CN106242379A - A kind of water proof type Diatomeae wall material compositions and utilize its method preparing wall material - Google Patents
A kind of water proof type Diatomeae wall material compositions and utilize its method preparing wall material Download PDFInfo
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- CN106242379A CN106242379A CN201610609514.6A CN201610609514A CN106242379A CN 106242379 A CN106242379 A CN 106242379A CN 201610609514 A CN201610609514 A CN 201610609514A CN 106242379 A CN106242379 A CN 106242379A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/28—Polysaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/22—Natural resins, e.g. rosin
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
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- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of waterproof ventilating type Diatomeae wall material compositions, component that described compositions comprises interior layer component and waterproof outer is breathed freely, wherein, described interior layer component comprises Diatomeae powder body, sierozem power and Pulvis Talci, and described waterproof outer component of breathing freely is that Waterproof is breathed freely component；Described Diatomeae powder body gives compositions the strongest absorption property, it is possible to the harmful substances such as formaldehyde in active adsorption air, benzene, simultaneously can anion releasing；Described interior layer component also comprises natural plant fibre and natural plants jointing material, further, also comprises anion powder.What compositions of the present invention used is environment-friendly type raw material, and it will not discharge any harmful substance, and its can the abundant harmful substance such as the formaldehyde in adsorption chamber, benzene, maintenance room air is fresh；The wall material prepared by compositions of the present invention be able to maintain that indoor humidity in OK range, and can anion releasing and far infrared, and, there is oil resistant pollution resistance, and there is cleaning property.
Description
Technical field
The present invention relates to building material field, particularly relate to a kind of water proof type wall material compositions.
Background technology
Along with wall material market expanding day, the application of decoration wall material is more extensive, and people are to the requirement of wall material also
More and more higher, focusing on single angle change attractive in appearance from the past is to indoor environment global comfort, the safety lattice feature of environmental protection
Pay attention to comprehensively.
The indoor decoration wall material sold in the market has organic chemical industry's character mostly, generally contain formaldehyde, benzene and
The volatile material to human health such as ammonia.In order to reduce the content of indoor harmful substance, kieselguhr wall material is subject in recent years
Pay close attention to and application to increasing, but, kieselguhr wall material of the prior art does not contains only chemical composition and it is to having
The absorption of pest matter is limited.Further, the existence of existing wall material is difficult to safeguard and clean, it is easy to be injected into coffee, ink or other color
The drawback that color liquid pollutes.
Summary of the invention
In order to solve the problems referred to above, present inventor has performed and study with keen determination, design the wall material combination of a kind of pure environment-friendly type
Thing, this wall material compositions not only will not discharge harmful substance, and can adsorb the harmful substance in air, and meanwhile, utilizing should
The wall material that wall material compositions prepares is difficult to be noted color, be easily maintained and clean；It is embodied in:
(1) a kind of water proof type Diatomeae wall material compositions, wherein, described compositions comprises interior layer component and waterproof outer is saturating
Gas component, wherein, described interior layer component comprise the Diatomeae powder body of 20～60 weight portions, 20～40 weight portion sierozem power, 10
～20 Pulvis Talci of weight portion；
(2) according to the compositions described in above-mentioned (1), wherein,
Described interior layer component also comprise the natural plant fibre of 2～10 weight portions, 2～8 weight portion natural plants bonding
Material,
Described waterproof outer component of breathing freely is that breathe freely component, preferably this component of Waterproof can form waterproof ventilated membrane；
(3) according to the compositions described in above-mentioned (1) or (2), wherein,
Described interior layer component comprises: the Diatomeae powder body of 30～50 weight portions, 25～35 sierozem power, 12～18 of weight portion
The Pulvis Talci of weight portion, 4～8 natural plant fibre, 4～6 natural plants jointing materials of weight portion of weight portion,
Preferably, described interior layer component comprises: the Diatomeae powder body of 40 weight portions, the sierozem power of 30 weight portions, 16 weight
The Pulvis Talci of part, the natural plant fibre of 6 weight portions, the natural plants jointing material of 5 weight portions；
(4) according to the compositions above-mentioned (1) to one of (3) Suo Shu, wherein,
Described Diatomeae powder body is kieselguhr powder body and/or tripoli powder body, preferably tripoli powder body, wherein, described
Kieselguhr powder body and/or tripoli powder body are respectively preferably calcining one-level kieselguhr powder body and/or calcining one-level tripoli powder body；
And/or
Described sierozem power is calcining one-level sierozem power；And/or
Described natural plant fibre is by crops such as rice husk, Caulis et Folium Oryzae, wheat straw, corn straw, Cotton Stalk, wood flour and bamboo bits
Plant fiber's powder that the stalk stem of straw or other plant is made；And/or
Described natural plants jointing material is selected from natural gum class jointing material, resinae jointing material, natural rubber and eats
One or more in jointing material；
Preferably, the particle diameter of described kieselguhr powder body is 50～2000 mesh, preferably 100～1500 mesh, more preferably 300
