CN106243534A - A kind of rubber fastening band and preparation method thereof - Google Patents
A kind of rubber fastening band and preparation method thereof Download PDFInfo
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- CN106243534A CN106243534A CN201610604868.1A CN201610604868A CN106243534A CN 106243534 A CN106243534 A CN 106243534A CN 201610604868 A CN201610604868 A CN 201610604868A CN 106243534 A CN106243534 A CN 106243534A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of rubber fastening band and preparation method thereof, it is made up of the raw material of following parts by weight, chlorinated polyethylene 100 parts, softening plasticizer 20～50 parts, acid-acceptor 5～20 parts, lubricant 1～5 parts, composite reinforcing agent 30～80 parts, vulcanizing activator 1～5 parts, vulcanization accelerator 2～10 parts, sulfur 0.3～2.0 parts.Present invention additionally comprises the preparation method of rubber fastening band.The present invention has low cost, environmental protection, processing characteristics is excellent, compression set is little, resistant to liquids penetrating power is big, heat resistant oils and alkali resistance solution more preferably feature, it is adaptable to sealing is used by building, subway, culvert, tunnel, closed conduit, checkdam, cistern and chemical plant etc. with engineerings such as particular/special requirement occasions.
Description
Technical field
The present invention relates to a kind of waterstop and preparation method thereof, be specifically related to a kind of rubber fastening band and preparation method thereof.
Background technology
Along with the development of modern society, China's infrastructure construction further speeds up, building, subway, culvert, tunnel, dark
The engineerings such as canal, checkdam, cistern get more and more.And rubber fastening band is widely used in above-mentioned engineering, market is to waterstop
Propose the highest performance requirement.Currently, China has two: one to be GB/ about the standard of rubber fastening band
T18173.2-2014, another is TB/T 3360.2-2014, and alkali resistance solution index is proposed by latter of which clearly to be wanted
Ask.Therefore, how to improve waterstop physical index, improve processing characteristics, reduce cost simultaneously and be particularly important.
Chlorinated polyethylene be by the high density polyethylene (HDPE) of certain molecular weight through chlorination prepare chlorinity about 35%
The saturated elastomeric material of random chlorine distribution, ozone weather-proof, resistance to, ageing-resistant excellence.It is with neoprene (CR), ethylene-propylene-diene monomer
Glue (EPDM) performance approximates, the most alternative CR, EPDM, for manufacturing the specific rubber used under severe conditions
Goods, and cost is lower.At present, the effective vulcanizing system of chlorinated polyethylene mainly has peroxide vulcanizing system, thiourea cure
System and Thiadiazole Curing System.Wherein, Thiadiazole Curing System vulcanizing agent is expensive, usually the 6 of thiourea accelerator
About times, time of scorch is short in use, and commercial production is not easily controlled, and the sizing material holding time is the longest, limits it typically
Application in rubber industry.The domestic employing of thiourea curing system mostly be ethylene thiourea (accelerant N A-22), NA-22 toxicity
Relatively big, curingprocess rate is slow, is already belonging to the product that will be eliminated.The easy incipient scorch of peroxide vulcanizing system elastomeric compound, is not suitable for without mould
Sulfuration, vulcanizate hot tear strength is low, though high temperature compression is little, but normal temperature compressed permanent deformation is big, and producing during sulfuration stimulates
The acetophenone of property abnormal smells from the patient, can cause relatively bad influence to the working environment of workers, during pressing, through be commonly encountered choke with resentment, mould
The problems such as type pollution and the difficult demoulding, tasteless peroxide is expensive.Such as prior art CN201110456832.0 discloses
A kind of CPE rubber fastening band, described waterstop is using saturated rubber CPE rubber as base material, by rubber curing forming work
Skill preparation is formed, and in described formula, the mass ratio of each component is as follows: saturated CPE rubber 100 parts, softens plasticizer 20-
50 parts, heat stabilizer 2-8 part, pH value regulator 8-20 part, lubricant 1-5 part, reinforcing agent 25-60 part and cross-linking agent 3-10 part,
Described saturated CPE rubber uses chlorinty to be the chlorinated polyethylene rubber of 25wt.%-45wt.%.This invention is with chlorinated polyethylene
Alkene is material of main part, uses peroxide to make vulcanizing agent, and lead salt used as stabilizers and cross-linking agent etc. are prepared rubber fastening band, improve
Performance, reduces cost, meets waterstop standard GB/T/T 18173.2-2000, but examines alkali resistance solution index
Amount, is not suitable for waterstop standard TB/T 3360.2-2014；And the saturated CPE rubber production of peroxide systems crosslinking is more difficult
Controlling, compression set is big, and tearing toughness and liquid barrier capabilities are poor, and environmental-protecting performance is the poorest.
