CN106240126A - Polyborosiloxane carbon fiber fabric swatch and dissolving dipping hot pressing thereof are for method - Google Patents

Polyborosiloxane carbon fiber fabric swatch and dissolving dipping hot pressing thereof are for method Download PDF

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Publication number
CN106240126A
CN106240126A CN201610605586.3A CN201610605586A CN106240126A CN 106240126 A CN106240126 A CN 106240126A CN 201610605586 A CN201610605586 A CN 201610605586A CN 106240126 A CN106240126 A CN 106240126A
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China
Prior art keywords
carbon cloth
polyborosiloxane
composite plate
carbon
hot pressing
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Granted
Application number
CN201610605586.3A
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Chinese (zh)
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CN106240126B (en
Inventor
刘艳辉
高景龙
苏靖宇
尹正帅
李勇
智业
臧翰文
张宇
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Shenyang Ligong University
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Shenyang Ligong University
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses polyborosiloxane carbon cloth composite plate and dissolve dipping hot pressing for method, with carbon cloth and polyborosiloxane performed polymer as raw material, carbon cloth being carried out pretreatment, prepares polyborosiloxane carbon cloth composite plate.Polyborosiloxane performed polymer is dissolved in a solvent, makes impregnation liquid, the carbon cloth through pretreatment is immersed impregnation liquid 38 minutes, after taking-up nature dries, put in vacuum drying oven and dry 12 hours at 50 DEG C；Carbon cloth after processing stacks in a mold, uses that accurate tablet machine is hot-forming obtains polyborosiloxane carbon cloth composite plate.This composite plate is difficult to layering, has preferable mechanical property and corrosion-resistant and high-temperature resistant performance, and it is simple that the present invention has preparation method, it is easy to the feature of operation.

Description

Polyborosiloxane-carbon fiber fabric swatch and dissolving dipping hot pressing thereof are for method
Technical field
The present invention relates to field of high polymer composite material preparation, be specifically related to a kind of polyborosiloxane-carbon cloth and Dissolve dipping hot pressing method for preparing.
Background technology
Carbon cloth is also known as carbon fiber woven cloth or carbon fiber reinforcement cloth, for tension, shearing resistance and the antidetonation of structural elements Reinforcing, this material and supporting dipping glue are used in conjunction with becoming carbon fibre composite, may make up the remarkable carbon of complete performance fine Dimension cloth sheet material reinforcement system.
In numerous Behavior of Carbon Fiber Reinforced Polymers, polymer matrix composite light weight, ratio that carbon cloth strengthens are strong Degree, specific stiffness and specific modulus is big, high temperature resistant, heat stabilizer is good, be widely used in the fields such as Aero-Space, military affairs, athletics sports, Can be used for manufacturing fuselage, rudder, the engine shell of rocket, guided missile air diffuser, fishing rod, baseball rod, ski, speedboat, feather The high-grade fire protecting clothing of the special occupations such as the structural members such as racket and army, fire-fighting, steel mill.
Along with the development of composite technology, and the chasing after of parts and structural member lightweight, high performance and functionalization Asking, the ratio of application carbon fiber reinforced polymers is more and more higher, and the parts of application carbon fiber reinforced polymers are increasing, and carbon is fine The structure of dimension cloth composite element also becomes increasingly complex.China is concentrated mainly on epoxy to the research of carbon fiber reinforced polymers Resin-based materials aspect.Peng Yongli etc. as matrix, pass through using carbon cloth as reinforcing material, phenolic resin, epoxy resin Dipping, the technique such as laminated into type, prepare carbon cloth and strengthen composite material of novolac epoxy resin, when epoxy resin mass fraction is When 25%, this composite has bending strength 265MPa of maximum.But epoxies adhesive resistance to elevated temperatures is bad, along with temperature Degree raises, and the tensile shear strength of epoxies adhesive reduces rapidly, and 800When during C, its tensile shear strength is only room temperature 37%, cause its epoxies adhesive premature failure between carbon cloth and composite material surface under naked light effect.
