CN106244051A - A kind of glue stick special-purpose anti-flaming type PUR - Google Patents

A kind of glue stick special-purpose anti-flaming type PUR Download PDF

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Publication number
CN106244051A
CN106244051A CN201610703598.XA CN201610703598A CN106244051A CN 106244051 A CN106244051 A CN 106244051A CN 201610703598 A CN201610703598 A CN 201610703598A CN 106244051 A CN106244051 A CN 106244051A
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CN
China
Prior art keywords
parts
pur
resin
glue stick
purpose anti
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610703598.XA
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Chinese (zh)
Inventor
姚寒
周铸成
方文革
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Yongda Plastic Industry Technology Development Co Ltd
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Anhui Yongda Plastic Industry Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Yongda Plastic Industry Technology Development Co Ltd filed Critical Anhui Yongda Plastic Industry Technology Development Co Ltd
Priority to CN201610703598.XA priority Critical patent/CN106244051A/en
Publication of CN106244051A publication Critical patent/CN106244051A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04Homopolymers or copolymers of ethene
    • C09J123/08Copolymers of ethene
    • C09J123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/005Glue sticks
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following weight portion: resin 80 95 parts, dioctyl phthalate 13 17 parts, attapulgite 18 21 parts, pentaerythritol ester 12 16 parts, ferrocene 34 parts, antioxidant TBM 63 7 parts, mica powder 14 parts, Benzoinum 13 parts, microwax 69 parts, paraffin oil 13 parts, magnesium oxide powder 26 parts, Radix Angelicae Sinensis oil 36 parts, 15 18 parts of potter's clay, 45 parts of glass dust, 68 parts of kieselguhr and blanc fixe 10 15 parts.It is few that the present invention prepares raw material, and preparation cost is low, and running into naked light will not be ignited, and fire resistance is good.

Description

A kind of glue stick special-purpose anti-flaming type PUR
Technical field
The present invention relates to PUR, a kind of glue stick special-purpose anti-flaming type PUR.
Background technology
PUR is with thermoplastic resin or elastomer as base material, adds tackifier, plasticizer, antioxidant, fire retardant And filler, through the solid adhesive agent of melting mixing.Have a lot compared with heat curing-type, solvent-borne type and water-based adhesive Superiority, so from the 1950's so far, PUR is developed rapidly in many fields, starts for building Build, the field such as aircraft, naval vessel and automobile interior trim, especially replaced with PUR in industries such as printing, packagings and bound with traditional thread binding, But the most most widely used PUR bound exactly, existing most of PUR material compositions are many, and preparation cost is high, And these PURs encounter naked light and be easily ignited, fire resistance is poor.
Summary of the invention
For above-mentioned technical problem, the present invention provides a kind of glue stick special-purpose anti-flaming type PUR, prepares raw material few, is prepared as This is low, and running into naked light will not be ignited, and fire resistance is good.
The technical problem to be solved realizes by the following technical solutions:
A kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following weight portion: resin 80-95 part, Dioctyl phthalate 13-17 part, attapulgite 18-21 part, pentaerythritol ester 12-16 part, ferrocene 3-4 part, antioxidant TBM-63-7 part, mica powder 1-4 part, Benzoinum 1-3 part, microwax 6-9 part, paraffin oil 1-3 part, magnesium oxide powder 2-6 part, when Return oil 3-6 part, potter's clay 15-18 part, glass dust 4-5 part, kieselguhr 6-8 part and blanc fixe 10-15 part.
A kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following optimum weight part: resin 87 parts, Dioctyl phthalate 157 parts, attapulgite 19 parts, pentaerythritol ester 14 parts, ferrocene 3 parts, antioxidant TBM-65 part, cloud Female 3 parts of powder, Benzoinum 2 parts, microwax 8 parts, paraffin oil 2 parts, magnesium oxide powder 4 parts, Radix Angelicae Sinensis oil 5 parts, 17 parts of potter's clay, glass dust 4 parts, 7 parts of kieselguhr and blanc fixe 12 parts.
As a preferred technical solution of the present invention, described resin be EVA resin, organic siliconresin, epoxy resin with In phenolic resin any two kinds.
The invention has the beneficial effects as follows: compared to existing technology, it is few that the PUR that the present invention obtains prepares raw material, preparation cost Lowly, running into naked light will not be ignited, and fire resistance is good.
Detailed description of the invention
In order to make technological means that the present invention realizes and creation characteristic be easy to understand, below the present invention is explained further State.
Embodiment one:
A kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following weight portion: resin 80 parts, adjacent benzene Dioctyl phthalate dioctyl ester 13 parts, attapulgite 18 parts, pentaerythritol ester 12 parts, ferrocene 3 parts, antioxidant TBM-63 part, mica powder 1 Part, Benzoinum 1 part, microwax 6 parts, paraffin oil 1 part, magnesium oxide powder 2 parts, Radix Angelicae Sinensis oil 3 parts, 15 parts of potter's clay, 4 parts of glass dust, 6 parts of kieselguhr and blanc fixe 10 parts.
Described resin is EVA resin, organic siliconresin, epoxy resin and any two kinds in phenolic resin.
Embodiment two:
A kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following weight portion: resin 87 parts, adjacent benzene Dioctyl phthalate dioctyl ester 157 parts, attapulgite 19 parts, pentaerythritol ester 14 parts, ferrocene 3 parts, antioxidant TBM-65 part, mica powder 3 parts, Benzoinum 2 parts, microwax 8 parts, paraffin oil 2 parts, magnesium oxide powder 4 parts, Radix Angelicae Sinensis oil 5 parts, 17 parts of potter's clay, 4 parts of glass dust, 7 parts of kieselguhr and blanc fixe 12 parts.
Described resin is EVA resin, organic siliconresin, epoxy resin and any two kinds in phenolic resin.
Embodiment three:
A kind of glue stick special-purpose anti-flaming type PUR, this PUR is made up of the component of following weight portion: resin 95 parts, adjacent benzene Dioctyl phthalate dioctyl ester 17 parts, attapulgite 21 parts, pentaerythritol ester 16 parts, ferrocene 4 parts, antioxidant TBM-67 part, mica powder 4 Part, Benzoinum 3 parts, microwax 9 parts, paraffin oil 3 parts, magnesium oxide powder 6 parts, Radix Angelicae Sinensis oil 6 parts, 18 parts of potter's clay, 5 parts of glass dust, 8 parts of kieselguhr and blanc fixe 15 parts.
Described resin is EVA resin, organic siliconresin, epoxy resin and any two kinds in phenolic resin.
By implementing one, implement two and implementing the PUR for preparing of three each compositions, compared to existing technology in common PUR, prepares raw material few, and preparation cost is low, and running into naked light will not be ignited, and fire resistance is good.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry The personnel simply present invention it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description Principle, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these change and Improvement both falls within scope of the claimed invention.Claimed scope is by appending claims and equivalence thereof Thing defines.

