CN106244270A - A kind of natural gas for cutting metal - Google Patents

A kind of natural gas for cutting metal Download PDF

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Publication number
CN106244270A
CN106244270A CN201610673452.5A CN201610673452A CN106244270A CN 106244270 A CN106244270 A CN 106244270A CN 201610673452 A CN201610673452 A CN 201610673452A CN 106244270 A CN106244270 A CN 106244270A
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CN
China
Prior art keywords
natural gas
ferrocene
tert
liquid phase
cutting metal
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CN201610673452.5A
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Chinese (zh)
Inventor
谢光玉
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Individual
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Individual
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Priority to CN201610673452.5A priority Critical patent/CN106244270A/en
Publication of CN106244270A publication Critical patent/CN106244270A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a kind of natural gas for cutting metal;It is higher than the natural gas of percentage by weight 95% including purity, accounts for aforementioned natural gas percentage by weight 0.3~the liquid phase Synergistic additives of 0.5%;Described liquid phase Synergistic additives includes following raw material: 200# solvent naphtha, acetylene, petroleum ether, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, isooctyl ester nitrate, dimethyl carbonate, tert-butyl group ferrocene or ferrocene, methyl tertiary butyl ether(MTBE) or octyl ferrocene, p-tert-Butylcatechol, azodiisobutyronitrile, polyethers;This is used for the natural gas cutting metal by adding a small amount of liquid phase Synergistic additives in natural gas, hence it is evident that improve ignition temperature and efficiency of combustion;The liquid phase Synergistic additives of the present invention is to the corrosivity of container is little and volatility good simultaneously.