Summary of the invention
The invention provides a kind of polyborosiloxane-carbon cloth composite plate for the problems referred to above and dissolve dipping hot pressing Preparation method.
The technical solution used in the present invention is: polyborosiloxane-carbon cloth composite plate, by the carbon fiber through pretreatment Cloth is stacked in mould, obtains through hot-forming.
The dissolving dipping hot pressing of polyborosiloxane-carbon cloth composite plate, for method, comprises the following steps
The pretreatment of step one carbon cloth: carbon cloth is cut into required size, puts in dehydrated alcohol with ultrasonic Ripple embathes 3-5 minute, puts in Muffle furnace in 450 after drying0C calcines 1 hour；
The preparation of step 2 impregnation liquid: being dissolved in a solvent by polyborosiloxane performed polymer, solution temperature is room temperature-800C, joins Make the impregnation liquid that concentration is 3-20g/L；
The preparation of step 3 hard board: the carbon cloth through pretreatment is immersed impregnation liquid 3-8 minute, takes out nature and dries After, put in vacuum drying oven in 500Dry 12 hours under C；Next the carbon cloth after drying overlays according to desired thickness In mould, utilize that accurate tablet machine is hot-forming obtains polyborosiloxane-carbon cloth composite plate.
As the preferred technical scheme of one: in polyborosiloxane-carbon cloth composite plate, the content of fiber is at 35%- 50%。
As the preferred technical scheme of one: carbon cloth is plain weave, twill or satin weave, the model of carbon cloth is 1K, 3K, 6K or 12K, density is 200,240 or 300g/m3。
As the preferred technical scheme of one: carbon cloth includes Two-dimensional Carbon fiber cloth and three-dimensional carbon fiber cloth.
As the preferred technical scheme of one: polyborosiloxane performed polymer is poly-diphenyl Borosiloxane performed polymer, its point Son amount is 500-1000, mol ratio 3:1-1:1 of silicon boron.
As the preferred technical scheme of one: the solvent preparing impregnation liquid can be dimethylbenzene, toluene, oxolane, second One or more in alcohol, N-Methyl pyrrolidone, dimethylformamide, pyridine.
As the preferred technical scheme of one: when utilizing accurate tablet machine hot-forming, temperature is 260-3000C, pressure is 6-9MPa, the time is 7-15 minute.
As the preferred technical scheme of one: the carbon cloth layer structure thickness alternate with polyborosiloxane performed polymer is extremely Less more than 1mm.
The invention has the beneficial effects as follows: utilize the dissolving dipping hot pressing of polyborosiloxane-carbon cloth composite plate for method The composite plate prepared is difficult to layering, has preferable mechanical property and corrosion-resistant and high-temperature resistant performance；The present invention has preparation method Simply, it is easy to the feature of operation.
Accompanying drawing explanation
Fig. 1 show the surface scan Electronic Speculum figure of polyborosiloxane-carbon cloth composite plate；
Fig. 2 show the scanning electron microscope (SEM) photograph after polyborosiloxane-carbon cloth composite plate tension failure.
Detailed description of the invention
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing Have technology to describe to be briefly described, it is therefore apparent that the accompanying drawing in describing below is only some embodiments of the present invention.
Embodiment 1:
By 3K plain weave, density is 200g/m3Carbon cloth be cut into 60mm × 40mm size, use dehydrated alcohol ultrasound wave Embathe 3 minutes, after drying, put in Muffle furnace 4500C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer silicon boron mole Ratio 3:1, molecular weight is 800.By poly-diphenyl Borosiloxane performed polymer in 800C is dissolved in dimethylbenzene, is configured to concentration and is The impregnation liquid of 10g/L.Carbon cloth through pretreatment is immersed impregnation liquid 4 minutes, after taking-up nature dries, puts into vacuum and dry In case 500Dry 12 hours under C；Treat that die sinking agent coated by mould, after carbon cloth is laminated to 3.1mm thickness, puts in mould, adopt Hot-forming with accurate tablet machine, temperature is 2600C, pressure is 8MPa, and the time is 10 minutes, obtains polyborosiloxane-carbon fine Dimension cloth composite plate.In prepared carbon cloth composite plate, fiber content is 40%, and the polyborosiloxane-carbon cloth of preparation is multiple Plywood hot strength is 202MPa, and elastic modelling quantity is 862MPa.
