CN106245347A - A kind of rubber coating fabric based on Nano microsphere and polymer and preparation method thereof - Google Patents
A kind of rubber coating fabric based on Nano microsphere and polymer and preparation method thereof Download PDFInfo
- Publication number
- CN106245347A CN106245347A CN201610838894.0A CN201610838894A CN106245347A CN 106245347 A CN106245347 A CN 106245347A CN 201610838894 A CN201610838894 A CN 201610838894A CN 106245347 A CN106245347 A CN 106245347A
- Authority
- CN
- China
- Prior art keywords
- polymer
- fabric
- nano microsphere
- coating
- base fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0025—Rubber threads; Elastomeric fibres; Stretchable, bulked or crimped fibres; Retractable, crimpable fibres; Shrinking or stretching of fibres during manufacture; Obliquely threaded fabrics
- D06N3/0027—Rubber or elastomeric fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0084—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments by electrical processes, e.g. potentials, corona discharge, electrophoresis, electrolytic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0281—Polyurethane fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0807—Coloured
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Plasma & Fusion (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides the preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer, comprise the following steps: using elastic fiber as raw material, form base fabric using plain weave structure as fabric structure, weaving, base fabric is obtained after plasma low temperature processes the base fabric of pretreatment；Polyvinyl alcohol, polyacrylic acid, attapulgite, silicone rubber and glycerol being added in deionized water, high-speed stirred obtains polymer, then pours in polymer by nano pipe/polyhenylethylene acrylic microspheres, grind, bleed, add cross-linking agent, mixed grinding, forms coating mix；Coating mix is coated on the base fabric upper surface of pretreatment, extruding, to bleed, solidification obtains rubber coating fabric based on Nano microsphere and polymer.Fabric prepared by the present invention can change color with the different of elastic force suffered by fabric.
Description
Technical field
The invention belongs to textile material technical field, be specifically related to a kind of based on Nano microsphere with the rubber coating of polymer
Fabric and preparation method thereof.
Background technology
It is known that dyestuff refers to the compound that fiber or other materials can be made in certain medium firmly to colour, point
For natural dye and synthetic dyestuffs, wherein the use ratio of synthetic dyestuffs accounts for major part, and the range of dyestuff is
Not only limit to the dyeing with textile and stamp, also have application in fields such as paint, plastics, leathers.But, grind
Studying carefully discovery, dyestuff itself or dyestuff in use can produce noxious substance and directly endanger the health of the mankind, and contains
Plant, soil etc. also can be caused the destructive power that can not estimate by the pollutant of dyestuff, and the succedaneum therefore seeking dyestuff seems outstanding
For important.
A kind of method of color nano ball dyeing cotton fabric disclosed in Chinese patent CN 104060480A, uses bafta
After epoxypropyltrimethylchloride chloride carries out cation modifying, impregnated in the polystyrene-methyl-prop containing disperse dyeing
In olefin(e) acid nanosphere dispersion liquid, fabric is taken out washing, dries, it is achieved dyeing.The method is mainly by the shape of nanosphere
Replace disperse dyes pigment particles in irregular shape, utilize spherical particle to improve the dye-uptake of disperse dyes, expand dispersion
The range of application of dyestuff, but still employ chemical dye, and also the adhesion of Nano microsphere and bafta is difficult to ensure that, face
The different control of aberration.The preparation of a kind of silk fabric with photonic crystal structure color disclosed in Chinese patent CN 104233802B
Method, is mixed to form nano-composite emulsion, by silk fabric by monodispersed polystyrene microsphere emulsion and TiO 2 sol
It is immersed, obtains the silk fabric with photonic crystal structure color.The method is by being formed nanosphere on the surface of fabric
Schemochrome, gives fabric color in the case of not using chemical dye, but its color is fixed, the nanometer of fabric face attachment
Combine not tight between ball thin film, be easily subject to destroy, and the use of fabric is the most restricted.
Nano microsphere is combined by the present invention with polymer phase, utilizes pressurization and vacuum pumping technology, by Nano microsphere in polymerization
In thing, arrangement forms close regular texture, manifests schemochrome, and this schemochrome is because of strong containing polymer stress-bearing capability, Er Qieke
Along with the situation turn colors of stress, there is certain market prospect.
