CN106243496A - A kind of plum tube toughening type masterbatch and preparation method - Google Patents
A kind of plum tube toughening type masterbatch and preparation method Download PDFInfo
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- CN106243496A CN106243496A CN201610629535.4A CN201610629535A CN106243496A CN 106243496 A CN106243496 A CN 106243496A CN 201610629535 A CN201610629535 A CN 201610629535A CN 106243496 A CN106243496 A CN 106243496A
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- plum tube
- toughening type
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- type masterbatch
- polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/16—Ethene-propene or ethene-propene-diene copolymers
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention open a kind of plum tube toughening type masterbatch and preparation method, belong to pipe material technical field.Plum tube toughening type masterbatch of the present invention includes the raw material of following mass percent: polypropylene 3 6%, polyethylene 3 6%, calcium carbonate 82 88%, Tissuemat E 3 6%, toughener 2 5%, antioxidant 0.1 0.3%, other auxiliary agents 0.3 0.5%.Toughening type masterbatch of the present invention joins and can reduce production cost in plum tube, improves the ring stiffness of plum tube, bending modulus, improves the intensity of plum tube, toughness and impact strength；The present invention adds linear low density polyethylene (LLDPE), improves fault growth rate and the tensile fracture of plum tube.
Description
Technical field
The invention belongs to pipe material technical field, relate to a kind of plum tube, specifically a kind of plum tube is female with toughening type
Material and preparation method.
Background technology
Plum tube is that the plum tube formed through unique mould for main material plus other formula with PVC particle is real
Thing shows the communication tubing of a kind of plum blossom-shaped, and also known as plum tube and honeycomb duct, this kind of pipe material inner wall is smooth, directly can wear optical cable,
Can save man-hour, it is rational in infrastructure, and use value is high, and the life-span is long.It is mainly used in advantage, movement, Tie Tong, UNICOM, Netcom, wide
The communication cable protecting pipes such as electricity.
Plum tube uses porous integrative-structure, good rigidity, uniform force.Product inwall coefficient of friction is little, wears cable brisk, executes
Work is simple and easy to do.There is position, multiple hole, pore can be reserved, improve communicating hole position utilization rate.Product Applicable temperature scope relatively big (+
80-40), all can use in the torrid zone and cold district.Joint uses socket join structure.Do not need any instrument can complete between pipe
Connect, it is simple to construct and safeguard.Plum tube is more than more than 30 years service life under Conditions of Buried Depth.
The toughening modifying of PVC material receives much concern always, utilizes elastic body toughening PVC, can cause the loss of rigidity simultaneously,
Inorganic filler can improve the rigidity of polymer, but because inorganic matter is poor with organic interface cohesion, makes toughness of material decline.
Summary of the invention
It is an object of the invention to provide a kind of plum tube toughening type masterbatch and preparation method.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of plum tube toughening type masterbatch, including the raw material of following mass percent: polypropylene 3-6%, polyethylene 3-
6%, calcium carbonate 82-88%, Tissuemat E 3-6%, toughener 2-5%, antioxidant 0.1-0.3%, other auxiliary agents 0.3-
0.5%.
As preferred further, polyethylene of the present invention be melt index be that the linear, low density of 2-6g/10min gathers
Ethylene.
As preferred further, antioxidant of the present invention is selected from Hinered phenols, hindered amines, phosphite ester or thioether
One or more in kind antioxidant, including in antioxidant 1010, antioxidant 1098, irgasfos 168 or antioxidant DSTDP
Plant or several.
As preferred further, toughener of the present invention selected from ethylene propylene diene rubber, polystyrene block copolymer,
One or more in polyolefin elastomer.
As preferred further, other auxiliary agents of the present invention one in coupling agent, the steady agent of light.
Invention additionally discloses a kind of method preparing plum tube toughening type masterbatch, it is characterised in that comprise the following steps:
(1) by proportioning, polypropylene, polyethylene, calcium carbonate, Tissuemat E, toughener, antioxidant, other auxiliary agents are added
In high-speed mixer, carry out mixed at high speed 5-10min, obtain mixture；
(2) said mixture is put in double screw extruder, carry out extrusion pelletize, obtain plum tube toughening type female
Material.
Beneficial effects of the present invention: toughening type masterbatch of the present invention joins and can reduce production cost in plum tube, improves prunus mume (sieb.) sieb.et zucc.
The ring stiffness of floral tube, bending modulus, improves the intensity of plum tube, toughness and impact strength；The present invention adds linear, low density
Polyethylene, improves elongation at break and the tensile fracture of plum tube.
Detailed description of the invention
Below in conjunction with embodiment, technical solution of the present invention is clearly and completely described, it is clear that described enforcement
Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiments that technical staff is obtained under not making creative work premise, broadly fall into present invention protection
Scope.
A kind of method preparing plum tube toughening type masterbatch, comprises the following steps: by proportioning, by polypropylene, polyethylene,
Calcium carbonate, Tissuemat E, toughener, antioxidant, other auxiliary agents join and carry out mixed at high speed 5-10min in high-speed mixer,
Obtain mixture；Mixture is put in double screw extruder, carry out extrusion pelletize, obtain plum tube toughening type masterbatch；With
In lower embodiment, polypropylene is PP (B8101), and polyethylene is LLDPE (7042)；
Embodiment 1
Proportioning weighs polypropylene 5%, polyethylene 5%, calcium carbonate 82%, Tissuemat E (PE wax) respectively by mass percentage
3%, ethylene propylene diene rubber 4.6%, antioxidant 1010 0.1%, coupling agent 0.3%, joins and carries out in high-speed mixer at a high speed
Mixing 5-10min, obtains mixture；Mixture is put in double screw extruder, carry out extrusion pelletize, obtain plum tube and increase
Tough type masterbatch.
After measured, embodiment 1 plum tube toughening type masterbatch is as follows for the performance preparing plum tube: impact strength
47kJ/m2, hot strength 38MPa, elongation at break 520%, bending strength 42MPa, bending modulus 1789MPa.
Embodiment 2
Proportioning weighs polypropylene 3%, polyethylene 3%, calcium carbonate 85%, Tissuemat E 5% respectively, gathers by mass percentage
Styrene block copolymer 3.2%, irgasfos 168 0.3%, silane coupler 0.5%, join and carry out height in high-speed mixer
Speed mixing 5-10min, obtains mixture；Mixture is put in double screw extruder, carry out extrusion pelletize, obtain plum tube and use
Toughening type masterbatch.
Measuring, the performance that embodiment 2 plum tube toughening type masterbatch is used for preparing plum tube is as follows: impact strength 43kJ/
m2, hot strength 40MPa, elongation at break 490%, bending strength 45MPa, bending modulus 1836MPa.
Embodiment 3
Proportioning weighs polypropylene 5%, polyethylene 4%, calcium carbonate 85%, Tissuemat E 3% respectively, gathers by mass percentage
Olefin elastomer 2.2%, antioxidant DSTDP 0.2%, antioxidant 10980.1%, the steady agent of light 0.5%, join mixed at high speed
Machine carries out mixed at high speed 5-10min, obtains mixture；Mixture is put in double screw extruder, carry out extrusion pelletize,
To plum tube toughening type masterbatch.
Measuring, the performance that embodiment 3 plum tube toughening type masterbatch is used for preparing plum tube is as follows: impact strength 45kJ/
m2, hot strength 45MPa, elongation at break 550%, bending strength 40MPa, bending modulus 2011MPa.
Embodiment 4
Proportioning weighs polypropylene 6%, polyethylene 6%, calcium carbonate 82%, Tissuemat E 3% respectively, gathers by mass percentage
Olefin elastomer 1.2%, polystyrene block copolymer 1%, irgasfos 168 0.2%, antioxidant 1010 0.1%, the steady agent of light
0.5%, join and high-speed mixer carries out mixed at high speed 5-10min, obtain mixture；Mixture is put into double screw extruder
In, carry out extrusion pelletize, obtain plum tube toughening type masterbatch.
Measuring, the performance that embodiment 4 plum tube toughening type masterbatch is used for preparing plum tube is as follows: impact strength 50kJ/
m2, hot strength 43MPa, elongation at break 514%, bending strength 42MPa, bending modulus 1985MPa.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and apply this
Bright.Case study on implementation obviously easily can be made various amendment by person skilled in the art, and described herein one
As principle be applied in other embodiments without through performing creative labour.Therefore, the invention is not restricted to enforcement case here
Example, those skilled in the art are according to the announcement of the present invention, and the improvement made without departing from scope and amendment all should be
Within protection scope of the present invention.
