CN106245018A - Efficient metal antirust agent - Google Patents
Efficient metal antirust agent Download PDFInfo
- Publication number
- CN106245018A CN106245018A CN201610633585.XA CN201610633585A CN106245018A CN 106245018 A CN106245018 A CN 106245018A CN 201610633585 A CN201610633585 A CN 201610633585A CN 106245018 A CN106245018 A CN 106245018A
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- CN
- China
- Prior art keywords
- parts
- antirust agent
- efficient metal
- metal antirust
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
- C23C22/367—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing alkaline earth metal cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Detergent Compositions (AREA)
Abstract
A kind of efficient metal antirust agent that the present invention provides, in parts by mass, including following component: phosphoric acid 35 45 parts, zinc oxide 14 parts, sodium gluconate 5 10 parts, NaF1 3 parts, 13 parts of calcium chloride, TX 10 phosphate ester 36 parts, defoamer 12 parts, surplus water is supplied, and making gross mass part is 100 parts.The effect that this efficient metal antirust agent has dedusting while cleaning rust cleaning, oil removing is cleaned, pretreatment procedure without carry out eliminating rust front dedusting, oil removing, and raw material of the present invention composition is simple, raw material sources are wide, do not contain heavy metal element and yttrium, production cost is low, compared with the commercially available prod of external import, has the performance of excellence in rust cleaning effect especially.The particularly reduction on cost, creates great market competition advantage for enterprise.
Description
Technical field
The present invention relates to a kind of metal conditioner, be specifically related to a kind of efficient metal antirust agent.
Background technology
The derusting of metallic article, antirust problem are always a major issue of relevant surfaces treatment industry technical staff.
It addition, as metallic article, some equipment construction bad environments, long-pending to have dust, dirt be the most universal, and engineering goods itself
It is also required to lubricating oil protection.Therefore, antirust agent as can not deoiling, be necessary in use, first to dust, oil stain etc.
Carrying out pre-treatment, to strengthen the penetration of rust remover, but this has been consequently increased cost and difficulty that enterprise is cleaned, time-consuming, take
Power, and, in implementation process for some large-scale workpiece or equipment, it is difficult to obtain preferable rust-proof effect.In early days special
Profit as the patent of invention of Application No. CN01131523.7 disclose one rust-eliminating and rust-preventing liquid, it include phosphoric acid, potassium dichromate,
Potassium nitrate, zinc oxide, sodium phosphate, sodium molybdate, hydroxymethyl cellulose.But containing poisonous raw materials for production heavy metallic salt in this patent
(chromium), it is impossible to grease proofing decontamination, penetration is not strong, has multiple raw material can not reach more preferably effect in component.
Along with the improvement of technology, Chinese patent CN201410352623.5 discloses a kind of antirust agent, by following number
Composition of raw materials component composition: 20-25 part hydrochloric acid, 23-26 part acetic acid, 20-22 part tartaric acid, 16-18 part carboxylic acid, 10-11 part
Hydrated ferric oxide., 11-13 part copper sulfate, 12-13 part aluminum sulfate, 5-6 part gelatin, 6-10 part silicone oil, 8-10 part Melanteritum powder, 3-5 part
Zinc oxide, 5-8 part calcium phosphate, 6-8 part tertiary sodium phosphate, 3-5 part zinc hydroxide, 4-5 part potassium sorbate, 6-8 part carboxymethyl cellulose
Element sodium, 6-7 part glycerol, 6-12 part succinic acid, 2-6 part methanol, 3-5 part thiourea dioxide, 2-8 part carbamide, 6-8 part sulfur are for second
Amide, 5-7 part fatty alcohol-polyoxyethylene ether, 7-8 part cocoanut fatty acid diethanolamide, 10-12 part Nonyl pheno
Ether, although this art solutions does not contains heavy metal element, but raw material composition complexity, cause cost of material and production cost
High.
Summary of the invention
For the problems referred to above, it is an object of the invention to provide a kind of efficient metal antirust agent, have and cleaning the same of rust cleaning
Time the effect cleaned of dedusting, oil removing, it is not necessary to the pretreatment procedure of carry out eliminating rust front dedusting, oil removing, and raw material of the present invention composition
Simply, raw material sources are wide, do not contain heavy metal element and yttrium, and production cost is low, with the commercially available product of external import
Condition ratio, has the performance of excellence in rust cleaning effect especially.
In order to realize the technical purpose of the present invention, the present invention adopts the following technical scheme that.
