CN106244798A - A kind of method utilizing sintering process Treatment of Wastewater in Coking - Google Patents

A kind of method utilizing sintering process Treatment of Wastewater in Coking Download PDF

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Publication number
CN106244798A
CN106244798A CN201610702754.0A CN201610702754A CN106244798A CN 106244798 A CN106244798 A CN 106244798A CN 201610702754 A CN201610702754 A CN 201610702754A CN 106244798 A CN106244798 A CN 106244798A
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CN
China
Prior art keywords
mixing granulation
time
waste water
coking
sintering
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610702754.0A
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Chinese (zh)
Inventor
周小辉
张庆
王延平
张英
梁栋
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Shandong Iron and Steel Group Co Ltd SISG
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Shandong Iron and Steel Group Co Ltd SISG
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Application filed by Shandong Iron and Steel Group Co Ltd SISG filed Critical Shandong Iron and Steel Group Co Ltd SISG
Priority to CN201610702754.0A priority Critical patent/CN106244798A/en
Publication of CN106244798A publication Critical patent/CN106244798A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24Binding; Briquetting ; Granulating

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention provides a kind of method utilizing sintering process Treatment of Wastewater in Coking;The method comprises the following steps: step 1 is by sintering mixing material, and flux and coke powder or coal dust proportionally carry out dispensing;Dispensing after proportioning is good in step 1 is delivered to the first cylindrical mixer by step 2, sprays coking chemical waste water, carries out mixing granulation for the first time, obtains mixing granulation material for the first time;Described first time mixing granulation material in step 2 is delivered in the second cylindrical mixer by step 3, again sprays coking chemical waste water, carries out second time mixing granulation, obtains second time mixing granulation material;Control the total moisture content of described second time mixing granulation 5% 10%;Described second time mixing granulation material is carried out cloth and lights a fire by distributing device by step 4, carries out oxygen-enriched sintering simultaneously;Poisonous, difficult degradation Organic substance in coking chemical waste water described in step 5 passes through the high temperature produced in sintering process, cracks, aoxidizes, and generates non-toxic gas and enters sintering flue gas.

