes the technological difficulties that such battery is researched and developed under cryogenic.
Current such battery negative plate is that other substances such as special zinc powder conjunction cream is suppressed, through water after pole plate chemical conversion It washes, dry, now mostly use natural drying technique, negative plate easily reacts in humid air, to the electric discharge to battery Performance, shelf characteric etc. have very big influence.
Invention content
The purpose of the present invention is designing, a kind of method is simple, operates easy zinc-silver oxide cell negative plate drying process.
The technical scheme is that a kind of zinc-silver oxide cell negative plate drying process, it is characterised in that:After negative plate chemical conversion It is put into rinse bath cleaning washing, is taken out from rinse bath, moisture extra on pole plate is blotted with filter paper, then pole plate is put into containing zinc In the zine plate of object 99.9%, pole plate is wrapped with filter paper, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 200 DEG C ~ 400 DEG C, drying time controls between 40min ~ 60min, waits for that pole plate temperature is down to room temperature after the completion of drying, is put into drying It is preserved in vessel.
The beneficial effects of the invention are as follows:1, it effectively prevent negative plate that oxidation reaction occurs in air, improves pole plate electric discharge Quality;2, after pole plate drying, polar board surface flatness is better than normal process production level;3, pole plate drying time is improved, is shortened Production cycle, product quality is improved, production cost is reduced.
Specific implementation mode
Embodiment is described in detail,
Embodiment 1,
A kind of zinc-silver oxide cell negative plate drying process is put into rinse bath cleaning washing, from rinse bath after negative plate chemical conversion It takes out, moisture extra on pole plate is blotted with filter paper, pole plate is put into the zine plate of object containing zinc 99.9%, with filter paper by pole plate packet It wraps, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 200 DEG C, and drying time control is completed in 60min, drying After wait for that pole plate temperature is down to room temperature, be put into dry vessel and preserve.
Embodiment 2,
A kind of zinc-silver oxide cell negative plate drying process is put into rinse bath cleaning washing, from rinse bath after negative plate chemical conversion It takes out, moisture extra on pole plate is blotted with filter paper, pole plate is put into the zine plate of object containing zinc 99.9%, with filter paper by pole plate packet It wraps, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 300 DEG C, and drying time control is completed in 50min, drying After wait for that pole plate temperature is down to room temperature, be put into dry vessel and preserve.
Embodiment 3
A kind of zinc-silver oxide cell negative plate drying process is put into rinse bath cleaning washing, from rinse bath after negative plate chemical conversion It takes out, moisture extra on pole plate is blotted with filter paper, pole plate is put into the zine plate of object containing zinc 99.9%, with filter paper by pole plate packet It wraps, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 400 DEG C, and drying time control is completed in 40min, drying After wait for that pole plate temperature is down to room temperature, be put into dry vessel and preserve.
The above embodiments are merely examples for clarifying the description, and does not limit the embodiments.For institute For the those of ordinary skill in category field, other various forms of variations or change can also be made on the basis of the above description It is dynamic.There is no necessity and possibility to exhaust all the enbodiments, and obvious variation extended from this or change Within the dynamic protection domain created still in the utility model.

Claims (1)

1. a kind of zinc-silver oxide cell negative plate drying process, it is characterised in that:Rinse bath cleaning washing is put into after negative plate chemical conversion, from It is taken out in rinse bath, moisture extra on pole plate is blotted with filter paper, then pole plate is put into the zine plate of object containing zinc 99.9%, with filter Paper wraps pole plate, is separated with zine plate;It places into Muffle furnace and dries, temperature is adjusted to 200 DEG C ~ 400 DEG C, drying time control Between 40min ~ 60min, waits for that pole plate temperature is down to room temperature after the completion of drying, be put into dry vessel and preserve.
CN201610884726.5A 2016-10-11 2016-10-11 A kind of zinc-silver oxide cell negative plate drying process Active CN106252612B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610884726.5A CN106252612B (en) 2016-10-11 2016-10-11 A kind of zinc-silver oxide cell negative plate drying process

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Application Number Priority Date Filing Date Title
CN201610884726.5A CN106252612B (en) 2016-10-11 2016-10-11 A kind of zinc-silver oxide cell negative plate drying process

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CN106252612A CN106252612A (en) 2016-12-21
CN106252612B true CN106252612B (en) 2018-08-03

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112216880A (en) * 2020-09-24 2021-01-12 中国电子科技集团公司第十八研究所 Zinc-silver reserve battery manufacturing method based on humidity control and zinc-silver reserve battery

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB191319109A (en) * 1913-08-22 1914-09-22 Emmanuel Hancock Improvements in Plates for Electrical or Secondary Batteries or Accumulators.
CN102097621A (en) * 2011-01-21 2011-06-15 江苏理士电池有限公司 Plate drying process
CN103050718A (en) * 2012-12-17 2013-04-17 上海空间电源研究所 Pole piece protecting method for prolonging dry storage life of zinc-silver battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB191319109A (en) * 1913-08-22 1914-09-22 Emmanuel Hancock Improvements in Plates for Electrical or Secondary Batteries or Accumulators.
CN102097621A (en) * 2011-01-21 2011-06-15 江苏理士电池有限公司 Plate drying process
CN103050718A (en) * 2012-12-17 2013-04-17 上海空间电源研究所 Pole piece protecting method for prolonging dry storage life of zinc-silver battery

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