～1000 mesh；And/or, described kieselguhr powder body contains micropore, and the aperture of described micropore is 50～3000nm, preferably 100～
1500nm, more preferably 200～800nm；And/or, the particle diameter of described tripoli powder body is 100～2000 mesh, preferably 500～
1500 mesh, more preferably 300～1000 mesh；And/or, described tripoli powder body contains micropore, the aperture of described micropore be 40～
80nm, preferably 50～70nm, more preferably 60nm；And/or, described natural plant fibre is powdery, and its mesh number is 10～200
Mesh, preferably 20～100 mesh, more preferably 50～80 mesh；
(5) according to the compositions above-mentioned (1) to one of (4) Suo Shu, wherein, described interior layer component also comprises 1～5 weight
Part, preferably 2～4 weight portions, the anion powder of more preferably 3 weight portions；
(6) according to the compositions above-mentioned (1) to one of (5) Suo Shu, wherein,
Described interior layer component also comprises natural toner, such as natural minerals toner, it is preferable that based in 1000 weight portions
Layer component, the consumption of natural toner is 0.5～10 weight portions, preferably 1～5 weight portions, more preferably 2～4 weight portions；With/
Or
Described interior layer component also comprises one or more in hollow glass micropearl, Graphene and albumen stone powder, it is preferable that
The particle diameter of described hollow glass micropearl is 20～200 μm, preferably 50～100 μm, more preferably 60～80 μm；And/or, described
The particle diameter of albumen stone powder is 100～10000 mesh, preferably 200～5000 mesh, more preferably 500～2000 mesh；And/or, described
The aperture of albumen stone powder is 5～50nm, preferably 10～40nm, more preferably 15～35nm；
(7) compositions according to claim 6, wherein,
Diatomeae powder body based on 100 weight portions, the consumption of Graphene is 2～10 weight portions, preferably 4～8 weight portions,
More preferably 6 weight portions；And/or
Diatomeae powder body based on 100 weight portions, the consumption of hollow glass micropearl is 2～15 weight portions, preferably 5～12
Weight portion, more preferably 8～10 weight portions；And/or
Diatomeae powder body based on 100 weight portions, the consumption of albumen stone powder is 5～30 weight portions, preferably 10～25 weights
Amount part, more preferably 15～20 weight portions；
(8) according to the compositions above-mentioned (1) to one of (7) Suo Shu, wherein, described Waterproof component of breathing freely is a kind of water
Property waterproof material, preferably emulsion paint with lotus leaf effect.
Another aspect of the present invention provides a kind of method utilizing above-mentioned composition to prepare water proof type wall material, specific as follows:
(9) method utilizing above-mentioned (1) to prepare water proof type wall material to the compositions one of (8) Suo Shu, comprises the following steps:
Step 1, take interior layer component, mix homogeneously, be added to the water, stirring, obtain internal layer slurry,
Step 2, take breathe freely component, preferably Waterproof of waterproof outer and breathe freely component, i.e. outer layer slurry,
Step 3, internal layer slurry step 1 obtained are applied on body of wall, obtain inner layer wall material,
Step 4, after inner layer wall material parches, then on it spraying or round brush outer layer slurry, obtain outer wall material；
(10) according to the method described in above-mentioned (9), wherein,
In step 1, interior layer component is 1:(1～1.4 with the weight ratio of water), preferably 1:(1～1.2), more preferably
1:1；And/or
In step 2, Waterproof component of breathing freely is pulpous state, can be used directly；And/or
The thickness of described inner layer wall material is 1-8mm, preferably 2-6mm, more preferably 3-5mm.
Detailed description of the invention
Below by the present invention is described in detail, the features and advantages of the invention will become more along with these explanations
For clear, clear and definite.
According to an aspect of the present invention, it is provided that a kind of water proof type Diatomeae wall material compositions, in described compositions comprises
Layer component and waterproof outer are breathed freely component.
Wherein, described interior layer component is used for preparing inner layer wall material, and described waterproof outer component of breathing freely is used for preparing outer wall
Material, when preparing wall material, after described interior layer component is applied in body of wall, then component of being breathed freely by waterproof outer covers outside it, obtains
There is the wall material of double-layer structure.
According to one of the present invention preferred embodiment, described interior layer component comprises following composition: Diatomeae powder body, ash calcium
Powder and Pulvis Talci.
According to one of the present invention preferred embodiment, described Diatomeae powder body is kieselguhr powder body and/or diatom rock dust
Body.
In further preferred embodiment, described Diatomeae powder body is tripoli powder body.
Wherein, kieselguhr powder body and tripoli powder body are respectively provided with microcellular structure, this microcellular structure give kieselguhr powder body and
The adsorptivity that tripoli powder body is the strongest, it is possible to the harmful substances such as the formaldehyde in adsorption chamber；Have simultaneously and absorb and discharge moisture
Effect, when indoor humidity is excessive, the moisture in micropore meeting absorption chamber, when indoor overdrying, micropore can discharge the moisture that it is interior, be used for
Control room humidity；Further, during micropore is to the absorption of moisture and release, class water fall effect can be produced, anion releasing,
I.e. alleged " air vitamin ", it is not only of value to health, and can eliminate the antibacterial in air, has sterilization and makees
With.Therefore, with kieselguhr powder body and/or tripoli powder body, the compositions as raw material is when for wall material, and the wall material obtained is not only
Will not discharge harmful substance, on the contrary can harmful substance in active adsorption air, and sterilization can be discharged and to useful negative of human body
Ion.