Description

A kind of natural gas for cutting metal
Technical field
The present invention relates to a kind of natural gas for cutting metal;This combustion gas can be utilized for Metal Cutting metal, welding.
Background technology
In China's industrial combustion gas consumption, 70% is propane flammable gas and acetylene gas.Use pure acetylene gas to carbon steel cutting gold During genus, it is easily generated cutting shoulder and melts, the phenomenons such as dross is many and not easy cleaning, tangent plane differential hardening, make cutting smithcraft not Ideal, and use pure acetylene environment can cause the biggest pollution, not environmentally.During welding, need to polish, add and produce into This.Shipyard, coastal area has forbidden using acetylene at shipbuilding platform, uses other novel cutting metal gas instead, for many years Come the people have attempted to use other fuel instead acetylene as cutting metal gas, but due to other fuel such as natural gas, liquefaction The fuel ignition temperatures in oxygen such as oil gas, propane flammable gas, propylene gas, artificial coal gas, dimethyl ether are less than 2500 DEG C and cut Metal speeds is slow, undesirable directly as cutting metal gas, need to add perfect combustion catalizer basis gas is catalyzed, cracking, Combustion-supporting, change fuel gas buring mode, thus promote flame temperature, it is allowed to burned flame temperature in oxygen and reaches or surmount second 3100 DEG C of alkynes, it is achieved substitute the purpose of acetylene;But after air can be caused exhaust emission, and interpolation by existing perfect combustion catalizer The calorific value of various fuel be still insufficiently to serve as combustion gas cutting metal.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of natural gas for cutting metal.
The present invention uses following concrete technical scheme:
A kind of natural gas for cutting metal, the raw material including following: purity is natural higher than percentage by weight 95% Gas, account for aforementioned natural gas percentage by weight 0.3~the liquid phase Synergistic additives of 0.5%;Described liquid phase Synergistic additives include with Lower raw material: 200# solvent naphtha, acetylene, petroleum ether, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, isooctyl ester nitrate, dimethyl carbonate, Tert-butyl group ferrocene or ferrocene, methyl tertiary butyl ether(MTBE) or octyl ferrocene, p-tert-Butylcatechol, azo two isobutyl Nitrile, polyethers.
Preferably, liquid phase Synergistic additives accounts for natural gas percentage by weight 0.4%.
Preferably, described liquid phase Synergistic additives includes following raw material, counts by weight: 200# solvent naphtha 46~50, Acetylene 4~5, petroleum ether 4~5, ethylene glycol monoethyl ether 4~5, Oleum Terebinthinae 4~5, Oleum Verniciae fordii 8~12, isooctyl ester nitrate 4~6, carbonic acid Dimethyl ester 13~17, tert-butyl group ferrocene or ferrocene 4~5, methyl tertiary butyl ether(MTBE) or octyl ferrocene 3~5, to the tert-butyl group Catechol 0.3~0.6, azodiisobutyronitrile 0.3~0.6, polyethers 1~3.
It is highly preferred that described liquid phase Synergistic additives includes following raw material, count by weight: 200# solvent naphtha 48, second Alkynes 3, petroleum ether 3, ethylene glycol monoethyl ether 3, Oleum Terebinthinae 3, Oleum Verniciae fordii 10, isooctyl ester nitrate 5, dimethyl carbonate 15, the tert-butyl group two cyclopentadienyl Ferrum or ferrocene 3, methyl tertiary butyl ether(MTBE) or octyl ferrocene 4, p-tert-Butylcatechol 0.5, azodiisobutyronitrile 0.5, Polyethers 2.
In raw material, 200# solvent naphtha, Oleum Terebinthinae, Oleum Verniciae fordii, isooctyl ester nitrate, dimethyl carbonate select technical pure;Acetylene, stone Oil ether, ethylene glycol monoethyl ether, tert-butyl group ferrocene, ferrocene, methyl tertiary butyl ether(MTBE), octyl ferrocene, to tert-butyl o benzene Diphenol, azodiisobutyronitrile, polyethers Analysis about Selection are pure, all can be bought by market and obtain.
Further, described liquid phase Synergistic additives be according to 200# solvent naphtha, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, Tert-butyl group ferrocene or ferrocene, p-tert-Butylcatechol, methyl tertiary butyl ether(MTBE) or octyl ferrocene, polyethers, acetylene, stone Oil ether, isooctyl ester nitrate, dimethyl carbonate, azodiisobutyronitrile order add stirring in reaction vessel to, stand afterwards.
Preferably, stir 50~70 minutes, stand 50~70 minutes afterwards.
It is highly preferred that stir 60 minutes, stand 60 minutes afterwards.
Reaction vessel typically uses reactor.The parameters of stirring is without limiting.Mixing temperature is in room temperature.Stirring Rear general standing in settling tank.
Beneficial effects of the present invention is as follows:
1, the natural gas for cutting metal of the present invention is by adding a small amount of liquid phase Synergistic additives in natural gas, bright Show and improve ignition temperature and efficiency of combustion;Simultaneously the liquid phase Synergistic additives of the present invention to the corrosivity of container little and volatility Good.
