CN106242300A - A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics - Google Patents
A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics Download PDFInfo
- Publication number
- CN106242300A CN106242300A CN201610663614.7A CN201610663614A CN106242300A CN 106242300 A CN106242300 A CN 106242300A CN 201610663614 A CN201610663614 A CN 201610663614A CN 106242300 A CN106242300 A CN 106242300A
- Authority
- CN
- China
- Prior art keywords
- glass
- vain
- crystallization
- expect
- building decorative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0063—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing waste materials, e.g. slags
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain, expects as primary raw material in vain with useless domestic glass, by adding appropriate additive, uses sintering process to carry out coring and crystallization, thus prepares building decorative glass ceramics；By weight percentage, during dispensing: useless domestic glass expects 73.00 93.50 parts in vain, 0 6.00 parts of calcium fluoride, calcium oxide 0 8.00 parts, aluminium oxide 0 3.00 parts, potassium nitrate 0 4.00 parts, boric acid 0 3.00 parts, waterglass 1.00 3.00 parts；The technical problem to be solved in the present invention is: do not carry out careful division by kind when utilizing for cullet, cause cullet utilization rate the highest, the problem that reconstituted product quality is unstable, a kind of method expecting in vain to produce building decorative glass ceramics with useless domestic glass is provided, recycling for cullet opens a new way, has preferable prospect, suitably promotes.
Description
Technical field
The present invention relates to the preparation method of a kind of building decorative glass ceramics, a kind of with the white material in cullet be
Primary raw material (＞ 73wt%), is induced by addition and promotes that the additive of crystallize uses sintering process to prepare the side of devitrified glass
Method.
Background technology
Devitrified glass is also referred to as glass ceramics, is a kind of a kind of composite glass being controlled crystallize and obtain, main
If making glass surface or internal generation different crystal by suitable heat treatment and making crystal homoepitaxial and obtain.Parent glass
Glass and separate out the performance of performance joint effect devitrified glass of crystal, so that devitrified glass can have low bulk, heat-resisting, high-strength
The various functions such as degree, high tenacity.Building decorative glass ceramics belongs to a kind of building material, and its physicochemical property and decorative effect are better than
Common glass, pottery, lithotome and sheet metal, is widely used in various top-grade building, is described as world today's building
The Novel centre material of adnornment industry.The production technology of devitrified glass mainly has two kinds: 1 fusion method.Its technique is: dispensing → found
Glass → cast molding → heat treatment crystallize → devitrified glass；2 sintering process.Its technique is: dispensing → fusion cast glass → shrend becomes
Glass particle → be dried → screening → loading refractory-material dies → sintering is crystallizated into devitrified glass.The molding work of both technique
Skill route and crystallize mode are different, have in common that needs design through composition, then by suitable heat treatment system
Degree makes glass can separate out particular kind of crystal at internal or interface, thus obtains special performance.Micro-for architectural decoration
For crystal glass, sintering process is ripe due to moulding process, is particularly well-suited to the production of large size plate, is that current building decoration is micro-
The main production process of crystal glass.Building nucleated glass is with CaO-Al2O3-SiO2Be glass be main, chemical composition is
(wt%): SiO250%-75%；CaO 5%-25%；Al2O33%-15%；Na2O+K2O 2%-15%；B2O31%-
5%；BaO 1%-10%；ZnO 1%-10%；Sb2O31%-2.5%, the crystal of precipitation is mainly wollastonite (CaSiO3),
The devitrified glass of different colours can be obtained by adding different colorant.The raw materials used mainly quartz sand of manufacture devitrified glass,
Kaolin, Anhydrite, calcite, limestone and some fluxs, clarifier, and a small amount of industrial chemicals is with adjusting component.