According to one of the present invention preferred embodiment, described Diatomeae powder body is calcining one-level Diatomeae powder body, specifically
Ground, described kieselguhr powder body and/or tripoli powder body are respectively preferably calcining one-level kieselguhr powder body and/or calcining one-level diatom
Rock dust body
Wherein, described calcining one-level Diatomeae powder body is to be obtained through calcining by Diatomeae powder body, and the purpose of calcining is cleaning
Impurity in Diatomeae powder body aperture, empties aperture, obtains more rich internal pore structure, and specific surface area significantly increases, and inhales
Attached performance significantly improves.
According to one of the present invention preferred embodiment, the particle diameter of described kieselguhr powder body is 50～2000 mesh.
In further preferred embodiment, the particle diameter of described kieselguhr powder body is 100～1500 mesh.
In the most preferred embodiment, the particle diameter of described kieselguhr powder body is 300～1000 mesh.
According to one of the present invention preferred embodiment, the particle diameter of described tripoli powder body is 100～2000 mesh.
In further preferred embodiment, the particle diameter of described tripoli powder body is 500～1500 mesh.
In the most preferred embodiment, the particle diameter of described tripoli powder body is 300～1000 mesh.
Wherein, the final purposes of described interior layer component is for wall material, is applied on body of wall, therefore, becomes in interior layer component
The particle diameter divided typically can not be too big, because wall material then can be caused too greatly to spread upon appearance after on body of wall be similar to the situation of pimple, because of
This, need its particle diameter the smaller the better, but, the least Cost Problems that will necessarily bring of particle diameter, therefore, size controlling is optimal one
In the range of.
According to one of the present invention preferred embodiment, described kieselguhr powder body contains micropore, and the aperture of described micropore is
50～3000nm.
In further preferred embodiment, described kieselguhr powder body contains micropore, the aperture of described micropore be 100～
1500nm。
In the most preferred embodiment, described kieselguhr powder body contains micropore, and the aperture of described micropore is 200
～800nm.
According to one of the present invention preferred embodiment, described tripoli powder body contains micropore, and the aperture of described micropore is
40～80nm.
In further preferred embodiment, described tripoli powder body contains micropore, the aperture of described micropore be 50～
70nm。
In the most preferred embodiment, described tripoli powder body contains micropore, and the aperture of described micropore is
60nm。
Wherein, the specific surface area of tripoli powder body is about 4 times of kieselguhr powder body, and its adsorption volume is about kieselguhr
4 times of powder body, therefore, its adsorption effect is far above kieselguhr powder body, and adsorption effect is more preferably the most repeatedly.Meanwhile, diatomite in powder
The aperture of body is much larger than the aperture of tripoli powder body, therefore, there will be the phenomenon of desorption when using kieselguhr powder body as wall material,
Because the molecular particle size of the harmful substance such as formaldehyde or benzene is respectively less than 1nm, and the aperture of kieselguhr powder body is 50～3000nm, far away
More than the particle diameter of the harmful substance of required absorption, therefore, it is easier to that after absorption desorption phenomenon occurs.And the aperture of tripoli powder body
Little much compared with for kieselguhr powder body, occur that the probability of desorption is the least；Further, in the space that aperture is less, moisture is carried out
When absorbing with release, collision between hydrone is more intensive is more prone to anion, and therefore, in theory, tripoli powder body is relatively
More anion can be discharged for kieselguhr powder body.Therefore, in this application, described Diatomeae powder body is preferably tripoli
Powder body.
According to one of the present invention preferred embodiment, in interior layer component, the consumption of Diatomeae powder body is 20～60 weights
Amount part.
In further preferred embodiment, in interior layer component, the consumption of Diatomeae powder body is 30～50 weight portions.
In the most preferred embodiment, in interior layer component, the consumption of Diatomeae powder body is 40 weight portions.
According to one of the present invention preferred embodiment, described sierozem power is calcining one-level sierozem power.
Wherein, described calcining one-level sierozem power is to be obtained through calcining by sierozem power.
According to one of the present invention preferred embodiment, in interior layer component, the consumption of sierozem power is 20～40 weight portions.
In further preferred embodiment, in interior layer component, the consumption of sierozem power is 25～35 weight portions.
In the most preferred embodiment, in interior layer component, the consumption of sierozem power is 30 weight portions.
According to one of the present invention preferred embodiment, described talcous particle diameter is 500～1500 mesh, preferably 800
～1300 mesh, about more preferably 1000 mesh.
Wherein, Pulvis Talci has resistance to fire action, therefore, gives the wall material flameproof effect finally given more preferably.
According to one of the present invention preferred embodiment, in interior layer component, talcous consumption is 10～20 weight portions.
In further preferred embodiment, in interior layer component, talcous consumption is 12～18 weight portions.
In the most preferred embodiment, in interior layer component, talcous consumption is 16 weight portions.
According to one of the present invention preferred embodiment, described interior layer component comprises the Diatomeae powder of 20～60 weight portions
Body, 20～40 sierozem power, 10～20 Pulvis Talci of weight portion of weight portion.