Summary of the invention
The technical problem to be solved is to provide a kind of low cost, environmental protection, processing characteristics is excellent, compression is permanent
Deform little, resistant to liquids penetrating power big, heat resistant oils and alkali resistance solution more preferably high-strength rubber waterstop and preparation method thereof,
This waterstop has excellent physical property, meets again two standards of rubber fastening band simultaneously.
The technical solution adopted for the present invention to solve the technical problems is, a kind of rubber fastening band, by following parts by weight
Raw material make, chlorinated polyethylene 100 parts, soften plasticizer 20～50 parts (preferably 20～40 parts), acid-acceptor 5～20 parts (excellent
Select 5～10 parts), lubricant 1～5 parts (preferably 2～4 parts), composite reinforcing agent 30～80 parts of (preferably 50～70 parts), sulfurate activities
Agent 1～5 parts (preferably 2～4 parts), vulcanization accelerator 2～10 parts (preferably 3～10 parts), sulfur 0.3～2.0 parts (preferably 0.5～2
Part).
Further, described softening plasticizer be di-n-octyl sebacate, dioctyl phthalate, trioctyl trimellitate (TOTM) and
One or more mixture in epoxy soybean oil.
Further, described acid-acceptor is magnesium oxide or magnesium hydroxide.
Further, one or more the mixture during described lubricant is Tissuemat E, paraffin and calcium stearate.
Further, described composite reinforcing agent is the one in white carbon black, white carbon, Kaolin, calcium carbonate and Pulvis Talci or two
Plant above mixture.
Further, described vulcanizing activator is zinc oxide and/or stearic acid.
Further, described vulcanization accelerator is Thiourea accelerator (preferably diethyl thiourea).
The present invention solves its technical problem further and be employed technical scheme comprise that, the preparation side of a kind of rubber fastening band
Method, comprises the following steps:
(1) by weight, by raw material chlorinated polyethylene 100 parts, soften plasticizer 20～50 parts, acid-acceptor 5～20 parts,
Lubricant 1～5 parts, composite reinforcing agent 30～80 parts, vulcanizing activator 1～5 parts, put in order in banbury refine glue 5～
10min, banburying temperature is 100～130 DEG C, returns glue 4～8min after binder removal on a mill until, and roll spacing is adjusted to 4～5mm and goes out film；
(2) gained film is added in banbury, addition vulcanization accelerator 2～10 parts and sulfur 0.3～2.0 parts mixing 1
～3min binder removal, temperature is 80～110 DEG C, returns glue 3～5min the most again in mill, is pressed into the semi-finished product film of lamellar；
(3) gained semi-finished product mixed sheet is molded into waterstop finished product by vulcanizer, wherein sulfide stress 8～
12Mpa, curing temperature 150～170 DEG C, cure time 15～20min；Or by extruding dies molding, through microwave vulcanization
It is shaped into rubber fastening band finished product.
