CN106243697A - A kind of high-transparency nylon composite film - Google Patents

A kind of high-transparency nylon composite film Download PDF

Info

Publication number
CN106243697A
CN106243697A CN201610693360.3A CN201610693360A CN106243697A CN 106243697 A CN106243697 A CN 106243697A CN 201610693360 A CN201610693360 A CN 201610693360A CN 106243697 A CN106243697 A CN 106243697A
Authority
CN
China
Prior art keywords
parts
nylon
butyl
composite film
transparency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610693360.3A
Other languages
Chinese (zh)
Inventor
张复光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongcheng City Hong Ye Plastic Co Ltd
Original Assignee
Tongcheng City Hong Ye Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongcheng City Hong Ye Plastic Co Ltd filed Critical Tongcheng City Hong Ye Plastic Co Ltd
Priority to CN201610693360.3A priority Critical patent/CN106243697A/en
Publication of CN106243697A publication Critical patent/CN106243697A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/10—Transparent films; Clear coatings; Transparent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The open a kind of high-transparency nylon composite film of the present invention, by weight, including following raw material components: nylon 60 70 parts, polrvinyl chloride 15 20 parts, corundum fine powder 14 20 parts, melamine cyanurate salt 9 13 parts, glass fibre 23 29 parts, 23 parts of gelatin, thermoplastic resin 25 35 parts, alcohol-soluble resin 18 28 parts, magnesium hypophosphite 14 20 parts, di-sec-butyl is to benzene 36 parts, meerschaum 37 parts, sodium salicylate 9 17 parts, Kaolin 38 parts, benzoin ethyl ether 10 20 parts, butyl titanate 1.2 1.4 parts, Boehmeria boon 12 14 parts, tributyl 2-acetylcitrate 13 15 parts, diethylene glycol ether acetate alone 23 parts, glycerol 34 parts.Nylon composite film prepared by the inventive method improves the transparency of thin film in the case of not affecting barrier, thus improves the visuality of package goods.