2, this heating value of natural gas height being used for cutting metal, the heat consumption reaching identical is few, can realize low cost and use, Ignition temperature is high, more than 3000~3200 DEG C so that it has obviously advantage in terms of commercial Application;To Metal Cutting When metal, punching, heat affected area is little, can ensure that workpiece performance and quality, processes optimal, such as military project to the part of high-precision requirement Product, high-tech product;Workpiece smooth cut, smooth, on workpiece otch not the side of stepping on, under not dross, reduce slag hitting operation;
3, this use being used for cutting the natural gas of metal can reduce the discharge of waste gas, and emission reduction effect is preferable, and without phosphorus, sulfur is released Put, nontoxic, tasteless, environmental protection, cleaning, it is achieved environmental protection purpose.
Detailed description of the invention
For being more fully understood that the present invention, the solution of the present invention will be further illustrated by specific embodiment below, this Bright protection domain should include the full content of claim, but is not limited to this.
Embodiment 1
A kind of natural gas for cutting metal, the raw material including following: the natural gas of purity percentage by weight 98%, account for The liquid phase Synergistic additives of aforementioned natural gas percentage by weight 0.4%.
Described liquid phase Synergistic additives includes following raw material, counts by weight: 200# solvent naphtha 48, acetylene 3, petroleum ether 3, ethylene glycol monoethyl ether 3, Oleum Terebinthinae 3, Oleum Verniciae fordii 10, isooctyl ester nitrate 5, dimethyl carbonate 15, tert-butyl group ferrocene 3, methyl-tert Butyl ether 4, p-tert-Butylcatechol 0.5, azodiisobutyronitrile 0.5, polyethers 2.
Described liquid phase Synergistic additives be according to solvent naphtha, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, tert-butyl group ferrocene, P-tert-Butylcatechol, methyl tertiary butyl ether(MTBE), polyethers, acetylene, petroleum ether, isooctyl ester nitrate, dimethyl carbonate, azo two are different Butyronitrile order adds stirring 60 minutes in reaction vessel to, stands 60 minutes afterwards.
Reaction vessel uses reactor.The parameters of stirring is without limiting.Mixing temperature is in room temperature.In precipitation after stirring Tank stands.
Solvent naphtha, Oleum Terebinthinae, Oleum Verniciae fordii, isooctyl ester nitrate, dimethyl carbonate select technical pure;Acetylene, petroleum ether, ethylene glycol Single ether, tert-butyl group ferrocene, methyl tertiary butyl ether(MTBE), p-tert-Butylcatechol, azodiisobutyronitrile, polyethers Analysis about Selection Pure.All can be bought by market and obtain.
Embodiment 2
A kind of natural gas for cutting metal, the raw material including following: purity is natural higher than percentage by weight 95% Gas, account for the liquid phase Synergistic additives of aforementioned natural gas percentage by weight 0.3%;
Described liquid phase Synergistic additives includes following raw material, counts by weight: 200# solvent naphtha 46, acetylene 4, petroleum ether 4, ethylene glycol monoethyl ether 4, Oleum Terebinthinae 4, Oleum Verniciae fordii 8, isooctyl ester nitrate 4, dimethyl carbonate 13, tert-butyl group ferrocene 4, methyl-tert fourth Base ether 3, p-tert-Butylcatechol 0.3, azodiisobutyronitrile 0.3, polyethers 1.
Described liquid phase Synergistic additives is according to 200# solvent naphtha, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, the tert-butyl group two Cyclopentadienyl ferrum, p-tert-Butylcatechol, methyl tertiary butyl ether(MTBE), polyethers, acetylene, petroleum ether, isooctyl ester nitrate, dimethyl carbonate, idol Nitrogen bis-isobutyronitrile order adds stirring 50 minutes in reaction vessel to, stands 50 minutes afterwards.
Embodiment 3
A kind of natural gas for cutting metal, the raw material including following: purity is natural higher than percentage by weight 95% Gas, account for the liquid phase Synergistic additives of aforementioned natural gas percentage by weight 0.5%;
Described liquid phase Synergistic additives includes following raw material, counts by weight: 200# solvent naphtha 50, acetylene 5, petroleum ether 5, ethylene glycol monoethyl ether 5, Oleum Terebinthinae 5, Oleum Verniciae fordii 12, isooctyl ester nitrate 6, dimethyl carbonate 17, ferrocene 5, octyl ferrocene 5, p-tert-Butylcatechol 0.6, azodiisobutyronitrile 0.6, polyethers 3.
Described liquid phase Synergistic additives is according to 200# solvent naphtha, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, ferrocene, right Tert-butyl catechol, octyl ferrocene, polyethers, acetylene, petroleum ether, isooctyl ester nitrate, dimethyl carbonate, azo two isobutyl Nitrile order adds stirring 70 minutes in reaction vessel to, stands 70 minutes afterwards.