Claims (3)

1. a glue stick special-purpose anti-flaming type PUR, it is characterised in that: this PUR is made up of the component of following weight portion: resin 60-88 part, paraffin 21-25 part, thermoplastic elastomer SBS's 3-5 part, fire retardant 2-5 part, antioxidant 3-7 part, polyisobutenyl Succimide 1-3 part, antimony oxide 1-2 part, lead sulfate tribasic 1-5 part and Flos Rosae Rugosae quintessence oil 2-6 part.
A kind of glue stick special-purpose anti-flaming type PUR the most according to claim 1, it is characterised in that: this PUR by following Good weight portion component composition: resin 69 parts, 23 parts of paraffin, thermoplastic elastomer SBS 4 parts, fire retardant 4 parts, 5 parts of antioxidant, Polyisobutylene succinamide 2 parts, antimony oxide 1 part, lead sulfate tribasic 3 parts and Flos Rosae Rugosae quintessence oil 4 parts.
A kind of glue stick special-purpose anti-flaming type PUR the most according to claim 1 and 2, it is characterised in that: described resin is EVA Resin, hydrogenation C5 Petropols, tert butyl phenolic resin and any two kinds in octyl phenolic.
CN201610703598.XA 2016-08-23 2016-08-23 A kind of glue stick special-purpose anti-flaming type PUR Pending CN106244051A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610703598.XA CN106244051A (en) 2016-08-23 2016-08-23 A kind of glue stick special-purpose anti-flaming type PUR

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610703598.XA CN106244051A (en) 2016-08-23 2016-08-23 A kind of glue stick special-purpose anti-flaming type PUR

Publications (1)

Publication Number Publication Date
CN106244051A true CN106244051A (en) 2016-12-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610703598.XA Pending CN106244051A (en) 2016-08-23 2016-08-23 A kind of glue stick special-purpose anti-flaming type PUR

Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103468167A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Anti-ultraviolet EVA hot melt adhesive
CN104031310A (en) * 2014-05-20 2014-09-10 十堰风神汽车橡塑制品有限公司 Automobile EVA damping rubber sheet and preparation method thereof
CN104531007A (en) * 2014-12-23 2015-04-22 安徽助成信息科技有限公司 Flame-retardant EVA (ethylene-vinyl acetate) hot-melt adhesive
CN106336833A (en) * 2016-08-23 2017-01-18 安徽永大胶业科技发展有限公司 Environment-friendly hot melt adhesive

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103468167A (en) * 2013-08-13 2013-12-25 安徽东方金河精密机械制造有限公司 Anti-ultraviolet EVA hot melt adhesive
CN104031310A (en) * 2014-05-20 2014-09-10 十堰风神汽车橡塑制品有限公司 Automobile EVA damping rubber sheet and preparation method thereof
CN104531007A (en) * 2014-12-23 2015-04-22 安徽助成信息科技有限公司 Flame-retardant EVA (ethylene-vinyl acetate) hot-melt adhesive
CN106336833A (en) * 2016-08-23 2017-01-18 安徽永大胶业科技发展有限公司 Environment-friendly hot melt adhesive

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