Description

A kind of high-transparency nylon composite film
Technical field
The present invention relates to field of material technology, specifically a kind of high-transparency nylon composite film.
Background technology
In recent years, the functional film packaging material of Devoting Major Efforts To Developing high added value have become countries in the world plastic package material Development trend.Functional film is generally of higher technology content, also has preferable economic benefit and stronger simultaneously The market competitiveness, therefore enjoys people to pay close attention to.Industrialization functional bag significant in packaging field the most Dress thin film has barrier packaging thin film, shrink package thin film, surface protection film, easily breaks a seal thin film, antistatic film, antirust thin Film, antibacterial film, degradable film etc., functional package thin film is the important kind of packaging material, the most a little particular envelope Indispensable material, has highly important status in plastic package material.Wherein nylon/polyethylene (polypropylene) multilamellar Coex composite membranes (sheet) has become a kind of new packaging material with fastest developing speed in the plastic package material of countries in the world, this The resistance oxygen that laminated film (sheet) has due to it, the function of the steam that blocks water, at bags such as meat product, grain and food, electronic products Dress field is widely applied.And due to the feature of environmental protection of this production technology, the life of the most this kind of laminated film (sheet) Produce to have also been obtained in China and develop faster.
Along with the progress of society, the packaging of commodity be it is also proposed the highest requirement, except requiring the function of packaging Outward, also requiring that the visuality after commodity packaging is good, people can be accurate, clearly sees the actual state of commodity, especially High-grade goods.This just requires that coex composite membranes (sheet) has resistance oxygen, outside the function of the steam that blocks water, also to have well The transparency.
Summary of the invention
It is an object of the invention to provide a kind of high-transparency nylon composite film.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 60-70 part, polychlorostyrene second Alkene 15-20 part, corundum fine powder 14-20 part, melamine cyanurate salt 9-13 part, glass fibre 23-29 part, gelatin 2-3 part, heat Plastic resin 25-35 part, alcohol-soluble resin 18-28 part, magnesium hypophosphite 14-20 part, di-sec-butyl are to benzene 3-6 part, meerschaum 3-7 Part, sodium salicylate 9-17 part, Kaolin 3-8 part, benzoin ethyl ether 10-20 part, butyl titanate 1.2-1.4 part, Boehmeria boon 12-14 part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol ether acetate alone 2-3 part, glycerol 3-4 part.
Preferably, described a kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 60 parts, polrvinyl chloride 15 parts, corundum fine powder 14 parts, melamine cyanurate salt 9 parts, glass fibre 23 parts, 2 parts of gelatin, thermoplastic Property resin 25 parts, alcohol-soluble resin 18 parts, magnesium hypophosphite 14 parts, di-sec-butyl to benzene 3 parts, meerschaum 3 parts, sodium salicylate 9 parts, Kaolin 3 parts, benzoin ethyl ether 10 parts, butyl titanate 1.2 parts, Boehmeria boon 12 parts, tributyl 2-acetylcitrate 13 parts, two Ethylene glycol monoethyl ether acetate 2 parts, glycerol 3 parts.
Preferably, described a kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 70 parts, polrvinyl chloride 20 parts, corundum fine powder 20 parts, melamine cyanurate salt 13 parts, glass fibre 29 parts, 3 parts of gelatin, thermoplastic Property resin 35 parts, alcohol-soluble resin 28 parts, magnesium hypophosphite 20 parts, di-sec-butyl are to benzene 6 parts, meerschaum 7 parts, sodium salicylate 17 Part, Kaolin 8 parts, benzoin ethyl ether 20 parts, butyl titanate 1.4 parts, Boehmeria boon 14 parts, tributyl 2-acetylcitrate 15 Part, diethylene glycol ether acetate alone 3 parts, glycerol 4 parts.
Preferably, described a kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 65 parts, polrvinyl chloride 18 parts, corundum fine powder 18 parts, melamine cyanurate salt 10 parts, glass fibre 25 parts, 2 parts of gelatin, thermoplastic Property resin 30 parts, alcohol-soluble resin 25 parts, magnesium hypophosphite 18 parts, di-sec-butyl are to benzene 5 parts, meerschaum 5 parts, sodium salicylate 12 Part, Kaolin 5 parts, benzoin ethyl ether 15 parts, butyl titanate 1.3 parts, Boehmeria boon 13 parts, tributyl 2-acetylcitrate 14 Part, diethylene glycol ether acetate alone 2 parts, glycerol 3 parts.
Beneficial effects of the present invention: nylon composite film prepared by the inventive method carries in the case of not affecting barrier The high transparency of thin film, thus improve the visuality of package goods.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 60 parts, polrvinyl chloride 15 parts, corundum fine powder 14 parts, melamine cyanurate salt 9 parts, glass fibre 23 parts, 2 parts of gelatin, thermoplastic resin 25 parts, alcohol Soluble resin 18 parts, magnesium hypophosphite 14 parts, di-sec-butyl are to benzene 3 parts, meerschaum 3 parts, sodium salicylate 9 parts, Kaolin 3 parts, peace Breath fragrant ether 10 parts, butyl titanate 1.2 parts, Boehmeria boon 12 parts, tributyl 2-acetylcitrate 13 parts, diethylene glycol monoethyl ether Acetate 2 parts, glycerol 3 parts.
The preparation method of the present invention is same as the prior art.
Embodiment 2
A kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 70 parts, polrvinyl chloride 20 parts, corundum fine powder 20 parts, melamine cyanurate salt 13 parts, glass fibre 29 parts, 3 parts of gelatin, thermoplastic resin 35 parts, alcohol Soluble resin 28 parts, magnesium hypophosphite 20 parts, di-sec-butyl are to benzene 6 parts, meerschaum 7 parts, sodium salicylate 17 parts, Kaolin 8 parts, peace Breath fragrant ether 20 parts, butyl titanate 1.4 parts, Boehmeria boon 14 parts, tributyl 2-acetylcitrate 15 parts, diethylene glycol monoethyl ether Acetate 3 parts, glycerol 4 parts.
The preparation method of the present invention is same as the prior art.
Embodiment 3
A kind of high-transparency nylon composite film, by weight, including following raw material components: nylon 65 parts, polrvinyl chloride 18 parts, corundum fine powder 18 parts, melamine cyanurate salt 10 parts, glass fibre 25 parts, 2 parts of gelatin, thermoplastic resin 30 parts, alcohol Soluble resin 25 parts, magnesium hypophosphite 18 parts, di-sec-butyl are to benzene 5 parts, meerschaum 5 parts, sodium salicylate 12 parts, Kaolin 5 parts, peace Breath fragrant ether 15 parts, butyl titanate 1.3 parts, Boehmeria boon 13 parts, tributyl 2-acetylcitrate 14 parts, diethylene glycol monoethyl ether Acetate 2 parts, glycerol 3 parts.
The preparation method of the present invention is same as the prior art.