Summary of the invention
The technical problem to be solved in the present invention be to provide a kind of rubber coating fabric based on Nano microsphere and polymer and
Its preparation method, employing elastic fabric is as base fabric, by the polymer-coated containing nano pipe/polyhenylethylene acrylic microspheres to elastic
The surface of fabric, by extruding evacuation, curing molding, obtains rubber coating fabric based on Nano microsphere and polymer.Should
Rubber coating fabric based on Nano microsphere and polymer prepared by method can change fabric according to the different of pulling force suffered by fabric
Color.
For solving above-mentioned technical problem, the technical scheme is that
A kind of rubber coating fabric based on Nano microsphere and polymer, described based on Nano microsphere with the rubber of polymer
Coated fabric includes that base fabric and coating, described base fabric are elastic fabric, and described coating is elastic coating, and described elastic fabric is machine
Fabric, described elastic fabric is made up of elastic fiber, and described elastic coating includes Nano microsphere, polymer and auxiliary agent, described in receive
Meter Wei Qiu is self-assembly of regular texture in the polymer.
Preferred as technique scheme, described Nano microsphere is polystyrene acrylic acid microsphere, and polymer includes gathering
Vinyl alcohol and polyacrylic acid, auxiliary agent includes attapulgite, silicone rubber, glycerol and cross-linking agent.
The present invention also provides for the preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer, including following
Step:
(1) using elastic fiber as raw material, using plain weave structure as fabric structure, weaving forms base fabric, by base fabric
The base fabric of pretreatment is obtained after plasma low temperature processes；
(2) polyvinyl alcohol, polyacrylic acid, attapulgite, silicone rubber and glycerol being added in deionized water, high-speed stirred obtains
To polymer, then nano pipe/polyhenylethylene acrylic microspheres is poured in polymer, grind, bleed, add cross-linking agent, mixing
Grind, form coating mix；
(3) coating mix prepared by step (2) is coated on the base fabric upper surface of pretreatment prepared by step (1), squeezes
Pressure, bleeds, and curing molding obtains rubber coating fabric based on Nano microsphere and polymer.
Preferred as technique scheme, in described step (1), described elastic fiber is polyurethane elastomeric fiber, PTT
Fiber or PBT fiber.
Preferred as technique scheme, in described step (1), the condition that plasma low temperature processes is: at air
Under atmosphere, with Power Processing 30-50s of 250-300W.
Preferred as technique scheme, in described step (2), the component in coating mix, by weight, bag
Include: polyvinyl alcohol 30-50 part, polyacrylic acid 20-40 part, attapulgite 10-20 part, silicone rubber 5-15 part, glycerol 8-16 part, receive
Rice polystyrene acrylic acid microsphere 15-25 part, cross-linking agent 5-10 part, deionized water 40-80 part.
Preferred as technique scheme, in described step (2), cross-linking agent is Ammonium persulfate..
Preferred as technique scheme, in described step (2), the particle diameter 200-250 mesh of coating mix.
Preferred as technique scheme, in described step (3), the technique of extruding is: by the upper table of coating mix
The lower surface of face and base fabric is coated with polytetrafluoroethylene film respectively, then clamps, under the pressure of 0.3-0.5MPa with clamping plate
Evacuation 10-30min.
Preferred as technique scheme, in described step (3), the temperature of curing molding is 100-120 DEG C, and the time is
10-15min。
Compared with prior art, the method have the advantages that
(1) base fabric of rubber coating fabric based on Nano microsphere and polymer prepared by the present invention is for by elastic fiber system
Standby fabric, elastic fiber optimization polyurethane elastic fiber, ptt fiber or PBT fiber, the percentage elongation of fiber is higher than 300%,
Can give the telescopicing performance that base fabric is excellent, and the organizational structure of fabric uses plain weave, fabric face is steady, is conducive to
The attachment of coating.
(2) coating of rubber coating fabric based on Nano microsphere and polymer prepared by the present invention includes nanometer polyphenyl second
Alkene acrylic microspheres, the outward appearance of nano pipe/polyhenylethylene acrylic microspheres in the most spherical, good dispersion, surface various active base
Group, can be self-assembly of regular structure, and be gathered in the polymer by nano pipe/polyhenylethylene acrylic microspheres by pressurization and air extracting
Close and form regular structure, manifest schemochrome, it is to avoid use dyestuff, and the structure between nano pipe/polyhenylethylene acrylic microspheres
Fix and be completely embedded, then by the case of certain external force, the gap of schemochrome changes, and shows different schemochromes.