Cullet belongs to a kind of city mineral resources, may be used for manufacturing construction material (tapestry brick, coating), pavement material
(glass asphalt, glass microballoon), insulation material (foam glass, glass cotton) etc..Give up in developed countries such as Switzerland, Germany, Japan
Glass recycles and has the most reached more than 80%, and world average level is also close to 50%.Stone matter metope paving such as Japan 1/3rd
The devitrified glass parian plate that patch manufactures with cullet.China is glass production big country and consumption big country, the useless glass of annual generation
Glass amount is about 31,000,000 tons, and recovery utilization rate is between 25～30%.And China mainly manufactures building to the utilization of cullet
The low value-added products such as material, glass microballoon, glass cotton, main cause is that China's cullet recycling is started late, classification
The social mechanism reclaimed falls behind, and renovation process is few.It is low that recycling system unsound directly results in cullet unit take-back cost,
Associated production enterprise uses cullet to be that raw material is not so good as newly to purchase mineral or industrial chemicals is calculated, and therefore result in China's cullet profit
By the lowest situation of rate.This situation had both destroyed environment, wasted again the regenerated resources of preciousness.Cullet is utilized to produce
Building decorative glass ceramics large usage quantity, so a heat subject of always cullet recycling research, and achieved with
A lot of achievements, this respect a lot of documents and patent report.As cullet is broken into powder by CN201310437328.5,
Use sintering process to prepare crystallizing glass sheet material in the range of 500-110 DEG C, do not add any additive, cullet kind used
Not segmentation, it is not indicated that separate out devitrified glass kind.CN201310330983.0 by discarded glass and melting waste slag by 1:
The ratio of 1.5 mixes, and then presses forming of wollastonite devitrified glass with mineral or industrial chemicals supplementary not enough or disappearance
Oxide, by compound through melted, uses sintering process to prepare devitrified glass after shrend.This patent uses additive to adjust micro-
The composition of crystal glass, precipitation crystal is wollastonite, but cullet kind is not the most segmented.CN200410104277.5 is by cullet
After pulverizing, add diopside type crystallize accelerator, wollastonite type crystallize accelerator, oligoclase type crystallize accelerator, leucite
One or more of type crystallize accelerator, carry out reaction-crystallization in 800～1050 DEG C of insulations 4～10h and sinter at ambient pressure
Building microcrystalline glass prepared by type.Cullet is not involved in crystallize, and the crystallize accelerator of addition is actually the micro-of certain specific composition
Crystal glass raw material, self crystallize of crystallize accelerator being sintered together with cullet powder under high temperature.CN201110305757.8
Using the waste residue of the low nickel matte of oxygen-enriched side-blowing melting and CRT cullet (wt%) melting waste slag 45% by weight percentage, CRT gives up glass
Glass 45%, calcite ash 3-5%, quartz sand 5%, the ratio mixing of additive 0.5-1% (cobalt oxide or nickel oxide), 1530
DEG C fusing, 1120 DEG C of crystallization prepare devitrified glass, for building materials and chemical industry.
Cullet is of a great variety, and if do not segmented directly use, glass ingredient fluctuation is excessive easily causes production technology
Control difficulty big, properties of product stability is also had a significant impact.SB/T 10900-2012 implements in JIUYUE in 2013 on the 1st, right
Cullet has carried out detailed division.By the difference of cullet kind, it is utilized targetedly, its utilization rate will be improved,
Increase product stability.The general designation of glass container that daily cullet refers to discard, glass packaging, Glass Craft etc..Daily
The white glass referring to coloured glass content less than 1wt% expected in vain by useless domestic glass.
Summary of the invention
The present invention solves above-mentioned deficiency, when utilizing for cullet, do not carry out careful division by kind, cause useless glass
Glass utilization rate is the highest, the problem that reconstituted product quality is unstable, it is provided that a kind of cullet produces building decorative glass ceramics
Method, the method particularly expecting in vain with useless domestic glass to produce building decorative glass ceramics, the recycling for cullet is opened up
One new way, has preferable sight, suitably promotes.
The technical solution adopted for the present invention to solve the technical problems is: provide a kind of Deformation of Glass-Ceramic Plate for Building Decoration material
Preparation method, mainly expects as raw material in vain with cullet, by adding appropriate calcium fluoride, calcium oxide, aluminium oxide, potassium nitrate, boron
Acid, waterglass are additive.By weight percentage, during dispensing: useless domestic glass expects 73.00-93.50 part, calcium fluoride 0-in vain
6.00 parts, calcium oxide 0-8.00 part, aluminium oxide 0-3.00 part, potassium nitrate 0-4.00 part, boric acid 0-3.00 part, waterglass 1.00-
3.00 part.Use sintering process to carry out coring and crystallization, thus prepare building decorative glass ceramics, specifically include following steps:
(1) pre-treatment: carry out cullet sorting, cleaning and homogenizing；
(2) crushing and screening: use hammer mill that cullet is broken into glass sand；
(3) mixing: weigh each raw material in proportion and put into mix homogeneously in mixer；
(4) die-filling: then compound to be loaded in refractory material or heat resisting steel mould, surface is struck off and is compacted；
(5) sintering crystallization: will be equipped with carrying out coring and crystallization in the mould feeding sintering crystallization furnace of compound；
(6) annealing: the devitrified glass crystalline phase annealing good by sintering crystallization, eliminates stress；
(7) demoulding: the devitrified glass sintered is removed from the molds；
(8) trimming: the burr of devitrified glass crude green body are cut away；
(9) grinding and polishing: the devitrified glass after trimming is polished the finished product being polished to different surfaces glossiness.