Description

A kind of method utilizing sintering process Treatment of Wastewater in Coking
Technical field
The present invention relates to metallurgical engineering technical field, particularly to a kind of side utilizing sintering process Treatment of Wastewater in Coking Method.
Background technology
Coking chemical waste water is always iron and steel enterprise's waste water control difficult problem, and at present, the discharge standard that Shandong Province newly performs is Below COD30ppm, enterprise by the way of biochemical treatment, then can not reach intended discharge standard.
There are some researches show, Organic substance contained in coking chemical waste water can decompose completely when 400 DEG C.At present, a patent: " a kind of Processes and apparatus utilizing converter dust-removing high-temperature flue gas pyrolysis coking chemical waste water " (application number or the patent No.: CN201410206286.9, applicant or patentee: Laiwu Iron & Steel Group Co., Ltd), its disclose the method use turn Stove high-temperature flue gas Treatment of Wastewater in Coking, but, Treatment of Wastewater in Coking amount is less, simultaneously need to catalyst and certain equipment are thrown Money, cost increases.
Summary of the invention
It is an object of the invention to, for solving the method for existing Treatment of Wastewater in Coking is existed drawbacks described above, the present invention Provide a kind of method utilizing sintering process Treatment of Wastewater in Coking;The method utilizes coking chemical waste water to have sticking feature, will It is applied to sintered compound granulation link, both can direct Treatment of Wastewater in Coking, save the cost of Treatment of Wastewater in Coking, be conducive to again The granulation of batch mixing, also a saving water resource simultaneously.The method comprises the following steps:
Step 1 is by sintering mixing material, and flux and coke powder or coal dust proportionally carry out dispensing;
Dispensing after proportioning is good in step 1 is delivered to the first cylindrical mixer by step 2, meanwhile, sprays coking and gives up Water, carries out mixing granulation for the first time in described first cylindrical mixer, obtains mixing granulation material for the first time;
Described first time mixing granulation material in step 2 is delivered in the second cylindrical mixer, meanwhile, again by step 3 Spray coking chemical waste water, described second cylindrical mixer carries out second time mixing granulation, obtain second time mixing granulation material;With Time, control the amount of coking chemical waste water, control the total moisture content of described second time mixing granulation material at 5%-10%;
Described second time mixing granulation material is carried out cloth and lights a fire by distributing device by step 4, carries out oxygen-enriched burning simultaneously Knot;
In coking chemical waste water described in step 5, Organic substance poisonous, difficult degradation passes through the high temperature of generation in sintering process, splits Solve, and aoxidize, generate non-toxic gas and enter sintering flue gas.Meanwhile, by sintering the high temperature sintering ore deposit of output, carry out crushing, Cooling processes.
Described coking chemical waste water, in sintering process, by utilizing the high temperature produced in sintering process, cracks, and oxygen Change, generate non-toxic gas and enter sintering flue gas, it is not necessary to realized by the technique of this high cost of biochemical treatment, protect Environment, reduces pollution level.
It is an advantage of the current invention that: on the basis of existing sintering process, will mixing granulation and second time mixing for the first time Water required in pelletization changes coking chemical waste water into, has saved water resource, solves iron and steel enterprise's coking chemical waste water and pollutes environment And use the high cost that brought of biochemical treatment and the problem for the treatment of effeciency difference;Make use of coking chemical waste water viscosity, enhance Sintered compound is pelletized, and improves the breathability of sintering process, adds the productivity of sintering deposit.The cracking of coking chemical waste water, aoxidizes institute The condition needed need not additionally use equipment and investment, at the ingenious high temperature utilizing generation in existing sintering process and oxidation environment Reason coking chemical waste water, reduces processing cost.
Accompanying drawing explanation
Fig. 1 present invention utilizes sintering process Treatment of Wastewater in Coking process chart
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail.
As it is shown in figure 1, the invention provides a kind of method utilizing sintering process Treatment of Wastewater in Coking;The method utilizes Jiao Change waste water and have sticking feature, be applied to sintered compound granulation link, both can directly Treatment of Wastewater in Coking, saving process The granulation of the cost of coking chemical waste water, the most beneficially batch mixing, also a saving water resource simultaneously.The method comprises the following steps:
Step 1 by Iron Ore Powder be in mass ratio 5% bar thick card powder, 18% bar coarse powder, 25%PB powder, 11% raise enlightening powder, 10% Sierra Leone powder, 11% return miscellaneous ore deposit, 10% prunus mume (sieb.) sieb.et zucc. Rhizoma Atractylodis Macrocephalae powder, 6% iron scale and 4% smelting waste steel composition sintering Mixing material, the quick lime flux of the 8% of mixing material quality and 5% coke powder of mixing material quality carry out mix;
Dispensing after proportioning is good in step 1 is delivered to the first cylindrical mixer by step 2, meanwhile, sprays coking and gives up Water, carries out mixing granulation for the first time in described first cylindrical mixer, obtains mixing granulation material for the first time;
Described first time mixing granulation in step 2 is delivered in the second cylindrical mixer, meanwhile, again by step 3 again Spray coking chemical waste water, described second cylindrical mixer carries out second time mixing granulation, obtain second time mixing granulation material;With Time, control the amount of coking chemical waste water, control the total moisture content of described second time mixing granulation material at 8%-9%;
Described second time mixing granulation material is carried out cloth and lights a fire by distributing device by step 4, carries out oxygen-enriched burning simultaneously Knot;
In coking chemical waste water described in step 5, Organic substance poisonous, difficult degradation passes through the high temperature of generation in sintering process, splits Solve, and aoxidize generation non-toxic gas entrance sintering flue gas, discharge through dedusting and desulfurization;Meanwhile, by sintering the height of output Temperature sintering deposit, carries out crushing, cooling processes.
Described coking chemical waste water, in sintering process, by utilizing the high temperature produced in sintering process, cracks, and oxygen Change, generate non-toxic gas and enter sintering flue gas, it is not necessary to realized by the technique of this high cost of biochemical treatment, protect Environment, reduces pollution level.
It should be noted last that, above example is only in order to illustrate technical scheme and unrestricted.Although ginseng According to embodiment, the present invention is described in detail, it will be understood by those within the art that, the technical side to the present invention Case is modified or equivalent, and without departure from the spirit and scope of technical solution of the present invention, it all should be contained in the present invention Right in the middle of.