Claims (4)

1. a high-transparency nylon composite film, it is characterised in that by weight, including following raw material components: nylon 60-70 Part, polrvinyl chloride 15-20 part, corundum fine powder 14-20 part, melamine cyanurate salt 9-13 part, glass fibre 23-29 part, bright Glue 2-3 part, thermoplastic resin 25-35 part, alcohol-soluble resin 18-28 part, magnesium hypophosphite 14-20 part, di-sec-butyl are to benzene 3-6 Part, meerschaum 3-7 part, sodium salicylate 9-17 part, Kaolin 3-8 part, benzoin ethyl ether 10-20 part, butyl titanate 1.2-1.4 Part, Boehmeria boon 12-14 part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol ether acetate alone 2-3 part, glycerol 3-4 Part.
A kind of high-transparency nylon composite film the most according to claim 1, it is characterised in that by weight, including with Lower raw material components: nylon 60 parts, polrvinyl chloride 15 parts, corundum fine powder 14 parts, melamine cyanurate salt 9 parts, glass fibre 23 Part, 2 parts of gelatin, thermoplastic resin 25 parts, alcohol-soluble resin 18 parts, magnesium hypophosphite 14 parts, di-sec-butyl are to benzene 3 parts, meerschaum 3 Part, sodium salicylate 9 parts, Kaolin 3 parts, benzoin ethyl ether 10 parts, butyl titanate 1.2 parts, Boehmeria boon 12 parts, acetyl Fructus Citri Limoniae Acid tributyl 13 parts, diethylene glycol ether acetate alone 2 parts, glycerol 3 parts.
A kind of high-transparency nylon composite film the most according to claim 1, it is characterised in that by weight, including with Lower raw material components: nylon 70 parts, polrvinyl chloride 20 parts, corundum fine powder 20 parts, melamine cyanurate salt 13 parts, glass fibre 29 Part, 3 parts of gelatin, thermoplastic resin 35 parts, alcohol-soluble resin 28 parts, magnesium hypophosphite 20 parts, di-sec-butyl are to benzene 6 parts, meerschaum 7 Part, sodium salicylate 17 parts, Kaolin 8 parts, benzoin ethyl ether 20 parts, butyl titanate 1.4 parts, Boehmeria boon 14 parts, acetyl lemon Lemon acid tributyl 15 parts, diethylene glycol ether acetate alone 3 parts, glycerol 4 parts.
A kind of high-transparency nylon composite film the most according to claim 1, it is characterised in that by weight, including with Lower raw material components: nylon 65 parts, polrvinyl chloride 18 parts, corundum fine powder 18 parts, melamine cyanurate salt 10 parts, glass fibre 25 Part, 2 parts of gelatin, thermoplastic resin 30 parts, alcohol-soluble resin 25 parts, magnesium hypophosphite 18 parts, di-sec-butyl are to benzene 5 parts, meerschaum 5 Part, sodium salicylate 12 parts, Kaolin 5 parts, benzoin ethyl ether 15 parts, butyl titanate 1.3 parts, Boehmeria boon 13 parts, acetyl lemon Lemon acid tributyl 14 parts, diethylene glycol ether acetate alone 2 parts, glycerol 3 parts.
CN201610693360.3A 2016-08-18 2016-08-18 A kind of high-transparency nylon composite film Pending CN106243697A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610693360.3A CN106243697A (en) 2016-08-18 2016-08-18 A kind of high-transparency nylon composite film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610693360.3A CN106243697A (en) 2016-08-18 2016-08-18 A kind of high-transparency nylon composite film