What the present invention provided utilizes cullet to expect the method preparing building decorative glass ceramics in vain, is characterized in: to being adopted
Cullet raw material be distinctly claimed, decrease the fluctuation requirement to process conditions of cullet material composition.Not to compound
Carry out high temperature melting, reduce devitrified glass energy consumption.Meanwhile, the devitrified glass sintering that this invention provides is with crystallization temperature relatively
Wollastonite devitrified glass is low, just can separate out at cullet interface with canasite (K at 750-850 DEG C2Na4Ca5Si12O30F4)
With a-canasite (K3Na3Ca5Si12O30F4) it is the R of principal crystalline phase2O-CaO-SiO2-F system glass ceramics.This kind of devitrified glass
It is sintered together with mother glass, makes final crystallized glass article have the advantage such as high intensity, high-fracture toughness.High-fracture toughness
The characteristic that this crystallized glass article is prone to processing can be given, its working (machining) efficiency and yield rate can be improved.
In sum, the present invention by expecting to be broken into the fine particle of suitable particle diameter in vain suitableeer by adding by cullet
Amount additive adjusts the cullet composition in interface, and making at a lower temperature to separate out principal crystalline phase between cullet granule is silicon alkali
The crystal of calcium stone.The method that the present invention provides, without cullet and additive are carried out high temperature melting, greatly reduces production energy
Consumption.The lath-shaped canasite being interspersed separated out, makes devitrified glass have the highest intensity and fracture toughness, is suitable to quickly
Processing and not easy fracture.Owing to have employed the white material in cullet, coloring ion content is low, is particularly suitable for preparing white micro-crystals glass
Glass.Present invention process is simple, and production cost is low, good product performance, and working (machining) efficiency is high, can be again the high added value circulation of cullet
Utilize and a new way is provided, there is good economic benefit and social benefit.
Accompanying drawing explanation
The present invention is further illustrated below in conjunction with accompanying drawing:
Fig. 1 is the microscopic appearance figure that the present invention is prepared as embodiment 1；
Fig. 2 is the microscopic appearance figure that the present invention is prepared as embodiment 2；
Detailed description of the invention
All features disclosed in this specification, or disclosed all methods or during step, except mutually exclusive
Feature and/or step beyond, all can combine by any way.
Any feature disclosed in this specification (including any accessory claim, summary), unless specifically stated otherwise,
By other equivalences or there is the alternative features of similar purpose replaced.I.e., unless specifically stated otherwise, each feature is a series of
An example in equivalence or similar characteristics.
Embodiment 1:
Useless domestic glass material in vain is utilized to prepare the step of devitrified glass:
(1) cullet selects the waste product of certain emulsion opal glass tableware manufacturing enterprise, for opaque white color, after crushing and screening after complete
Portion passes through 60 mesh sieves.
(2) according to the following percentages by weight (wt%) weighs each raw material.Useless domestic glass expects 93.00 parts in vain, calcium fluoride 1.00
Part, calcium oxide 2.00 parts, aluminium oxide 1.00 parts, potassium nitrate 1.00 parts, boric acid 0.50 part, waterglass 1.50 parts.Calcium fluoride, oxidation
Calcium, aluminium oxide, potassium nitrate, boric acid iron-holder≤0.1wt%.Wherein calcium fluoride, calcium oxide and aluminium oxide all by 300 mesh,
Potassium nitrate and boric acid are all by 200 mesh.Modulus of water glass is 1, is sprayed onto on raw material when mixing after diluting 5 times.