Fig. 1 is the scanning electron microscope (SEM) photograph of embodiment 1 polyborosiloxane-carbon cloth composite surface, and Fig. 2 is poly-borosilicate oxygen Scanning electron microscope (SEM) photograph after alkane-carbon cloth composite plate tension failure.It is clear from fig. 1 that polyborosiloxane is substantially completely Be impregnated into carbon cloth in parallel, and together with carbon cloth tight bond, define and spread all over different layers carbon cloth All composite plates.Figure it is seen that intersect between polyborosiloxane-carbon cloth composite plate fiber and pin down, fracture Time be the fibrous fracture parallel with draw direction, the polyborosiloxane playing cementation fragments into powdery completely, such that it is able to Improve intensity and the anti-fatigue ability of material.
Embodiment 2:
By 3K plain weave, density is 240g/m3Carbon cloth be cut into 60mm × 40mm size, use dehydrated alcohol ultrasound wave Embathe 4 minutes, after drying, put in Muffle furnace 4500C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer silicon boron mole Ratio 3:1, molecular weight is 700.By poly-diphenyl Borosiloxane performed polymer in 500C is dissolved in oxolane, is configured to concentration and is The impregnation liquid of 15g/L.Carbon cloth through pretreatment is immersed impregnation liquid 3 minutes, after taking-up nature dries, puts into vacuum and dry In case 500Dry 12 hours under C；Treat that die sinking agent coated by mould, after carbon cloth is laminated to 2.2mm thickness, puts in mould, adopt Hot-forming with accurate tablet machine, temperature is 2800C, pressure is 7MPa, and the time is 13 minutes, obtains polyborosiloxane-carbon fine Dimension cloth composite plate.In prepared carbon cloth composite plate, fiber content is 41%, and the polyborosiloxane-carbon cloth of preparation is multiple Plywood hot strength is 189MPa, and elastic modelling quantity is 726MPa.
Embodiment 3:
By 12K plain weave, density is 300g/m3Carbon cloth be cut into 61mm × 40mm size, ultrasonic with dehydrated alcohol Ripple embathes 4 minutes, puts in Muffle furnace 450 after drying0C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer, silicon boron rubs You are ratio 2:1, and molecular weight is 1000.Poly-diphenyl Borosiloxane performed polymer is mixed in dehydrated alcohol and dimethylbenzene in room-temperature dissolution In liquid (dimethylbenzene and dehydrated alcohol volume ratio are 1:1), it is configured to the impregnation liquid that concentration is 3g/L.By fine for the carbon through pretreatment Wei Bu immerses impregnation liquid 4 minutes, takes out after nature dries, and puts in vacuum drying oven 500Dry 12 hours under C；Treat that mould is coated out Mould agent, after carbon cloth is laminated to 2.0mm thickness, puts in mould, uses accurate tablet machine hot-forming, and temperature is 2900C, pressure is 7MPa, and the time is 15 minutes, obtains polyborosiloxane-carbon cloth composite plate.Prepared carbon cloth In composite plate, fiber content is 38%, and the polyborosiloxane of preparation-carbon cloth composite plate hot strength is 164MPa, springform Amount is 607MPa.
Embodiment 4:
By 1K plain weave, density is 200g/m3Carbon cloth be cut into 58mm × 43mm size, use dehydrated alcohol ultrasound wave Embathe 3 minutes, after drying, put in Muffle furnace 4500C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer silicon boron mole Ratio 1:1, molecular weight is 900.By poly-diphenyl Borosiloxane performed polymer in room-temperature dissolution in N-Methyl pyrrolidone, be configured to Concentration is the impregnation liquid of 20g/L.Carbon cloth through pretreatment is immersed impregnation liquid 3 minutes, after taking-up nature dries, puts into In vacuum drying oven 500Dry 12 hours under C；Treat that die sinking agent coated by mould, after carbon cloth is laminated to 2.9mm thickness, put into mould In tool, using accurate tablet machine hot-forming, temperature is 2800C, pressure is 8MPa, and the time is 12 minutes, obtains poly-borosilicate oxygen Alkane-carbon cloth composite plate.In prepared carbon cloth composite plate, fiber content is 42%, the polyborosiloxane-carbon of preparation Fiber cloth composite plate hot strength is 192MPa, and elastic modelling quantity is 801MPa.