Publications (1)

Publication Number Publication Date
CN106243697A true CN106243697A (en) 2016-12-21

Family

ID=57592620

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610693360.3A Pending CN106243697A (en) 2016-08-18 2016-08-18 A kind of high-transparency nylon composite film

Country Status (1)

Country Link
CN (1) CN106243697A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556743A (en) * 2017-10-24 2018-01-09 安徽松泰包装材料有限公司 A kind of high-transparency nylon CPP laminated films
CN113372597A (en) * 2021-06-02 2021-09-10 潘秋 PA film and production process thereof
CN115139615A (en) * 2022-08-25 2022-10-04 河北泰达包装材料有限公司 Flexible package modified CPP film and production method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103044909A (en) * 2012-11-25 2013-04-17 安徽六方重联机械股份有限公司 Packaging plastic substrate thin film containing nylon PA6
CN104479199A (en) * 2014-11-27 2015-04-01 苏州市贝克生物科技有限公司 Medical film material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103044909A (en) * 2012-11-25 2013-04-17 安徽六方重联机械股份有限公司 Packaging plastic substrate thin film containing nylon PA6
CN104479199A (en) * 2014-11-27 2015-04-01 苏州市贝克生物科技有限公司 Medical film material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556743A (en) * 2017-10-24 2018-01-09 安徽松泰包装材料有限公司 A kind of high-transparency nylon CPP laminated films
CN113372597A (en) * 2021-06-02 2021-09-10 潘秋 PA film and production process thereof
CN115139615A (en) * 2022-08-25 2022-10-04 河北泰达包装材料有限公司 Flexible package modified CPP film and production method thereof

Similar Documents

Publication Publication Date Title
CN106243697A (en) A kind of high-transparency nylon composite film
CN104553153B (en) Light weight high-barrier scratch resistant color paper plastic-aluminum milk powder packaging composite construction and method
CN109505193A (en) A kind of composite paper-plastic material water-soluble coating material and preparation method thereof that recyclable regenerative utilizes
CN107089413A (en) Straight line easily tears complex pocket and its manufacture method
CN107415382A (en) Transparent Easy tearing lid sealed membrane and its manufacture method
CN107556743A (en) A kind of high-transparency nylon CPP laminated films
CN102731995B (en) Method for preparing puncture-resistant nylon composite film
CN106317858A (en) Nylon-PE mixed plastic film
CN206048938U (en) A kind of flexible compound aluminium foil
CN104476881A (en) Polyester/low-density polyethylene composite film for packaging and preparation method of polyester/low-density polyethylene composite film
CN102729463A (en) Preparation method of high-transparency nylon composite film
CN105196679A (en) Multilayer plastic uptake deep forming packaging film material and production technology thereof
CN209063654U (en) A kind of transparency high separation plating aluminum oxide polyester film packaging structure
CN204431864U (en) A kind of packaging uses flame retardant plastics film
CN210082585U (en) Biaxial stretching extinction, high-barrier and heat-sealable polyamide film
CN106956488A (en) A kind of membrane material structure and its vacuum heat-insulating plate with high anti-zoned puncture energy
CN205498232U (en) Chocolate shaping packing is with electroplating PVC adhesive tape
CN207107297U (en) Straight line easily tears complex pocket
CN202046559U (en) Healthy food packaging film
CN106243564A (en) A kind of semi-rigid polrvinyl chloride description calendered film
CN104356471A (en) Transparent macromolecule packing material
CN106142791A (en) A kind of preparation method bakeing the bright gas flush packaging film of the special height of based food
CN203157259U (en) Environment-friendly adhesive modified polyester-aluminum-polypropylene composite film for medicine/food packaging
CN200999124Y (en) Foodstuff packaging film
CN204701215U (en) Key works Drug packing aluminium foil

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161221