According to one of the present invention preferred embodiment in, described interior layer component also comprises natural plant fibre and natural plants
Thing jointing material.
According to one of the present invention preferred embodiment, described natural plant fibre is by rice husk, Caulis et Folium Oryzae, wheat straw, Semen Maydis
Plant fiber's powder that the stalk stem of the agricultural crop straws such as straw, Cotton Stalk, wood flour and bamboo bits or other plant is made.
Wherein, natural plant fibre is used to ensure that the environment-friendly type of compositions, pure natural property.Meanwhile, natural plant fibre
Addition be the plasticity improving compositions as coupling agent, give the cracking resistance that the wall material that obtains of later stage is certain.
According to one of the present invention preferred embodiment, the mesh number of described natural plant fibre is 10～200 mesh.
In further preferred embodiment, the mesh number of described natural plant fibre is 20～100 mesh.
In the most preferred embodiment, the mesh number of described natural plant fibre is 50～80 mesh.
Wherein, the mesh number of natural plant fibre is also the smaller the better, and its mesh number is the least, and the wall material surface obtained is the most smooth,
But its mesh number had better not be less than the pore size of Diatomeae powder body, because the aperture of Diatomeae powder body can be caused like that to block up
Plug, affects its absorption property.From many-sided consideration such as cost, wall material outward appearance, the mesh number controlling natural plant fibre is 10～200
Mesh.
According to one of the present invention preferred embodiment in, in interior layer component, the consumption of natural plant fibre is 2～10
Weight portion.
In further preferred embodiment, in interior layer component, the consumption of natural plant fibre is 4～8 weight portions.
In the most preferred embodiment, in interior layer component, the consumption of natural plant fibre is 6 weight portions.
According to one of the present invention preferred embodiment, described natural plants jointing material selected from natural gum class jointing material,
One or more in resinae jointing material, natural rubber and edible adhesive material.
In further preferred embodiment: described natural gum class jointing material includes gum arabic powder, peach gum powder, really
Rubber powder and tragacanth gum powder；Described resinae jointing material includes rosin tree cosmetics；Described edible adhesive material includes starch, Oryza glutinosa
Powder and mealy potato.
In the most preferred embodiment, described natural plants jointing material selected from natural plants rubber, I
One or more in uncle's natural gum powder, glutinous rice flour and mealy potato.
Wherein, described natural plants jointing material is ep-type material, pure natural raw material.
According to one of the present invention preferred embodiment, in interior layer component, the consumption of natural plants jointing material be 2～
8 weight portions.
In further preferred embodiment, in interior layer component, the consumption of natural plants jointing material is 4～6 weights
Amount part.
In the most preferred embodiment, in interior layer component, the consumption of natural plants jointing material is 5 weight
Part.
According to one of the present invention preferred embodiment in, described interior layer component also comprises 2～10 the natural of weight portion and plants
Fibres, 2～8 natural plants jointing materials of weight portion.
According to one of the present invention preferred embodiment, described interior layer component comprises: the Diatomeae powder of 30～50 weight portions
Body, 25～35 sierozem power, 12～18 Pulvis Talci, 4～8 natural plant fibre, 4～6 weights of weight portion of weight portion of weight portion
The natural plants jointing material of amount part.
In further preferred embodiment, described interior layer component comprises: the Diatomeae powder body of 40 weight portions, 30 weight
The sierozem power of part, the Pulvis Talci of 16 weight portions, the natural plant fibre of 6 weight portions, the natural plants jointing material of 5 weight portions.
According to one of the present invention preferred embodiment in, described interior layer component also comprises anion powder.
According to one of the present invention preferred embodiment, in interior layer component, the consumption of anion powder is 1～5 weight portions.
In further preferred embodiment, in interior layer component, the consumption of anion powder is 2～4 weight portions.
In the most preferred embodiment, in interior layer component, the consumption of anion powder is 3 weight portions.
According to one of the present invention preferred embodiment, described interior layer component also includes natural toner.
Wherein, described natural toner is natural minerals toner, its objective is to regulate the color of interior layer component.
According to one of the present invention preferred embodiment, interior layer components based on 1000 weight portions, the consumption of natural toner
It is 0.5～10 weight portions.
In further preferred embodiment, interior layer components based on 1000 weight portions, the consumption of natural toner be 1～
5 weight portions.
In the most preferred embodiment, interior layer components based on 1000 weight portions, the consumption of natural toner is 2
～4 weight portions.
According to one of the present invention preferred embodiment, described interior layer component also include hollow glass micropearl, Graphene and
One or more in albumen stone powder.