Efficient metal antirust agent, in parts by mass, including following component: phosphoric acid 35-45 part, zinc oxide 1-4 part, glucose
Acid sodium 5-10 part, NaF1-3 part, calcium chloride 1-3 part, TX-10 phosphate ester 3-6 part, defoamer 1-2 part, surplus water is supplied, and makes
Gross mass part is 100 parts.
Preferably, efficient metal antirust agent, in parts by mass, including following component: phosphatase 24 0 part, zinc oxide 2 parts, Fructus Vitis viniferae
Sodium saccharate 6 parts, NaF1 part, 2 parts of calcium chloride, TX-10 phosphate ester 5 parts, defoamer 1 part, surplus water is supplied, and makes gross mass part be
100 parts.
Preferably, efficient metal antirust agent, in parts by mass, including following component: phosphoric acid 35 parts, zinc oxide 1 part, Fructus Vitis viniferae
Sodium saccharate 5 parts, NaF2 part, 3 parts of calcium chloride, TX-10 phosphate ester 6 parts, defoamer 1 part, surplus water is supplied, and makes gross mass part be
100 parts.
Preferably, efficient metal antirust agent, in parts by mass, including following component: phosphatase 24 5 parts, zinc oxide 4 parts, Fructus Vitis viniferae
Sodium saccharate 10 parts, NaF3 part, 1 part of calcium chloride, TX-10 phosphate ester 3 parts, defoamer 2 parts, surplus water is supplied, and makes gross mass part
It it is 100 parts.
Preferably, the particle mean size of described zinc oxide is 1-5 micron.
Preferably, described defoamer is polyoxyethylene polyoxypropylene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, gathers
At least one in oxypropylene glycerin ether and polyoxyethylene polyoxypropylene glycerin ether.
The invention has the beneficial effects as follows: the invention provides a kind of efficient metal antirust agent, compared with prior art, have
Following advantage.A kind of efficient metal antirust agent that the present invention provides, has dedusting while cleaning rust cleaning, the effect of oil removing cleaning
Really, it is not necessary to the pretreatment procedure of carry out eliminating rust front dedusting, oil removing, and raw material of the present invention composition is simple, and raw material sources are wide, do not contain
Having heavy metal element and yttrium, production cost is low, compared with the commercially available prod of external import, in rust cleaning effect more
It is the performance having excellence, creates great market competition advantage for enterprise.
Detailed description of the invention
In order to be better understood from the present invention, below in conjunction with specific embodiment, invention is described in detail.
Embodiment 1
Efficient metal antirust agent, in parts by mass, including following component: phosphoric acid 35-45 part, zinc oxide 1-4 part, glucose
Acid sodium 5-10 part, NaF1-3 part, calcium chloride 1-3 part, TX-10 phosphate ester 3-6 part, defoamer 1-2 part, surplus water is supplied, and makes
Gross mass part is 100 parts.
Embodiment 2
Efficient metal antirust agent, in parts by mass, including following component: phosphatase 24 0 part, zinc oxide 2 parts, sodium gluconate 6
Part, NaF1 part, 2 parts of calcium chloride, TX-10 phosphate ester 5 parts, defoamer 1 part, surplus water is supplied, and making gross mass part is 100 parts.
Embodiment 3
Efficient metal antirust agent, in parts by mass, including following component: phosphoric acid 35 parts, zinc oxide 1 part, sodium gluconate 5
Part, NaF2 part, 3 parts of calcium chloride, TX-10 phosphate ester 6 parts, defoamer 1 part, surplus water is supplied, and making gross mass part is 100 parts.
Embodiment 4
Efficient metal antirust agent, in parts by mass, including following component: phosphatase 24 5 parts, zinc oxide 4 parts, sodium gluconate
10 parts, NaF3 part, 1 part of calcium chloride, TX-10 phosphate ester 3 parts, defoamer 2 parts, surplus water is supplied, and making gross mass part is 100
Part.
Abluent prepared in pending workpiece embodiment 1-4 will be carried out, to scavenging period used by it, go
The aspects such as dirty rate, usage amount, cleaning cost, compare with commercially available prod, and result is as shown in table 1.
Note: above-mentioned raw materials cost is to calculate with 100wt% concentration in embodiment, time actually used, by mass percentage,
Antirust agent is diluted to the concentration of 6%, is i.e. watered 94%.