Claims (1)

1. the method utilizing sintering process Treatment of Wastewater in Coking;It is characterized in that, the method comprises the following steps:
Step 1 is by sintering mixing material, and flux and coke powder or coal dust proportionally carry out dispensing;
Dispensing after proportioning is good in step 1 is delivered to the first cylindrical mixer by step 2, meanwhile, sprays coking chemical waste water, Described first cylindrical mixer carries out mixing granulation for the first time, obtains mixing granulation material for the first time;
Described first time mixing granulation material in step 2 is delivered in the second cylindrical mixer by step 3, again sprays meanwhile Coking chemical waste water, carries out second time mixing granulation in described second cylindrical mixer, obtains second time mixing granulation material;Meanwhile, Control the amount of coking chemical waste water, control the total moisture content of described second time mixing granulation material at 5%-10%;
Described second time mixing granulation material is carried out cloth and lights a fire by distributing device by step 4, carries out oxygen-enriched sintering simultaneously;
In coking chemical waste water described in step 5, Organic substance poisonous, difficult degradation passes through the high temperature of generation in sintering process, cracks, And aoxidize, generate non-toxic gas and enter sintering flue gas.
CN201610702754.0A 2016-08-22 2016-08-22 A kind of method utilizing sintering process Treatment of Wastewater in Coking Pending CN106244798A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106893857A (en) * 2017-02-16 2017-06-27 钢研晟华工程技术有限公司 A kind of method that sintering process reduces flue gas pollutant discharge
CN108929948A (en) * 2018-07-26 2018-12-04 上海慧安科技股份有限公司 A kind of iron ore mixing powder dropping sheet, synergy using Sierra Leone coarse powder
CN108929949A (en) * 2018-07-26 2018-12-04 上海慧安科技股份有限公司 It is a kind of using the broken drop of pelletizing this, the iron ore of synergy mix powder
CN108950190A (en) * 2018-07-26 2018-12-07 上海慧安科技股份有限公司 A kind of iron ore mixing powder dropping sheet, synergy using reduced iron powder
CN109292856A (en) * 2018-11-06 2019-02-01 杭州沁欣环保科技有限公司 A kind of device and method using sintering processes coking wastewater
CN109487077A (en) * 2018-11-27 2019-03-19 安徽工业大学 A method of based on coking wastewater denatured fuel emission reduction Ore Sintering Process NOx
CN117342718A (en) * 2023-09-27 2024-01-05 湖北金盛兰冶金科技有限公司 Coking wastewater reinforced granulating process method

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106893857A (en) * 2017-02-16 2017-06-27 钢研晟华工程技术有限公司 A kind of method that sintering process reduces flue gas pollutant discharge
CN108929948A (en) * 2018-07-26 2018-12-04 上海慧安科技股份有限公司 A kind of iron ore mixing powder dropping sheet, synergy using Sierra Leone coarse powder
CN108929949A (en) * 2018-07-26 2018-12-04 上海慧安科技股份有限公司 It is a kind of using the broken drop of pelletizing this, the iron ore of synergy mix powder
CN108950190A (en) * 2018-07-26 2018-12-07 上海慧安科技股份有限公司 A kind of iron ore mixing powder dropping sheet, synergy using reduced iron powder
CN109292856A (en) * 2018-11-06 2019-02-01 杭州沁欣环保科技有限公司 A kind of device and method using sintering processes coking wastewater
CN109292856B (en) * 2018-11-06 2023-11-21 杭州沁欣环保科技有限公司 Device and method for treating coking wastewater by utilizing sintering
CN109487077A (en) * 2018-11-27 2019-03-19 安徽工业大学 A method of based on coking wastewater denatured fuel emission reduction Ore Sintering Process NOx
CN117342718A (en) * 2023-09-27 2024-01-05 湖北金盛兰冶金科技有限公司 Coking wastewater reinforced granulating process method

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Application publication date: 20161221