Embodiment 5
By 6K plain weave, density is 200g/m3Carbon cloth be cut into 61mm × 40mm size, use dehydrated alcohol ultrasound wave Embathe 3 minutes, after drying, put in Muffle furnace 4500C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer silicon boron mole Ratio 3:1, molecular weight is 800.By poly-diphenyl Borosiloxane performed polymer in room-temperature dissolution in dimethylbenzene, being configured to concentration is The impregnation liquid of 10g/L.Carbon cloth through pretreatment is immersed impregnation liquid 4 minutes, after taking-up nature dries, puts into vacuum and dry In case 500Dry 12 hours under C；Treat that die sinking agent coated by mould, after carbon cloth is laminated to 4.2mm thickness, puts in mould, adopt Hot-forming with accurate tablet machine, temperature is 3000C, pressure is 6MPa, and the time is 13 minutes, obtains polyborosiloxane-carbon fine Dimension cloth composite plate.In prepared carbon cloth composite plate, fiber content is 40%, and the polyborosiloxane-carbon cloth of preparation is multiple Plywood hot strength is 225MPa, and elastic modelling quantity is 859MPa.
Embodiment 6
By 6K plain weave, density is 200g/m3Carbon cloth be cut into 58mm × 39mm size, use dehydrated alcohol ultrasound wave Embathe 5 minutes, after drying, put in Muffle furnace 4500C calcines 1 hour.In poly-diphenyl Borosiloxane performed polymer silicon boron mole Ratio 2:1, molecular weight is 600.By poly-diphenyl Borosiloxane performed polymer in 800C is dissolved in dimethylbenzene, is configured to concentration and is The impregnation liquid of 15g/L.Carbon cloth through pretreatment is immersed impregnation liquid 8 minutes, after taking-up nature dries, puts into vacuum and dry In case 500Dry 12 hours under C；Treat that die sinking agent coated by mould, after carbon cloth is laminated to 5.0mm thickness, puts in mould, adopt Hot-forming with accurate tablet machine, temperature is 3000C, pressure is 9MPa, and the time is 7 minutes, obtains polyborosiloxane-carbon fiber Cloth composite plate.In prepared carbon cloth composite plate, fiber content is 35%, and the polyborosiloxane-carbon cloth of preparation is combined Plate stretching intensity is 248MPa, and elastic modelling quantity is 945MPa.
It should be noted last that, above example is only unrestricted in order to supplementary explaination technical scheme.To the greatest extent The present invention has been described in detail by pipe with reference to embodiment, and this area vast is it will be appreciated by the skilled person that skill to the present invention Art scheme is modified or replaces on an equal basis, and without departure from the spirit and scope of technical solution of the present invention, it all should be contained at this In the middle of the right of invention.

Claims (9)

1. polyborosiloxane-carbon cloth composite plate, it is characterised in that: it is stacked in mould by the carbon cloth through pretreatment In, obtain through hot-forming.
2. the dissolving dipping hot pressing of polyborosiloxane-carbon cloth composite plate is for method, it is characterised in that: comprise the following steps step The pretreatment of a rapid carbon cloth: carbon cloth is cut into required size and puts in dehydrated alcohol and embathe 3-with ultrasound wave 5 minutes, put into after drying in Muffle furnace in 4500C calcines 1 hour；The preparation of step 2 impregnation liquid: by polyborosiloxane pre-polymerization Body dissolves in a solvent, and solution temperature is room temperature-800C, is configured to the impregnation liquid that concentration is 3-20g/L；Step 3 hard board Preparation: the carbon cloth through pretreatment is immersed impregnation liquid 3-8 minute, takes out after nature dries, put in vacuum drying oven in 500Dry 12 hours under C；Next the carbon cloth after drying stacks in a mold according to desired thickness, utilizes accurate tabletting Machine is hot-forming obtains polyborosiloxane-carbon cloth composite plate.