The present invention uses vulcanization accelerator to be prepared into sizing material and is difficult to incipient scorch, stores the time long, and sulfuration is without bad smell, at mould
During stampings, easy-formation, do not choke with resentment, model pollutes and the problem such as the difficult demoulding, molded vulcanization can be simultaneously suitable for and squeeze
Going out two kinds of techniques of continuous vulcanization, processing characteristics is excellent.Moreover, use body material chlorinated polyethylene material price well below three
Unit's EP rubbers and neoprene, and operation of not plasticating, when manufacturing and apply, technological process is simple, can directly be processed into
Type, has lacked energy resource consumption significantly, shortens the process-cycle, is prepared into waterstop and has good resistance to ozone, ageing-resistant, low temperature resistant
The physical property that performance, high tensile and high-tear strength etc. are excellent；Meanwhile, it is not added with any stabilizer, age resistor just can expire
The standard-required of foot waterstop, and raw materials is general chemicals, does not use the toxic raw materials such as lead salt, produces, makes
During with more environmentally-friendly.
In brief, the present invention has low cost, environmental protection, processing characteristics is excellent, compression set is little, resistant to liquids infiltration
Ability is big, high tensile, anti tear, heat resistant oils and alkali resistance solution more preferably feature, can application factory etc. to sealing with
Particular/special requirement occasion.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is illustrated further.
Embodiment 1
(1) by weight, be 25 by raw material chlorinity～the chlorinated polyethylene 100 parts of 45%, phthalic acid two are pungent
Ester 35 parts, magnesium oxide 5 parts, 1 part of paraffin, white carbon black 45 parts, Kaolin 25 parts, zinc oxide 1 part, stearic acid 1 part, put in order
Refining glue 5 minutes in banbury, banburying temperature is 100 DEG C, returns glue on a mill until 5 minutes after binder removal, and roll spacing is adjusted to 4～5mm and goes out
Film；
(2) gained film is added in banbury, adds diethyl thiourea 5 parts and mixing 1 minute binder removal of 1.5 parts of sulfur,
Temperature is 80 DEG C, returns glue the most again 3 minutes in mill, is pressed into the semi-finished product film of lamellar；
(3) gained semi-finished product mixed sheet is molded into waterstop finished product, sulfide stress 10Mpa, sulfuration by vulcanizer
Temperature 165 DEG C, cure time 18 minutes.
Embodiment 2
(1) by weight, be 25 by raw material chlorinity～the chlorinated polyethylene 100 parts of 45%, phthalic acid two are pungent
Ester 25 parts, di-n-octyl sebacate 5 parts, epoxy soybean oil 5 parts, 8 parts of magnesium hydroxide, 1 part of paraffin, Tissuemat E 1 part, white carbon black 35
Part, white carbon 10 parts, calcium carbonate 25 parts, zinc oxide 3 parts, stearic acid 1 part, put in order in banbury and refine glue 5 minutes, close
Refining temperature is 100 DEG C, returns glue on a mill until 5 minutes after binder removal, and roll spacing is adjusted to 4～5mm and goes out film；
(2) gained film is added in banbury, adds diethyl thiourea 10 parts and mixing 1 minute binder removal of 2.0 parts of sulfur,
Temperature is 80 DEG C, returns glue the most again 3 minutes in mill, is pressed into the semi-finished product film of lamellar；
(3) gained semi-finished product mixed sheet is molded into waterstop finished product, sulfide stress 10Mpa, sulfuration by vulcanizer
Temperature 160 DEG C, cure time 15 minutes.
Embodiment 3
(1) by weight, be 25 by raw material chlorinity～the chlorinated polyethylene 100 parts of 45%, phthalic acid two are pungent
Ester 40 parts, magnesium oxide 10 parts, 1 part of paraffin, Tissuemat E 1 part, calcium stearate 1 part, white carbon black 45 parts, Kaolin 15 parts, Pulvis Talci
15 parts, zinc oxide 1 part, stearic acid 1 part, put in order and banbury refine glue 8 minutes, banburying temperature is 105 DEG C, after binder removal
Returning glue on a mill until 8 minutes, roll spacing is adjusted to 4～5mm and goes out film；
(2) gained film is added in banbury, adds diethyl thiourea 6 parts and mixing 2 minutes binder removals of 1.0 parts of sulfur,
Temperature is 90 DEG C, returns glue the most again 5 minutes in mill, is pressed into the semi-finished product film of lamellar；
(3) by gained semi-finished product mixed sheet by extruder extrusion die molding, only it is shaped into rubber through microwave vulcanization
Water band finished product.
Embodiment 4
(1) by weight, be 25 by raw material chlorinity～the chlorinated polyethylene 100 parts of 45%, phthalic acid two are pungent
Ester 10 parts, trioctyl trimellitate (TOTM) 20 parts, epoxy soybean oil 5 parts, 15 parts of magnesium hydroxide, 1 part of paraffin, calcium stearate 1 part, poly-second
1 part of alkene wax, white carbon black 40 parts, Pulvis Talci 15 parts, Kaolin 10 parts, zinc oxide 2 parts, put into 5 points of glue of refining in banbury in order
Clock, banburying temperature is 100 DEG C, returns glue on a mill until 5 minutes after binder removal, and roll spacing is adjusted to 4～5mm and goes out film；
(2) gained film is added in banbury, adds diethyl thiourea 3 parts and mixing 1 minute binder removal of 0.5 part of sulfur,
Temperature is 80 DEG C, returns glue the most again 3 minutes in mill, is pressed into the semi-finished product film of lamellar；
(3) by gained semi-finished product mixed sheet, it is molded into waterstop finished product, sulfide stress 10Mpa, sulfuration by vulcanizer
Temperature 165 DEG C, cure time prepares rubber fastening band finished product in 20 minutes.
The performance indications of the rubber fastening band of embodiment 1～4 preparation see table 1, and as shown in Table 1, prepared by embodiment 1～4
Rubber fastening band performance meet two standard-requireds of GB/T18173.2-2014 Yu TB/T 3360.2-2014 the most simultaneously.
The performance indications of the rubber fastening band of table 1-embodiment 1～4 preparation
Claims (10)
1. a rubber fastening band, it is characterised in that be made up of the raw material of following parts by weight, chlorinated polyethylene 100 parts, softening
Plasticizer 20～50 parts, acid-acceptor 5～20 parts, lubricant 1～5 parts, composite reinforcing agent 30～80 parts, vulcanizing activator 1～5
Part, vulcanization accelerator 2～10 parts, sulfur 0.3～2.0 parts.
Rubber fastening band the most according to claim 1, it is characterised in that be made up of the raw material of following parts by weight, chlorination
Polyethylene 100 parts, softening plasticizer 20～40 parts, acid-acceptor 5～10 parts, lubricant 2～4 parts, composite reinforcing agent 50～70 parts,
Vulcanizing activator 2～4 parts, vulcanization accelerator 3～10 parts, sulfur 0.5～2 parts.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described softening plasticizer is that decanedioic acid two is pungent
One or more mixture in ester, dioctyl phthalate, trioctyl trimellitate (TOTM) and epoxy soybean oil.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described acid-acceptor is magnesium oxide or hydroxide
Magnesium.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described lubricant be Tissuemat E, paraffin and
One or more mixture in calcium stearate.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described composite reinforcing agent is white carbon black, Linesless charcoal
One or more mixture in black, Kaolin, calcium carbonate and Pulvis Talci.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described vulcanizing activator be zinc oxide and/or
Stearic acid.
Rubber fastening band the most according to claim 1 and 2, it is characterised in that described vulcanization accelerator is that Thiourea promotes
Agent.
Rubber fastening band the most according to claim 8, it is characterised in that described Thiourea accelerator is diethyl thiourea.