Wherein:
Described hollow glass micropearl is a kind of glass microballoon through special processed, and its thermal conductance is poor, has the strongest
Heat insulation effect, simultaneously can alleviate weight and there is soundproof effect；
Graphene is the thinnest material, and it has the obdurability of excellence, gives the preferable mechanical property of wall material；Its tool simultaneously
There is bigger specific surface area, it is possible to play the effect of the harmful substances such as absorption indoor formaldehyde.Further, Graphene can enter diatom
Within the aperture of class powder body, not only make Graphene fine dispersion, and further increase the specific surface area of Diatomeae powder body,
I.e. improve its absorption property；On the other hand, Graphene has the highest ion-exchange capacity and high conductivity, and wall material is not likely to produce
Electrostatic, effectively prevent the absorption to dust of the wall material surface；
Described albumen stone powder is through calcining, acquisition of pulverizing and/or sieve by opal, and it has microcellular structure equally, its
Micropore is more than Diatomeae powder body, therefore, compared with Diatomeae powder body, albumen stone powder less than the micropore of Diatomeae powder body, porosity
There is more preferable absorption property, due to its small-bore, its to the De contamination probability of harmful substance less than Diatomeae powder body, i.e. its
Absorption to harmful substance is better than Diatomeae powder body.Meanwhile, albumen stone powder can be with anion releasing, and it is to make up Diatomeae
The situation that the burst size of powder body anion is inadequate, secondly, described albumen stone powder can also discharge far infrared, wherein, far infrared energy
Enough make hydrone activation, the oxygen content of raising health, improve microcirculqtory system, and can enhance metabolism.
According to one of the present invention preferred embodiment, the particle diameter of described hollow glass micropearl is 20～200 μm.
In further preferred embodiment, the particle diameter of described hollow glass micropearl is 50～100 μm.
In the most preferred embodiment, the particle diameter of described hollow glass micropearl is 60～80 μm.
Wherein, the particle diameter of hollow glass micropearl can not be too big, and particle diameter is the biggest affects the attractive in appearance of metope.The least meeting of particle diameter causes
Unnecessary cost waste.
According to one of the present invention preferred embodiment, the particle diameter of described albumen stone powder is 100～10000 mesh, is preferably
200～5000 mesh, more preferably 500～2000 mesh.
According to one of the present invention preferred embodiment, the aperture of described albumen stone powder is 5～50nm, preferably 10～
40nm, more preferably 15～35nm.
Wherein, the aperture of albumen stone powder is the least, even less than the aperture of Diatomeae powder body.So, it is relatively beneficial to be adsorbed with
Pest matter and be not resulted in that De contamination phenomenon occurs.
According to one of the present invention preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of Graphene is
2～10 weight portions.
In further preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of Graphene is 4～8
Weight portion.
In the most preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of Graphene is 6
Weight portion.
Wherein, the consumption of Graphene seldom just can play well effect, the problem that therefore, there is no need to worry cost.
According to one of the present invention preferred embodiment, Diatomeae powder body based on 100 weight portions, hollow glass micropearl
Consumption is 2～15 weight portions.
In further preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of hollow glass micropearl
It is 5～12 weight portions.
In the most preferred embodiment, Diatomeae powder body based on 100 weight portions, the use of hollow glass micropearl
Amount is 8～10 weight portions.
According to one of the present invention preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of albumen stone powder
It is 5～30 weight portions.
In further preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of albumen stone powder is 10
～25 weight portions.
In the most preferred embodiment, Diatomeae powder body based on 100 weight portions, the consumption of albumen stone powder is
15～20 weight portions.
Wherein, albumen stone powder consumption need not be too many, in the present invention, or with Diatomeae powder body as bulk composition, and albumen
Stone powder has been miscellaneous function.
According to one of the present invention preferred embodiment, described waterproof outer component of breathing freely is that Waterproof is breathed freely component.
At further preferred embodiment, described Waterproof component of breathing freely can form waterproof ventilated membrane.
Wherein, described Waterproof component of breathing freely is the outer layer of wall material, gives that wall material is waterproof, antifouling, the characteristic of easy to clean.
Described Waterproof component of breathing freely is slurry, is applied in wall outer side, after it solidifies, is formed on wall material surface and has one
Determining thickness and have resilient waterproof membrane, this waterproof membrane can be contaminated by protective bulkhead material, and owing to it has water proofing property, easily
In cleaning or scouring.Meanwhile, the waterproof membrane of formation has breathability, so not affecting the suction to indoor harmful substance of the inner layer wall material
Attached, nor affect on inner layer wall material to the absorption of indoor moisture and release, the most do not affect internal kieselguhr powder body or diatom rock dust
Body anion releasing.Therefore, on the basis of inner layer wall material, apply outer wall material, not only do not interfere with the performance of inner layer wall material,
And improve the overall resistance of wall material, easy to clean.
According to one of the present invention preferred embodiment, described Waterproof component of breathing freely is a kind of Waterproof material,
Such as can use the existing waterproof material of prior art.
In further preferred embodiment, described Waterproof component of breathing freely uses ISPO company and Guangzhou of Germany
The micro structure organosilicon emulsion paint that Pu Hua environmental friendly material company limited develops according to lotus leaf effect mechanism, i.e. lotus leaf effect latex
Paint.
Wherein, the employing of this emulsion paint with lotus leaf effect has the materials such as the hypogalactia agent organic silicon emulsion of lasting hydrophobicity,
And form a nanoscale microstructure, so that its film has the surface texture of similar Flos Nelumbinis leaf, reach hydrophobic permeable
The Waterproof material of clean-keeping function.