(3) load weighted various raw materials are put in mixer, action of forced stirring 5-15 minute, until the mixing of all raw materials
Uniformly.
(4) compound is put on belt conveyor the intermediate bunker being delivered to above mould.60 kilograms are weighed with electronic scale
Compound, is uniformly laid in mould.Mould inner wall scribbles kaolin paste or lays one layer of heat-resistant fibrous paper.
(5) mould that will be equipped with compound is sent in roller kilns, rises to 450 DEG C by the heating rate of 2 DEG C/min, then presses
The heating rate of 5 DEG C/min rises to 550 DEG C and is incubated 2h, then rises to 950 DEG C by the heating rate of 10 DEG C/min and is incubated 1h,
With after annealing.
(6) microcrystal glass plate after annealing is removed from the molds, cuts into 1000 × 1000mm size, then throw
Light makes devitrified glass finished product sheet material.
The finished product crystallizing glass sheet material made is prepared as its performance of suitable sample test.Performance parameter is as follows: density
2.51g/cm3；Mohs' hardness 6.5；Rupture strength 60.0MPa；Comprcssive strength 450.0MPa；Glossiness 89 °；Water absorption rate 0.By micro-
Crystal glass burnishing surface soaks 30 seconds in the HF acid solution kind that concentration is 5% (v%), by its microcosmic shape of electronics scanning electron microscopic observation
Looks, as shown in Figure 1.
Embodiment 2:
Useless domestic glass material in vain is utilized to prepare the step of devitrified glass:
(1) cullet selects the useless emulsion opal glass bottle reclaimed, for opaque white color, through choosing, clean, dry, crush, sieving
All by 60 mesh sieves after point.
(2) according to the following percentages by weight (wt%) weighs each raw material.Useless domestic glass expects 89.00 parts in vain, calcium fluoride 3.00
Part, calcium oxide 2.00 parts, aluminium oxide 1.00 parts, potassium nitrate 2.00 parts, boric acid 1.50 parts, waterglass 1.50 parts.Calcium fluoride, oxidation
Calcium, aluminium oxide, potassium nitrate, boric acid iron-holder≤0.1wt%.Wherein calcium fluoride, calcium oxide and aluminium oxide all by 300 mesh,
Potassium nitrate and boric acid are all by 200 mesh.Modulus of water glass is 1, is sprayed onto on raw material when mixing after diluting 5 times.
(3) load weighted various raw materials are put in mixer, action of forced stirring 5-15 minute, until the mixing of all raw materials
Uniformly.
(4) compound is put on belt conveyor the intermediate bunker being delivered to above mould.60 kilograms are weighed with electronic scale
Compound, is uniformly laid in mould.Mould inner wall scribbles kaolin paste or lays one layer of heat-resistant fibrous paper.
(5) mould that will be equipped with compound is sent in sintering furnace, rises to 450 DEG C by the heating rate of 2 DEG C/min, then presses
The heating rate of 5 DEG C/min rises to 650 DEG C and is incubated 2h, then rises to 1050 DEG C by the heating rate of 10 DEG C/min and is incubated
1h, with after annealing.
(6) microcrystal glass plate after annealing is removed from the molds, cuts into 1000 × 1000mm size, then throw
Light makes devitrified glass finished product sheet material.
The finished product crystallizing glass sheet material made is prepared as its performance of suitable sample test.Performance parameter is as follows: density
2.49g/cm3；Mohs' hardness 6.0；Rupture strength 53.0MPa；Comprcssive strength 390.0MPa；Glossiness 85 °；Water absorption rate 0.1%.
Devitrified glass burnishing surface is soaked 30 seconds in the HF acid solution kind that concentration is 5% (v%), with its microcosmic of electronics scanning electron microscopic observation
Pattern, as shown in Figure 2.
The basic teaching of the present invention is illustrated, for there is the people of the usual technical ability in this area, and many extensions and change
Changing will be aobvious and the person of being apparent from.The present invention disclosed due to description can be other spy without departing from present invention spirit or general characteristics
Definite form is implemented, and some forms of these particular forms have been noted, so, description embodiments of the disclosure should be regarded as
Illustrate rather than restriction.The scope of the present invention is to be defined by appended claim rather than by described above institute circle
Fixed, within the scope of falling into being changed and will be included in it of the impartial meaning of claim and scope.