(3) coating of rubber coating fabric based on Nano microsphere and polymer prepared by the present invention include polyvinyl alcohol and
Polyacrylic acid, both of which is excellent spinning sizing agent, has the filming performance of excellence, and between fabric, binding strength is tight, logical
Cross attapulgite, silicone rubber, glycerol and Ammonium persulfate., make the stability of coating, film property, viscosity and humidity more stable, have
It is beneficial to polymer coating and is homogeneously applied to the upper surface of base fabric.
(4) present invention uses extruding evacuation and the method being heating and curing to be combined tightly with elastic base fabric by polymer coating
Close, reduce the air between polymer coating itself and polymer coating and elastic base fabric, reduce air and polymer is coated with
The impact of Rotating fields color, increases color fastness.
(5) color of rubber coating fabric based on Nano microsphere and polymer prepared by the present invention is by polymer coating
Schemochrome manifests, it is to avoid use conventional chemical dye, and containing polymer in the gap of schemochrome, the existence of polymer can make
The sound construction of self assembly, has certain load ability, and color fastness is good, and when elastic fabric under tension, schemochrome
Also can show different color, add the interest of fabric and intelligent, be conducive to applying to intelligence textile garment or
Person's furnishing fields.
Detailed description of the invention
The present invention is described in detail, in illustrative examples and the explanation of this present invention below in conjunction with specific embodiment
It is used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1:
(1) using polyurethane elastomeric fiber as raw material, base fabric is formed using plain weave structure as fabric structure, weaving,
By base fabric under air atmosphere, obtain the base fabric of pretreatment with power plasma K cryogenic treatment 30s of 250W.
(2) by weight, by the polyvinyl alcohol of 30 parts, the polyacrylic acid of 20 parts, the attapulgite of 10 parts, the silicon of 5 parts
The glycerol of rubber and 8 parts adds in the deionized water of 40 parts, and high-speed stirred obtains polymer, is then 20nm by the particle diameter of 15 parts
Nano pipe/polyhenylethylene acrylic microspheres pour in polymer, grind, bleed, add the Ammonium persulfate. cross-linking agent of 5 parts, mixing
Grind, form the coating mix that particle diameter is 200 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 10min under the pressure of 0.3MPa, then
Curing molding 10min at 100 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 2:
(1) using PTT elastic fiber as raw material, using plain weave structure as fabric structure, weaving forms base fabric, by base
Cloth, under air atmosphere, obtains the base fabric of pretreatment with power plasma K cryogenic treatment 50s of 300W.
(2) by weight, by the polyvinyl alcohol of 50 parts, the polyacrylic acid of 40 parts, the attapulgite of 20 parts, the silicon of 15 parts
The glycerol of rubber and 16 parts adds in the deionized water of 80 parts, and high-speed stirred obtains polymer, then by the particle diameter of 25 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 100nm is poured in polymer, grinds, bleeds, and adds the Ammonium persulfate. crosslinking of 10 parts
Agent, mixed grinding, form the coating mix that particle diameter is 250 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 30min under the pressure of 0.5MPa, then
Curing molding 15min at 120 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 3:
(1) using person's PBT elastic fiber as raw material, base fabric is formed using plain weave structure as fabric structure, weaving, will
Base fabric, under air atmosphere, obtains the base fabric of pretreatment with power plasma K cryogenic treatment 40s of 280W.
(2) by weight, by the polyvinyl alcohol of 45 parts, the polyacrylic acid of 25 parts, the attapulgite of 15 parts, the silicon of 10 parts
The glycerol of rubber and 12 parts adds in the deionized water of 45 parts, and high-speed stirred obtains polymer, then by the particle diameter of 20 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 80nm is poured in polymer, grinds, bleeds, add the Ammonium persulfate. cross-linking agent of 7 parts,
Mixed grinding, forms the coating mix that particle diameter is 220 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 20min under the pressure of 0.4MPa, then
Curing molding 12min at 110 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 4:
(1) using polyurethane elastomeric fiber as raw material, base fabric is formed using plain weave structure as fabric structure, weaving,
By base fabric under air atmosphere, obtain the base fabric of pretreatment with power plasma K cryogenic treatment 40s of 270W.