Claims (7)

1. the natural gas being used for cutting metal, it is characterised in that include following raw material: purity is higher than percentage by weight The natural gas of 95%, account for aforementioned natural gas percentage by weight 0.3~the liquid phase Synergistic additives of 0.5%;Described liquid phase potentiation adds Add agent and include following raw material: 200# solvent naphtha, acetylene, petroleum ether, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, isooctyl ester nitrate, Dimethyl carbonate, tert-butyl group ferrocene or ferrocene, methyl tertiary butyl ether(MTBE) or octyl ferrocene, p-tert-Butylcatechol, Azodiisobutyronitrile, polyethers.
Natural gas for cutting metal the most according to claim 1, it is characterised in that preferably, described liquid phase potentiation Additive accounts for natural gas percentage by weight 0.4%.
Natural gas for cutting metal the most according to claim 1, it is characterised in that described liquid phase Synergistic additives bag Include following raw material, by weight meter: 200# solvent naphtha 46~50, acetylene 4~5, petroleum ether 4~5, ethylene glycol monoethyl ether 4~ 5, Oleum Terebinthinae 4~5, Oleum Verniciae fordii 8~12, isooctyl ester nitrate 4~6, dimethyl carbonate 13~17, tert-butyl group ferrocene or ferrocene 4 ~5, methyl tertiary butyl ether(MTBE) or octyl ferrocene 3~5, p-tert-Butylcatechol 0.3~0.6, azodiisobutyronitrile 0.3~ 0.6, polyethers 1~3.
Natural gas for cutting metal the most according to claim 1, it is characterised in that it is highly preferred that described liquid phase increases Effect additive includes following raw material, counts by weight: 200# solvent naphtha 48, acetylene 3, petroleum ether 3, ethylene glycol monoethyl ether 3, pine Fuel-economizing 3, Oleum Verniciae fordii 10, isooctyl ester nitrate 5, dimethyl carbonate 15, tert-butyl group ferrocene or ferrocene 3, methyl tertiary butyl ether(MTBE) or just Octyl ferrocene 4, p-tert-Butylcatechol 0.5, azodiisobutyronitrile 0.5, polyethers 2.
Natural gas for cutting metal the most according to claim 1, it is characterised in that described liquid phase Synergistic additives is According to 200# solvent naphtha, ethylene glycol monoethyl ether, Oleum Terebinthinae, Oleum Verniciae fordii, tert-butyl group ferrocene or ferrocene, to tert-butyl o benzene two Phenol, methyl tertiary butyl ether(MTBE) or octyl ferrocene, polyethers, acetylene, petroleum ether, isooctyl ester nitrate, dimethyl carbonate, azo two are different Butyronitrile order adds stirring in reaction vessel to, stands afterwards.
Natural gas for cutting metal the most according to claim 5, it is characterised in that stir 50~70 minutes, afterwards Stand 50~70 minutes.
Natural gas for cutting metal the most according to claim 5, it is characterised in that stir 60 minutes, stand afterwards 60 minutes.
CN201610673452.5A 2016-08-15 2016-08-15 A kind of natural gas for cutting metal Pending CN106244270A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109207219A (en) * 2018-11-07 2019-01-15 车亿达河北新能源科技有限公司 natural gas special synergistic additive and preparation method thereof
WO2019114184A1 (en) * 2017-12-13 2019-06-20 代纪东 Effect-increasing and energy-saving cutting method for continuous casting steel blank

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710062A (en) * 2014-01-02 2014-04-09 北京大通鸿业科技发展有限公司 Efficient natural gas

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710062A (en) * 2014-01-02 2014-04-09 北京大通鸿业科技发展有限公司 Efficient natural gas

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019114184A1 (en) * 2017-12-13 2019-06-20 代纪东 Effect-increasing and energy-saving cutting method for continuous casting steel blank
CN109207219A (en) * 2018-11-07 2019-01-15 车亿达河北新能源科技有限公司 natural gas special synergistic additive and preparation method thereof

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