Claims (8)
1. utilize useless domestic glass to expect the method preparing building decorative glass ceramics in vain, it is characterized in that: with useless domestic glass
White material is primary raw material, by adding appropriate additive, uses sintering process to carry out coring and crystallization, thus it is micro-to prepare building decoration
Crystal glass；Its composition of raw materials is, prepares by following weight ratio: useless domestic glass expects 73.00-93.50 part, calcium fluoride 0-6.00 in vain
Part, calcium oxide 0-8.00 part, aluminium oxide 0-3.00 part, potassium nitrate 0-4.00 part, boric acid 0-3.00 part, waterglass 1.00-3.00
Part.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 1, its
Feature is: described useless domestic glass expects it is clear glass or emulsion opal glass in vain.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 1, its
Feature is: described additive is calcium fluoride, calcium oxide, aluminium oxide, potassium nitrate, the group of one or more in boric acid and waterglass
Close.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 1, its
Feature is: described sintering process includes coring and two processes of crystallization；In described nucleating course: nucleation temperature is 450 DEG C-650 DEG C,
Nucleation time is 0.5h-5h；Described crystallization process: crystallization temperature is 750 DEG C-1050 DEG C, crystallization time is 0.5h-7h.
5. utilize useless domestic glass to expect to prepare the side of building decorative glass ceramics in vain according to any one described in claim 1-4
Method, is characterized in that, described preparation method comprises the following steps:
(1) expect useless domestic glass in vain to carry out to sort, clean, homogenizing；
(2) crushing and screening: use hammer mill to expect in vain to crush by useless domestic glass；
(3) mixing: weigh each raw material in proportion and put into mix homogeneously in mixer；
(4) die-filling: to coat kaolin paste or one layer of heat-resistant fibrous paper of place mat at refractory material or heat resisting steel mould inner wall, then
Compound is loaded in refractory material or heat resisting steel mould, use scraper plate struck off on surface and be compacted；
(5) sintering crystallization: will be equipped with compound mould send into sintering crystallization furnace in, the sintering crystallization furnace of employing be shuttle kiln,
Tunnel cave or roller kilns；Nucleation temperature is 450 DEG C-650 DEG C, and nucleation time is 0.5h-5h, and crystallization temperature is 750 DEG C-1050
DEG C, crystallization time is 0.5h-7h；Also crystallization process can be directly entered through suitable heating rate, crystallization temperature is 750 DEG C-
1050 DEG C, crystallization time is 0.5h-7h；
(6) annealing: according to die-filling thickness, uses known Annealing Temperature of Glass system to anneal；
(7) demoulding: use machinery or the method for manpower, the devitrified glass sintered is removed from the molds；
(8) trimming: cut away the burr of devitrified glass crude green body with cutting machine；
(9) grinding and polishing: use the special polished machine of devitrified glass or stone polishing machine that the devitrified glass after trimming is prepared as different table
The finished product of face glossiness.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 5, its
Feature is: in described step (2), useless domestic glass expects to be broken for 26-90 mesh glass sand in vain.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 5, its
Feature is: the thickness loading compound time die-filling in described step (4) is 10mm-25mm.