(2) by weight, by the polyvinyl alcohol of 40 parts, the polyacrylic acid of 30 parts, the attapulgite of 20 parts, the silicon of 12 parts
The glycerol of rubber and 13 parts adds in the deionized water of 65 parts, and high-speed stirred obtains polymer, then by the particle diameter of 21 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 50nm is poured in polymer, grinds, bleeds, add the Ammonium persulfate. cross-linking agent of 6 parts,
Mixed grinding, forms the coating mix that particle diameter is 250 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 15min under the pressure of 0.4MPa, then
Curing molding 11min at 100 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 5:
(1) using polyurethane elastomeric fiber as raw material, base fabric is formed using plain weave structure as fabric structure, weaving,
By base fabric under air atmosphere, obtain the base fabric of pretreatment with power plasma K cryogenic treatment 30s of 300W.
(2) by weight, by the polyvinyl alcohol of 30 parts, the polyacrylic acid of 40 parts, the attapulgite of 20 parts, the silicon of 5 parts
The glycerol of rubber and 16 parts adds in the deionized water of 40 parts, and high-speed stirred obtains polymer, then by the particle diameter of 25 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 80nm is poured in polymer, grinds, bleeds, add the Ammonium persulfate. cross-linking agent of 5 parts,
Mixed grinding, forms the coating mix that particle diameter is 250 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 30min under the pressure of 0.3MPa, then
Curing molding 15min at 100 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 6:
(1) using PTT elastic fiber as raw material, using plain weave structure as fabric structure, weaving forms base fabric, by base
Cloth, under air atmosphere, obtains the base fabric of pretreatment with power plasma K cryogenic treatment 30s of 300W.
(2) by weight, by the polyvinyl alcohol of 40 parts, the polyacrylic acid of 30 parts, the attapulgite of 10 parts, the silicon of 8 parts
The glycerol of rubber and 8 parts adds in the deionized water of 80 parts, and high-speed stirred obtains polymer, is then 40nm by the particle diameter of 25 parts
Nano pipe/polyhenylethylene acrylic microspheres pour in polymer, grind, bleed, add the Ammonium persulfate. cross-linking agent of 5 parts, mixing
Grind, form the coating mix that particle diameter is 210 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 15min under the pressure of 0.5MPa, then
Curing molding 10min at 100 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 7:
(1) using PBT elastic fiber as raw material, using plain weave structure as fabric structure, weaving forms base fabric, by base
Cloth, under air atmosphere, obtains the base fabric of pretreatment with power plasma K cryogenic treatment 30s of 280W.
(2) by weight, by the polyvinyl alcohol of 40 parts, the polyacrylic acid of 30 parts, the attapulgite of 15 parts, the silicon of 8 parts
The glycerol of rubber and 10 parts adds in the deionized water of 70 parts, and high-speed stirred obtains polymer, then by the particle diameter of 15 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 30nm is poured in polymer, grinds, bleeds, add the Ammonium persulfate. cross-linking agent of 5 parts,
Mixed grinding, forms the coating mix that particle diameter is 250 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 15min under the pressure of 0.45MPa, then
Curing molding 11min at 110 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
Embodiment 8:
(1) using polyurethane elastomeric fiber as raw material, base fabric is formed using plain weave structure as fabric structure, weaving,
By base fabric under air atmosphere, obtain the base fabric of pretreatment with power plasma K cryogenic treatment 30s of 250W.
(2) by weight, by the polyvinyl alcohol of 40 parts, the polyacrylic acid of 40 parts, the attapulgite of 10 parts, the silicon of 8 parts
The glycerol of rubber and 13 parts adds in the deionized water of 60 parts, and high-speed stirred obtains polymer, then by the particle diameter of 25 parts is
The nano pipe/polyhenylethylene acrylic microspheres of 80nm is poured in polymer, grinds, bleeds, add the Ammonium persulfate. cross-linking agent of 8 parts,
Mixed grinding, forms the coating mix that particle diameter is 200 mesh.
(3) coating mix is coated on the base fabric upper surface of pretreatment, by the upper surface of coating mix and base fabric
Lower surface is coated with polytetrafluoroethylene film respectively, then clamps with clamping plate, evacuation 15min under the pressure of 0.35MPa, then
Curing molding 10min at 120 DEG C, obtains rubber coating fabric based on Nano microsphere and polymer.