Another aspect of the present invention provides a kind of method utilizing above-mentioned Diatomeae wall material compositions to prepare wall material, wherein,
Said method comprising the steps of:
Step 1, take interior layer component, mix homogeneously, be added to the water, stirring, obtain internal layer slurry.
According to one of the present invention preferred embodiment, in step 1, the weight ratio of interior layer component and water be 1:(1～
1.4)。
In further preferred embodiment, in step 1, interior layer component is 1:(1～1.2 with the weight ratio of water).
In the most preferred embodiment, in step 1, interior layer component is 1:1 with the weight ratio of water.
Wherein, in step 1, interior layer component is added water and form slurry, in order to spread upon on body of wall, if the consumption of water
Too much, then slurry is diluter, the most easy to apply or smear disposed slurry can occur flowing be difficult to solidification, if the consumption of water is very little, then in
Layer component does not can be uniformly dispersed in water, and the slurry obtained is uneven, and particulate matter may be contained in inside.
Step 2, take breathe freely component, preferably Waterproof of waterproof outer and breathe freely component, i.e. outer layer slurry.
According to one of the present invention preferred embodiment, in step 2, Waterproof component of breathing freely is pulpous state, and it is not required to
To mix with water, but directly to use.
In step 1, mixing time is unrestricted, as long as can stir, and general stirring 10～30min.
Step 3, internal layer slurry step 1 obtained are applied on body of wall, it is preferable that thickness is 1-8mm, preferably 2-
6mm, more preferably 3-5mm. obtain inner layer wall material.
Wherein, before internal layer slurry is applied in body of wall, first body of wall is cleaned, repairs hollowing and the crackle of body of wall
Deng.
According to one of the present invention preferred embodiment, the thickness of described inner layer wall material is 1～8mm.
In further preferred embodiment, the thickness of described inner layer wall material is 2～6mm.
In the most preferred embodiment, the thickness of described inner layer wall material is 3～5mm.
Step 4, after inner layer wall material parches, then on it spraying or round brush step 2 prepare outer layer slurry, obtain outer layer
Wall material.
After above-mentioned steps 1～step 4, i.e. obtain the wall material prepared by above-mentioned Diatomeae wall material compositions, described wall
Material includes two-layer；Internal layer is prepared by interior layer component, it is possible to the harmful substance in absorption air, keeps indoor humidity balance, and energy
Anion releasing and far infrared；Outer layer is prepared by waterproof outer component of breathing freely, i.e. outer layer is Waterproof ventilated membrane, and it does not affects
The performance of internal layer, and improve pollution resistance and the cleanablity of wall material.
The present invention is had the advantages that
(1) Diatomeae wall material composition components of the present invention is simple, and raw material is easy to get；
(2) what Diatomeae wall material compositions of the present invention used is environment-friendly type raw material, and it will not discharge any harmful
Material；
(3) the wall material prepared by Diatomeae wall material compositions of the present invention is environment-friendly type wall material, will not distribute nuisance
Matter, and its can the abundant harmful substance such as the formaldehyde in adsorption chamber, benzene, maintain room air fresh；
(4) the wall material prepared by Diatomeae wall material compositions of the present invention is able to maintain that indoor humidity is in OK range
In, and can anion releasing and far infrared；
(5) the wall material prepared by Diatomeae wall material compositions of the present invention has insulation, the advantage such as heat insulation, fire-resistant；
(6) the wall material prepared by Diatomeae wall material compositions of the present invention has an oil resistant pollution resistance, and have can be clear
Rationality.
Embodiment
The present invention is further described below by way of specific embodiment.But these embodiments are the most exemplary, not
Protection scope of the present invention is constituted any restriction.
The preparation of embodiment 1 wall material
Take calcining one-level tripoli 200g, calcining one-level sierozem power 400g, Pulvis Talci 200g, natural plant fibre respectively
20g, gum arabic powder 20g, anion powder 50g, albumen stone powder 60g and natural toner 0.95g, add in agitator, fully
Stirring 10min, adds 950g water, stirs 20min, obtains inner layer wall material slurry；
Take 900g Waterproof to breathe freely component i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
The preparation of embodiment 2 wall material
Take calcining one-level kieselguhr 300g, calcining one-level sierozem power 350g, Pulvis Talci 180g, natural plant fibre respectively
40g, rosin tree cosmetics 40g, anion powder 40g, albumen stone powder 75g, hollow glass micropearl 15g and natural toner 2g, addition is stirred
Mix in device, be sufficiently stirred for 5min, add 1100g water, stir 25min, obtain inner layer wall material slurry；
Take 900g Waterproof to breathe freely component i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
The preparation of embodiment 3 wall material
Take calcining one-level kieselguhr 400g, calcining one-level sierozem power 300g, Pulvis Talci 160g, natural plant fibre respectively
60g, starch 50g, anion powder 30g, Graphene 25g, hollow glass micropearl 30g and natural toner 4g, add in agitator, fill
Divide stirring 15min, add 1100g water, stir 20min, obtain inner layer wall material slurry；
Take 1000g Waterproof, i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
The preparation of embodiment 4 wall material
Take calcining one-level tripoli 250g, calcining one-level kieselguhr 250g, calcining one-level sierozem power 250g, Pulvis Talci respectively
120g, natural plant fibre 80g, glutinous rice flour 60g, anion powder 20g and natural toner 3g, add in agitator, be sufficiently stirred for
10min, adds 1050g water, stirs 20min, obtains inner layer wall material slurry；
Take 1000g watery water-proofing agent, i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
The preparation of embodiment 5 wall material
Take calcining one-level tripoli 600g, calcining one-level sierozem power 200g, Pulvis Talci 100g, natural plant fibre respectively
100g, gum arabic powder 80g and anion powder 10g, add in agitator, be sufficiently stirred for 10min, add 1100g water, stir
Mix 20min, obtain inner layer wall material slurry；
Take 1100g, i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
The preparation of embodiment 6 wall material
Take calcining one-level tripoli 600g, calcining one-level sierozem power 200g, Pulvis Talci 100g, natural plant fibre respectively
100g, gum arabic powder 80g, anion powder 10g and 20g Graphene, add in agitator, be sufficiently stirred for 10min, add
1100g water, stirs 20min, obtains inner layer wall material slurry；
Take 1100g water preparation, i.e. outer wall material slurry；
Inner layer wall material slurry is applied on body of wall, obtains inner layer wall material；
After inner layer wall material parches, then spraying or round brush outer wall material slurry on it, obtain outer wall material.