According to upper table data it is apparent that a kind of efficient metal antirust agent of present invention offer, have and remove in cleaning
The effect that dedusting while rust, oil removing are cleaned, it is not necessary to the pretreatment procedure of carry out eliminating rust front dedusting, oil removing, and the present invention is former
Material composition is simple, and raw material sources are wide, do not contain heavy metal element and yttrium, and production cost is low, with external import
Commercially available prod is compared, and has the performance of excellence in rust cleaning effect especially.Particularly the reduction on cost, creates for enterprise
Market competition advantage greatly.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described.The technical staff of the industry should
Understanding, above-described embodiment limits the present invention the most in any form, and the mode of all employing equivalents or equivalent transformation is obtained
Technical scheme, all falls within protection scope of the present invention.
Claims (6)
1. efficient metal antirust agent, it is characterised in that in parts by mass, including following component: phosphoric acid 35-45 part, zinc oxide 1-4
Part, sodium gluconate 5-10 part, NaF1-3 part, calcium chloride 1-3 part, TX-10 phosphate ester 3-6 part, defoamer 1-2 part, surplus is used
Water is supplied, and making gross mass part is 100 parts.
Efficient metal antirust agent the most according to claim 1, it is characterised in that in parts by mass, including following component: phosphorus
Acid 40 parts, zinc oxide 2 parts, sodium gluconate 6 parts, NaF1 part, 2 parts of calcium chloride, TX-10 phosphate ester 5 parts, defoamer 1 part, surplus
Supplying with water, making gross mass part is 100 parts.
Efficient metal antirust agent the most according to claim 1, it is characterised in that in parts by mass, including following component: phosphorus
Acid 35 parts, zinc oxide 1 part, sodium gluconate 5 parts, NaF2 part, 3 parts of calcium chloride, TX-10 phosphate ester 6 parts, defoamer 1 part, surplus
Supplying with water, making gross mass part is 100 parts.
Efficient metal antirust agent the most according to claim 1, it is characterised in that in parts by mass, including following component: phosphorus
Acid 45 parts, zinc oxide 4 parts, sodium gluconate 10 parts, NaF3 part, 1 part of calcium chloride, TX-10 phosphate ester 3 parts, defoamer 2 parts, remaining
Amount water is supplied, and making gross mass part is 100 parts.
5. according to the efficient metal antirust agent described in any one of claim 1-4, it is characterised in that: the average particle of described zinc oxide
Degree is 1-5 micron.
Efficient metal antirust agent the most according to claim 5, it is characterised in that: described defoamer is polyoxyethylene polyoxy third
In alkene tetramethylolmethane ether, polyoxyethylene polyoxy propanol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether
At least one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610633585.XA CN106245018A (en) | 2016-08-03 | 2016-08-03 | Efficient metal antirust agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610633585.XA CN106245018A (en) | 2016-08-03 | 2016-08-03 | Efficient metal antirust agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106245018A true CN106245018A (en) | 2016-12-21 |
Family
ID=58079239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610633585.XA Pending CN106245018A (en) | 2016-08-03 | 2016-08-03 | Efficient metal antirust agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN106245018A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566301A (en) * | 2003-06-25 | 2005-01-19 | 蓝星清洗工程有限公司 | Three-in-one cleaning agent |
| CN102181854A (en) * | 2011-04-19 | 2011-09-14 | 罗森鹤 | Environment-friendly steel water-based rust inhibitor and preparation method thereof |
| CN103046036A (en) * | 2012-12-06 | 2013-04-17 | 安徽未来表面技术有限公司 | Metal derusting and antirusting agent and preparation method of metal derusting and antirusting agent |
| CN105483728A (en) * | 2015-11-25 | 2016-04-13 | 沈阳黎明航空发动机(集团)有限责任公司 | Long-life aluminum and alloy oil removing activating solution and application |
-
2016
- 2016-08-03 CN CN201610633585.XA patent/CN106245018A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566301A (en) * | 2003-06-25 | 2005-01-19 | 蓝星清洗工程有限公司 | Three-in-one cleaning agent |
| CN102181854A (en) * | 2011-04-19 | 2011-09-14 | 罗森鹤 | Environment-friendly steel water-based rust inhibitor and preparation method thereof |
| CN103046036A (en) * | 2012-12-06 | 2013-04-17 | 安徽未来表面技术有限公司 | Metal derusting and antirusting agent and preparation method of metal derusting and antirusting agent |
| CN105483728A (en) * | 2015-11-25 | 2016-04-13 | 沈阳黎明航空发动机(集团)有限责任公司 | Long-life aluminum and alloy oil removing activating solution and application |
Non-Patent Citations (1)
| Title |
|---|
| 唐劲松等: "《食品添加剂应用与检测技术》", 28 February 2012 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161221 |