Polyborosiloxane the most according to claim 1-carbon cloth composite plate, it is characterised in that: polyborosiloxane-carbon is fine In dimension cloth composite plate, the content of fiber is at 35%-50%.
Polyborosiloxane the most according to claim 1-carbon cloth composite plate, it is characterised in that: carbon cloth be plain weave, Twill or satin weave, the model of carbon cloth is 1K, 3K, 6K or 12K, and density is 200,240 or 300g/m3。
Polyborosiloxane the most according to claim 1-carbon cloth composite plate, it is characterised in that: carbon fiber includes two dimension Carbon cloth and three-dimensional carbon fiber cloth.
Polyborosiloxane the most according to claim 2-carbon cloth composite plate dissolving dipping hot pressing for method, its feature It is: polyborosiloxane performed polymer is poly-diphenyl Borosiloxane performed polymer, and its molecular weight is 500-1000, the mol ratio of silicon boron 3:1-1:1.
The most according to claim 2, the dissolving dipping hot pressing of polyborosiloxane-carbon cloth composite plate is for method, and its feature exists In: the solvent preparing impregnation liquid can be dimethylbenzene, toluene, oxolane, ethanol, N-Methyl pyrrolidone, dimethyl formyl One or more in amine, pyridine.
Polyborosiloxane the most according to claim 2-carbon cloth composite plate dissolving dipping hot pressing for method, its feature It is: when utilizing accurate tablet machine hot-forming, temperature is 260-3000C, pressure is 6-9MPa, and the time is 7-15 minute.
Polyborosiloxane the most according to claim 2-carbon cloth composite plate dissolving dipping hot pressing for method, its feature It is: the carbon cloth layer structure thickness alternate with polyborosiloxane performed polymer is at least above 1mm.
CN201610605586.3A 2016-07-29 2016-07-29 Polyborosiloxane-carbon fiber fabric swatch and its dissolving dipping hot pressing the preparation method Expired - Fee Related CN106240126B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401320A (en) * 2018-09-13 2019-03-01 沈阳理工大学 The poly- aryl ethane of electronic beam curing/heat vulcanized silicone rubber composite material method
CN112920551A (en) * 2021-03-30 2021-06-08 吉林大学 Bionic resin-based carbon fiber composite material and preparation method thereof
CN114790121A (en) * 2022-05-12 2022-07-26 宁波金鼎紧固件有限公司 Heat-resistant high-strength carbon/ceramic fastener and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013067138A (en) * 2011-09-26 2013-04-18 Mitsubishi Electric Corp Nonflammable composite material, nonflammable fiber-reinforced composite material, method for manufacturing them, and elevator car member
CN104031376A (en) * 2014-06-17 2014-09-10 大连理工大学 Continuous carbon fiber reinforced phthalazinone structure containing polyarylether nitrile resin-based composite material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013067138A (en) * 2011-09-26 2013-04-18 Mitsubishi Electric Corp Nonflammable composite material, nonflammable fiber-reinforced composite material, method for manufacturing them, and elevator car member
CN104031376A (en) * 2014-06-17 2014-09-10 大连理工大学 Continuous carbon fiber reinforced phthalazinone structure containing polyarylether nitrile resin-based composite material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109401320A (en) * 2018-09-13 2019-03-01 沈阳理工大学 The poly- aryl ethane of electronic beam curing/heat vulcanized silicone rubber composite material method
CN109401320B (en) * 2018-09-13 2021-04-06 沈阳理工大学 Method for curing polyarylacetylene/heat vulcanized silicone rubber composite material by electron beam
CN112920551A (en) * 2021-03-30 2021-06-08 吉林大学 Bionic resin-based carbon fiber composite material and preparation method thereof
CN114790121A (en) * 2022-05-12 2022-07-26 宁波金鼎紧固件有限公司 Heat-resistant high-strength carbon/ceramic fastener and preparation method thereof

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