A kind of method utilizing useless domestic glass to expect preparation building decorative glass ceramics in vain the most according to claim 5, its
Feature is: in described step (5), compound is in sintering crystallization temperature-rise period, during by room temperature to 450 DEG C, heating rate≤2 DEG C/
min；When 450 DEG C to 1050 DEG C, heating rate≤10 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610663614.7A CN106242300A (en) | 2016-08-12 | 2016-08-12 | A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610663614.7A CN106242300A (en) | 2016-08-12 | 2016-08-12 | A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106242300A true CN106242300A (en) | 2016-12-21 |
Family
ID=57592028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610663614.7A Pending CN106242300A (en) | 2016-08-12 | 2016-08-12 | A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106242300A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107311459A (en) * | 2017-06-30 | 2017-11-03 | 合肥利裕泰玻璃制品有限公司 | A kind of devitrified glass and preparation method thereof |
| CN108083644A (en) * | 2017-12-28 | 2018-05-29 | 武汉理工大学 | A kind of method that devitrified glass is prepared using molten blast furnace slag |
| CN110117815A (en) * | 2019-06-21 | 2019-08-13 | 鲁米星特种玻璃科技股份有限公司 | A kind of method and device of artificial synthesized large scale fluorophologopite |
| CN113732955A (en) * | 2021-09-03 | 2021-12-03 | 维达力实业（赤壁）有限公司 | Frosted glass and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445956A (en) * | 2014-12-01 | 2015-03-25 | 南昌航空大学 | Method for preparing porous glass ceramics by waste glass through low-temperature melting and high temperature foaming |
| CN105293929A (en) * | 2015-10-27 | 2016-02-03 | 武汉理工大学 | Method for preparing microcrystalline glass grinding balls through molybdenum tailings |
-
2016
- 2016-08-12 CN CN201610663614.7A patent/CN106242300A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445956A (en) * | 2014-12-01 | 2015-03-25 | 南昌航空大学 | Method for preparing porous glass ceramics by waste glass through low-temperature melting and high temperature foaming |
| CN105293929A (en) * | 2015-10-27 | 2016-02-03 | 武汉理工大学 | Method for preparing microcrystalline glass grinding balls through molybdenum tailings |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107311459A (en) * | 2017-06-30 | 2017-11-03 | 合肥利裕泰玻璃制品有限公司 | A kind of devitrified glass and preparation method thereof |
| CN108083644A (en) * | 2017-12-28 | 2018-05-29 | 武汉理工大学 | A kind of method that devitrified glass is prepared using molten blast furnace slag |
| CN110117815A (en) * | 2019-06-21 | 2019-08-13 | 鲁米星特种玻璃科技股份有限公司 | A kind of method and device of artificial synthesized large scale fluorophologopite |
| CN113732955A (en) * | 2021-09-03 | 2021-12-03 | 维达力实业（赤壁）有限公司 | Frosted glass and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103539357B (en) | A kind of Silicon-slag microcrystalline glass and preparation method thereof | |
| CN103395995B (en) | Production method for producing microcrystalline glass by using waste glass and smelting waste | |
| CN102942303B (en) | A kind of utilize granite waste material to prepare high-strength wearable engineering devitrified glass and preparation method | |
| CN101265027A (en) | Formulation of imperforate micro-spar sheet material and manufacturing method thereof | |
| CN105669173A (en) | Thermal insulating decorative ceramic plate produced by comprehensive utilization of perlite waste and production method thereof | |
| CN106242300A (en) | A kind of method utilizing useless domestic glass to expect in vain to prepare building decorative glass ceramics | |
| CN102079625A (en) | Microcrystal glass manufactured by using tailing solid waste and manufacturing method thereof | |
| CN102923958A (en) | Novel microcrystal glass ceramic composite board and preparation method thereof | |
| CN109704583A (en) | A kind of devitrified glass and its production method | |
| CN102795774A (en) | Method for manufacturing nano microcrystal sheet material by utilizing quartz sand | |
| CN108358455B (en) | Method for preparing microcrystalline glass by using lead-zinc tailings and quartz tailings | |
| CN107572826B (en) | A kind of microcrystalline jade ornament materials and preparation method thereof based on graphene | |
| CN105884200A (en) | Method for producing microcrystalline glass-ceramic composite material from industrial fly ash and vitrification slag | |
| CN102219380A (en) | Method for producing glass-ceramics plate by using construction waste | |
| CN1329328C (en) | Method for preparing micro crystal glass plate for building using waste glass | |
| CN108358456A (en) | A method of preparing devitrified glass using golden tailing and fluorite tailing | |
| CN101787786A (en) | Preparation method of non-porous nano crystalline glass ground decoration tile | |
| CN101792264A (en) | Microcrystalline jade and preparation method thereof | |
| CN102690061A (en) | Method for producing high-whiteness glass ceramic product | |
| CN105819694B (en) | Devitrified glass and preparation method thereof | |
| CN101811827A (en) | Glass ceramic raw material prepared by utilizing scrapped glass ceramic and method for producing glass ceramic products by utilizing same | |
| CN102344251A (en) | Preparation method for lepidolite glass ceramic | |
| CN108395105A (en) | A method of preparing devitrified glass using copper silver tailing and cullet | |
| CN108558214A (en) | A method of preparing devitrified glass using crystal waste slag and cullet | |
| CN106630647A (en) | Heatproof microcrystalline glassware formula and manufacturing technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination |