CN106242282A - A kind of ceramic glaze of absorbable electromagnetic radiation and preparation method thereof - Google Patents
A kind of ceramic glaze of absorbable electromagnetic radiation and preparation method thereof Download PDFInfo
- Publication number
- CN106242282A CN106242282A CN201610716893.9A CN201610716893A CN106242282A CN 106242282 A CN106242282 A CN 106242282A CN 201610716893 A CN201610716893 A CN 201610716893A CN 106242282 A CN106242282 A CN 106242282A
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- CN
- China
- Prior art keywords
- glaze
- electromagnetic radiation
- ceramic glaze
- witherite
- buddha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 24
- 230000005670 electromagnetic radiation Effects 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 26
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims abstract description 14
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 11
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052907 leucite Inorganic materials 0.000 claims abstract description 11
- 239000002893 slag Substances 0.000 claims abstract description 11
- 229910052642 spodumene Inorganic materials 0.000 claims abstract description 11
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 acrylic acid core polysaccharide Chemical class 0.000 claims abstract description 7
- YLSLSHTYFFBCKG-UHFFFAOYSA-N bismuth;oxomolybdenum Chemical compound [Mo].[Bi]=O YLSLSHTYFFBCKG-UHFFFAOYSA-N 0.000 claims abstract description 6
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims abstract description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 6
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 6
- 239000005017 polysaccharide Substances 0.000 claims abstract description 6
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000000498 ball milling Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 238000003682 fluorination reaction Methods 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 239000011521 glass Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses ceramic glaze of a kind of absorbable electromagnetic radiation and preparation method thereof, relate to ceramic glaze technical field, be mainly made up of leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, plant ash, Firebrake ZB, magnesium carbonate, strontium carbonate, aluminium fluoride, lead monoxide, diboron trioxide, molybdenum oxide bismuth, witherite, acrylic acid core polysaccharide, polyvinyl alcohol etc..The ceramic glaze glaze surface evenness of the present invention is high; surface gloss is good; composition lead monoxide, Buddha's warrior attendant YAOSHI and the witherite wherein added; electromagnetic wave near its human body that can absorb and decay; and the electromagnetic wave of absorption is distributed with form of thermal energy; so can form an electromagnetic wave weakened region plane centered by it, thus play the effect of protection electromagnetic radiation, contribute to protecting health.
Description
Technical field
The present invention relates to ceramic glaze technical field, the ceramic glaze of a kind of absorbable electromagnetic radiation and system thereof
Preparation Method.
Background technology
Ceramic glaze is attached to the nature of glass thin layer on ceramic body surface.With raw mineral materials (such as Anhydrite, quartz, Kaolin
Mix according to a certain ratio with industrial chemicals and be finely ground into paste liquid, imposing on billet surface, forming through high-temperature calcination.Tie from microcosmic
Structure is seen, the crystal separated out during containing glass state material and a small amount of bubble, non-vitreous silica granule and cooling.Have and be analogous to glassy state
Physics and chemical characteristic, waterproof, smooth and glossy, be difficult to stain, and the mechanical strength of goods, heat stability can be improved
And chemical stability.Glaze also can use various decoration to strengthen the artistic effect of goods.
Along with the development of society, various household electrical appliance are the most gradually employed, and therewith, family's electromagnetic radiation is more and more tighter
Weight, existing ceramic glaze does not has the effect of absorption of electromagnetic radiation, increasingly can not meet the requirement of people.
Summary of the invention
The invention aims to make up the deficiencies in the prior art, it is provided that the ceramic glaze of a kind of absorbable electromagnetic radiation and
Its preparation method.
It is an object of the invention to be achieved through the following technical solutions:
The ceramic glaze of a kind of absorbable electromagnetic radiation, is made up of following raw material: leucite 14-16, spodumene 6-8, antimony
Slag 4-6, Buddha's warrior attendant YAOSHI 7-9, plant ash 3-5, Firebrake ZB 2-4, magnesium carbonate 2-4, strontium carbonate 1-3, aluminium fluoride 1-2, an oxidation
Lead 2-4, diboron trioxide 3-5, molybdenum oxide bismuth 2-4, witherite 5-7, acrylic acid core polysaccharide 1-3, polyvinyl alcohol 6-8.
The preparation method of the ceramic glaze of a kind of absorbable electromagnetic radiation, comprises the following steps:
(1) each raw material is weighed by weight；
(2) roasting, grinding: by leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, witherite mix homogeneously, pulverize, and crosses 50-100
Mesh sieve, then at 780-820 DEG C, roasting 2-3 hour, then remain each raw material with other and appropriate water joins in the lump
In ball mill, it is desirable to the weight percent content of water controls at 35%-45%, at 55-58 DEG C, ball milling 13-15 hour, to glaze
Slurry granularity is 30-40 μm；
(3) heat old: glaze slip is stored in cylinder, is heated to 60-65 DEG C of insulation, deposits 30-36 hour；
(4) glaze spraying: be sprayed onto by glaze slip in 56-60 DEG C of adobe, glaze spraying thickness is 0.1-0.2mm for the first time, and then skin drying enters
Row second time glaze spraying, glaze spraying thickness is 0.3-0.5mm for the second time, dries；
(5) burn till: base substrate is sent in flint tunnel-type and sinter, in nitrogen protection atmosphere at 1450-1470 DEG C, be incubated 4-6
Hour, then it is cooled to room temperature with the speed of 65-70 DEG C/h.
It is an advantage of the current invention that:
The ceramic glaze glaze surface evenness of the present invention is high, and surface gloss is good, the composition lead monoxide that wherein adds, Buddha's warrior attendant YAOSHI and
Witherite, the electromagnetic wave near its human body that can absorb and decay, and the electromagnetic wave of absorption is distributed with form of thermal energy, so can
Form an electromagnetic wave weakened region plane centered by it, thus play the effect of protection electromagnetic radiation, contribute to protecting people
Body is healthy.
Detailed description of the invention
Embodiment 1, the ceramic glaze of a kind of absorbable electromagnetic radiation, it is made up of following weight portion (kg) raw material: leucite 14,
Spodumene 6, antimony slag 4, Buddha's warrior attendant YAOSHI 7, plant ash 3, Firebrake ZB 2, magnesium carbonate 2, strontium carbonate 1, aluminium fluoride 1, lead monoxide 2,
Diboron trioxide 3, molybdenum oxide bismuth 2, witherite 5, acrylic acid core polysaccharide 1, polyvinyl alcohol 6.
The preparation method of the ceramic glaze of a kind of absorbable electromagnetic radiation, comprises the following steps:
(1) each raw material is weighed by weight；
(2) roasting, grinding: by leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, witherite mix homogeneously, pulverize, and crosses 50-100
Mesh sieve, then at 780 DEG C, roasting 2 hours, then remain each raw material with other and appropriate water joins ball mill in the lump
In, it is desirable to the weight percent content of water controls 35%, and at 55 DEG C, ball milling 13 hours, is 30 μm to glaze slip granularity；
(3) heat old: glaze slip is stored in cylinder, is heated to 60 DEG C of insulations, deposits 30 hours；
(4) glaze spraying: being sprayed onto by glaze slip in 56 DEG C of adobes, glaze spraying thickness is 0.1mm for the first time, skin drying, then carries out second
Secondary glaze spraying, glaze spraying thickness is 0.3mm for the second time, dries；
(5) burn till: base substrate is sent in flint tunnel-type and sinter, in nitrogen protection atmosphere at 1450 DEG C, be incubated 4 hours, then
It is cooled to room temperature with the speed of 65 DEG C/h.
Embodiment 2, the ceramic glaze of a kind of absorbable electromagnetic radiation, it is made up of following weight portion (kg) raw material: leucite 15,
Spodumene 7 antimony slag 5, Buddha's warrior attendant YAOSHI 8, plant ash 4, Firebrake ZB 3, magnesium carbonate 3, strontium carbonate 2, aluminium fluoride 1, lead monoxide 3, three
Aoxidize two boron 4, molybdenum oxide bismuth 3, witherite 6, acrylic acid core polysaccharide 2, polyvinyl alcohol 7.
The preparation method of the ceramic glaze of a kind of absorbable electromagnetic radiation, comprises the following steps:
(1) each raw material is weighed by weight；
(2) roasting, grinding: by leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, witherite mix homogeneously, pulverize, and crosses 50-100
Mesh sieve, then at 800 DEG C, roasting 2.5 hours, then remain each raw material with other and appropriate water joins ball milling in the lump
In machine, it is desirable to the weight percent content of water controls 40%, at 57 DEG C, ball milling 14 hours, is 35 μm to glaze slip granularity；
(3) heat old: glaze slip is stored in cylinder, is heated to 63 DEG C of insulations, deposits 33 hours；
(4) glaze spraying: being sprayed onto by glaze slip in 58 DEG C of adobes, glaze spraying thickness is 0.1mm for the first time, skin drying, then carries out second
Secondary glaze spraying, glaze spraying thickness is 0.4mm for the second time, dries；
(5) burn till: base substrate is sent in flint tunnel-type and sinter, in nitrogen protection atmosphere at 1460 DEG C, be incubated 5 hours, then
It is cooled to room temperature with the speed of 68 DEG C/h.
Embodiment 3, the ceramic glaze of a kind of absorbable electromagnetic radiation, it is made up of following weight portion (kg) raw material: leucite 16,
Spodumene 8, antimony slag 6, Buddha's warrior attendant YAOSHI 9, plant ash 5, Firebrake ZB 4, magnesium carbonate 4, strontium carbonate 3, aluminium fluoride 2, lead monoxide 4,
Diboron trioxide 5, molybdenum oxide bismuth 4, witherite 7, acrylic acid core polysaccharide 3, polyvinyl alcohol 8.
The preparation method of the ceramic glaze of a kind of absorbable electromagnetic radiation, comprises the following steps:
(1) each raw material is weighed by weight；
(2) roasting, grinding: by leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, witherite mix homogeneously, pulverize, and crosses 50-100
Mesh sieve, then at 820 DEG C, roasting 3 hours, then remain each raw material with other and appropriate water joins ball mill in the lump
In, it is desirable to the weight percent content of water controls 45%, and at 58 DEG C, ball milling 15 hours, is 40 μm to glaze slip granularity；
(3) heat old: glaze slip is stored in cylinder, is heated to 65 DEG C of insulations, deposits 36 hours；
(4) glaze spraying: being sprayed onto by glaze slip in 60 DEG C of adobes, glaze spraying thickness is 0.2mm for the first time, skin drying, then carries out second
Secondary glaze spraying, glaze spraying thickness is 0.5mm for the second time, dries；
(5) burn till: base substrate is sent in flint tunnel-type and sinter, in nitrogen protection atmosphere at 1470 DEG C, be incubated 6 hours, then
It is cooled to room temperature with the speed of 70 DEG C/h.
The ceramic glaze main performance testing result that above-described embodiment 1-3 prepares is as shown in the table:
The ceramic glaze main performance testing result that table 1 embodiment 1-3 prepares
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Glossiness | 112 | 113 | 110 |
| Rupture strength (MPa) | 104 | 107 | 105 |
Claims (2)
1. the ceramic glaze of an absorbable electromagnetic radiation, it is characterised in that: it is made up of following raw material: leucite 14-16,
Spodumene 6-8, antimony slag 4-6, Buddha's warrior attendant YAOSHI 7-9, plant ash 3-5, Firebrake ZB 2-4, magnesium carbonate 2-4, strontium carbonate 1-3, fluorination
Aluminum 1-2, lead monoxide 2-4, diboron trioxide 3-5, molybdenum oxide bismuth 2-4, witherite 5-7, acrylic acid core polysaccharide 1-3, polyethylene
Alcohol 6-8.
The preparation method of the ceramic glaze of a kind of absorbable electromagnetic radiation the most according to claim 1, it is characterised in that: include
Following steps:
(1) each raw material is weighed by weight；
(2) roasting, grinding: by leucite, spodumene, antimony slag, Buddha's warrior attendant YAOSHI, witherite mix homogeneously, pulverize, and crosses 50-100
Mesh sieve, then at 780-820 DEG C, roasting 2-3 hour, then remain each raw material with other and appropriate water joins in the lump
In ball mill, it is desirable to the weight percent content of water controls at 35%-45%, at 55-58 DEG C, ball milling 13-15 hour, to glaze slip
Granularity is 30-40 μm；
(3) heat old: glaze slip is stored in cylinder, is heated to 60-65 DEG C of insulation, deposits 30-36 hour；
(4) glaze spraying: be sprayed onto by glaze slip in 56-60 DEG C of adobe, glaze spraying thickness is 0.1-0.2mm for the first time, and then skin drying enters
Row second time glaze spraying, glaze spraying thickness is 0.3-0.5mm for the second time, dries；
(5) burn till: base substrate is sent in flint tunnel-type and sinter, in nitrogen protection atmosphere at 1450-1470 DEG C, be incubated 4-6
Hour, then it is cooled to room temperature with the speed of 65-70 DEG C/h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716893.9A CN106242282B (en) | 2016-08-25 | 2016-08-25 | A kind of ceramic glaze and preparation method thereof of absorbable electromagnetic radiation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716893.9A CN106242282B (en) | 2016-08-25 | 2016-08-25 | A kind of ceramic glaze and preparation method thereof of absorbable electromagnetic radiation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106242282A true CN106242282A (en) | 2016-12-21 |
| CN106242282B CN106242282B (en) | 2019-01-11 |
Family
ID=57595543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610716893.9A Active CN106242282B (en) | 2016-08-25 | 2016-08-25 | A kind of ceramic glaze and preparation method thereof of absorbable electromagnetic radiation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106242282B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110965004A (en) * | 2019-09-04 | 2020-04-07 | 陈淑萍 | Preparation method of high-temperature corrosion resistant Mg-Pb-Al-B nuclear shielding material |
| CN111875252A (en) * | 2020-08-11 | 2020-11-03 | 鲁山花瓷股份有限公司 | Ore health-preserving fancy glaze and glazing method thereof |
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| CN103396164A (en) * | 2013-07-25 | 2013-11-20 | 郑州大学 | High-temperature stereoscopic glaze and preparation method thereof |
| CN103482958A (en) * | 2013-09-03 | 2014-01-01 | 金正敏 | Manufacturing method of radiation-resistant architectural ceramic |
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2016
- 2016-08-25 CN CN201610716893.9A patent/CN106242282B/en active Active
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| CN1084143A (en) * | 1993-08-08 | 1994-03-23 | 广州市长凌实业有限公司 | A kind of making of artificial crystalline stone and colorize method |
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| CN103482958A (en) * | 2013-09-03 | 2014-01-01 | 金正敏 | Manufacturing method of radiation-resistant architectural ceramic |
| WO2016091048A1 (en) * | 2014-12-09 | 2016-06-16 | 大汉国际控股有限公司 | Ultra-smooth glaze and preparation method thereof |
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| Title |
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| 苏珊•皮特森等: "《陶瓷工艺与艺术》", 31 July 2009 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110965004A (en) * | 2019-09-04 | 2020-04-07 | 陈淑萍 | Preparation method of high-temperature corrosion resistant Mg-Pb-Al-B nuclear shielding material |
| CN110965004B (en) * | 2019-09-04 | 2022-05-24 | 扬州斯帕克实业有限公司 | Preparation method of high-temperature corrosion resistant Mg-Pb-Al-B nuclear shielding material |
| CN111875252A (en) * | 2020-08-11 | 2020-11-03 | 鲁山花瓷股份有限公司 | Ore health-preserving fancy glaze and glazing method thereof |
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| Publication number | Publication date |
|---|---|
| CN106242282B (en) | 2019-01-11 |
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