Comparative example
The preparation of comparative example 1 wall material
Repeating the preparation process of embodiment 5, wherein, in step 1, without tripoli, remaining condition is the most constant.
The preparation of comparative example 2 wall material
Repeating the preparation process of embodiment 5, wherein, in step 1, without gum arabic powder, remaining condition is the most not
Become.
The preparation of comparative example 3 wall material
Repeat the preparation process of embodiment 5, wherein, do not carry out step 2 and step 4, the most only smear interior layer component, do not smear
Waterproof is breathed freely component, and remaining condition is the most constant.
Experimental example
Experimental example 1
Take respectively in the compositions addition 550g water that 500g is prepared by embodiment 5 and comparative example 2, stir, then divide
Other film, on A face wall and B face wall, carries out observing finding after 10h:
Wall material caking property on A face wall is good, does not has any shedding phenomenon；
Wall material caking property on B face wall is slightly worse, occurs in that shedding phenomenon.
Analyzing reason: B face wall uses the compositions prepared by comparative example 2, said composition is not added with natural plants and glues
Condensation material.
Experimental example 2
Taking in the compositions addition 800g water that 800g is prepared by embodiment 5, stir, film is in confined space C
On wall；Take commercially available conventional coating for wall surface film on the interior wall of confined space D, wherein, in smearing the first two confined space
All without any harmful substance.
After 24h, confined space is detected, in confined space C, do not detect the harmful substances such as any formaldehyde, but airtight
The detection harmful substance such as formaldehyde, benzene in the D of space, is about: free formaldehyde 1.07mg/m3, benzene 1.10mg/m3。
Thus illustrating that compositions of the present invention is environment-friendly type wall material compositions, it is used as during wall material to discharge any to have
Pest matter, low-carbon (LC), zero-emission.
Experimental example 3
Take compositions that 800g prepares by embodiment 5 and the compositions that 800g is prepared by comparative example 1 respectively, be separately added into
Stirring in 800g water, film is on the interior wall of confined space E and confined space F the most respectively, wherein, and two confined spaces
, the most just contain the mixture of formaldehyde, benzene and toluene；
Detecting after 0.5h, find that the harmful substance in E reduces to the 50% of original vol, the harmful substance contents in F is several
Constant；
Testing after 1h, find that the harmful substance in E reduces to the 20% of original vol, the harmful substance contents in F is almost
Constant；
Detecting after 1.5h, find that the harmful substance in E disappears, can't detect, the harmful substance contents in F is but
Almost unchanged.
Thus illustrate, compositions of the present invention can harmful substance in active adsorption environment, purify air.
Experimental example 4
Take respectively in the compositions addition 550g water that 500g is prepared by embodiment 5 and comparative example 3, stir, then divide
Other film, on G face wall and H face wall, smears greasy dirt at G face wall and H face wall: the greasy dirt on G face wall can use water artificially respectively
Wipe；
Greasy dirt on H face wall can not be wiped with water, does not therefore have rational treating method, can only again brush.
It is indicated above that the wall material prepared by compositions of the present invention has clanability.
Above in association with detailed description of the invention and exemplary example, the present invention is described in detail, but these explanations are also
It is not considered as limiting the invention.It will be appreciated by those skilled in the art that without departing from the spirit and scope of the invention,
Can carry out technical solution of the present invention and embodiment thereof multiple equivalencing, modify or improve, these each fall within the present invention
In the range of.Protection scope of the present invention is as the criterion with claims.
Claims (10)
1. a waterproof ventilating type Diatomeae wall material compositions, it is characterised in that described compositions comprises interior layer component and outer layer
Waterproof and breathable component, wherein,
Described interior layer component comprises the Diatomeae powder body of 20～60 weight portions, 20～40 sierozem power, 10～20 weight of weight portion
The Pulvis Talci of part.