Claims (6)
1. a plum tube toughening type masterbatch, it is characterised in that include the raw material of following mass percent: polypropylene 3-6%,
Polyethylene 3-6%, calcium carbonate 82-88%, Tissuemat E 3-6%, toughener 2-5%, antioxidant 0.1-0.3%, other auxiliary agents
0.3-0.5%.
Plum tube toughening type masterbatch the most according to claim 1, it is characterised in that described polyethylene is that melt index is
The linear low density polyethylene (LLDPE) of 2-6g/10mi n.
Plum tube toughening type masterbatch the most according to claim 1, it is characterised in that described antioxidant is selected from hindered phenol
One or more in class, hindered amines, phosphite ester or thioether kind antioxidant, including antioxidant 1010, antioxidant 1098, resist
One or more in oxygen agent 168 or antioxidant DSTDP.
Plum tube toughening type masterbatch the most according to claim 1, it is characterised in that described toughener is selected from EPDM
One or more in rubber, polystyrene block copolymer, polyolefin elastomer.
Plum tube toughening type masterbatch the most according to claim 1, it is characterised in that other auxiliary agents described are selected from coupling
One in agent, the steady agent of light.
6. the method preparing plum tube toughening type masterbatch, it is characterised in that comprise the following steps:
(1) by proportioning, polypropylene, polyethylene, calcium carbonate, Tissuemat E, toughener, antioxidant, other auxiliary agents are joined height
Speed mixer carries out mixed at high speed 5-10mi n, obtains mixture；
(2) said mixture is put in double screw extruder, carry out extrusion pelletize, obtain plum tube toughening type masterbatch.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610629535.4A CN106243496A (en) | 2016-08-03 | 2016-08-03 | A kind of plum tube toughening type masterbatch and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610629535.4A CN106243496A (en) | 2016-08-03 | 2016-08-03 | A kind of plum tube toughening type masterbatch and preparation method |
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| CN106243496A true CN106243496A (en) | 2016-12-21 |
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| CN201610629535.4A Pending CN106243496A (en) | 2016-08-03 | 2016-08-03 | A kind of plum tube toughening type masterbatch and preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936367A (en) * | 2017-11-14 | 2018-04-20 | 舒城恒通通讯器材有限责任公司 | Plum tube tubular object extruding material and its preparation process are used in one kind communication |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100087C (en) * | 1998-06-18 | 2003-01-29 | 中国科学院化学研究所 | Stuffing mother particle for toughening polyolefine and preparation process and usage thereof |
| CN102040774A (en) * | 2010-12-20 | 2011-05-04 | 深圳市科聚新材料有限公司 | PP (polypropylene) filled masterbatch and method for preparing same |
| CN102746572A (en) * | 2011-04-21 | 2012-10-24 | 广东生之源数码电子有限公司 | Special modified polypropylene material for TV set rear shell and its production method |
| CN103214734A (en) * | 2013-03-26 | 2013-07-24 | 安徽双荣电器电缆有限公司 | Multifunctional polypropylene masterbatch and preparation method thereof |
-
2016
- 2016-08-03 CN CN201610629535.4A patent/CN106243496A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100087C (en) * | 1998-06-18 | 2003-01-29 | 中国科学院化学研究所 | Stuffing mother particle for toughening polyolefine and preparation process and usage thereof |
| CN102040774A (en) * | 2010-12-20 | 2011-05-04 | 深圳市科聚新材料有限公司 | PP (polypropylene) filled masterbatch and method for preparing same |
| CN102746572A (en) * | 2011-04-21 | 2012-10-24 | 广东生之源数码电子有限公司 | Special modified polypropylene material for TV set rear shell and its production method |
| CN103214734A (en) * | 2013-03-26 | 2013-07-24 | 安徽双荣电器电缆有限公司 | Multifunctional polypropylene masterbatch and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107936367A (en) * | 2017-11-14 | 2018-04-20 | 舒城恒通通讯器材有限责任公司 | Plum tube tubular object extruding material and its preparation process are used in one kind communication |
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Application publication date: 20161221 |