After testing, the color characteristics of rubber coating fabric based on Nano microsphere and polymer prepared by embodiment 1-8
Result is as follows:
As seen from the above table, the color even of rubber coating fabric based on Nano microsphere and polymer prepared by the present invention,
After stress, color can change, and color fastness is preferable.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for limiting the present invention.Any ripe
Above-described embodiment all can be modified under the spirit and the scope of the present invention or change by the personage knowing this technology.Cause
This, have usually intellectual such as complete with institute under technological thought without departing from disclosed spirit in art
All equivalences become are modified or change, and must be contained by the claim of the present invention.
Claims (10)
1. a rubber coating fabric based on Nano microsphere and polymer, it is characterised in that: described based on Nano microsphere with poly-
The rubber coating fabric of compound includes that base fabric and coating, described base fabric are elastic fabric, and described coating is elastic coating, described bullet
Property fabric is woven fabric, and described elastic fabric is made up of elastic fiber, and described elastic coating includes Nano microsphere, polymer and helps
Agent, described Nano microsphere is self-assembly of regular texture in the polymer.
A kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 1, it is characterised in that: institute
Stating Nano microsphere is polystyrene acrylic acid microsphere, and described polymer includes that polyvinyl alcohol and polyacrylic acid, described auxiliary agent include
Attapulgite, silicone rubber, glycerol and cross-linking agent.
3. the preparation method of a rubber coating fabric based on Nano microsphere and polymer, it is characterised in that include following step
Rapid:
(1) using elastic fiber as raw material, form base fabric using plain weave structure as fabric structure, weaving, by base fabric through etc.
The base fabric of pretreatment is obtained after gas ions K cryogenic treatment；
(2) polyvinyl alcohol, polyacrylic acid, attapulgite, silicone rubber and glycerol being added in deionized water, high-speed stirred is gathered
Compound, then pours in polymer by nano pipe/polyhenylethylene acrylic microspheres, grinds, bleeds, add cross-linking agent, and mixing is ground
Mill, forms coating mix；
(3) coating mix prepared by step (2) is coated on the base fabric upper surface of pretreatment prepared by step (1), extruding, take out
Gas, curing molding, obtain rubber coating fabric based on Nano microsphere and polymer.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
Being characterised by: in described step (1), described elastic fiber is polyurethane elastomeric fiber, ptt fiber or PBT fiber.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
Being characterised by: in described step (1), the condition that plasma low temperature processes is: under air atmosphere, with the power of 250-300W
Process 30-50s.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
It is characterised by: in described step (2), the component in coating mix, by weight, including: polyvinyl alcohol 30-50 part, poly-
Acrylic acid 20-40 part, attapulgite 10-20 part, silicone rubber 5-15 part, glycerol 8-16 part, nano pipe/polyhenylethylene acrylic microspheres
15-25 part, cross-linking agent 5-10 part, deionized water 40-80 part.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
Being characterised by: in described step (2), cross-linking agent is Ammonium persulfate..
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
It is characterised by: in described step (2), the particle diameter 200-250 mesh of coating mix.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
Being characterised by: in described step (3), the technique of extruding is: the upper surface of coating mix and the lower surface of base fabric are used respectively
Polytetrafluoroethylene film is coated with, and then clamps with clamping plate, evacuation 10-30min under the pressure of 0.3-0.5MPa.
The preparation method of a kind of rubber coating fabric based on Nano microsphere and polymer the most according to claim 3, its
Being characterised by: in described step (3), the temperature of curing molding is 100-120 DEG C, the time is 10-15min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610838894.0A CN106245347B (en) | 2016-09-21 | 2016-09-21 | A kind of rubber coating fabric based on nanoparticle and polymer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610838894.0A CN106245347B (en) | 2016-09-21 | 2016-09-21 | A kind of rubber coating fabric based on nanoparticle and polymer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106245347A true CN106245347A (en) | 2016-12-21 |
| CN106245347B CN106245347B (en) | 2018-03-23 |
Family
ID=57600410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610838894.0A Active CN106245347B (en) | 2016-09-21 | 2016-09-21 | A kind of rubber coating fabric based on nanoparticle and polymer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106245347B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104233802A (en) * | 2014-09-28 | 2014-12-24 | 苏州印丝特纺织数码科技有限公司 | Preparation method of natural silk fabric with photonic crystal structure color |
| CN104562679A (en) * | 2014-12-29 | 2015-04-29 | 浙江理工大学 | Preparation method of colorful textile in photonic crystal structure capable of regulating and controlling hydrophobicity |
| CN105182567A (en) * | 2015-09-24 | 2015-12-23 | 复旦大学 | Material with schemochrome and capable of being induced to change color through stress and preparation method of material |
-
2016
- 2016-09-21 CN CN201610838894.0A patent/CN106245347B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104233802A (en) * | 2014-09-28 | 2014-12-24 | 苏州印丝特纺织数码科技有限公司 | Preparation method of natural silk fabric with photonic crystal structure color |
| CN104562679A (en) * | 2014-12-29 | 2015-04-29 | 浙江理工大学 | Preparation method of colorful textile in photonic crystal structure capable of regulating and controlling hydrophobicity |
| CN105182567A (en) * | 2015-09-24 | 2015-12-23 | 复旦大学 | Material with schemochrome and capable of being induced to change color through stress and preparation method of material |
Non-Patent Citations (1)
| Title |
|---|
| 袁伟: "结构色纤维/面料的制备及其光学性质研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106245347B (en) | 2018-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109629240B (en) | preparation method and application of color-containing fabric coating agent | |
| WO2018227751A1 (en) | Super-hydrophobic fabric and preparation method therefor | |
| Song et al. | Green and efficient inkjet printing of cotton fabrics using reactive dye@ copolymer nanospheres | |
| CN107254248A (en) | Multi-functional high-strength compound textile coating agent, coating and preparation method and application | |
| CN103554346B (en) | Graphene oxide modified polyacrylate prepares the method for pigment printing binding agent | |
| CN108855803A (en) | A kind of preparation method of schemochrome film | |
| CN103409801A (en) | Preparation method of high-strength crosslinked polymer photonic crystal film | |
| CN105113247B (en) | A kind of coating solution of emulsion particle antireflective and its preparation method and application | |
| CN112778446B (en) | Preparation method of cationic color copolymer microspheres | |
| Diaa et al. | Printing wool fabrics with natural dyes curcuma and alkanet (a critique) | |
| Ragheb et al. | Development of printing natural fabrics with curcuma natural dye via nanotechnology | |
| Hu et al. | Development of photochromic wood material by microcapsules | |
| CN106245347A (en) | A kind of rubber coating fabric based on Nano microsphere and polymer and preparation method thereof | |
| CN110080011A (en) | A kind of functionalization schemochrome dyestuff and its preparation and application | |
| Li et al. | Facile and binder-free fabrication of deep colors on cotton fabrics with hand-feel enhancement via screen printing | |
| CN102108110A (en) | Method for preparing acrylate printing adhesive | |
| CN116814280A (en) | Preparation of anti-ultraviolet emulsifier and application of anti-ultraviolet emulsifier in aspect of color-changing microcapsules | |
| CN109232794B (en) | Anti-pinhole-down acrylic ester coating emulsion, coating adhesive and preparation method thereof | |
| CN104862980A (en) | Preparation method and apparition of wet rubbing fastness improver containing copper microcapsules | |
| CN114775306B (en) | Preparation method of polyethyleneimine composite dye nanospheres | |
| Fu et al. | Effect of pigment particle character on dyeing performance of cotton fabrics | |
| CN114539806B (en) | Preparation method of nano-coated disperse dye | |
| CN109680516A (en) | A kind of nanometer fibroin base microbe colouring substance particle and preparation method thereof that graphene is modified | |
| CN103485202A (en) | Dyeing process of polyester fabric by using nano-carbon black | |
| CN115323802A (en) | Polyamide coating slurry, preparation method and process for preparing polyamide coated fabric for printing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhou Kaifeng Inventor before: Wang Wenqing |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180212 Address after: No. 24, Tangjiao Road, Tangjiao, Changping Town, Dongguan, Guangdong Applicant after: DONGGUAN AOXIAO WEAVING CO.,LTD. Address before: 523000 Guangdong province Dongguan City Songshan Lake high tech Industrial Zone Building 406 industrial development productivity Applicant before: Dongguan Lianzhou Intellectual Property Operation Management Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: 523000 No. 223, Zhenxing West Road, Changping Town, Dongguan City, Guangdong Province Patentee after: DONGGUAN AOXIAO WEAVING CO.,LTD. Address before: No. 24, Tangjiao Road, Tangjiao Village, Changping Town, Dongguan, Guangdong 523578 Patentee before: DONGGUAN AOXIAO WEAVING CO.,LTD. |