Compositions the most according to claim 1, it is characterised in that
Described interior layer component also comprises the natural plant fibre of 2～10 weight portions, 2～8 natural plants jointing materials of weight portion；
Described waterproof outer component of breathing freely is that breathe freely component, preferably this component of Waterproof can form waterproof ventilated membrane.
Compositions the most according to claim 1 and 2, it is characterised in that
Described interior layer component comprises: the Diatomeae powder body of 30～50 weight portions, 25～35 sierozem power, 12～18 weight of weight portion
Part Pulvis Talci, 4～8 natural plant fibre, 4～6 natural plants jointing materials of weight portion of weight portion；
Preferably, described interior layer component comprises: the Diatomeae powder body of 40 weight portions, the sierozem power of 30 weight portions, 16 weight portions
Pulvis Talci, the natural plant fibre of 6 weight portions, the natural plants jointing material of 5 weight portions.
4. according to the compositions one of claims 1 to 3 Suo Shu, it is characterised in that
Described Diatomeae powder body is kieselguhr powder body and/or tripoli powder body, preferably tripoli powder body, wherein, described diatom
Soil powder body and/or tripoli powder body are respectively preferably calcining one-level kieselguhr powder body and/or calcining one-level tripoli powder body；With/
Or
Described sierozem power is calcining one-level sierozem power；And/or
Described natural plant fibre is by agricultural crop straws such as rice husk, Caulis et Folium Oryzae, wheat straw, corn straw, Cotton Stalk, wood flour and bamboo bits
Or Plant fiber's powder that the stalk stem of other plant is made；And/or
Described natural plants jointing material is selected from natural gum class jointing material, resinae jointing material, natural rubber and edible adhesive
One or more in material；
Preferably, the particle diameter of described kieselguhr powder body is 50～2000 mesh, preferably 100～1500 mesh, more preferably 300～
1000 mesh；And/or, described kieselguhr powder body contains micropore, and the aperture of described micropore is 50～3000nm, preferably 100～
1500nm, more preferably 200～800nm；And/or, the particle diameter of described tripoli powder body is 100～2000 mesh, preferably 500～
1500 mesh, more preferably 300～1000 mesh；And/or, described tripoli powder body contains micropore, the aperture of described micropore be 40～
80nm, preferably 50～70nm, more preferably 60nm；And/or, described natural plant fibre is powdery, and its mesh number is 10～200
Mesh, preferably 20～100 mesh, more preferably 50～80 mesh.
5. according to the compositions one of Claims 1-4 Suo Shu, it is characterised in that
Described interior layer component also comprises 1～5 weight portions, preferably 2～4 weight portions, the anion powder of more preferably 3 weight portions.
6. according to the compositions one of claim 1 to 5 Suo Shu, it is characterised in that
Described interior layer component also comprises natural toner, such as natural minerals toner, it is preferable that internal layer groups based on 1000 weight portions
Point, the consumption of natural toner is 0.5～10 weight portions, preferably 1～5 weight portions, more preferably 2～4 weight portions；And/or
Described interior layer component also comprises one or more in hollow glass micropearl, Graphene and albumen stone powder, it is preferable that described
The particle diameter of hollow glass micropearl is 20～200 μm, preferably 50～100 μm, more preferably 60～80 μm；And/or, described albumen
The particle diameter of stone powder is 100～10000 mesh, preferably 200～5000 mesh, more preferably 500～2000 mesh；And/or, described albumen
The aperture of stone powder is 5～50nm, preferably 10～40nm, more preferably 15～35nm.
Compositions the most according to claim 6, it is characterised in that
Diatomeae powder body based on 100 weight portions, the consumption of Graphene is 2～10 weight portions, and preferably 4～8 weight portions are more excellent
Elect 6 weight portions as；And/or
Diatomeae powder body based on 100 weight portions, the consumption of hollow glass micropearl is 2～15 weight portions, preferably 5～12 weight
Part, more preferably 8～10 weight portions；And/or
Diatomeae powder body based on 100 weight portions, the consumption of albumen stone powder is 5～30 weight portions, preferably 10～25 weight portions,
More preferably 15～20 weight portions.
8. according to the compositions one of claim 1 to 7 Suo Shu, it is characterised in that described Waterproof component of breathing freely is a kind of
Waterproof material, preferably emulsion paint with lotus leaf effect.
9. the method that the compositions utilizing one of claim 1 to 8 described prepares water proof type wall material, comprises the following steps:
Step 1, take interior layer component, mix homogeneously, be added to the water, stirring, obtain internal layer slurry；
Step 2, take breathe freely component, preferably Waterproof of waterproof outer and breathe freely component, i.e. outer layer slurry；
Step 3, internal layer slurry step 1 obtained are applied on body of wall, obtain inner layer wall material；
Step 4, after inner layer wall material parches, then on it spraying or the outer layer slurry of round brush step 2, obtain outer wall material.
Method the most according to claim 9, wherein,
In step 1, interior layer component is 1:(1～1.4 with the weight ratio of water), preferably 1:(1～1.2), more preferably 1:1；
And/or
In step 2, Waterproof component of breathing freely is pulpous state, and it can be used directly；And/or
In step 3, the thickness of described inner layer wall material is 1-8mm, preferably 2-6mm, more preferably 3-5mm.
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