10. the preparation method of the rubber fastening band as described in claim 1～9, it is characterised in that comprise the following steps:
(1) by weight, by raw material chlorinated polyethylene 100 parts, plasticizer 20～50 parts, acid-acceptor 5～20 parts, lubrication are softened
Agent 1～5 parts, composite reinforcing agent 30～80 parts, vulcanizing activator 1～5 parts, put in order in banbury refine glue 5～
10min, banburying temperature is 100～130 DEG C, returns glue 4～8min after binder removal on a mill until, and roll spacing is adjusted to 4～5mm and goes out film；
(2) gained film is added in banbury, add vulcanization accelerator 2～10 parts and sulfur 0.3～2.0 parts mixing 1～
3min binder removal, temperature is 80～110 DEG C, returns glue 3～5min the most again in mill, is pressed into the semi-finished product film of lamellar；
(3) gained semi-finished product mixed sheet is molded into waterstop finished product, wherein sulfide stress 8～12Mpa, sulfur by vulcanizer
Change temperature 150～170 DEG C, cure time 15～20min；Or by extruding dies molding, it is shaped into rubber through microwave vulcanization
Glue waterstop finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610604868.1A CN106243534A (en) | 2016-07-28 | 2016-07-28 | A kind of rubber fastening band and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610604868.1A CN106243534A (en) | 2016-07-28 | 2016-07-28 | A kind of rubber fastening band and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106947203A (en) * | 2017-04-27 | 2017-07-14 | 河北润石橡塑有限公司 | A kind of being folded without breaking rubber fastening band and its preparation technology |
| CN107189240A (en) * | 2017-07-05 | 2017-09-22 | 衡水大禹工程橡塑科技开发有限公司 | A kind of mildewproof rubber waterstop and its preparation technology |
| CN111376505A (en) * | 2018-12-29 | 2020-07-07 | 河北昊德橡塑有限公司 | Preparation method of rubber waterstop and rubber waterstop |
| CN114672102A (en) * | 2022-05-26 | 2022-06-28 | 中裕铁信交通科技股份有限公司 | Hydrogen sulfide corrosion resistant rubber waterstop and preparation method thereof |
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| CN1450105A (en) * | 2003-04-29 | 2003-10-22 | 上海交通大学 | High-performace water-absorbing expansion rubber and process for preparing same |
| CN102585390A (en) * | 2011-12-31 | 2012-07-18 | 衡水新陆交通器材有限公司 | Formula and preparation technology of CPE (Chlorinated Polyethylene) rubber waterstop |
| CN103087367A (en) * | 2013-01-18 | 2013-05-08 | 中国石油天然气股份有限公司 | High-performance water-swellable rubber and preparation method thereof |
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| CN1450105A (en) * | 2003-04-29 | 2003-10-22 | 上海交通大学 | High-performace water-absorbing expansion rubber and process for preparing same |
| CN102585390A (en) * | 2011-12-31 | 2012-07-18 | 衡水新陆交通器材有限公司 | Formula and preparation technology of CPE (Chlorinated Polyethylene) rubber waterstop |
| CN103087367A (en) * | 2013-01-18 | 2013-05-08 | 中国石油天然气股份有限公司 | High-performance water-swellable rubber and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106947203A (en) * | 2017-04-27 | 2017-07-14 | 河北润石橡塑有限公司 | A kind of being folded without breaking rubber fastening band and its preparation technology |
| CN106947203B (en) * | 2017-04-27 | 2019-03-08 | 河北润石橡塑有限公司 | A kind of being folded without breaking rubber fastening band and its preparation process |
| CN107189240A (en) * | 2017-07-05 | 2017-09-22 | 衡水大禹工程橡塑科技开发有限公司 | A kind of mildewproof rubber waterstop and its preparation technology |
| CN111376505A (en) * | 2018-12-29 | 2020-07-07 | 河北昊德橡塑有限公司 | Preparation method of rubber waterstop and rubber waterstop |
| CN111376505B (en) * | 2018-12-29 | 2021-12-17 | 河北昊德橡塑有限公司 | Preparation method of rubber waterstop and rubber waterstop |
| CN114672102A (en) * | 2022-05-26 | 2022-06-28 | 中裕铁信交通科技股份有限公司 | Hydrogen sulfide corrosion resistant rubber waterstop and preparation method thereof |
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Application publication date: 20161221 |